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1.

Background  

Seasonal changes in pore water and sediment redox geochemistry have been observed in many near-surface sediments. Such changes have the potential to strongly influence trace metal distribution and thus create seasonal fluctuations in metal mobility and bioavailability.  相似文献   

2.
Carbon and nitrogen dynamics were examined throughout the River Sava watershed, a major tributary of the River Danube, in 2005 and 2006. The River Sava exported 2.1 × 1011 mol C/yr as dissolved inorganic carbon (DIC), and emitted 2.5 × 1010 mol C/yr as CO2 to the atmosphere. Stable carbon isotope ratios indicate that up to 42% of DIC originated from carbonate weathering and 23% from degradation of organic matter. Loads of dissolved and particulate organic carbon increased with discharge and export rates were calculated to be 2.1 × 1010 mol C/yr and up to 4.1 × 109 mol C/yr, respectively. Isotopic compositions (δ13C and δ15N) and C/N ratios indicated that soil organic matter was the dominant source of particulate organic matter for 59% of the samples. Eighteen percent of the samples were dominated by plankton, 12% by periodic inputs of fresh terrestrial plant detritus with C/N > 15, and about 11% of the samples were dominated by the contribution of aquatic vascular plants. Nitrate inputs were controlled by land use in the River Sava watershed. δ15NNO3 values <6‰ were found in predominantly forested watersheds, while values >6‰ typically represented watersheds with a higher percentage of agricultural and/or urban land use. Elevated δ15NNO3 values (up to +25.5‰) at some sites were probably due to the combined effects of low-flow and inputs from sewage and/or animal waste.  相似文献   

3.

Background  

A profile across 8 layers from a fossil travertine terrace from a low temperature geothermal spring located in Svalbard, Norway has been studied using both Raman spectroscopy and SEM (Scanning Electron Microscopy) techniques to identify minerals and organic life signals.  相似文献   

4.
The concentrations of total suspended sediments (TSS), dissolved organic carbon (DOC) and particulate organic carbon (POC) were measured in water samples taken monthly in the Apure, Caura and Orinoco rivers during a hydrological cycle (between Sept. 2007 and Aug. 2008). The DOC concentration values ranged between 1.5 and 6.8 mgC l−1 in the Apure River; 2.07 and 4.9 mgC l−1 in the Caura River and 1.66 and 5.35 mgC l−1 in the Orinoco River. The mean concentration of DOC was 3.9 mgC l−1 in the Apure River, 3.24 mgC l−1 in the Caura River and 2.92 mgC l−1 in the Orinoco River at Puerto Ordaz. The three rivers showed a similar temporal pattern in the concentrations of DOC, with higher DOC values during the increasing branch of the hydrograph due to wash-out processes of the organic material stored in soils. The mean concentration values of POC were 1.33 mgC l−1; 0.77 mgC l−1 and 0.91 mgC l−1 in the Apure, Caura and Orinoco rivers, respectively. The inverse relationship found between the percentage in weight of the POC and the concentrations of TSS in the three rivers fits a logarithmic model, as it has been previously reported for other worldwide rivers. The POC concentrations in the Orinoco River showed a positive relationship with the TSS, suggesting that the POC in the Orinoco is the result of terrestrially organic matter. Although the fluxes of organic carbon (OC) in the three studied rivers are dependent on the values of water discharge, the fluxes of DOC during the increasing branch of the hydrograph are higher than those found during the decreasing stage, due to the yield of organic material accumulated in soils during the preceding dry season. The mean annual flux of total organic carbon (TOC) of the Orinoco River at Puerto Ordaz was about 4.27 × 106 TonC yr−1. Of this, 3.28 × 106 TonC yr−1 (77%) represents the flux of DOC and about 0.99 TonC yr−1 (23%) represents the flux of POC. The mean annual input of TOC from the Apure River to the Orinoco River was about 4.92 × 105 TonC yr−1 (11.5%), while the contribution of TOC from the Caura River to the Orinoco River was estimated at 3.05 × 105 TonC yr−1 (7.1%).The values of annual transport of TOC calculated for the Apure, Caura and Orinoco rivers were lower than those reported twenty years ago. This could be related to interannual variations of precipitation in the Orinoco Basin, due to runoff variations can have a strong effect on the fluxes of OC from land to rivers.  相似文献   

5.
The failure of a lava dam 165,000 yr ago produced the largest known flood on the Colorado River in Grand Canyon. The Hyaloclastite Dam was up to 366 m high, and geochemical evidence linked this structure to outburst-flood deposits that occurred for 32 km downstream. Using the Hyaloclastite outburst-flood deposits as paleostage indicators, we used dam-failure and unsteady flow modeling to estimate a peak discharge and flow hydrograph. Failure of the Hyaloclastite Dam released a maximum 11 × 109 m3 of water in 31 h. Peak discharges, estimated from uncertainty in channel geometry, dam height, and hydraulic characteristics, ranged from 2.3 to 5.3 × 105 m3 s−1 for the Hyaloclastite outburst flood. This discharge is an order of magnitude greater than the largest known discharge on the Colorado River (1.4 × 104 m3 s−1) and the largest peak discharge resulting from failure of a constructed dam in the USA (6.5 × 104 m3 s−1). Moreover, the Hyaloclastite outburst flood is the oldest documented Quaternary flood and one of the largest to have occurred in the continental USA. The peak discharge for this flood ranks in the top 30 floods (>105 m3 s−1) known worldwide and in the top ten largest floods in North America.  相似文献   

6.
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7.
The Alaknanda and Bhagirathi Rivers originate in the mountainous regions of the Himalayas (Garhwal) and result in high sediment yields causing flood hazards downstream of the Ganga River and high sediment flux to the Bay of Bengal. The rivers are perennial, since runoff in these rivers is controlled by both precipitation and glacial melt. In the present study, three locations in the upper reaches of the Ganga River were monitored for 1 yr (daily observations of, more than >1000 samples) for suspended sediment concentrations. In addition, more than one hundred samples were collected from various locations of the Alaknanda and Bhagirathi Rivers at different periods to observe spatial and temporal variations in river suspensions. Further, multi-annual data (up to 40 yrs) of water flow and sediment concentrations were used for inferring the variations in water flow and sediment loads on longer time scales. In most previous studies of Himalayan Rivers, there has been a general lack of long term water flow and sediment load data. In the present study, we carried out high frequency sampling, considered long term discharge data and based on these information, discussed the temporal and spatial variations in water discharge and sediment loads in the rivers in the Himalayan region. The results show that, >75% of annual sediment loads are transported during the monsoon season (June through September). The annual physical weathering rates in the Alaknanda and Bhagirathi River basins at Devprayag are estimated to be 863 tons km−2 yr−1 (3.25 mm yr−1) and 907 tons km−2 yr−1 (3.42 mm yr−1) respectively, which are far in excess of the global average of 156 tons km−2 yr−1 (0.58 mm yr−1).  相似文献   

8.
A 61-m-long sediment core (HB-1) and 690 km of high-resolution seismic profiles from offshore of the Yellow River delta, Bohai Sea, were analyzed to document the stratigraphy and sea-level changes during the Late Pleistocene and Holocene. Accelerator mass spectrometry 14C dating and analyses of benthic foraminifera, ostracods, the mineral composition, and sedimentary characteristics were performed for core HB-1, and seven depositional units (DU 1–DU 7 in descending order) were identified. The seismic reflection data were interpreted in light of the sedimentological data of the core and correlated with other well-studied cores obtained previously in the Bohai Sea area. Seven seismic units (SU 1 to SU 7 in descending order) were distinguished and interpreted as follows: SU 7 corresponds to marine facies in Marine Isotopic Stage (MIS) 5; SU 6, to terrestrial facies in MIS 4; SU 5 and SU 4, to alternating terrestrial and marine facies (DU 7–DU 5) in MIS 3; SU 3, to terrestrial facies (DU 4) in MIS 2; SU 2, to Holocene marine facies (DU 3 and DU 2); and SU 1, to modern Yellow River delta sediments deposited since 1855 (DU 1).The sedimentary facies from DU 7 to DU 5 reflect sea-level fluctuations during MIS 3, and the boundary between DU 5 and DU 6, which coincides with that between SU 4 and SU 5, is a distinctive, laterally continuous, undulating erosion surface, with up to 20 m of relief. This surface reflects subaerial exposure between transgressions during MIS 3. Estimated sea levels during MIS 3 ranged from −35 ± 5 to −60 ± 5 m or lower, with short-term fluctuations of 20 m. Sedimentary environments in the Bohai Sea area were governed mainly by eustatic sea-level changes and the Bohai Strait topography, which controls the entry of sea water into the Bohai Sea area.The mineral composition of the sediment core suggests that the Yellow River did not discharge into the Bohai Sea, or at least did not influence the study area significantly, during parts of MIS 3 and MIS 2 to the early Holocene (11–8.5 cal kyr BP).  相似文献   

9.
The combined geothermal discharge from over 10,000 features in Yellowstone National Park (YNP) can be can be estimated from the Cl flux in the Madison, Yellowstone, Falls, and Snake Rivers. Over the last 30 years, the Cl flux in YNP Rivers has been calculated using discharge measurements and Cl concentrations determined in discrete water samples and it has been determined that approximately 12% of the Cl flux exiting YNP is from the Snake River. The relationship between electrical conductivity and concentrations of Cl and other geothermal solutes was quantified at a monitoring site located downstream from the thermal inputs in the Snake River. Beginning in 2012, continuous (15 min) electrical conductivity measurements have been made at the monitoring site. Combining continuous electrical conductivity and discharge data, the Cl and other geothermal solute fluxes were determined. The 2013–2015 Cl fluxes (5.3–5.8 kt/yr) determined using electrical conductivity are comparable to historical data. In addition, synoptic water samples and discharge data were obtained from sites along the Snake River under low-flow conditions of September 2014. The synoptic water study extended 17 km upstream from the monitoring site. Surface inflows were sampled to identify sources and to quantify solute loading. The Lewis River was the primary source of Cl, Na, K, Cl, SiO2, Rb, and As loads (50–80%) in the Snake River. The largest source of SO4 was from the upper Snake River (50%). Most of the Ca and Mg (50–55%) originate from the Snake Hot Springs. Chloride, Ca, Mg, Na, K, SiO2, F, HCO3, SO4, B, Li, Rb, and As behave conservatively in the Snake River, and therefore correlate well with conductivity (R2 ≥ 0.97).  相似文献   

10.
Qaidam Basin is a hyperarid inland basin with an area of 121 × 103 km2 located on the northern Tibetan Plateau. Today, one fourth of the basin is covered by playas and hypersaline lakes. Nearly 80% of brine lithium found in China is contained in four salt lakes: Bieletan (BLT), DongTaijinaier (DT), XiTaijinaier (XT) and Yiliping (YLP). In the past decade, great attention was paid to improving the technology for the extraction of lithium from the brine deposits, but studies on origin and mode of formation of the brine deposits remained limited. Our recent investigations found that: (1) ~ 748.8 t of lithium was transported annually into the lower catchment of the four salt lakes via the Hongshui–Nalinggele River (H–N River), the largest river draining into the Qaidam Basin, (2) Li+-rich brines are formed only in salt lakes associated with inflowing rivers with Li+ concentrations greater than 0.4 mg/L, and (3) the water Li+ concentration is positively correlated with both the inflowing river and the associated subsurface brine, including saline lakes with low lithium concentrations. These findings clearly indicate that long-term input of Li+ from the H–N River controls the formation of lithium brine deposits. Here we determine that the source of the lithium is from hydrothermal fields where two active faults converge in the upper reach of the Hongshui River. The hydrothermal fields are associated with a magmatic heat source, as suggested by the high Li+ and As3 + content water from geysers. Based on the assumption of a constant rate of lithium influx, we estimate that the total reserves of lithium were likely formed since the postglacial period. Our data indicate that lithium reserves in each of the four salt lakes depend on the influx of Li+-bearing water from the H–N River. The data also suggest that during the progradation of the alluvial Fan I, the H–N River drained mostly into the BLT salt lake until the Taijinaier River shifted watercourse to the north and began to feed the salt lakes of the DT, XT and YLP, alongside with the Fan II progradation. The inference is consistent with stratigraphic evidence from the sediment cores of the four salt lakes. One of the major findings of our work is the importance of the contrasting hydroclimatic conditions between the high mountains containing ice caps and the terminal salt lakes. The greater than 4000 m of relief in the watershed enables a massive amount of ions, such as K+, to be weathered and transported together with detrital material from the huge, relatively wet alpine regions to the hyperarid terminal basins, where intense evaporation rapidly enriches the lake water, resulting in evaporite deposition and associated K+- and Li+-rich brine deposits.  相似文献   

11.

Background  

This study provides experimental evidence for biologically induced precipitation of magnesium carbonates, specifically dypingite (Mg5(CO3)4(OH)2·5H2O), by cyanobacteria from an alkaline wetland near Atlin, British Columbia. This wetland is part of a larger hydromagnesite (Mg5(CO3)4(OH)2·4H2O) playa. Abiotic and biotic processes for magnesium carbonate precipitation in this environment are compared.  相似文献   

12.
《Applied Geochemistry》2005,20(5):919-931
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13.
The objective of this study was to examine the interaction between the Atchafalaya River and the Atchafalaya Delta estuarine complex. Measurements of suspended sediments, inorganic nutrients (NO3 ?, NH4 +, PO4 3?), chlorophylla (chla), and-salinity were taken monthly from December 1996 to January 1998. These data were compiled by season, and the Atchafalaya River plume data were also analyzed using the Generalized Additive Model technique. There were significant decreases in NO3 ? concentrations during summer, fall, and winter as river water passed through the estuary, that were attributable to chemical and biological processes rather than dilution with ambient water. In some regions there were higher chla concentrations during summer and fall compared to winter and spring, when river discharge and the introduction of inorganic nutrients were highest, suggesting biological processes were active during this study. The presence of NH4 +, as a percentage of available dissolved inorganic nitrogen, increased with distance from the Atchafalaya River, indicative of remineralization processes and NO3 ? reduction. Mean PO4 3? concentrations were often higher in the estuarine regions compared to the Atchafalaya River. During summer total suspended solid (TSS) concentrations increased with distance from the river mouth, suggesting a turbidity maximum. Highest chla concentrations were found in the bayous and shallow water bodies of the Terrebonne marshes, as were the lowest TSS concentrations. The low chla concentrations found in other areas of this study, despite high inorganic nutrient concentrations, suggest light limitation as the major control of phytoplankton growth. Salinity reached near seawater concentrations at the outer edge of the Atchafalaya River plume, but much lower salinities (<10 psu) were observed at all other regions. The Atchafalaya Delta estuarine complex buffers the impact of the Atchafalaya River on the Louisiana coastal shelf zone, with a 41% of 47% decrease in Atchafalaya River NO3 ? concentrations before reaching Gulf waters.  相似文献   

14.
Rb-Sr isotopic data for anorthosites, charnockites, ferrodioritic to quartz monzonitic plutons, and high-grade gneisses of the Blue Ridge of central Virginia show evidence of post-emplacement metamorphism, but in some cases retain Grenville ages. The Pedlar River Charnockite Suite yields an isochron age of 1021 +/-36 Ma, (initial 87Sr/86Sr ratio of 0.7047 +/-6), which agrees with published U-Pb zircon ages. Five samples of that unit which contain Paleozoic mylonitic fabrics define a regression line of 683 Ma, interpreted as a mixing line with no age significance. Samples of the Roseland Anorthosite Complex show excessive scatter on a Rb-Sr evolution diagram probably due to Paleozoic (475 m.y.) metamorphism. Data from the ferrodioritic to quartz monzonitic plutons of the area yield an age of 1009 +/-26 Ma (inital ratio=0.7058 +/-4), which is in the range of the U-Pb zircon ages of 1000–1100 Ma. The Stage Road Layered Gneiss yields an age of 1147 +/-34 Ma (initial ratio of 0.7047 +/- 5).Sm-Nd data for the Pedlar River Charnockite Suite reflect a pre-Grenville age of 1489 +/-118 Ma ( Nd=+6.7 +/-1.2). Data for the Roseland Anorthosite Complex and the ferrodioritic to quartz monzonitic plutons yield Grenville isochron ages of 1045 +/44 Ma ( Nd=+1.0 +/-0.3) and 1027 +/-101 Ma ( Nd=+1.4 +/-1.0), respectively. Two Roseland Anorthosite samples plot far above the isochron, demonstrating the effects of post-emplacement disturbance of Sm-Nd systematics, while mylonitized Pedlar River Charnockite Suite samples show no evidence of Sm-Nd redistribution.The disparity of the Sm-Nd age and other isotopic ages for the Pedlar River Charnockite Suite probably reflects a Sm-Nd source age, suggesting the presence of an older crust within this portion of the ca. 1 Ga old basement.  相似文献   

15.
Pyrite-induced hydroxyl radical formation and its effect on nucleic acids   总被引：1，自引：0，他引：1  

Background  

Pyrite, the most abundant metal sulphide on Earth, is known to spontaneously form hydrogen peroxide when exposed to water. In this study the hypothesis that pyrite-induced hydrogen peroxide is transformed to hydroxyl radicals is tested.  相似文献   

16.

Background  

A realistic estimation of the health risk of human exposure to solid-phase arsenic (As) derived from historic mining operations is a major challenge to redevelopment of California's famed "Mother Lode" region. Arsenic, a known carcinogen, occurs in multiple solid forms that vary in bioaccessibility. X-ray absorption fine-structure spectroscopy (XAFS) was used to identify and quantify the forms of As in mine wastes and biogenic solids at the Lava Cap Mine Superfund (LCMS) site, a historic "Mother Lode" gold mine. Principal component analysis (PCA) was used to assess variance within water chemistry, solids chemistry, and XAFS spectral datasets. Linear combination, least-squares fits constrained in part by PCA results were then used to quantify arsenic speciation in XAFS spectra of tailings and biogenic solids.  相似文献   

17.
The influence of the northern Atlantic and tropical monsoonal systems, as recorded by the River Nile, on the climate variability of the southeastern Mediterranean was studied in two cores taken by the R/V Marion Dufresne: one core taken SE of Cyprus representing the northern Levantine Basin (core 9501, 980 m water depth) and the other located ˜380 km further south, represents the southeastern Levantine Basin in an area influenced by the River Nile plume (core 9509, 884 m water depth). The study was performed at relatively high resolution using several proxies: δ18O of Globigerinoides ruber, sediment characteristics and index colour parameters in core sections representing the last 86 ka. A low-resolution alkenone sea surface temperature record was also measured. The time frame in both cores was mostly constrained by ‘wiggle’ matching with the nearby well-dated δ18O and δ13C record of the Soreq Cave, which is mainly influenced by the eastern Mediterranean water vapor. The sedimentary record of the southern core is strongly influenced by the River Nile contribution throughout the last 86 ka, as evidenced by the higher sedimentation rates compared with the northern core (20 cm/ka vs. 5 cm/ka), continuously darker sediment colour, and higher TOC values (0.6–0.9 vs. 0.25 wt% not including sapropels). During sapropels S1 and S3, present in both cores, the influence of the River Nile became more widespread, reaching as far as Cyprus. Yet, the influence of the River Nile remained stronger in the south, as evident by the higher TOC values in the southern core throughout the entire 90 ka period and the longer duration of S1 in the southern core. An anomalous low δ18O interval that is not recorded in western Mediterranean occurred between 58 and 49 ka in the Levantine Basin and is more developed in the northern core. This period correlates with D-O interstadial 14 and maximum northern hemisphere insolation during the lastglacial cycle, suggesting that the warming mainly impacted the northern Levant.The Eastern Mediterranean Sea and land area was considerably warmer than the western Mediterranean throughout the LGM – Holocene transition, and the δ18OG. ruber drop of 4.5‰ is significantly greater than the 3‰ shift found for the western Mediterranean δ18OG. bulloides, both differences reflecting an increased continental effect from the western to eastern Mediterranean. Comparison between the marine and the land δ18O records suggests that the origin of rain over the land is composed of mixed signal from the southern and northern Levantine Basin. The study of Δδ18Osea–land variations demonstrates that various factors have influenced the sea–land relationship during the last 90 ka. The ‘amount effect’ has an important influence on rainfall δ18O during interglacial periods (particularly sapropel periods), whereas during glacial periods, increased land distances and elevation differences arising from decrease in sea level may have brought about decrease in δ18O of rainfall due to Rayleigh distillation processes. These influences were superimposed on those of sea surface water δ18O changes brought about by continental ice melting, and the strong effects felt in the southern Levantine Basin of the high River Nile input during periods of enhanced monsoonal activity.  相似文献   

18.
Proterozoic metamorphosed sequences are identified in the Transversal Zone (TZ) domain of the Borborema geological province, Northeast Brazil. This TZ domain is located between the well-known E–W Patos and Pernambuco continental shear zones. In its eastern part, in the Taquaritinga region, a large mass of augen gneisses with a conspicuous horizontal to subhorizontal tectonic foliation forms one of the most important rock types in the region that displays U–Pb zircon ages ca. 1.52 Ga. Paleoproterozoic orthogneisses dated by U–Pb on zircon at ca. 1.97 Ga and older paragneisses and banded gneisses represent basement rocks, which were cross-cut by these Mesoproterozoic augen gneisses, and have been in turn intruded by plutonic rocks in upper Neoproterozoic (U–Pb and Rb–Sr, ca. 0.6 Ga) times.Chemical analyses of major, minor, and trace elements (including REE) for the basement orthogneisses indicate calcalkaline affinities and a signature very similar to volcanic arc granites, representing crustal accretion during the Paleoproterozoic Transamazonian/Eburnean orogenesis in the region. In turn, the chemical data for augen gneisses indicate that they are relatively homogeneous and evolved metaluminous metaplutonic rocks with characteristics very similar to A-type granites generated and emplaced in an extensional anorogenic setting. Relatively high 87Sr/86Sr initial ratio and negative Nd(t) are signatures of crustal components in these rocks.Based on geochemical, geochronological, and structural data, the Taquaritinga region is composed of Paleoproterozoic (>1.97 Ga) rocks intruded by Mesoproterozoic (ca. 1.5 Ga) anorogenic granites and Neoproterozoic granites (ca. 0.6 Ga). These data also suggest that the tectonometamorphic structures displayed by Meso and Neoproterozoic suites were developed by the Brasiliano/Pan-African orogeny and that the record of Transamazonian/Eburnean orogeny is restricted to basement rocks. This means that there is no evidence for a compressional event in Mesoproterozoic times (Cariris Velhos=Grenville) as suggested for the central and western part of the TZ. It is important to remark that the Taquaritinga augen gneisses are, up to now, the only unit that represents magmatic pulses associated with extensional episodes with this age (ca. 1.5 Ga) in the TZ and in the whole Borborema Province.

Resumen

A zona Transversal da Província Borborema está geologicamente situada entre os lineamentos Pernambuco e Patos. Na sua parte oriental, na região de Taquaritinga (PE), dominam augen gnaisses com uma penetrativa e proeminente foliação tectônica subhorizontal, com idade de cristalização de 1.52 Ga obtida em zircão. Estas rochas são intrusivas em ortognaisses e paragnaisses do embasamento com idade mínima em torno de 1.97 Ga, e são intrudidas por rochas plutônicas associadas ao Ciclo Brasiliano (ca. 0.6 Ga).Análises de elementos maiores, menores e traços (incluindo terras raras) nos augen gnaisses mostram caráter metaluminoso para esta suíte ígnea e fortes semelhanças com os granitos tipo-A gerados em ambiente anorogênico. Razões iniciais 87Sr/86Sr relativamente altas e Nd(t) negativos são assinaturas indicadoras de forte contribuição crustal nestes augen gnaisses.A conjunção dos dados geoquímicos, geocronológicos e de campo indicam que na região de Taquaritinga onde são identificadas rochas de idades paleo (>1.95 Ga), meso (ca. 1.5 Ga) e neoproterozóicas (ca. 0.6 Ga), o ciclo orogênico Transamazônico é restrito às rochas do embasamento, e que todas as estruturas dúcteis identificadas nas rochas meso e neoproterozóicas foram desenvolvidas durante o Ciclo orogênico Brasiliano. Não foram encontradas evidências que atestem a existência do Ciclo Cariris Velhos nesta parte da Província Borborema. Contudo, está bem marcado que nesta Zona Transversal e na Província Borborema, os augen gnaisses de Taquaritinga são, até o momento, os únicos marcadores de pulsos magmáticos associados com eventos extensionais crustais datados do Mesoproterozóico inferior.  相似文献   

19.
The abandoned Sn-W Ribeira mine, northeast of Portugal, contained quartz veins with cassiterite, wolframite, scheelite, pyrite, arsenopyrite, sphalerite, chalcopyrite, manganocolumbite, bismuthinite, native bismuth, phosphates and carbonates. The exploration took place on the northern slope of the Viveiros stream, which is an affluent of the Sabor River. The waste-rock dumps and tailings were deposited on the hillside, close to the mine and are nowadays exposed to significant weathering and erosion, as they are not vegetated. The eroded material is transported by the Viveiros stream toward the Sabor River. A seasonal stream drains the tailings. The stream sediments samples were collected along the Viveiros stream, in the seasonal stream, in a seasonal spring at the bottom of the tailings, in the Sabor River and in other streams not affected by mine workings, following the mine influence along the Viveiros stream and in the Sabor River (1.2 km away from the mine workings). The data show that the degree of pollution increases along the Viveiros stream, especially in winter. The highest degree of pollution is for As, In, W, Sn and Bi. The sediments from the drainage of the main tailings are particularly polluted during winter, by Bi, In and Sn. The sedimentary precipitate from the spring is polluted in Cu, As, In, Sn, Ta, W, Bi, Zn, Nb, Ag, Sb and Ta. The sediments from the Sabor River are significantly polluted by As, Ag, In, Sn, W and Bi. The sediments from the regional streams, Viveiros stream and Sabor River have similar REE (NASC normalized) patterns (ΣREE = 131.7–185.9 mg/kg, LaN/LuN = 1.23–1.42 and Eu/Eu* = 1.02), while those from the seasonal stream, crossing the main tailings, are enriched in REE (ΣREE = 250.3–283.6 mg/kg, LaN/LuN = 1.6–2.09 and Eu/Eu* = 0.96). The general decrease in LaN/LuN values with increase in total Fe2O3 can be explained by the partitioning of HREE to the solid Fe-oxides phase. The sedimentary precipitate and coatings, which are mainly formed by Fe-oxy-hydroxides, but also contain jarosite, are impoverished in all REE. The impoverishment can be explained by the release of REE from the surface of the Fe-oxy-hydroxides, which occurs due to a local lowering of pH, caused by jarosite dissolution. During successive alternate cycles of wet and dry conditions, takes place the formation of Fe-oxy-hydroxides and jarosite in the sedimentary precipitate and coatings. The subsequent dissolution of jarosite releases acidity, thus promoting de-sorption of REE from the Fe-oxy-hydroxides mineral phases.  相似文献   

20.
A detailed investigation of the fluvial geochemistry of the Han River system allows to estimate the rates of chemical weathering and the consumption of CO2. The Han River drains approximately 26,000 km2 and is the largest river system in South Korea in terms of both water discharge and total river length. It consists of two major tributaries: the North Han River (NHR) and the South Han River (SHR). Distinct differences in basin lithology (silicate vs. carbonate) between the NHR and SHR provide a good natural laboratory in which to examine weathering processes and the influence of basin geology on water quality. The concentrations of major elements and the Sr isotopic compositions were obtained from 58 samples collected in both summer and winter along the Han River system in both 2000 and 2006. The concentrations of dissolved loads differed considerably between the NHR and SHR; compared with the SHR, the NHR had much lower total dissolved solids (TDS), Sr, and major ion concentrations but a higher Si concentration and 87Sr/86Sr ratio. A forward model showed that the dissolved loads in the NHR came primarily from silicate weathering (55 ± 11%), with a relatively small portion from carbonates (30 ± 14%), whereas the main contribution to the dissolved loads in the SHR was carbonate weathering (82 ± 3%), with only 11 ± 4% from silicates. These results are consistent with the different lithologies of the two drainage basins: silicate rocks in the NHR versus carbonate rocks in the SHR. Sulfuric acid derived from sulfide dissolution in coal-containing sedimentary strata has played an important role in carbonate weathering in the SHR basin, unlike in the NHR basin. The silicate weathering rate (SWR) was similar between the NHR and SHR basins, but the rate of CO2 consumption in the SHR basin was lower than in the NHR basin due to an important role of sulfuric acid derived from pyrite oxidation.  相似文献   

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