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1.
Abstract Petrogenetic grids for ultrahigh-pressure (UHP) metamorphism were calculated at different Xco2 conditions in the model system CaO-MgO-SiO2-CO2-H2O involving coesite (Co), diopside (Di), dolomite (Do), enstatite (En), forsterite (Fo), magnesite (Ms), quartz (Qz), talc (Tc), tremolite (Tr) using a published internally consistent thermodynamic data set. Two P-T grids at Xco2= 0.01 and 0.5 are described. In the calculated P-T grid at Xco2= 0.01, four out of 10 stable invariant points, Co-En-Ms-Tc, Co-Di-En-Tc-Tr, Co-Di-Ms-Tc-Tr and Di-En-Ms-Tc-Tr lie within the stability field of coesite. If the fluid phase has Xco2= 0.5, no invariant point is stable under UHP conditions. Some magnesite-bearing assemblages are stabilized by the following three reactions: Di + Ms = Do + Fo + CO2, Ms + Tr = Do + Fo + CO2+ H2O and Ms + Tc = Fo+ CO2+ H2O at Xco2= 0.01 and by reaction Ms + Tc = Fo + CO2+ H2O together with these three at Xco2= 0.5. Ten possible UHP assemblages for mafic and ultramafic compositions at very low Xco2 conditions include the following: Co-Do-Ms, Co-Di-Ms, Co-Di-Tc, Di-Ms-Tc, Di-En-Tc-, Di-En-Ms, Co-Di-En, Di-En-Fo, Di-Fo-Ms, Di-Do-Fo. Among them, talc-bearing assemblages are restricted to Xco2 < 0.02 and their high-P limit is 31.7 kb (749°C) at Xco2= 0.01. Dolomite-magnesite-silica assemblages have large P-T stability fields even if Xco2 is as low as 0.1, and could occur in cold subduction zones with very low geothermal gradients. Reported UHP coesite-dolomite assemblage is restricted only to a calc-silicate rock interlayered with marble where Xco2 is relatively higher; no such assemblage appears for mafic and ultramafic rocks with low Xco2 evidenced by the occurrence of diopside (or omphacite) at the expense of dolomite + coesite. The effect of Xco2 on the stability of coesite-dolomite-magnesite, diopside-enstatite-magnesite, diopside-talc assemblages is examined and the occurrence of coesite-dolomite, magnesite-bearing and talc-bearing assemblages in the Dabie UHP rocks are interpreted by employing the calculated P-T grids. 相似文献
2.
Abstract Various modes of occurrence of talc were identified in piemontite‐quartz schists collected from schist and eclogite units in the Kotsu area of the Sanbagawa Belt, eastern Shikoku, Japan. They can be classified into the following types: (A) matrix and (B) pull‐apart talc. The matrix talc is associated with aegirineaugite or glaucophane in the eclogite unit and with albite or chlorite in the schist unit. The pull‐apart talc is developed at the pull‐apart of microboudin structures of Na‐amphibole, along with albite or chlorite in samples from both units, suggesting that the pull‐apart talc was formed by Na‐amphibole consuming reactions in both units. The talc–aegirineaugite–phengite association is found in a thin layer (a few millimetres thick), with higher Na2O/(Na2O + Al2O3 + MgO) ratio in the ANM (Al2O3–Na2O–MgO) diagram projected from phengite, epidote and other minerals, in the eclogite unit. Crystals of aegirineaugite have decreased jadeite content [= 100 × Al/(Na + Ca)] and increased aegirine content [= 100 × (Na – Al)/(Na + Ca)] from the core (ca Jd40Aeg40Di20) to the rim (ca Jd23Aeg53Di24), and are replaced by winchite and albite in varying degrees at the crystal margins. Na‐amphibole is glaucophane/crossite, commonly rimmed by Al‐poor crossite or winchite at the margin in the eclogite unit, although it is relatively homogeneous crossite in the schist unit. These textures suggest that the talc‐phengite‐(aegirineaugite or glaucophane) assemblage equilibrated during an early stage of metamorphism and the pull‐apart talc was formed at a later stage in the eclogite unit. A plausible petrogenetic grid in the NCKFe3+MASH system with excess piemontite (regarded as epidote), hematite, quartz and water, pseudosection analysis for the aegirineaugite‐bearing layer and the observed mineral assemblages suggest that the talc‐aegirineaugite‐phengite assemblage is stable under high pressure conditions (ca 560–580°C and 18–20 kbar). The pull‐apart talc was formed at ca 565–580°C and 9.5–10.5 kbar by the reaction of glaucophane/crossite + paragonite = talc + albite during the decompression stage, suggesting that the piemontite‐quartz schist in the eclogite unit experienced high‐pressure metamorphism at ca 50–60 km depth and was then exhumed to ca 30 km depth under nearly adiabatic conditions. 相似文献
3.
In Yuka-Luofengpo area of the north Qaidam Mountains, eclogitic metapelites are recognized. The metapelites enclosed lenses
of eclogites, and locally intercalated with eclogites. Their typical mineral assemblages are garnet+kyanite+chloritoid+phengite+quartz+rutile.
Strong growth zoning is preserved in garnets of metapelites, and phengite contains up to 3.4 Si per formula units. The petrographic
observations and textural relations testify to the following sequence of mineral assemblages connected to three metamorphic
stage: (1) Grt+ChlI+CldI +PheI ± StI+Qtz; (2) Grt+Ky+PheII±CldII+Qtz; and (3) Grt+CldIII+ChlII+PheIII+StII ± ky+ Qtz. Applying
THERMOCALC Program, Grt-Phe thermometer and Grt-Ky-Phe-Qtz barometry, P-T conditions for three metamorphic stages were obtained: P=1.07±0.31GPa, T=564±22? (prograde stage); P=2.3–3.1GPa, T=615–700°C-(peak stage); and P =1.22 ± 0.26GPa, T=581±20°C (retrograde stage). A hairpin shape P-T path similar to that of adjacent eclogite is inferred. In combination with eclogitic mineral relics in marbles and orthogneisses
enclosing eclogites, we thought that the relationship between eclogites and country rocks is “in situ” rather than “tectonic emplacement”. 相似文献
4.
An estimation of tsunami inundation flow velocity is one of the most challenging issues among tsunami research. Based on field data of inundation depth and inundation flow velocity u estimated using Bernoulli's theorem and inundation depth, fundamental characteristics of the relationship between inundation flow velocity and inundation depth are examined. Fundamental characteristics of the velocity coefficient where g is gravitational acceleration, hf and hr are inundation depths at the front and the back of structures such as a rectangular building with vertical walls, respectively) implicitly included in the relationship are examined through hydraulic experiments. As a result, Cv = 0.6 is recommended as its simple and practical value. It is confirmed through these examinations that the Froude number, defined by where , ranges 0.7–2.0, and when Cv = 0.6 is adopted this Froude number ranges 0.42–1.2. By using the relationship and Cv = 0.6, two simple and practical relationships are presented for two cases where inundation flow velocity exerts the largest or the smallest fluid force on structures. These relationships can be used to roughly grasp the practical side of tsunami damage, and estimate fluid force acting on individual structures, moving velocity and collision force of floating objects and sediment transport such as boulder and sand. Fundamental characteristics of the waterline (tsunami trace) distribution around/on the typical object model (square pillar, corn and column) are also examined through steady flow experiments, and it is confirmed that the maximum and the minimum values of hf/h0 in the full type model of the square pillar are almost the same as those of hf/hr obtained by field surveys where h0 is uniform flow depth. It is also confirmed that hr ? h0 when the Froude number, defined by where u0 is uniform flow velocity, is much less than 1.0. Using a newly defined velocity coefficient, tsunami inundation flow velocity on land can be estimated practically and would be useful for checking proposed sediment transport models that are now being developed by tsunami geologists. 相似文献
5.
Abstract The talc (Tlc) + phengite (Phn) + albite (Ab) assemblage is newly confirmed in MnOtotal -rich (1.65 wt% in average) piemontite-quartz schists from the intermediate- and high-grade part of the Sanbagawa belt, central Shikoku, Japan. Talc is in direct contact with Phn, Ab and chlorite (Chl) with sharp boundaries, suggesting that these four phases mutually coexist. Other primary constituents of the Tlc-bearing piemontite-quartz schist are spessartine, braunite, hematite (Ht), crossite/barroisite and dolomite. Phlogopite (Phl) rarely occurs as a later stage mineral developing along the rim of Phn. The studied piemontite-quartz schist has mg# (= Mg/(Mg + Fe2+ )) ~ 1.0, because of its high oxidation state. Schreinemakers' analysis in the KNMASH system and the mineral assemblage in the Sanbagawa belt propose a possible petrogenetic grid, in which the Tlc–Phn assemblage is stable in a P-T field surrounded by the following reactions: lower-pressure limit by Chl + Phl + quartz (Qtz) = Phn + Tlc + H2 O as proposed by previous workers; higher-pressure limit by glaucophane + Qtz = Tlc + Ab + H2 O; and higher-temperature limit by Tlc + Phn + Ab = Phl + paragonite + Qtz + H2 O. Thermodynamic calculation based on the database of Holland & Powell (1998) , however, suggests that the Tlc–Phn stability field defined by these reactions is unrealistically limited around 580–600 °C at 11.6–12.0 (± 0.7) kbar. Schreinemakers' analysis in the KNMA-Fe3+ -SH system and the observed mineral assemblage predict that Chl + crossite = Tlc + Ab + Ht + H2 O is a preferable Tlc-forming reaction in the intermediate-grade part of the Sanbagawa belt and that excess Ab + hematite narrows the stability field of the Tlc–Phn assemblage. 相似文献
6.
Ji-Hoon Kim Myong-Ho Park Urumu Tsunogai Tae-Jin Cheong Byong-Jae Ryu Young-Joo Lee Hyun-Chul Han Jae-Ho Oh Ho-Wan Chang 《Island Arc》2007,16(1):93-104
Abstract Geochemical analyses of sediments, pore water and headspace gas of the piston cores taken from the eastern part of Ulleung Basin of the East Sea (Japan Sea) were carried out to assess the origin of the sedimentary organic matter and interstitial fluid. Several tephra layers within the core are identified as the Ulleung‐Oki (10.1 ka), the Aira‐Tanzawa (23 ka) and the Ulleung‐Yamato (30.9 ka) tephras. With the exception of these volcanic layers, the cores consist predominantly of muddy sediments that contain >0.5% total organic carbon. Atomic C/N ratios and δ13Corg values suggest that the organic matter originated from marine algae rather than from land vascular plants, whereas Rock‐Eval pyrolysis suggests that the organic matter is thermally immature and comes from a land vascular plant (Type III). These conflicting results seem to be caused by the heavy oxidization of the marine organic matter. Sulphate concentration profiles of pore waters show strongly linear depletion (r2 > 0.97) with sediment depth. The estimated sulphate–methane interface (SMI) depth using the sulphate concentration gradient was nearly 3.5 m below seafloor (mbsf) in the southern part of the study area, and deeper than 6 mbsf in the northern part of the area. The difference in SMI depths is likely associated with the amount of the methane flux. The methane concentration below the SMI in the two southern cores increases rapidly, implying the occurrence of methanogenesis and anaerobic methane oxidation (AMO). In contrast, the two northern cores have a low methane concentration below the SMI. values measured from all cores were in the range of −83.5 to −69.5‰, which suggests that the methane derives from a methanogenic microbe. values become decreased toward SMI, but increased below SMI; therefore, has eventually the minimum value near the SMI. The values are also decreased when the methane concentration is increased. These phenomena support the typical occurrence of AMO in the study area. 相似文献
7.
Studies on the hydrogeological conditions of the Mesogea basin in east Attica reveal that the aquifers developed on the post‐alpine formations at the inner part of the coastal brackish zone exhibit positive hydraulic head. These Neogene and Quaternary deposits present high salt concentrations. Selected points were sampled (total 85: 51 wells and 34 boreholes) in order to obtain hydrogeological and hydrochemical data for a better understanding of the structure, operation and dynamics of the aquifer of the area. Statistical methods, R‐mode factor analysis and scatter‐plot diagrams were used for the hydrochemical analysis and presentation of the data. The groundwater resources are relatively weak and there is significant quality degradation due to the geological structure of the greater area, as well as the bad management of the aquifer and anthropogenic activities. Groundwater is characterized by high salt concentrations. Electrical conductivity values range between 260 and 6970 µS cm?1. High salt concentrations at the coastal aquifers are due to sea intrusion, whereas they are attributed to the dissolution of minerals of the geological environment in the inland area. The groundwaters of the study area can be classified into five water types: Ca–HCO3, Mg–HCO3, Na–HCO3, Na–Cl and Mg–Cl. They are saturated in dolomite and calcite, whereas they are unsaturated in anhydrite. High ion concentrations, e.g. ] (0‐221 mg l?1), ] (0·01‐1·88 mg l?1), ] (0·01‐6·75 mg l?1), as well as high heavy metals concentrations are attributed to anthropogenic impacts. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
8.
ZHANG Jianxin MENG Fancong & YANG Jingsui Institute of Geology Chinese Academy of Geological Sciences Beijing China 《中国科学D辑(英文版)》2004,47(12)
The presence of relics of high-pressure and ultra-high pressure metamorphic assemblages in metasedi-ments and granitoid gneisses provides important evi-dence for deep subduction of continental crust (litho-sphere), and also an important criteria on "in situmetamorphism" and "tectonic emplacement" relation-ship between gneisses and enclosed eclogites. In re-cent years, eclogite and garnet peridotite lenses en-closed within quartz-feldspathic gneisses or peliticgneisses were discovered separately… 相似文献
9.
D. Beaufort P. Patrier A. Meunier M.M. Ottaviani 《Journal of Volcanology and Geothermal Research》1992,51(1-2)
Epidote and/or chlorite are common minerals in the roots of the fossil geothermal system of Saint Martin (Lesser Antilles). They appear in four distinct assemblages: (1) epidote+actinolite+quartz±magnetite near the contact between the tuffaceous host rocks (andesitic modal composition) and the quartz-diorite intrusion of Philipsburg; (2) epidote+chlorite+quartz in host rocks as far as a lateral distance of about 3 km from the intrusion; (3) epidote+chlorite+haematite+quartz locally in iron and manganese rich host rocks; (4) chlorite±phengite±magnetite appearing as late sealing of porosity in fracture-controlled quartz veins with strongly phengitized wall rocks. All these assemblages constitute a large alteration grading from propylitic alteration to thermal metamorphism (actinolite-bearing assemblage).Detailed microprobe studies of epidotes replacing plagioclases and of chlorites replacing glass and mafic minerals reveal notable compositional variations which have been studied with respect to temperature paleogradients (estimated from fluid inclusions study), distance from the thermal source and fo2 conditions. The mean Ps+Pm [100 × (Fe3+ + Mn3+)/(Al3+ + Fe3+ + Mn3+)] of epidotes vary from 21 in the presence of magnetite near the intrusion to 32 in haematite-bearing iron and/or manganese volcanic and sedimentary formations. The intra-grain chemical scattering of epidotes increases with increasing distance of the pluton and decreasing temperature of crystallization. All the chlorites coexisting with epidote are Mg-rich (XFe<0.50). Their main compositional variation consists in a significant enrichment in magnesium (toward the chlinochlore end member) in presence of haematite. The intra-grain chemical scattering of chlorite (expressed by the aluminium content in the structural formula) increases with increasing distance of the pluton and decreasing temperature of crystallization. Chlorites associated with phengite and magnetite in vein alteration are Fe- and Al-rich. The Mössbauer spectra indicate that the Fe3+ content of chlorite varies between 25 and 32% of total Fe in the presence of epidote; the higher content being attained in the presence of haematite. The Fe3+ content of chlorite associated with magnetite and phengite is 16% of total Fe. The compositional variations of epidote and/or chlorite of the four distinct assemblages observed at Saint Martin result from the combined effects of fO2, temperature, and time of heating. The effect of fO2 is particularly perceptible in the control of the epidote Ps content, of the chlorite XFe ratio of Fe3+ distribution between coexisting epidotes and chlorites. Despite the fact that it may be partially canceled out by the effect of fO2, the variation of compositional ranges of both epidotes and chlorites, which increases toward the outer part of the geothermal system in response to the combination of decreasing temperatures and decreasing time of heating of the rocks, suggests that chemical equilibrium has not been attained in the assemblages bearing epidotes and chlorites. 相似文献
10.
The Khalkhab–Neshveh (KN) pluton is a part of Urumieh–Dokhtar Magmatic Arc and was intruded into a covering of basalt and andesite of Eocene to early Miocene age. It is a medium to high‐K, metaluminous and I‐type pluton ranging in composition from quartz monzogabbro, through quartz monzodiorite, granodiorite, and granite. The KN rocks show subtle differentiation trends strongly controlled by clinopyroxene, plagioclase, hornblende, apatite, and titanite, where most major elements (except K2O) are negatively correlated with SiO2; and Al2O3, Na2O, Sr, Eu, and Y define curvilinear trends. Considering three processes of magmatic differentiation including mixing and/or mingling between basaltic and dacitic magmas, gravitational fractional crystallization and in situ crystallization revealed that the latter is the most likely process for the evolution of KN magma. This is supported by the occurrence of all rock types at the same level, the lack of mafic enclaves in the granitoid rocks, the curvilinear trends of Na2O, Sr, and Eu, and the constant ratios of (87Sr/86Sr)i from quartz monzodiorite to granite (0.70475 and 0.70471, respectively). In situ crystallization took place via accumulation of plagioclase and clinopyroxene phenocrysts and concentration of these phases in the quartz monzogabbro and quartz monzodiorite at the margins of the intrusion at T ≥ 1050°C, and by filter pressing and fractionation of hornblende, plagioclase, and later biotite in the granitoids at T = ～880°C. 相似文献
11.
In this study, bench‐scale experiments were conducted to examine the UV/H2O2 oxidation of 17α‐ethynyestradiol (EE2) in water in a batch operation mode. The EE2 degradation exhibited pseudo‐first‐order kinetics, and the removal was ascribed to the production of hydroxyl radicals (?OH) by the UV/H2O2 system. Typically, the EE2 oxidation rate increased with increasing UV intensity and H2O2 dose, and with deceasing initial EE2 levels and solution pH. At EE20 = 650 µg/L, UV intensity = 154 µW/cm2, H2O2 = 5 mg/L, and neutral pH, the UV/H2O2 treatment was able to remove 90% of the EE2 content within 30 min. Four anions commonly present in water were found to inhibit EE2 degradation to varying degrees: > > Cl? > . Our results demonstrate that the described UV/H2O2 process is an effective method to control EE2 pollution in water. 相似文献
12.
The role of gypsum and/or dolomite dissolution in tufa precipitation: lessons from the hydrochemistry of a carbonate–sulphate karst system 
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下载免费PDF全文 The precipitation of freshwater carbonates (tufa) along karstic rivers is enhanced by degassing of carbon dioxide (CO2) downstream of karstic springs. However, in most karstic springs CO2 degassing is not enough to force the precipitation of tufa sediments. Little is known about the role of dissolution of gypsum or dolomite in the hydrochemistry of these systems and how this affects the formation of tufa deposits. Here we present a monitoring study conducted over a year in Trabaque River (Spain). The river has typical karst hydrological dynamics with water sinking upstream and re‐emerging downstream of the canyon. Mixing of calcium–magnesium bicarbonate and calcium sulphate waters downstream of the sink enhances the dissolution of carbonates and potentially plays a positive role in the formation of tufa sediments. However, due to the common‐ion effect, dissolution of dolomite and/or gypsum causes precipitation of underground calcite cements as part of the incongruent dissolution of dolomite/dedolomitization process, which limits the precipitation of tufa sediments. Current precipitation of tufa is scant compared to previous Holocene tufa deposits, which likely precipitated from solutions with higher saturation indexes of calcite (SIcc values) than nowadays. Limited incongruent dissolution of dolomite/dedolomitization favours higher SIcc values. This circumstance occurs when waters with relatively high supersaturation of dolomite and low SO42? composition sink in the upper sector of the canyon. In such a scenario, the process of mixing waters enhances the exclusive dissolution of limestones, preventing the precipitation of calcite within the aquifer and favouring the increase of SIcc values downstream of the springs. Such conditions were recorded during periods of high water level of the aquifers and during floods. This research shows that the common‐ion effect caused by the dissolution of gypsum and/or dolomite rocks can limit [or favour] the precipitation of tufa sediments depending on the occurrence [or not] of incongruent dissolution of dolomite/dedolomitization. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
13.
Abstract Jadeite‐bearing eclogites and associated blueschists locally crop out in a greenschist facies area at Kuldkourla, near the Akeyazhi River in the western Chinese Tianshan region, northwestern China. Garnet in these metamorphic rocks shows prograde zoning with increasing Mg and decreasing Mn from the crystal center towards the rim, and is divided into Ca‐poor/Fe‐rich core and Ca‐rich/Fe‐poor mantle parts. The garnet cores include the assemblages of (i) jadeite/omphacite (Xjd = 0.34–0.96) + barroisite/taramite; and (ii) omphacite + barroisite/pargasite, with paragonite, epidote, rutile and quartz as major phases with rare albite. The garnet mantles rarely contain inclusions of omphacite, glaucophane, epidote, rutile and quartz. Major matrix phases of the pre‐exhumation stage are omphacite, glaucophane, paragonite, rutile and quartz. These mineral parageneses give pressure (P)‐temperature (T) conditions of 0.9 GPa/390°C?1.4 GPa/560°C for the stage of the garnet core formation, 1.8 GPa/520°C for the stage of the garnet mantle formation, and 2.2 GPa/495°C‐2.4 GPa/535°C for the peak eclogite facies assemblage in the matrix. The estimated P‐T conditions and continuous changes of mineral parageneses imply a counterclockwise P‐T path which is a combination of (i) an early prograde stage of high‐pressure/low‐temperature (HP/LT) blueschist facies and/or LP/LT eclogite facies; (ii) a later prograde stage involving compression with minimal heating; and (iii) a climax‐of‐subduction stage characterized by a slight decrease of temperature with increasing pressure. The negative dP/dT of the latest subduction stage is possibly a record of the following events after a continuous subduction and ridge approach: (i) material migration within the upper part of the subducting slab, which has an inverse thermal gradient caused by ductile flow and/or slab break during subduction; and/or (ii) temporary cooling of the wedge mantle–slab interface by continuous subduction of a relatively cold slab following subduction of a hotter ridge. 相似文献
14.
Near-bed mass flux profiles in aeolian sand transport: high-resolution measurements in a wind tunnel
Graeme R. Butterfield 《地球表面变化过程与地形》1999,24(5):393-412
Vertical profiles of the streamwise mass flux of blown sand in the near-bed (< 17 mm) region are analysed from high-resolution measurements made using an optical sensor in a wind tunnel. This analysis is complemented by detailed measurements of mass flux and mean velocity profiles throughout the boundary layer depth (0·17 m) using passive, chambered sand traps of small dimensions and armoured thermal anemometers, respectively. The data permit a preliminary analysis of the relations between the observed forms of the profiles of near-bed fluid stress and horizontal mass flux within a carefully conditioned boundary layer. Profiles of mass flux density are found to be characterized by three regions of differing gradient with transitions at about 2 mm and 19 mm above the bed. The exponential decay of mass flux with height is confirmed for elevations above 19 mm, and when plotted as a function of u*2/g (a parameter of mean vertical trajectory height in saltation), the gradient of mass flux in this region scales with the wake-corrected friction velocity (u), where u > 0·30 m s−1. A separate near-bed region of more intense transport below 19 mm is identified which carries 80 per cent of the total mass flux. This region is evident in some previous field and wind tunnel data but not in profiles simulated by numerical models. Ventilated passive sand traps underestimate mass flux in this region by 37 per cent. At slow or moderate wind speeds a third significant region below 2 mm is observed. These regions are likely to be related to grain populations in successive saltation, low-energy ejections and intermittent bed contact, respectively. Optical measurements reveal locally high grain concentrations at some elevations below 5 mm; these heights scale with transport rate, mass flux gradient and wind speed. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
15.
LIU Fulai YANG Jingsui & XU Zhiqin Institute of Geology Chinese Academy of Geological Sciences Beijing China 《中国科学D辑(英文版)》2005,48(2):175-184
Laser Raman spectroscopy and cathodoluminescence (CL) image reveal that zircons separated from paragneisses in the southwestern Sulu terrane (eastern China) preserve multi-stage mineral assemblages in different zircon domains. In the same paragneiss zircon sample, some zircon grains retain inherited (detrital) cores with abundant low-pressure mineral inclusions of Qtz + Phe + Ap + impurities and Qtz + Phe + impurities. The ultrahigh-pressure (UHP) metamorphic overgrowths mantles of these zircons preserve Coe, Coe + Phe and other UHP mineral inclusions, indicating that these inherited (detrital) zircons from protoliths experienced metamorphic recrystallization during the Sulu UHP metamorphic event. However, other zircon grains preserve UHP mineral inclusions of Coe, Coe + Ap and Coe + Phe in the cores and mantles, whereas the outmost rims contain quartz (Qtz) and other low-pressure mineral inclusions. These phenomena prove that the second group zircons were crystallized at UHP metamorphic stage and overpr 相似文献
16.
Michael A. Slawinski Michael P. Lamoureux Raphael A. Slawinski R. James Brown 《Geophysical Prospecting》2003,51(2):131-140
We present a method for calculating the anisotropy parameter of a buried layer by inverting the total traveltimes of direct arrivals travelling from a surface source to a well‐bore receiver in a vertical seismic profiling (VSP) geometry. The method assumes two‐dimensional media. The medium above the layer of interest (and separated from it by a horizontal interface) can exhibit both anisotropy and inhomogeneity. Both the depth of the interface as well as the velocity field of the overburden are assumed to be known. We assume the layer of interest to be homogeneous and elliptically anisotropic, with the anisotropy described by a single parameter χ. We solve the function describing the traveltime between source and receiver explicitly for χ. The solution is expressed in terms of known quantities, such as the source and receiver locations, and in terms of quantities expressed as functions of the single argument xr, which is the horizontal coordinate of the refraction point on the interface. In view of Fermat's principle, the measured traveltime T possesses a stationary value or, considering direct arrivals, a minimum value, . This gives rise to a key result ‐‐ the condition that the actual anisotropy parameter . Owing to the explicit expression , this result allows a direct calculation of in the layer of interest. We perform an error analysis and show this inverse method to be stable. In particular, for horizontally layered media, a traveltime error of one millisecond results in a typical error of about 20% in the anisotropy parameter. This is almost one order of magnitude less than the error inherent in the slowness method, which uses a similar set of experimental data. We conclude by detailing possible extensions to non‐elliptical anisotropy and a non‐planar interface. 相似文献
17.
Incorporating spatially heterogeneous infiltration capacity into hydrologic models with applications for simulating post‐wildfire debris flow initiation 下载免费PDF全文
下载免费PDF全文 Luke A. McGuire Francis K. Rengers Jason W. Kean Dennis M. Staley Benjamin B. Mirus 《水文研究》2018,32(9):1173-1187
Soils in post‐wildfire environments are often characterized by a low infiltration capacity with a high degree of spatial heterogeneity relative to unburned areas. Debris flows are frequently initiated by run‐off in recently burned steeplands, making it critical to develop and test methods for incorporating spatial variability in infiltration capacity into hydrologic models. We use Monte Carlo simulations of run‐off generation over a soil with a spatially heterogenous saturated hydraulic conductivity (Ks) to derive an expression for an aerially averaged saturated hydraulic conductivity ( ) that depends on the rainfall rate, the statistical properties of Ks, and the spatial correlation length scale associated with Ks. The proposed method for determining is tested by simulating run‐off on synthetic topography over a wide range of spatial scales. Results provide a simplified expression for an effective saturated hydraulic conductivity that can be used to relate a distribution of small‐scale Ks measurements to infiltration and run‐off generation over larger spatial scales. Finally, we use a hydrologic model based on to simulate run‐off and debris flow initiation at a recently burned catchment in the Santa Ana Mountains, CA, USA, and compare results to those obtained using an infiltration model based on the Soil Conservation Service Curve Number. 相似文献
18.
Abstract Reaction zones of 0.5–10.0 m thick are commonly observed between serpentinite and pelitic schist in the Nishisonogi metamorphic rocks, Kyushu, Japan. Each reaction zone consists of almost monomineralic or bimineralic layers of talc + carbonates, actinolite (or carbonates + quartz), chlorite, muscovite and albite from serpentinite to pelitic schist. Magnesite + quartz veins extend into the serpentinite from the talc + carbonates layer, while dolomite veins extend into the pelitic schist from the muscovite layer. These veins are filled by subhedral minerals with oriented growth features. Primary fluid inclusions yield the same homogenization temperatures (145–150°C) both in the reaction zone and in the veins, suggesting their simultaneous formation. Mass-balance calculations using the isocon method indicate that SiO2 , MgO, H2 O and K2 O are depleted in the reaction zone relative to the protoliths. These components were probably extracted from the reaction zone as fluids during the formation of the reaction zone. 相似文献
19.
Hydrogeochemical evolution of Ordovician limestone groundwater in Yanzhou,North China 总被引：1，自引：0，他引：1
Yong Han Guangcai Wang Charles A Cravotta III Weiyue Hu Yueyue Bian Zongwen Zhang Yuanyuan Liu 《水文研究》2013,27(16):2247-2257
Major‐ion compositions of groundwater are employed in this study of the water–rock interactions and hydrogeochemical evolution within a carbonate aquifer system. The groundwater samples were collected from boreholes or underground tunnels in the Ordovician limestone of Yanzhou Coalfield where catastrophic groundwater inflows can be hazardous to mining and impact use of the groundwater as a water supply. The concentration of total dissolved solid (TDS) ranged from 961 to 3555 mg/l and indicates moderately to highly mineralized water. The main water‐type of the middle Ordovician limestone groundwater is Ca‐Mg‐SO4, with SO42‐ ranging from 537 to 2297 mg/l, and average values of Ca2+ and Mg2+ of 455.7 and 116.6 mg/l, respectively. The water samples were supersaturated with respect to calcite and dolomite and undersaturated or saturated with respect to gypsum. Along the general flow direction, deduced from increases of TDS and Cl‐, the main water–rock interactions that caused hydrogeochemical evolution of the groundwater within the aquifer were the dissolution of gypsum, the precipitation of calcite, the dissolution or precipitation of dolomite, and ion exchange. Ion exchange is the major cause for the lower mole concentration of Ca2+ than that of SO42‐. The groundwater level of Ordovician aquifer is much higher than that of C‐P coal‐bearing aquifers, so the potential flow direction is upward, and the pyrite in coal is not a possible source of sulfate; additional data on the stable sulfur and oxygen isotopic composition of the sulfate may be helpful to identify its origin. Although ion exchange probably accounts for the higher mole concentration of Na+ than that of Cl‐, the dissolution of aluminosilicate cannot be ruled out. The data evaluation methods and results of this study could be useful in other areas to understand flow paths in aquifers and to provide information needed to identify the origin of groundwater. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
20.
In order to understand the origin of iron-rich olivine in the matrices of type 3 ordinary chondrites, the reaction of metallic iron and enstatite, with and without forsterite and SiO2, has been experimentally reproduced at temperatures between 1150° and 800°C and PO2 between 10−11 and 10−16 atm (between the IQF and MW buffers). The olivine produced ranges from Fo58 to Fo34 and this composition does not change significantly with temperature and time of the runs. The magnesian olivine which forms does become more magnesian with increasing forsterite/enstatite ratio of the starting materials. Iron-rich olivine (Fo< 35) cannot be formed by the reaction of enstatite and metallic iron, with or without forsterite as starting materials but it can be formed in the presence of free silica. The composition of olivine becomes more iron-rich with increasing silica/enstatite ratio. The compositional range of olivine formed from each mixture is 25–30 mole% Fo regardless of the temperature, composition, mineral assemblage, and run duration.From these experimental results, two possibilities suggested for the origin of the iron-rich olivine in the matrices of type 3 ordinary chondrites: (1) free silica must have been present if the iron-rich olivine was formed by solid-state reactions under oxidizing condition in the solar nebula; (2) reaction of silicon-rich gas with metallic iron took place under oxidizing condition in the solar nebula. Though it is difficult to define which alternative was dominant, the formation of free silica or silicon-rich gas may be a result of fractional condensation. This is possible if there is a reaction relation between forsterite and gas to produce enstatite. The suggested fractional condensation is supported by the fact that the compositions of the fine-grained matrices of type 3 ordinary chondrites are more silica-rich than the bulk compositions of the chondrites. Though it is not known whether such conditions were established all over the nebula or locally in the nebula, both fractionation and more oxidizing conditions than the average solar nebula are required for the formation of matrix olivine. 相似文献