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闽西南地区才溪岩体锆石SHRIMP定年及其地球化学特征 总被引：15，自引：0，他引：15
锆石SHRIMP年龄测试结果表明,闽西南地区才溪岩体的形成年龄为150±3Ma。才溪二长花岗岩富硅、富碱,弱过铝。岩石富集LREE,具Eu负异常,*Eu值为0.54~0.66,亏损Ba、Nb、Ta、Sr、P、Eu、Ti。(87Sr/86Sr)i值较高,为0.710462~0.712265,εNd(t)为-8.68~-9.81,t2DM为1.51~1.61Ga。岩石中黑云母富铝、镁,在Fe2 -Fe3 -Mg2 三角图上落入壳幔混源区。根据岩体地质学、地球化学特征,结合岩石学和矿物学特征认为,才溪二长花岗岩是由中元古代地壳物质熔融形成的壳源型花岗岩,在岩浆形成过程中有少量幔源物质的加入,形成于由挤压向伸展过渡的构造环境。 相似文献
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黑龙江省东部楚山兴凯期花岗闪长岩体的特征和成因 总被引：3，自引：1，他引：3
楚山花岗闪长岩体产在佳木斯隆起内,与元古界麻山群变质岩系密切伴生,呈交代-侵入接触,并侵入震旦系龙山村群。岩体的Rb-Sr等时线年龄626Ma,K-Ar年龄670Ma,属兴凯旋回早期。岩体呈巨大岩基,受南北向牡丹江深断裂控制。主要岩性为花岗闪长岩,局部为花岗岩及石英闪长岩。岩相学上既显示岩浆结晶特点又有交代作用的迹象。按其矿物-地球化学特征属半原地的S型花岗岩类,~(87)Sr/~(86)Sr初始值为0.710,原岩浆为陆壳部分熔融的产物。 相似文献
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吉林东部延边地区二长花岗岩年代学、岩石成因学及其构造意义研究 总被引：7，自引：5，他引：2
高岭岩体位于吉林省延边地区和龙市东侧,大地构造位置上位于华北板块北缘东段,岩性主要为似斑状二长花岗岩,基质为中粒-中细粒结构。LA-ICP-MS锆石U-Pb测年结果显示,样品YH04和N-5的加权平均年龄分别为172.25±0.97Ma和170.9±0.68Ma,表明岩体侵位时代为中侏罗世。岩石地球化学特征上,高岭岩体样品具有高硅(69.60%~74.30%)、富铝(13.90%~15.80%)、富钾(3.05%~4.50%)和低镁(0.22%~0.82%)及Mg#(26~37)的特点。样品富集轻稀土元素,相对亏损重稀土元素(LREE/HREE=13~21),具有微弱的负Eu到正Eu异常(δEu=0.78~2.14),其稀土元素配分模式图与埃达克岩稀土元素配分模式图类似。高岭岩体样品富集大离子亲石元素Cs、Rb、Ba、K、Sr和高场强元素Th、U和Zr,同时亏损高场强元素Nb、Ta以及P元素。同时样品具有较低的初始87Sr/86Sr值(0.7039~0.7051)和负的εNd(t)值(-0.6~-0.3),且其t DM1和t DM2模式年龄分别为922~928Ma和984~1011Ma,表明研究区新元古代存在地壳增生事件。Sr-Nd同位素特征及岩石地球化学特征表明高岭岩体母源岩浆来源于加厚下地壳基性岩石部分熔融且受到了新元古代增生物质的影响。结合区域构造演化,中侏罗世高岭岩体侵位构造环境可能受到环太平洋构造体系和华北板块与西伯利亚板块持续碰撞的叠加影响。 相似文献
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东昆仑五龙沟晚二叠世花岗闪长岩LA-ICP-MS锆石U-Pb定年、岩石成因及意义 总被引：6，自引：0，他引：6
《地学前缘》2015,(5)
报道了东昆仑东段五龙沟岩体的锆石U-Pb年代学、全岩和痕量元素地球化学、Sr-Nd同位素和原位锆石Hf同位素数据。五龙沟岩体的LA-ICP-MS锆石U-Pb定年表明花岗闪长岩主要侵位于260 Ma左右。花岗闪长岩具有适中的SiO2、高Al2O3和全碱含量,属于中钾钙碱性弱过铝质系列。样品富集LREE,大离子亲石元素(LILE),亏损高场强元素(HFSE),具有陆缘弧花岗岩的特征。此外,花岗闪长岩具有弱的负Eu异常(δEu=0.8~1.0),高Sr((377~484)×10-6),低Y((8.7~17.5)×10-6)和Yb((0.89~1.57)×10-6),类似于埃达克质岩石的地球化学特征。岩石具有较均一(87Sr/86Sr)i值(0.709 1~0.707 6),较低的全岩εNd(t)值(-4.3~-5.3)和古老的Nd模式年龄T2DM(1.6~1.7Ga)。原位锆石Hf同位素显示εHf(t)值介于0.6~-3.5,对应二阶段模式年龄T2DM(1.3~1.5Ga)。上述地球化学特征说明花岗闪长质岩浆是由古老的基性下地壳部分熔融而成,其形成深度在30~40km。岩体中出露的同生成基性岩墙指示该时期有幔源岩浆活动,部分熔融作用可能与岩浆底侵作用相关。因此,结合区域地质研究,我们认为晚二叠世五龙沟花岗闪长岩形成于活动大陆边缘的局部伸展环境,这种背景可能响应了布青山—阿尼玛卿洋洋壳北向俯冲过程中俯冲极性的突变。 相似文献
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王安镇杂岩体主要由花岗闪长岩、二长花岗岩、花岗岩、石英闪长岩、二长闪长岩组成,LA-ICP-MS锆石U-Pb测年显示,花岗闪长岩和石英闪长岩分别形成于129±2.7Ma和128.3±1.9Ma,说明该杂岩体形成于早白垩世。王安镇杂岩体具有高Sr/Y比值(3.63~83.5),和高Sr(373×10-6~821×10-6),及低Y(7.36×10-6~22.21×10-6)、Yb(0.95×10-6~1.27×10-6)含量的地球化学特征,这与埃达克岩相似。该杂岩体具有相对低的87Sr/86Sr初始比值(0.706538~0.709484)和明显偏低的εNd(128Ma)值(-18.4~-12.8)。结合太行山中生代中-基性侵入岩中地幔包体已有的研究成果,认为具有高Sr/Y特征的王安镇杂岩体是在下地壳发生大规模拆沉的基础上,随着软流圈上涌其所携带的热促使加厚基性下地壳发生部分熔融,之后熔融岩浆在上升的过程中发生了角闪石的结晶分异和岩浆混合作用形成。 相似文献
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《地质通报》2019,(Z1)
多坝沟黑云二长花岗岩体出露于敦煌地块南缘,呈近东西向带状分布,侵位于太古宙—古元古代敦煌岩群。LA-ICP-MS锆石U-Pb年龄显示,该岩体形成于晚二叠世,~(206)Pb/~(238)U年龄加权平均值为252.1±2.3Ma。该岩体具高SiO_2含量(68.32%～72.82%)和全碱含量(7.76%～8.00%);A/CNK值为0.97～1.02,均小于1.1,为高钾钙碱性准铝质花岗岩。岩石具有明显的轻、重稀土元素分异和弱的负Eu异常,具高Sr/Yb和(La/Yb)_N值富集大离子亲石元素(K、Rb、Ba、Cs),显著亏损Nb、Ta、P和Ti,表明源岩具有经典岛弧岩石地球化学特征;(~(87)Sr/~(86)Sr)_i值为0.707083,ε_(Nd)(t)为-2.22,Nd模式年龄T_(DM2)=1102Ma。元素和同位素地球化学特征显示,多坝沟花岗岩形成于加厚下地壳中岛弧玄武岩的部分熔融。结合岩体地质特征、年代学和区域地质背景,初步认为敦煌地块在晚古生代晚期依然受古亚洲洋汇聚碰撞相关的造山活动的影响,可能是中亚造山带的最南缘组成部分。 相似文献
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西藏羌塘南缘早白垩世普让岩体的锆石U-Pb年龄和地球化学特征及其地质意义 总被引：1，自引：0，他引：1
普让岩体位于西藏羌塘南缘多龙矿集区西北部,岩体的岩石类型组合为石英二长岩—二长岩—二长闪长岩,侵位于三叠纪日干配错群灰岩中,并形成矽卡岩型磁铁矿。石英二长岩LA-ICP-MS的锆石~(206)Pb/~(238)U加权平均年龄为116±2Ma(MSWD=6.5),与该带上的多龙含矿斑岩成岩年龄基本一致。普让岩体不含白云母,且标准矿物中富含透辉石,具有较高的Al_2O_3,较低的Ti O_2,富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土元素(HREE),显示Nb和Ta的负异常,具有明显的岛弧型岩石的地球化学特征,属于准铝质I型花岗岩。与多龙含矿斑岩相比,普让岩体具有相似的ε_(Nd)(t)值(-7.22~-6.81),n(~(87)Sr)/n(~(86)Sr)i值(0.707525~0.708243)和古老的Nd的模式年龄(1.29~1.63Ga)。研究表明:普让岩体可能是在班公湖—怒江洋壳北向俯冲的背景下,下地壳重熔,且在上升的过程中经历了分离结晶和地壳混染作用下形成的。多龙外围的岩浆岩带不仅具有寻找斑岩铜矿的潜力,也是形成和寻找的矽卡岩型多金属矿的有利地区。 相似文献
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安徽狮子山矿田南洪冲岩体形成时代及成因机制研究 总被引：10，自引：10，他引：10
南洪冲岩体是狮子山矿田内一个隐伏岩体,通过 LA-ICPMS 锆石 U-Pb 定年,获得~(206)Pb/~(238)U 年龄为141.2±1.6Ma,与矿田内其它岩体形成时代较为接近,说明南洪冲岩体是晚侏罗—早白垩世岩浆活动的产物。岩体的岩性为花岗闪长岩,主量元素以富碱(Na_2O>K_2O)、准铝质和高钾钙碱性为特征;微量元素表现为 Rb、Ba、Sr 等大离子亲石元素(HLE)和 Th、U富集,Nb、Ta、Ti 等高场强元素(HFSE)亏损;LREE 与 HREE 分馏显著((La/Yb)_N=21.07～24.28),无明显的 Eu 异常(δEu=0.92～1.03)。岩体的(~(87)Sr/~(86)Sr)_i 值偏高(0.70792～0.70793),ε_(Nd)(t)值偏低(-9.5～-9.1),Nd 模式年龄为中元古代(1.67～1.71Ga),与铜陵地区,特别是狮子山矿田内岩浆岩的 Sr-Nd 同位素初始组成和 Nd 模式年龄相仿。上述研究表明,南洪冲花岗闪长岩与矿田内乃至铜陵地区的燕山期岩浆岩具有相近的地球化学特征,说明成岩物质起源于富集型的岩石圈地幔,在中国东部地壳由挤压向伸展-减薄过渡的构造转换期,岩浆上升侵位,以同化混染与分离结晶作用方式产生了大量岩体。但南洪冲花岗闪长岩的形成主要与分离结晶作用有关,反映了岩浆作用过程中存在一定差异。 相似文献
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胶东地区大规模金成矿作用与中生代郭家岭期岩浆活动关系紧密,但针对胶东郭家岭期岩浆岩体的成因仍存在不同认识。本文选择焦家金矿带北段与金矿具有时空关系的郭家岭期丛家岩体作为研究对象,开展系统岩相学、地球化学、LA- MC- ICP- MS 锆石U- Pb年代学及Sr—Nd同位素研究。丛家岩体花岗岩的 Na2O/K2O分别为0. 69～1. 23,Na2O+K2O值为7. 29%～9. 58%,A/CNK值为1. 39～1. 51,为高钾钙碱性系列过铝质花岗岩;丛家岩体具有轻稀土富集、重稀土亏损、负铕异常（0. 41～0. 68）、大离子亲石元素Ba、Sr等富集、 Nb、Ta、Ti等高场强元素亏损、以及高Sr/Y值（81. 59～235. 5）等岩石地球化学特征;丛家岩体锆石LA- MC- ICP- MS的U- Pb年龄为126. 1±0. 3 Ma,可以代表丛家岩体结晶年龄;岩体n(87Sr)/n(86Sr) 值为0. 711463,其低于地壳的平均值（0. 7170）,高于地幔的平均值（0. 7090）,表明其有幔源物质的参与;\[n(87Sr)/n(86Sr)\]i 为0. 711117, Nd (t)的值为-17. 14,亏损地幔模式年龄( TDM2 ) 为3396 Ma。综合分析成因为幔源基性岩浆与下地壳重熔中酸性岩浆发生混合而成,并在上侵过程中受到玲珑期花岗岩的同化混染,是典型幔源物质直接参与混合的壳幔混合成因的花岗岩。 相似文献
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长白山天池火山粗面岩成因与岩浆房系统演化 总被引：1，自引：0，他引：1
长白山天池火山是典型的大陆板内碱性火山,岩石组合以玄武岩盾和粗面岩、碱流岩等碱性岩为主。为厘清天池火山粗面岩的形成过程,本文在综合前人研究的基础上,结合本文新发表数据,检验了粗面岩的成因。研究结果显示天池火山粗面岩不可能由古老的华北克拉通下地壳部分熔融形成,也不符合造盾玄武岩部分熔融的模式。通过主量元素、微量元素定性和定量计算后认为粗面岩是由进化玄武质岩浆(玄武粗安岩)经历了分离结晶作用所形成,粗面岩形成过程中岩浆遭受了地壳混染,并且具有高n(~(87)Sr)/n(~(86)Sr)和低n(~(87)Sr)/n(~(86)Sr)两种截然不同的混染趋势。结合岩相和层序信息,作者认为两种演化趋势是上地壳岩浆房系统变化的反映。早期玄武质岩(头道白山期)上侵至上地壳演化,因与上地壳直接接触,沿高n(~(87)Sr)/n(~(86)Sr)趋势演化。随着岩浆房接受补给,岩浆房逐渐增大,新侵入的岩浆与地壳被早期岩浆房结晶形成的岩浆房壁所隔挡,使得年轻粗面岩和碱流岩只与早期粗面质岩浆的残留体等进行物质交换,最终沿着低Sr同位素比值趋势演化。 相似文献
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流体包裹体RbSr等时线定年的可靠性 总被引：11，自引：0，他引：11
通过对Rb-Sr等时线原理应用的必要条件及流体包裹体样品的成因特点的分析，认为是否可以用流体包裹体Rb-Sr定年在理论上尚需解决以下问题：（1）因矿物中常有不同期次、不同成因的流体包裹体存在，必须保证所选择的各流体包裹体样品具有相同的初始Sr同位素比值；（2）流体包裹中Rb与Sr的分异机理以及分异程度问题，即流体中Rb与Sr之间是否存在分异和分异程度是否可以达到Sr同位素分析的精度分析。已有的流体包裹体的Rb-Sr等时线年龄研究资料和数据的分析检验结果普遍存在以下问题：等时线图上数据点分散；拟合年龄较老；等时线拟合品质参数的MSWD偏大，可靠性低。 相似文献
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The Kalka Intrusion, central Australia has a 5000 m-thick layered sequence comprising Pyroxenite, Norite and Anorthosite Zones; an Olivine Gabbro Zone is enclosed by, and has a facies relationship with, the Norite Zone. Contamination is evidenced by high initial 87Sr/86Sr ratios ( 0.708) in the lower four-fifths of the intrusion, and resulted in pyroxenite rather than peridotite as a basal crystal accumulate. After an early phase of erratic buildup in contamination due to assimilation of ragged granulite wall-rock, armouring of the walls and mixing produced an homogeneous Norite Zone (threshold) magma body crystallising opx-cpx-plag. Within the succeeding 3500 m of section plagioclase An values have a general decline up sequence (An74-60-feldspar threshold) with superimposed short term digressions to more calcic compositions. Initial 87Sr/86Sr ratios also fall very gradually (0.7081-0.7078 — isotopic threshold) with transient fluctuations to distinctly lower values. Maxima in plagioclase An contents and 87Sr/ 86Sr minima may be correlated with the spasmodic appearance of olivine and pronounced lithological variation. Such features are explained by the ponding of fresh bodies of uncontaminated magma on the floor of the chamber; these formed a hybrid with threshold magma that temporarily dominated crystallisation thereby perturbing plagioclase and isotopic compositions; eventually, mixing of the hybrid into the overlying threshold magma returned crystallisation to its initial state. The facies-controlled Olivine Gabbro Zone is the physical expression of ponded basal hybrid magmas. The onset of the Anorthosite Zone is marked by a pronounced decline in 87Sr/86Sr ratios to around 0.705 registering a major influx of new magma. In this instance the new magma dominated the system and a change to plagioclase as the dominant liquidus phase indicates a drastic change in input magma composition. The evolution of Kalka was determined by an interplay of crystal fractionation, fresh magma pulses, and magma mixing, with the latter effects producing both increases and decreases in plagioclase An contents; the complete process can only be revealed by combined mineral composition and isotopic data. 相似文献
14.
The Taylor Creek Rhyolite of southwest New Mexico consists of 20 lava domes and flows that were emplaced during a period of a few thousand years or less in late Oligocene time. Including genetically associated pyroclastic deposits, which are about as voluminous as the lava domes and flows, the Taylor Creek Rhyolite represents roughly 100 km3 of magma erupted from vents distributed throughout an area of several hundred square kilometers. Major-element composition is metaluminous to weakly peraluminous high-silica rhyolite and is nearly constant throughout the lava field. The magma reservoir for the Taylor Creek Rhyolite was vertically zoned in trace elements, 87Sr/86Sr, and phenocryst abundance and size. Mean trace-element concentrations, ranges in concentrations, and element-pair correlations are similar to many subalkaline silicic ignimbrites. However, the polarity of the zonation was opposite that in reservoirs for ignimbrites, for most constituents. For example, compared to the Bishop Tuff, only 87Sr/86Sr and Sc increased upward in both reservoirs. Quite likely, a dominant but nonerupted volume of the magma reservoir for the Taylor Creek Rhyolite was zoned like that for the Bishop Tuff, whereas an erupted, few-hundred-meter-thick cap on the magma body was variably contaminated by roof rocks whose contribution to this part of the magma system moderated relatively extreme trace-element concentrations of uncontaminated Taylor Creek Rhyolite but did not change the sense of correlation for most element pairs. The contaminant probably was a Precambrian rock of broadly granitic composition and with very high 87Sr/86Sr. Although examples apparently are not yet reported in the literature, evidence for a similar thin contaminated cap on reservoirs for large-volume silicic ignimbrites may exist in the bottom few meters of ignimbrites or perhaps only in the pumice fallout that normally immediately precedes ignimbrite emplacement. 87Sr/86Sr in sanidine phenocrysts of the Taylor Creek Rhyolite is higher than that of their host whole rocks. Covariation of this isotope ratio with sanidine abundance and size indicates positive correlations for all three features with decreasing distance to the roof of the magma reservoir. The sanidine probably is more radiogenic than host whole rock because growing phenocrysts partly incorporated Sr from the first partial melt of roof rocks, which contained the highly radiogenic Sr of Precambrian biotite ± hornblende, whereas diffusion was too slow for sanidine to incorporate much of the Sr from subsequently produced less radiogenic partial melt of roof rocks, before eruption quenched the magma system. Disequilibrium between feldspar phenocrysts and host groundmass is fairly common for ignimbrites, and a process of contamination similar to that for the Taylor Creek Rhyolite may help explain some of these situations. 相似文献
15.
岩浆长期分离结晶对岩石锶同位素初始比值的影响 总被引：6，自引：0，他引：6
讨论了在岩浆长期分离结晶作用的模式,由于晚期残留熔体相对于早期结晶相其Rb/Sr比增高,当有一定滞留时间条件下,将导致晚期结晶相~(87)Sr/~(86)Sr初始比增高,因而在一个复式岩基内会形成具有不同锶同位素初始比的多个岩石单元。文中以安徽地洼阶段的黄山一狮子岭岩体为例,通过模拟计算,得到其初始岩浆(?)=0.7122,(Rb/Sr)0=3,该岩浆的80％分离结晶形成黄山岩体,其(?)=0.7143(t=130Ma),其余20％的残余熔体结晶后形成狮子岭岩体,其(?)=0.7180(t=123.1Ma)。 相似文献
16.
Joachim Hoefs Gunter Faure David H. Elliot 《Contributions to Mineralogy and Petrology》1980,75(3):199-203
Theδ18O (SMOW) values of the Kirkpatrick Basalt (Jurassic) on Mt. Falla, Queen Alexandra Range, vary between +6.3‰ and +8.6‰ The apparent enrichment of these rocks in18O excludes the possibility that they were altered by interaction with aqueous solutions of meteoric origin. Theδ18O values of the flows correlate significantly with the initial87Sr/86Sr ratios and all major elements. These correlations confirm the hypothesis that the basalt magma was contaminated by rocks of the continental crust through which it was extruded. Estimates of the chemical composition of the basalt magma and the contaminant, based on extrapolations of the new oxygen data, generally confirm earlier estimates based on extrapolations of initial87Sr/86Sr ratios. The87Sr/86Sr ratio of the uncontaminated basalt was 0.7093 which indicates that magma may have originated by melting either in old Rb-enriched lithospheric mantle under Antarctica or in the overlying crust, or both. 相似文献
17.
Initial 87Sr/86Sr ratios, major and trace element compositions have been determined for the Paleogene granitic rocks in the Tsukuba district, Japan. Isotopic ages strongly suggest that the granitic rocks (seven units) were continuously emplaced and solidified during a short time interval. Initial 87Sr/86Sr ratios for seven granitic units vary from 0.7082 to 0.7132, while sedimentary and metasedimentary country rocks have ratios at the time of granitic magma emplacement ranging from 0.7149 to 0.7298. Continuous linear arrays for the granitic rocks in the diagrams of initial 87Sr/86Sr ratios versus some chemical parameters can be explained by either of following two processes. One is the assimilation — fractional crystallization (AFC) process between the parental magma (SiO2 of 68% and initial ratio of 0.7078) and sedimentary country rocks, and the other is magma mixing process between above parental magma and sediment derived acidic magma (melt) (SiO2 of 75%). The high initial ratios (0.7078–0.7098) for basic rocks such as gabbro or diorite in the Tsukuba district and the similar characteristics observed in the rocks of Ryoke belt (SW Japan) suggest that the parental magma had the same source region as the basic rocks, probably the lower crustal source. 相似文献
18.
Isotopic Composition of Strontium in Rocks of the Fen Alkaline Complex, South Norway 总被引：1，自引：0，他引：1
The isotopic composition of Sr and the abundances of Rb andSr have been determined in the alkaline rocks of the Fen Complex,South Norway. The 87Sr/88Sr ratios range from as low as 0.703in carbonatite (s?vite) to as high as 0.710 in rauhaugite. Thewhole rock analyses do not plot on a Nicolaysen diagram as anisochron. Calculation of the initial isotopic composition ofSr in the rocks at the time of intrusion of the complex, approximately550 m.y. ago, shows that the rocks are not simply related asthe differentiation products of a single magma, since they donot possess similar initial 87Sr/86Sr ratios. The lowest initialratio is seen in the s?vites and it is concluded that this rockrepresents the magma from which the other rocks of the complexwere derived. Production of hybrid rocks by bulk assimilationof granite gneiss in carbonatite is inadequate to account forthe observed Rb/Sr ratios. It is envisaged that selective concentrationof granitic Sr of high 87Sr/86Sr ratio together with loss orgain of variable amounts of Rb has taken place. The processis closely connected with the fenitization observed at the marginsof the complex and is of a metasomatic nature. Thus, the genesisof rocks of the melteigite-ijolite-urtite series may be consideredto be a rheomorphic process. The 87Sr/86Sr ratios observed inr?dberg and rauhaugite can be explained in terms of the metasomaticalteration of damtjernite. 相似文献
19.
Most of the flows in the Palaeocene lava pile remnant of Skyeare members of the Skye Main Lava Series (SMLS), comprisingtransitional basalts and two associated suites of evolved lavas.The first suite evolves through Fe-rich hawaiites and mugearitesto benmoreites, and the second suite evolves through Fe-poorintermediates to trachytes. Ca-rich, alkali-poor olivine tholeiites(the Preshal Mhor magma type) occur as sparse flows in the stratigraphicallyhighest parts of the lava pile remnant and are abundant in thedyke swarm transecting it. Initial 87Sr/86Sr ratios rangingfrom 0.70308 to 0.70571 in 45 SMLS samples show no significantcorrelation with degree of zeolitization (H2O+), silica saturation,or 87Rb/86Sr. A moderately good negative correlation with totalSr confirms published Pb-isotope evidence of interaction withancient, sialic crust. Details of the (87Sr/86Sr)l versus Srpattern are consistent with previous hypotheses that the SMLSbasalt-benmoreite suite evolved at a depth near the Moho, whilstthe low-Fe trend to trachyte resulted from near-surface basaltfractionation. (87Sr/86Sr)l values ranging from 0.70307 to 0.70621 for PreshalMhor basalts show a strong positive correlation with total Sr,consistent with a model of extensive fractionation within theupper crust of a mantle-derived low 87Sr/86Sr-low Sr magma,which became progressively contaminated with comparatively radiogeniccrustal Sr. The lowest measured (87Sr/86Sr)l values of 0.70307and 0.70308, for a Preshal Mhor basalt and for an SMLS basaltrespectively, are consistent with the hypothesis that thesetwo magma types were produced by successive phases of partialmelting from a single volume of upper mantle. (87Sr/86Sr)l values for additional miscellaneous basaltic lavas,dykes and major intrusives from Skye and from nearby Isle ofMull exhibit considerable variability within the range 0.7038to 0.7072, whilst three basaltic dykes from Northern Englandare in the range 0.7089 to 0.7123. The latter values overlapwith published (87Sr/86Sr)l values for some of the granitesin the Tertiary Province of northwest Scotland and indirectlyremove objections based on Sr-isotopic arguments to the genesisof the granites by fractionation of basalt contaminated withcrustal Sr, but neither prove this nor disprove large-scalecrustal partial fusion. 相似文献
20.
Carbonates in a 30 cm wide zoned kimberlite dyke from the De Beers Mine, Kimberley, S. Africa were studied by cathodoluminescence and electron microprobe techniques and their 87Sr/86Sr ratios were measured using an AEI-IM20 ion microprobe. Primary carbonates (including calcite dendrites, rhombohedral calcites in segregation vesicles and mosaic dolomite) have high Sr (0.69–1.35 wt.% SrO) and Ba (0.24–0.44% BaO) and 87Sr/86Sr ratios in the range 0.7046 to 0.7056. Secondary sparry calcite in amygdales and veins is characterised by low Ba (<0.05% BaO) and 87Sr/86Sr near 0.72. Rhombohedral calcite 0.5 cm from a contact with 2,900 my. old biotite-gneiss has minor element chemistry like that of primary carbonate, but an elevated 87Sr/86Sr ratio of 0.7103, possibly indicating crustal contamination in a boundary layer of the kimberlite magma. Amygdale-like segregations of carbonate and/or serpentine originated as gas-cavities and were not formed by liquid immiscibility. They are now filled either by secondary calcite or by minerals precipitated from residual kimberlite liquid. However, dendritic calcite and primary dolomite and calcite with high Sr, Ba and low 87Sr/86Sr demonstrate shared chemical characteristics between these carbonates and carbonatite. The primary kimberlite magma had initial 87Sr/86Sr close to 0.7046. 相似文献