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1.
硫化物Rb-Sr同位素定年研究进展 总被引：4，自引：0，他引：4
针对金属矿床成矿年代确定混乱的问题,国内外许多矿床学家和同位素地球化学家对金属矿物常规同位素定年方法进行了有益的探索研究,尤其是对于矿石矿物以闪锌矿、方铅矿和黄铁矿为主的铅锌矿床,硫化物矿物Rb-Sr同位素定年方法显示出了其独特的优势。结合近几年开展的工作,总结国内外硫化物Rb-Sr同位素定年研究取得的成果、闪锌矿中Rb、Sr的赋存状态与定年机理以及定年适应性问题。采用闪锌矿Rb-Sr同位素组成数据拟合成等时线源自热液流体与闪锌矿之间Rb和Sr的不同分异作用,但并不是所有的闪锌矿均适合该定年技术。要成功获得年龄,需结合野外地质特征采集代表性的矿石样品,并在镜下鉴定基础上挑选合适的单矿物;在分析测试过程中,需尽可能去除次生包裹体和粘土矿物。 相似文献
2.
流体包裹体中Sr同位素的激光剥蚀多接收等离子体质谱原位微区分析 总被引：3，自引：0，他引：3
本文研究了用激光剥蚀多接收等离子体质谱（LA-MC-ICPMS）技术原位微区分析包裹体中Sr同位素的分析方法。5、10、16和30μm剥蚀序列进行包裹体的Sr同位素组成分析结果表明,包裹体中Sr同位素比值和Rb含量明显高于与包裹体接触的方解石矿物,从大个体包裹体（大于2μm）可获得较准确的Sr同位素组成（精密度为0.08%）。由于87Rb的含量只能通过85Rb计算而来,有限包裹体分析信号而导致的Sr同位素分析精度较传统的化学方法略差,因此本方法不能得到包裹体中的Rb-Sr年龄。 相似文献
3.
徐家村金矿床位于佳木斯地块西南部，矿体赋存于晚二叠世二长花岗岩中.通过对含金石英脉石英中的流体包裹体进行Rb-Sr同位素年龄及H、O同位素测定，获取成矿年龄，探讨成矿流体来源及其与赋矿花岗岩的成因联系.结果显示：石英流体包裹体Rb-Sr等时线年龄为229±8.6 Ma，比含矿岩体形成时代（254.2±0.95 Ma、230.44±0.54 Ma）稍晚或接近.石英中H、O同位素特征显示成矿流体应为晚二叠世花岗岩浆分异出的热液，后期有少量的大气降水的加入，暗示了含矿石英脉与赋矿花岗岩体具有密切的成因联系.综合认为，成岩成矿可能发生在同一地质事件中，即与古亚洲洋板块向佳蒙地块俯冲作用有关. 相似文献
4.
选取了碧大群铜矿床中筏子坝、阳坝和大茅坪三个黄铜矿矿脉中的黄铜矿物样品，通过大量的条件实验及方法研究，用溶解法获取了黄铜矿中的液态包裹体中流体并得出了与实际地质背景一致的Rb-Sr等时线年龄，建立了黄铜矿中液态包裹体Rb-Sr同位素定年的分析方法。 相似文献
5.
微区-微量样品Rb-Sr同位素分析技术及其应用前景 总被引：1，自引：0，他引：1
利用微钻取样技术和微量样品Rb-Sr同位素分析方法,本文对出露在东秦岭造山带的中生代合峪花岗岩的自形钾长石巨晶进行微区-微量样品Rb-Sr同位素组成分析。分析结果表明,钾长石斑晶具有显著的Rb/Sr比值和Sr同位素组成变化,斑晶和基质钾长石均构成年龄为132~133Ma的Rb-Sr等时线,代表岩浆的后期冷却时代。钾长石晶体的初始87Sr/86Sr比值由边缘相到中心相没有明显的变化,代表花岗质岩浆结晶阶段的Sr同位素组成,暗示合峪花岗岩的钾长石巨晶为原生成因。以高空间分辨率为特征,微区取样技术已经广泛地应用在变质岩和深成岩浆岩的同位素年代学和成因研究。结合微量样品同位素分析技术,微区-微量样品Rb-Sr同位素方法有望在火山岩的成因和年代学方面得到应用。 相似文献
6.
安徽月山石英闪长岩氧同位素分馏、Rb-Sr等时线定年与矿物蚀变之间的关系 总被引：7，自引：3，他引：7
受热液蚀变影响的侵入岩能否给出合理的矿物Rb-Sr等时线年龄是同位素年代学研究的一个重要课题。对月山岩体中的一个石英闪长岩样品进行了研究,对蚀变程度不同的矿物进行了氧同位素分析以及Rb-Sr等时线定年。各未蚀变矿物与石英构成的矿物对氧同位素表观温度的大小为:石英-角闪石对(470±15℃)>石英-黑云母对(340±10℃)>石英-斜长石对(265±20℃),表明了岩石在冷却过程中的氧同位素退化平衡。与此相应,3个未蚀变矿物(黑云母,角闪石,斜长石)的Rb-Sr等时线年龄为137.6±1.2Ma(MSWD=0.07),等时线的线性非常好,且与前人得到的Ar-Ar年龄在误差范围内一致。而石英-蚀变黑云母对的氧同位素表观温度(310±10℃)和石英-蚀变钭长石对的表观温度(325±25℃)与相应石英-未蚀变矿物对的相比,发生了显著改变,表明这两种矿物的氧同位素体系在蚀变过程中受到了扰动。但是未蚀变和蚀变共6个矿物的Rb-Sr等时线年龄为136.81±0.77Ma(MSWD=0.81),此等时线的线性也很好,且年龄与未蚀变矿物的在误差范围内一致。由于蚀变的影响,蚀变黑云母和斜长石的Rb、Sr含量和Sr同位素比值都发生了变化,但是蚀变矿物的~(87)Rb/~(86)Sr和~(87)Sr/~(86)Sr比值沿着等时线移动,因此等时线年龄不变,指示了蚀变时相当于全岩成分的内部流体与矿物之间的同位素交换。这表明受内部流体影响使花岗岩发生低温热液蚀变时,即使氧同位素体系受到扰动,Rb-Sr等时线仍可以有地质意义。 相似文献
7.
大义山矿田处于华南褶皱带南岭成矿带中段北缘,位于阳明山－大义山－上堡东西向基底断裂、攸县－宁远北东向基底断裂和郴州－邵阳北西向隐伏深断裂带的交汇部位,主要受大义山岩体控制,其中云英岩脉型锡矿为该矿田典型的成矿类型之一.对该矿田白沙子岭锡矿床云英岩脉型锡矿脉中的石英进行了流体包裹体Rb-Sr同位素测年及其地质意义的讨论.结果显示,矿脉中石英流体包裹体Rb-Sr同位素等时线年龄为160±1 Ma,属于南岭地区中生代160~150 Ma时段成矿高峰期产物;成矿与大义山岩体中侏罗世二长花岗岩具有密切的时间、空间和成因联系,为该期岩浆晚期热液成矿作用的产物;流体包裹体Rb-Sr同位素87Sr/86Sr初始比值为0.706 79±0.003 66,预示其成矿流体有幔源物质的参与,具有地壳和地幔混合流体的特征. 相似文献
8.
白云鄂博矿床白云岩的Sm—Nd、Rb—Sr同位素体系 总被引：17，自引：4，他引：17
白云鄂博矿床的年龄和成因长期争论.本文报道了白云鄂博矿床白云岩及其组成矿物的Sm-Nd、Rb-Sr同位素分析结果.采自该矿床主、东矿等地的15个白云岩样品的Sm-Nd同位素分析结果呈现一条等时线,等时年龄1273±100(2σ)Ma,INd=0.510919士36(2d),MSWD1.01.全岩Rb-Sr同位素分析结果分散,不构成等时线.87Rb/86Sr0～2.092×100-2,87Sr/86Sr0.70341～0.70541.白云岩矿物的Sm-Nd同位素分析结果给予了与全岩类似的Sm-Nd等时年龄,t=1250士210(2σ)Ma,1Nd=0.510914±77(2σ),MSWD
0.56.白云鄂博矿床可能是中元古代末期大离子亲石微量元素略为富集地幔源区部分熔融岩浆活动产物. 相似文献
9.
10.
滇西金满铜矿床成矿年龄测定 总被引：11，自引：1，他引：11
采用石英流体包裹体Rb Sr等时线法和磷灰石裂变径迹法对滇西金满铜矿床的成矿时代进行测定。研究结果表明燕山晚期为金满矿床的初始成矿期 ,喜山期是主要成矿时期 ;流体包裹体的Rb Sr法和裂变径迹法测定热液矿床的成矿年龄具有一定的意义 ,但需进一步探讨 ;锶同位素数据为成矿流体来源提供了进一步的证据 相似文献
11.
David Alan Spears 《Geochimica et cosmochimica acta》1974,38(2):235-244
The RbSr age dating method has been applied to a sequence of Carboniferous shales for which some geochemical information was already available. In the marine shales, the Rb/Sr ratio is higher than in the non-marine and brackish water shales. Although the range of values can be attributed to depositional processes, the range of Rb/Sr values is too small to give a depositional isochron, and thus the age of deposition can not be determined. If samples with a variable mineralogy had been selected for the isotope study, the range of Rb/Sr could have been extended. Only by chance, however, would the depositional age have been obtained.A comparison of the RbSr isotope values in the Carboniferous shales with those in probable source rocks shows that a reduction in the Sr87/Sr86 ratio relative to the Rb87/Sr86 ratio may have taken place. Such a reduction could have occurred on the Carboniferous land-mass during the formation of the clay minerals. 相似文献
12.
高Rb/Sr岩石样品中Sr同位素多接收等离子体质谱分析校正方法研究 总被引：1，自引：1，他引：0
在利用多接收电感耦合等离子体质谱(MC-ICPMS)进行Sr同位素研究中,87Rb对于87Sr干扰严重。岩石样品经化学分离后,若Rb/Sr≤0.0005,可以采用传统的Rb干扰扣除方法对87Sr/86Sr测定值进行准确校正;但如果样品经化学分离后仍含有较高的Rb/Sr比,同量异位素的干扰不能完全消除,则无法准确校正87Sr/86Sr测定值,直接影响测试结果的准确度。本文针对Rb含量较高的地质样品设计两组实验,确定了87Sr/86Sr同位素比值与Rb/Sr元素含量比值的关系曲线,并在理论分析的基础上,提出包含同位素分馏校正在内的重叠干扰校正方法。通过实际地质样品验证,该校正方法在较高含量Rb元素共存(Rb/Sr<0.2)的Sr纯化液中,能够较为准确地测量87Sr/86Sr同位素比值,降低了MC-ICPMS分析地质样品中Sr同位素时对化学分离步骤的要求。而对于Rb/Sr>0.2的地质样品,因仪器分馏效应和记忆效应影响,测试精确度大大降低,无论采用何种校正方法均无法得到准确的Sr同位素组成。 相似文献
13.
The Rb/Sr ratios of magmas increase significantly during fractionalcrystallization. Hence, the rate of change of the 87Sr/86Srratio in successive residual liquids increases as crystallizationproceeds. In slowly solidifying igneous complexes the totalchange in 87Sr/86Sr ratio exceeds analytical uncertainty andis manifested in several ways. Whole rock 87Rb/86Sr versus 87Sr/86Sr plots for an entire complexwill produce errorchrons, which may be improved by consideringsmall subsets of the complex. These subsets will show a generalincrease in initial 87Sr/86Sr with increasing average Rb/Srratio. Thus, quenched liquids, mineral ages and fractionatedcumulates from the same complex can show different ages andinitial 87Sr/86Sr ratios. The Murrumbidgee granitoid complex shows parallel isochronsfor geochemically controlled subsets which give an age co-incidentwith the metamorphic aureole while an isochron for the entirecomplex gives an unrealistically old age. Quenched liquids inthe Rosses granitic complex are apparently younger than theirassociated crystal accumulates using conventional isochron interpretations,but this can be reconciled within the magmatic ageing model.Increasing initial 87Sr/86Sr ratios with height within the BushveldComplex need not be due to several independent magmas but resultfrom slow cooling of two magmas having the same initial ratio. 相似文献
14.
中亚盆地钾盐矿床的形成时代目前被限定为晚侏罗世至早白垩世,较为宽泛。盐类矿物沉积之后若未被改造,可测定其形成时代;若被改造则可利用同位素测年研究其沉积后作用。为了得到中亚盆地钾盐矿床的形成时代和/或了解盐类矿物受到的后期改造过程,利用Rb-Sr同位素定年对矿床中的盐类矿物进行了测定。结果表明,无法形成可靠的Rb-Sr等时线,说明钾盐矿床中盐类矿物在形成以后Rb-Sr体系并未保持封闭;钾盐样品模式年龄介于9～4 Ma之间,岩盐样品模式年龄约为190～170 Ma。岩盐Rb含量低,积累的放射性87Sr较少,而钾盐Rb含量高,积累的放射性87Sr较多。后期受到外来流体或者光卤石结合水的作用,盐类矿物发生溶解,重结晶后造成岩盐中87Sr/86Sr值升高而钾盐87Sr/86Sr值降低。结合世界上其它钾盐矿床的Rb-Sr测年结果,认为盐类矿物并不适合研究其成矿时代,但可用来揭示钾盐盆地的变质作用过程和水文演化历史。 相似文献
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16.
河北平原地下水锶同位素形成机理 总被引：5，自引：0，他引：5
为了研究河北平原地下水锶同位素的来源与形成机理, 对所采水样进行了分析.研究了87Sr/86Sr比值“时间积累效应”: 随着地下水年龄和埋深的增大而增大; 与地下水中过剩4Heexc呈正相关关系, 与δ18O和δD呈负相关关系.探讨了Sr2+与87Sr/86Sr比值的关系, 将地下水分为3类: (1) 中等Sr2+含量与高87Sr/86Sr比值水(Ⅰ类水); (2) 低Sr2+含量与高87Sr/86Sr比值水(Ⅱ类水); (3) 高Sr2+含量与低87Sr/86Sr比值水(Ⅲ类水), 即热水.通过综合分析认为: (1) 河北平原第四系地下水中的放射成因Sr是由富含Na和Rb的硅酸盐矿物风化作用提供的, 主要矿物为斜长石; (2) 黄骅港热水中的放射成因Sr是由碳酸盐溶解形成的, 87Sr/86Sr比值低, Sr/Na比值大; (3) 补给区地下水是由流经火成岩和变质岩区地下水的侧向补给的, 87Sr/86Sr比值中等.第三系地下水放射成因Sr的来源及形成机理尚须进一步研究. 相似文献
17.
西藏南部晚白垩世厚壳蛤的锶同位素年龄标定 总被引：11，自引：0，他引：11
沉积岩样品年龄的直接标定是沉积学与地层学研究的难点之一.由于锶在海水中的残留时间(≈106a) 大大长于海水的混合时间(≈103a), 因而同一时间全球海水的锶元素在同位素组成上是均一的, 并造成地质历史中海水的锶同位素组成是时间的函数, 这是锶同位素地层学(SIS) 的基本原理和利用锶同位素地层学进行海相地层定年的理论基础.本文根据锶同位素地层学的基本原理, 测试了西藏南部岗巴剖面上白垩统宗山组上段地层中厚壳蛤化石的锶同位素组成, 尝试对这些化石进行了年龄标定, 4个样品分别位于剖面累计厚度381, 362, 358和296m处, 其87Sr/86Sr比值分别为0.707832, 0.707769, 0.707768和0.707695, 年龄的标定结果分别是65.68, 69.34, 69.39和72.32Ma, 定年的平均误差为±1Ma左右.研究结果表明, 锶同位素地层学在海相地层定年方面具有潜在价值. 相似文献
18.
Jean M. Richardson John Blenkinsop Keith Bell 《Contributions to Mineralogy and Petrology》1990,104(5):516-529
Magmato-hydrothermal cassiterite-topaz ore at the Carboniferous East Kemptville (EK) greisenhosted tin deposit (Nova Scotia, Canada) is cross-cut by veins containing apatite, triplite, vivianite and fluorite. Initial 87Sr/86Sr ratios of these minerals have an extreme range (0.7135 to 0.8284). The initial ratios of the host rocks, EK quartz-topaz rock and Davis Lake biotite monzogranite (0.729±0.001, 0.727±0.004), are also high. The adjacent Meguma Group metasedimentary rocks are more typical of crustal material (0.712–0.719 at 330 Ma). Rb and Sr contents of EK fluorite (max.: 13.0, 1420 ppm) and apatite (max.: 88.1, 6660 ppm) are unusually high and variable. Unexpectedly, high Sr contents correlate positively with the high initial 87Sr/86Sr ratios. Fluorite and phosphate minerals from the first set of post-greisen veins at East Kemptville reflect the unusual chemistry of a high 87Sr/86Sr fluid present in the deposit after ore formation. The most extreme composition of this fluid was characterized by 87Sr/86Sr>0.8284, high Rb/Sr, high P, Rb, Cu, Zn and Fe contents, but low abundances of Ca, Pb and Sn with respect to the Davis Lake monzogranite. Such a fluid could have been derived from the greisen fluid and modified by reaction with the overlying Meguma metawacke. A second alternative, which cannot be well constrained at present, is that an extremely radiogenic fluid entered the deposit after ore formation and mixed with the postore fluid. In either case, the modified fluid subsequently mixed with meteoric water and precipitated the minerals with much lower 87Sr/86Sr ratios and Rb and Sr contents. 相似文献
19.
John C. Butler 《Lithos》1982,15(3):207-214
The rubidium-strontium isochron procedure has proven to be a powerful tool in many geochemical studies. An isochron is said to exist if a plot of (87Sr/86Sr) versus (87Rb/86Sr) produces a linear trend with a large correlation coefficient. However, the variables selected to portray the isochron have the same denominator (86Sr) and Pearson long ago noted that a large correlation could be induced when such ratios are formed from uncorrelated numerators and denominators. A set of numerical experiments are described that illustrate the common denominator effects as applied specifically to rubidium-strontium systematics. For at least one previously published RbSr isochron it can be shown that the common denominator effect is capable of producing a correlation coefficient that is very nearly 1.000. However, it is also shown that, for the data sets analyzed, the common denominator effect can not produce a geologically meaningful isochron. The numerical approach to assessing the common denominator effect can be applied only to those sets of isotopic analyses in which 87Rb and 86Sr have been determined by isotope dilution techniques. For the many data sets in which only the ratios (87Sr/86Sr) and (87Rb/86Sr) have been determined the common denominator effect can neither be assessed nor dismissed as trivial. 相似文献
20.
Rb‐Sr and K‐Ar measurements have been made on five glauconite samples from the near basal Treuer Member of the Vaughan Springs Quartzite of the Ngalia Basin, Northern Territory, Australia. Comparison of results between and within the two groups of data demonstrates that variable losses of radiogenic strontium and argon have occurred, but allows a minimum age of 1280 m.y. to be calculated for the member. Sedimentation began in the Ngalia Basin shortly before the time of deposition of this member. Regional correlations suggest that this minimum age applies to the adjacent Amadeus Basin as well. Measurements were also made on glauconite from a single sample of the Lower Palaeozoic Djagamara Formation which is in the same sequence. It yields a mid‐Ordovician K‐Ar age which generally agrees with the broad range of post‐Lower Cambrian to pre‐Carboniferous age determined from fossil evidence in bounding formations. A low Rb/Sr ratio prevented calculation of a Rb‐Sr age, but the combination of K‐Ar age and Rb‐Sr measurements allowed an accurate initial 87Sr/86Sr ratio of .739 to be determined. This is much greater than ocean water values, and it appears that such information on young samples and/or those of low Rb/Sr ratio could help define the source material for glauconite formation. 相似文献