共查询到20条相似文献，搜索用时 15 毫秒
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徐有生 《矿物岩石地球化学通报》1997,(4)
高温高压下水和氯化钠溶液的物理化学性质研究徐有生（中国科学院地球化学研究所，贵阳５５０００２）关键词高温高压水和ＮａＣｌ溶液物理化学性质水和ＮａＣｌ溶液是地质上最常见的溶液，了解其物理化学性质有助于研究水溶液在地球内部各种地质作用和地质过程中所起的作... 相似文献
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《地学前缘(英文版)》2022,13(2):101342
Hydrous minerals within the subducting oceanic slab are important hosts for water. Clarification of the stability field of hydrous minerals helps to understand transport and distribution of water from the surface to the Earth’s interior. We investigated the stability of brucite, a prototype of hydrous minerals, by means of electrical conductivity measurements in both open and closed systems at 3 GPa and temperatures up to 1300 K. Dramatic increase of conductivity in association with characteristic impedance spectra suggests that partial dehydration of single-crystal brucite in the open system with a low water fugacity occurs at 950 K, which is about 300 K lower than those previously defined by phase equilibrium experiments in the closed system. By contrast, brucite completely dehydrates at 1300 K in the closed system, consistent with previous studies. Partial dehydration may generate a highly defective structure but does not lead to the breakdown of brucite to periclase and water immediately. Water activity plays a key role in the stability of hydrous minerals. Low water activity (aH2O) caused by the high wetting behavior of the subducted oceanic slab at the transition zone depth may cause the partial dehydration of the dense hydrous magnesium silicates (DHMSs), which significantly reduces the temperature stability of DHMS (this mechanism has been confirmed by previous study on super hydrous phase B). As a result, the transition zone may serve as a ‘dead zone’ for DHMSs, and most water will be stored in wadsleyite and ringwoodite in the transition zone. 相似文献
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蛇纹石脱水与大洋俯冲带中源地震(70~300km)的关系 总被引：4，自引：2，他引：4
蛇纹石脱水致裂作用是诱发大洋俯冲带中源地震(70~300km)的一种重要成因机制,它与中等深度双地震带的形成有很密切的关系。双地震带在冷俯冲带中是一种常见现象,它由上下相距20~40km的两个平行地震层组成。上地震层位于俯冲洋壳中,可能是洋壳蓝片岩脱水形成榴辉岩的系列脱水反应诱发了地震;下地震层位于大洋俯冲地幔中,可能是部分交代的地幔橄榄岩脱水控制着中源地震的分布。蛇纹岩在高温高压条件下的变形实验证实蛇纹石在脱水过程中引起岩石弱化和脆性破裂,这已经得到了对蛇纹石脱水过程中岩石物理性质和变形后样品的显微构造等理论研究上的支持。在蛇纹石脱水过程中,产生的流体与固体残留物分离,形成了大量的I型(张性)微裂隙,最终导致岩石破裂和形成断层。根据叶蛇纹石脱水反应相图,理论上在大洋俯冲带中蛇纹石脱水位置会出现双层结构,但只有平行于俯冲板块顶层等温线的一支才可能脱水诱发地震,并对应于双地震带的下地震层。下地震层所处的位置具有低的vp/vs值,暗示岩石圈大洋地幔顶层发生了部分交代。但它的交代机制尚不清楚,可能是海水通过洋底转换断层和/或沿着在外海沟隆起中形成的断层渗入大洋地幔顶层,并发生了洋壳和大洋地幔交代。双地震带在120~200km深度合一以后,冷俯冲带中所发生的中源地震可能与蛇纹石脱水有关,在热俯冲带中更可能与“湿”榴辉岩脱水有关。 相似文献
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Youjun Zhang Toshimori Sekine Yin Yu Hongliang He Chuanmin Meng Fusheng Liu Mingjian Zhang 《Physics and Chemistry of Minerals》2014,41(5):313-322
Antigorite is one kind of hydrous serpentine that is present in meteorites and in the Earth mantle. In order to understand its dynamic behaviors, metastability and decomposition, shock experiments on antigorite have been conducted using a two-stage gas gun, and wave profiles of particle velocities have been measured to obtain the Hugoniot up to ~130 GPa and sound velocity at high pressures. The results show three regions of low-pressure phase below ~43 GPa and its metastable extension above a pressure of ~43 GPa for short durations of shock and high-pressure phase(s) above a pressure of ~43 GPa for long durations of shock. The dynamic behaviors of antigorite depend on not only the pressure but also the compression duration. Metastable extension state indicates that antigorite may survive beyond the stability depending on the shock conditions. Shock temperatures for antigorite are calculated along the Hugoniot. The pressure–density, sound velocity–pressure and shock temperature–pressure plots demonstrate that the decomposition reaction of antigorite into high-pressure phase(s) is accompanied by a volume expansion, sound velocity increase and temperature decrease, relative to the metastable extension phase above ~43 GPa. The decomposition should be sluggish and needs enough reaction time to complete and to overcome the activation energy. As a result of the high metastability of antigorite and possible decomposition assemblages, the hydrous serpentine (antigorite) may play a crucial role for the origin of water during the Earth accretion. 相似文献
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The electric conductivity of gabbro has been measured at 1.0 - 2.0 GPa and 320-700℃, and the conduction mechanism has been analyzed in terms of the impedance spectra.Experimental results indicated that the electric conductivity depends on the frequency of alternative current. Impedance arcs representing the conduction mechanism of grain interiors are displayed in the complex impedance plane, and the mechanism is dominated at high pressure.These arcs occur over the range of 102 - k× 105 Hz (k is the positive integer from 1 to 9). On the basis of our results and previous work, it is concluded that gabbro cannot form any high conductivity layer (HCL) in the middle-lower crust. 相似文献
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With lamprophyre and pyrite from the Laowangzhai gold deposit, Yunnan Province, China, as starting materials, and at pressures from 1.5 to 3.0 GPa and temperatures from 1160 to 1560℃ , an experimental study was carried out on the liquid immiscibility of lamprophyre-sulfide melt at high temperature and ultra-high pressure in the DS-29A cubic 3600T/6-type high pressure apparatus. Results showed that the liquid immiscibility of lampro-pyre-sulfide melt in the magmatic system would happen during the early magma... 相似文献
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高温高压实验作为地球科学研究的重要方向之一,通过模拟地球深部的温度和压力条件,了解地球深部物质的物理化学性质、地球内部结构和动力学演化。角闪石属于双链硅酸盐矿物,为地幔岩石圈的重要组成,广泛分布在海洋地壳、俯冲板块、变质岩和火成岩中。作为俯冲带的重要含水矿物,角闪石的广泛分布和高温高压下的脱水对于理解俯冲带水含量以及水迁移具有重要作用,同时在俯冲带的地震活动、高电导率异常、地震波速异常和岩浆活动中扮演重要角色。在过去的近百年时间里,国内外学者对角闪石高温高压物理化学性质进行了大量的研究。角闪石具有非常复杂的元素组成和结构特征,由此也导致了不同角闪石物理化学性质存在显著不同,包括脱水与脱羟基反应中元素迁移的差异、角闪石形成与分解过程中碱性元素(K+Na)和H2O含量对热稳定的影响、不同空间群结构下的高压结构相变、原位条件下不同结晶方向的电导率异常、不同结晶学优选方位(CPO)下的波速异常等。已有的研究对于角闪石的物理化学性质以及其在俯冲带中发挥的作用有了比较清楚的认识,但仍然有许多问题需要进一步研究,如角闪石的高压脱水动力学、热物性和变形机制等。 相似文献
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在YJ3000t高压装置上,利用超声波脉冲透射-反射法测量恒压0.6GPa,1.0GPa和2.0GPa,室温至1 195℃条件下斜长角闪岩的纵波波速(Vp),统计了实验中间产物中各组分的体积百分含量和熔体形态(二面角),并根据主要矿物含量和弹性参数,利用VRH平均模型计算了高温高压下斜长角闪岩的Vp。结果显示,不同压力下,样品的Vp随温度升高首先缓慢降低,在温度达约850℃～950℃时转而快速下降。实验产物观测显示,随温度升高熔体含量显著增加,二面角不断减小,熔体由封闭囊状演变为连通薄膜,部分熔融是导致岩石Vp快速降低的主要因素。高温高压下Vp计算结果与测量结果有相同的Vp-T变化趋势,其对比研究表明,岩石初始熔融时,熔体尚未连通,此时熔体含量控制着岩石Vp的降低。部分熔融加剧导致熔体逐渐连通,此时不同压力下熔体导致Vp下降有差异,这可能与熔体连通过程中熔体薄膜的形态因子变化有关。 相似文献
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本文应用金刚石压腔装置结合拉曼光谱分析技术原位观测了高温高压条件下水镁石的结构变化特征。结果表明：常温升至300℃过程中,随温度升高,水镁石中表征H-O对称伸缩振动的3652 cm-1拉曼特征峰向低波数移动,拉曼特征峰波数与对应的体系温度呈现良好的线性相关关系。常温条件下体系加压过程中,当压力升高至1.19 GPa时,水镁石中表征H-O振动的3652 cm-1拉曼峰向高波数移动并逐渐消失,同时产生表征方镁石的1078 cm-1拉曼特征峰,表明水镁石脱水相变为方镁石。随后压力降低过程中,表征水镁石H-O振动的3652 cm-1拉曼特征峰没有重新出现,脱水相变过程不可逆。 相似文献
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Eiji Ohtani Naohisa Hirao Tadashi Kondo Masayoshi Ito Takumi Kikegawa 《Physics and Chemistry of Minerals》2005,32(1):77-82
We observed a direct reaction of metallic iron with water to form iron hydride and iron oxide, 3Fe + H2O–>2FeHx + FeO, at pressures from 6 GPa to 84 GPa and temperatures above 1,000 K in diamond anvil cell (DAC). Iron hydride is dhcpFeHx or -FeHx, and iron oxide has the rhombohedral or B1 structure at pressures at least up to 37 GPa. The formation of an assembly composed of dhcpFeHx and FeO with the B8 structure was observed at 84 GPa. In primordial Earth, water formed by dehydration of the low temperature primitive materials reacts with metallic iron in the high temperature component to form iron hydride FeHx and iron oxide FeO. The former would be incorporated in the iron forming the core. Thus hydrogen could be an important element of the Earths core. This reaction would be essential for transport of hydrogen into the core in the accretion stage of the Earth. 相似文献
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Water is the most active component in all geological systems.It has an important effect on the physical properties of minerals and melts.It also plays a key role in the evolution of the Earth.Accurate thermodynamics data on water are currently confined to pressures below 1.0GPa and temperatures below 900℃.Presented in this paper are new data available on the P-T properties of water at pressures up to 5.0GPa,develoged from differential thermal analysis and ultrasonic wave amplitude analysis.It has been found that there may exist another ternary point at 3.0GPa and that ultrasonic wave amplitude change of ice-water transition shows two inflection points above 2.0GPa, consistent with the two peaks of differential thermal curves above 2.0GPa .It may be a new phenomenon which needs further study. 相似文献
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Dehydration melting of a basaltic composition amphibolite at 1.5 and 2.0 GPa: implications for the origin of adakites 总被引：50，自引：0，他引：50
This study presents the results of dehydration melting experiments on a basaltic composition amphibolite under conditions appropriate to a hot slab geotherm (1.5 and 2.0 GPa and temperatures of 850 to 1150° C). Dehydration melting produces an omphacitic augite and garnet bearing residue coexisting with rhyolitic to andesitic composition melts. At 1.5 GPa, the amphibolite melts in two stages between 800 and 1025° C. The 2.0 GPa data also define two melting stages. At 2.0 GPa, the first stage involves nearly modal melting of the original amphibolite minerals (qtz, pl, amp) to produce melt + cpx + grt. During the second stage, the eclogite restite melts non-modally (0.86 cpx + 0.14 grt = 1 melt). The experimental results were combined with data from the literature to generate a composite P-T phase diagram for basaltic composition amphibolites over the 800 to 1100° C temperature range for pressures up to 2.0 GPa. Comparison of the major element compositions of the experimentally produced melts with compositions of presumed slab melts (adakites) shows that partial melting of amphibolite at conditions appropriate to a hot-slab geotherm produces melts similar to andesitic and dacitic adakites except for significant MgO and CaO depletions. Trace element modelling of amphibolite dehydration melting using the 2.0 GPa melting reactions produces REE abundances similar to those of adakites at 10–15 wt% batch melting, but the models do not reproduce the high Sr/Y ratios characteristic of adakites. Taken together, the major and trace element results are not consistent with the derivation of adakites by dehydration melting of the subducted slab with little or no interaction with the mantle wedge or crust. If adakites are partial melts of the subducted slab, they must undergo significant interaction with the mantle and/or crust, during which they acquire a number of their distinctive characteristics. 相似文献
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Huaiwei Ni Hans Keppler M. A. G. M. Manthilake Tomoo Katsura 《Contributions to Mineralogy and Petrology》2011,162(3):501-513
We report the first study of electrical conductivities of silicate melts at very high pressures (up to 10 GPa) and temperatures
(up to 2,173 K). Impedance spectroscopy was applied to dry and hydrous albite (NaAlSi3O8) glasses and liquids (with 0.02–5.7 wt% H2O) at 473–1,773 K and 0.9–1.8 GPa in a piston-cylinder apparatus, using a coaxial cylindrical setup. Measurements were also
taken at 473–2,173 K and 6–10 GPa in two multianvil presses, using simple plate geometry. The electrical conductivity of albite
melts is found to increase with temperature and water content but to decrease with pressure. However, at 6 GPa, conductivity
increases rapidly with temperature above 1,773 K, so that at temperatures beyond 2,200 K, conductivity may actually increase
with pressure. Moreover, the effect of water in enhancing conductivity appears to be more pronounced at 6 GPa than at 1.8 GPa.
These observations suggest that smaller fractions of partial melt than previously assumed may be sufficient to explain anomalously
high conductivities, such as in the asthenosphere. For dry melt at 1.8 GPa, the activation energy at T > 1,073 K is higher than that at T < 1,073 K, and the inflection point coincides with the rheological glass transition. Upon heating at 6–10 GPa, dry albite
glass often shows a conductivity depression starting from ~1,173 K (due to crystallization), followed by rapid conductivity
enhancement when temperature approaches the albite liquidus. For hydrous melts at 0.9–1.8 GPa, the activation energies for
conductivity at ≥1,373 K are lower than those at <973 K, with a complex transition pattern in between. Electrical conductivity
and previously reported Na diffusivity in albite melt are consistent with the Nernst–Einstein relation, suggesting the dominance
of Na transport for electrical conduction in albite melts. 相似文献
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Zheng Haifei Xie Hongsen Xu Yousheng Song Maoshuang Zhang Yueming Wang Mingzai Xu Huigang Department of Geology Peking University Beijing Institute of Geochemistry Chinese Academy of Sciences Guiyang Guizhou 《《地质学报》英文版》1996,70(2):157-167
The experimental study on the melting of potassic basalt and eclogite with about 2% waterat 800-1300℃ and 1.0-3.5 GPa shows that the solidi of both rocks are significantly lower thanthose obtained from the previous experiments of the same type of rocks under dry conditions,and the former which is enriched in potassium has a lower melting point than the latter. It is con-sistent with the previous study. The melting temperature of eclogite increases with pressure,whereas potassic basalt has similar properties only at 1.5—2.5 GPa and>3.0 GPa, and at 2.5—3.0 GPa the melting temperature decreases with pressure. This can be explained as follows: (1)eclogite only has one hydrous mineral amphibole and the dehydous temperature is lower than thewet solidus of the rock. (2) Amphibole exists in potassic basalt at the pressures lower than 2.5GPa and phlogopite exists at pressures higher than 2.5 GPa, and the special compositions of bothminerals determine that amphibole has a dehydration temperature higher than or close to that ofthe wet solidus of the rocks, while phlogopite has a dehydration temperature lower than that ofthe wet solidus. On the other hand the features of the continuous solidus in the experiment ofhydrous eclogite were produced by the fact that the dehydration temperature of its amphibolelower than or close to the melting temperature of the hydrous conditions. So the melting tempera-ture lowers at higher pressures. Therefore, the composition of the rocks in the lithosphere and thetypes of hydrous minerals and their stable P-T conditions are the important factors controllingthe solidi of rocks. It can quite well explain the partial melting of rocks and the origin of the lowvelocity zone in the deep lithosphere. 相似文献
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高温超高压模拟实验研究--Ⅱ.高温高压下烷烃产物的演化特征 总被引：17，自引：1，他引：16
对不成熟泥炭样品进行了高压（0.1～2 GPa) 、高温( 200 ℃～400 ℃）模拟实验,并对实验后样品的烷烃产物进行了分析。结果显示,同一压力条件下,温度升高,烷烃参数表现出更成熟的特征;温度较低时（200 ℃）,压力升高,烷烃参数表现出不成熟,温度较高时（400 ℃）,除个别特殊点之外,压力增大,烷烃参数愈来愈不成熟,说明温压条件都是影响有机质成熟的重要因素,压力的存在会抑制有机质的成熟作用。用模拟实验手段来探讨压力的作用和影响,具有重要的理论及实际意义。 相似文献
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Electrical conductivity of talc was measured at 0.5 GPa and ~473 to ~1,300 K by using impedance spectroscopy both before and after dehydration. Before dehydration, the electrical conductivity of talc increased with temperature and is ~10?4 S/m at 1,078 K. After dehydration, most of the talc changed to a mixture of enstatite and quartz and the total water content is reduced by a factor 6 or more. Despite this large reduction in the total water content, the electrical conductivity increased. The activation enthalpy of electrical conductivity (~125 kJ/mol) is too large for the conduction by free water but is consistent with conduction by small polaron. Our results show that a majority of hydrogen atoms in talc do not enhance electrical conductivity, implying the low mobility of the hydrogen atoms in talc. The observed small increase in conductivity after dehydration may be attributed to the increase in oxygen fugacity that enhances conductivity due to small polaron. 相似文献
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实验岩石学对埃达克岩成因的限定——兼论中国东部富钾高Sr/Y比值花岗岩类 总被引：15，自引：0，他引：15
大量变玄武岩脱水熔融实验表明,制约埃达克岩形成的主要因素是源岩、水和地壳热结构(p-T轨迹)。变玄武岩低到中等程度(10％～40％)的部分熔融过程中,含水矿物(主要是角闪石)脱水反应产生埃达克岩熔体,残余相组合为石榴石+单斜辉石±斜方辉石±角闪石(没有斜长石)。在俯冲带,当压力为1.6～2.2 GPa(约70～90 km)和温度为800～1150℃时,具有高的剪切热速率和非常年轻的(<25 Ma)、热的俯冲大洋岩石圈就会发生脱水熔融形成埃达克熔体。在增厚地壳内,具有高的热状态的底侵玄武质下地壳在压力≥0.8 GPa(>35 km)和温度介于800～1100℃之间发生部分熔融形成埃达克质熔体。然而,中国东部晚中生代富钾高Sr/Y比值花岗岩类,可能形成于加厚地壳开始减薄及地壳从挤压向拉张伸展转换的环境下,所对应的岩浆,与下地壳底侵的碱性玄武岩和/或拉斑玄武岩在压力1.0～1.5 GPa和温度850～1080℃之间发生部分熔融有关,熔融的残余相为辉石岩类,岩浆在上升侵位过程中还受到了地壳AFC的影响。中国东部中生代岩石圈从加厚转变为减薄的过程,就可能与玄武质岩浆的底侵作用及随后含石榴石辉石岩类残余体的拆沉作用有关。 相似文献