共查询到20条相似文献，搜索用时 15 毫秒
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设计合成一种尚未见文献报道的酚醚型双臂开链冠醚化合物L(L=2,6-二(8’-喹啉氧甲基)-4-甲基-苯甲醚)，经元素分析、IR、1HNMR、MS等方法确定了其组成和结构。其Ag(Ⅰ)、Cu(Ⅱ)、Ni(Ⅱ)固体配合物的元素分析结果表明金属离子不同，则其配合物的配位比(M∶L)不同，Ag(Ⅰ)配合物为1∶1，Cu(Ⅱ)、Ni(Ⅱ)配合物为2∶3。并运用热重-差热分析对其热稳定性进行初步研究。 相似文献
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Alterations to nomenclature for two common intertidal New Zealand ‘top shells’ necessitated by re‐examination of type material have been confused by ambiguities in the way the alterations were first presented. We draw attention to recent misinterpretations and clarify the nomenclature. Condensed synonymies that indicate names used for each species during the interregnum are given, allowing papers dealing with these trochids to be read without uncertainty as to which species were really meant by the authors. 相似文献
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Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins 总被引：1，自引：0，他引：1
Raffaela Biesuz Giancarla Alberti Girolamo D'Agostino Emanuele Magi Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189
The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log αM(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 1020 M− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log αM(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations. 相似文献
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The aim of this study was to investigate nitrogen and phosphorus released in the process of the decomposition of giant jellyfish in the laboratory and found the evidence to verify the influence of nutrients released by the decomposition of jellyfish on the ecosystem in the field. The release of nitrogen and phosphorus from the decomposition of Nemopilema nomurai was examined in a series of experiments under different incubation conditions such as different p H values, salinity values, temperatures and nitrogen and phosphorus concentrations. The results showed that the complete decomposition of Nemopilema nomurai generally took about 4–8 d. The release of nitrogen and phosphorus from the decomposition of Nemopilema nomurai could be divided into two stages: the early stage and the later stage, although the efflux rate of nitrogen was one order more than phosphorus. In the early stage of the decomposition of Nemopilema nomurai, the concentrations of dissolved nitrogen, dissolved phosphorus, total nitrogen and total phosphorus in seawater increased rapidly, and the concentration of nitrogen could reach the highest level in the whole degradation process. In the later stage of the decomposition, the concentrations of dissolved nitrogen and total nitrogen declined slowly, while the concentration of phosphorus in water could reach a maximum in the degradation process. High p H, low salinity,high temperature and N/P will promote the release of nitrogen; low p H is unfavorable to the release of nitrogen but favorable to the release of phosphorus. In addition, we found the concentrations of ammonium and phosphate in the bottom water were higher than those in the surface water during the period of jellyfish bloom in the Jiaozhou Bay, proving that nutrients released by the decomposition of jellyfish have significant influence on nitrogen and phosphorus in the field. For the whole Yellow Sea, nutrients released by jellyfish carcasses may reach up to(2.63±2.98)×107 mol/d of dissolved nitrogen(DN) and(0.74±0.84)×106 mol/d of dissolved phosphorus(DP) during the period of jellyfish bloom. The values are comparable to riverine inputs in a day, but much higher than sediment–water exchange flux in the Yellow Sea. The great amounts of nutrients must have significant influence on the nutrients balance of the Yellow Sea during the period of jellyfish dead and decomposition. Both the experimental data and field observations proved that the decomposition of jellyfish may release a great amount of nutrient to the surrounding environment during the period of jellyfish decomposition. 相似文献
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用化学品对藻类毒性测试的标准试验方法,分别研究了硫属元素Se(Ⅳ)和Te(Ⅳ)单组分对钝顶螺旋藻(Spirulina platensis)的毒性效应,用相加指数法评价了Se(Ⅳ)和Te(Ⅳ)双组分对螺旋藻的联合毒性效应.结果表明,Te(Ⅳ)对螺旋藻的毒性大于Se(Ⅳ),其EC50,96h分别为125.2 mg/L和36.1 mg/L;Se(IV)和Te(Ⅳ)的联合毒性效应为拮抗作用, 其EC50,96h为103.1 mg/L. 相似文献
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九龙江河口区水体中的226Ra和228Ra 总被引：8，自引：0，他引：8
用ＭｎＯ２－纤维富集大体积水样中的Ｒａ同位素，并用直接射气法测定２２６Ｒａ和２２８Ａｃ的β计数法测定２２８Ｒａ的方法，研究了九龙江河口区２２６Ｒａ，２２８Ｒａ的行为，结果表明：在该河口区２２６Ｒａ，２２８Ｒａ均呈非保守行为，２２６Ｒａ，２２８Ｒａ的最高值分别在盐度为１９和９处测得。２２８Ｒａ／２２６Ｒａ）Ａ．Ｒ．值在盐度小于１９的区域约为３左右。与世界其他河口区相比，九龙江河口区的２２６Ｒａ，２２ 相似文献
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从钝顶螺旋藻(Spirulina platensis)中提取纯化藻蓝蛋白(Phycocyanin,PC),光吸收值A620/A280为3.1,观察Se(Ⅳ)与PC相互作用的光谱行为及红硒化现象。光谱检测发现,加入SeO32-后,PC在620 nm的特征光吸收减弱,并随Se(Ⅳ)浓度增加和时间延长单调降低,278 nm和347 nm的光吸收增强;PC的荧光发射和荧光激发也均呈现衰减。另外,PC与Na2SeO3相互作用后,观察到红硒化现象,透射电镜(TEM)证明主要存在形态为红色纳米硒。结果提示PC可能是SeO32?作用的敏感靶点,Se(Ⅳ)对PC主要表现为氧化损伤,而Se(Ⅳ)被还原为红色纳米硒。 相似文献
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Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide
(DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity
(minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation
≤7%) and linearity (r
2 > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample
to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity. 相似文献
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Daniel L. Orange Ana García-García Dan McConnell Tom Lorenson Gary Fortier Fabio Trincardi Emrah Can 《Marine Geophysical Researches》2005,26(2-4):247-266
The need for quantifying and understanding the distribution of shallow gas is both of academic interest and of relevance to
offshore facilities. The combination of seafloor mapping, subbottom profiling, and multi-channel seismic data can provide
information on regions of possible shallow gas, where the gas impacts the acoustic properties of the host material and the
seafloor. In this paper, we present two case studies – one academic and one industry – that evaluate the distribution of shallow
gas in two field areas in the Mediterranean. In the first case study, geophysical data from Iskenderun Bay, southeastern Turkey,
indicate the presence and distribution of shallow gas. Pockmarks on the seafloor are associated with acoustic wipeout in the
shallow subbottom data. Although deeper seismic data do not show bright spots or other indicators of possible gas, instantaneous
frequency analysis clearly shows laterally restricted anomalies indicating gas-rich zones. The interpretation of possible
shallow gas resulted in moving a proposed drilling location to a nearby area characterized by fewer (but still present) shallow
gas signatures. In the second case study, cores acquired in the Po Delta, Adriatic Sea, provide quantitative ground-truthing
of shallow gas – as suggested by geophysical data – and provide minimum estimates of the percentage of gas in the subsurface.
Cores targeted on anomalous subbottom data yielded up to 41,000 ppm methane; cores with anomalous gas content are associated
with thick recent flood deposits which may effectively isolate reactive terrigenous organic matter from biologic and physical
re-working. 相似文献