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1.
The wetting characteristics of liquid Fe–Si alloys in a matrix of the respective predominating stable silicate mantle mineral (forsterite or silicate perovskite) at pressures of 2–5 and 25 GPa and temperatures of 1600–2000 °C were studied by determining the liquid metal–solid silicate contact angles. The median angle values from texturally equilibrated samples were found to be independent of pressure, temperature, silicate mineralogy and the Si content in the metal fraction and range between 130° and 140° which is far above the critical wetting boundary of 60°. This shows that within the studied range of conditions dissolved Si does not lower the surface energies between Fe-rich liquids and silicate mantle grains. As a consequence, under reducing conditions the presence of Si in the metal phase of planetary bodies would not have enhanced percolative flow as an effective metal–silicate separation process.  相似文献   

2.
Phase equilibrium experiments were performed on typical ‘oceanic’ and ‘cratonic’ peridotite compositions and a Ca, Al-rich orthopyroxene composition, to test the proposal that garnet lherzolites exsolved from high-temperature harzburgites, and to further our understanding of the origin of ancient cratonic lithospheres. ‘Oceanic’ peridotites crystallize a garnet harzburgite assemblage at pressures above 5 GPa in the temperature range 1450–1600°C, but at 5 GPa and temperatures less than 1450°C, crystallize clinopyroxene to become true lherzolites. ‘Cratonic’ peridotites crystallize a garnet harzburgite assemblage at pressures above 5 GPa in the temperature range 1300–1600°C. Garnet-free harzburgite crystallizes from both ‘cratonic’ and ‘oceanic’ peridotite at temperatures above 1450°C and pressures below 4.5–5 GPa. Phase relations for the high Ca, Al-rich orthopyroxene composition essentially mirror those for ‘oceanic’ peridotite.The complete solution of garnet and clinopyroxene into orthopyroxene observed in all three starting compositions at temperatures near or above the mantle solidus at pressures less than 6 GPa supports the hypothesis that garnet lherzolite could have exsolved from harzburgite. The inferred cooling path for the original high-temperature harzburgite protoliths of garnet lherzolites differs depending on bulk composition. The precursor harzburgite protoliths of garnet lherzolites and harzburgites with ‘cratonic’ bulk compositions apparently experienced simple isobaric cooling from formation temperatures near the peridotite solidus to those at which most of these peridotites were sampled in the mantle (< 1200°C). The cooling histories for harzburgite protoliths of sheared garnet lherzolites with ‘oceanic’ compositional affinity are speculated to have involved convective circulation of mantle material to depths deeper than those at which it was originally formed.Phase equilibria and compositional relationships for orthopyroxenes produced in phase equilibrium experiments on peridotite and komatiite are consistent with an origin for ‘cratonic’ peridotite as a residue of Archean komatiite extraction, which has since cooled and exsolved clinopyroxene and garnet to become the common low-temperature, coarse-grained peridotite thought to comprise the bulk of the mantle lithosphere beneath the Archean Kaapvaal craton.  相似文献   

3.
Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献   

4.
The self-diffusivity of liquid iron has been measured between 2 and 20 GPa and 1883 and 2393 K. There is a large pressure dependence across the pressure range studied and simple Arrhenius extrapolation to outer core conditions yields unrealistically low diffusivities. The large pressure and temperature range covered, however, allows different a priori diffusion models to be tested using the experimental results. The free volume model [J. Chem. Phys. 31 (1959) 1164] is found to be in excellent agreement with the experimental data and provides a basis for extrapolation of the results to outer core conditions. An extrapolation to core–mantle boundary (CMB) pressure at 4300 K yields a self-diffusivity for liquid iron of 2.5×10−5 cm2 s−1, which corresponds to a viscosity of 11 mPa s, in reasonable agreement with previous, theoretical, estimates.  相似文献   

5.
Phase relations in Mg0.5Fe0.5SiO3 and Mg0.25Fe0.75SiO3 were investigated in a pressure range from 72 to 123 GPa on the basis of synchrotron X-ray diffraction measurements in situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). Results demonstrate that Mg0.5Fe0.5SiO3 perovskite is formed as a single phase at 85–108 GPa and 1800–2330 K, indicating a high solubility of FeO in (Mg,Fe)SiO3 perovskite at high pressures. Post-perovskite appears coexisting with perovskite in Mg0.5Fe0.5SiO3 above 106 GPa at 1410 K, the condition very close to the post-perovskite phase transition boundary in pure MgSiO3. The coexistence of perovskite and post-perovskite was observed to 123 GPa. In addition, post-perovskite was formed coexisting with perovskite also in Mg0.25Fe0.75SiO3 bulk composition at 106–123 GPa. In contrast to earlier experimental and theoretical studies, these results show that incorporation of FeO stabilizes perovskite at higher pressures. This could be due to a larger ionic radius of Fe2+ ion, which is incompatible with a small Mg2+ site in the post-perovskite phase.  相似文献   

6.
The phase relations in hydrous and anhydrous mid-ocean ridge basalt were determined at pressures of 18-28 GPa. Liquidus phase relations in hydrous and anhydrous MORB are different. Garnet is the liquidus phase at pressures below 21 GPa, Ca-Al (CAS) phase and stishovite are the liquidus phases at pressures of 22-27 GPa, and stishovite and Ca-perovskite are the liquidus phases above 27 GPa, whereas Ca-perovskite is a liquidus phase of anhydrous MORB at pressures above 23 GPa. Under subsolidus conditions, we have found that in the hydrous MORB system the stability fields of Al-bearing perovskite and Na-Al (NAL) phase might shift to lower pressure by about 1.5 GPa compared to the dry MORB system. This shift could be explained by oxidation of a garnet-bearing assemblage by hydrous fluid and formation of Fe3+-bearing aluminous perovskite at lower pressures relative to the anhydrous system and/or differences in water solubility of the phases existing in perovskite-bearing assemblages. Our data indicate that hydrous basaltic crust remains denser than peridotite along the geotherm of a subducting slab, i.e. there is no density crossover between peridotite and basalt. Therefore, in slabs going through the 660 km discontinuity, basalt would gravitationally sink into the lower mantle under relatively hydrous conditions. The delamination of former basaltic crust near the 660 km discontinuity might be possible under relatively dry conditions of subduction. There are no stable highly hydrous phases in MORB above 10 GPa even at lower temperatures corresponding to subducting slabs. Therefore, MORB cannot be an important carrier of water to the deep Earth interior. However, it can be constantly supplied by water-bearing fluid from the underlying peridotite part of the descending slab. Thus, it is plausible that water can control subduction of the oceanic crust into the lower mantle.  相似文献   

7.
We determined the partition coefficients of 19 elements between metallic liquid and silicate liquid at 20 GPa and 2500°C, and between metallic liquid and silicate perovskite at 27 GPa and 2200°C. Remarkable differences were observed in the partitioning behaviors of Si, P, W, Re, and Pb among the silicate liquid, perovskite, and magnesiowüstite coexisting with metallic liquid, reflecting incompatibility of the elements in the silicate or oxide phase. We could not observe any significant difference in the partitioning behaviors of V, Cr, Mn, Co, Ni, and Cu among the phases coexisting with metallic liquid.

Comparison of the present partitioning data with those obtained previously at lower pressure and temperature suggests that the exchange partition coefficients, Kmet/sil, of Co, Ni, Mo, and W decrease, whereas those of V, Cr, and Mn increase and tend to approach unity with increasing pressure and temperature. We also made preliminary experiments to clarify the effect of sulfur on the partitioning behaviors. Sulfur lowers the exchange partition coefficients, Kmet/sil, of Mo and W between metallic liquid and silicate liquid significantly at 20 GPa and 2300°C.

The mantle abundances of Co, Ni, Cu, Mo, and W calculated for the metal-silicate equilibrium model are lower than those of the real mantle, whereas P, K, and Mn are overabundant in the calculated mantle. The discrepancies in the abundances of Co and Ni could be explained by the chemical equilibrium at higher pressure and temperature. Large discrepancies in Mo and W between the calculated and real mantles could be accounted for by the effect of sulfur combined with the effects of pressure and temperature on the chemical equilibrium. The mantle abundances of P, K, and Cu could be accounted for by volatile loss in the nebula, perhaps before accretion of the Earth, combined with the chemical equilibrium at higher pressure and temperature. Thus the observed mantle abundances of P, K, Co, Ni, Cu, Mo, and W may be consistent with a model of sulfur-bearing metal-silicate equilibrium in lower-mantle conditions.  相似文献   


8.
A review of experimental data for systems, pertaining to anhydrous fertile garnet-lherzolite shows strong convergence in the liquidus and solidus temperatures for the range 6.5–15 GPa. These can converge either to a common temperature or to temperatures which differ by only ～ 100°C. The major-element composition of magmas generated by even minor degrees of partial melting may be similar to the primordial bulk silicate Earth composition in an upper-mantle stratigraphic column extending over 160 km in depth.The convergence of the solidus and liquidus temperatures is a consequence of the highly variable dTdP of the fusion curves for minerals which crystallize in peridotite systems. In particular, dTdP for the forsterite fusion curve is much less than that for diopside and garnet. Whether or not the solidus and liquidus intersect, the liquidus mineralogy for undepleted garnet-lherzolite compositions changes from olivine at low pressures to pyroxene, garnet, or a complex pyroxene-garnet solid solution at pressures in excess of 10–15 GPa. Geochemical data for the earliest Archean komatiites are consistent with an upper-mantle phase diagram having garnet as a liquidus phase for garnet-lherzolite compositions at high pressures. All estimates of the anhydrous solidus and liquidus for the range 10–15 GPa are consistent with silicate liquid compressibility data, which indicate that olivine may be neutrally buoyant in ultramafic magmas at these pressures.  相似文献   

9.
利用冲击波进行的动高压实验对研究超高压下的物质性质也是十分有效的.本文报告了对大麻坪采集的橄榄石进行压力在10~45GPa范围的冲击波动高压实验结果.结合前人等温冷压实验结果,确定了实验过程的温度,对于冲击波实验压力从10GPa变化到30GPa时,温度在摄氏几十度到摄氏800多度之间.测量了岩石超高压下密度变化,在3.627~4.009g·cm~(-3)之间.通过回收实验和确定的温度,表明小于30GPa压力实验条件下,没有发生相变过程.同时也确定了状态方程的参数.最后,指出了实验结果在上地幔地球内部物质运动过程的含义,即冷板块中的亚临界橄榄岩可以存在地幔转换带中.  相似文献   

10.
In situ X-ray diffraction measurements on a calcium aluminosilicate (CAS) phase have been carried out using a laser-heated diamond anvil cell up to a pressure of 44 GPa, employing a synchrotron radiation source. CAS is the major mineral formed from sediments subducted into the Earth's mantle. The sample was heated using a YAG laser after each pressure increment to relax the deviatoric stress in the sample. X-ray diffraction measurements were carried out at T = 300 K using an angle-dispersive technique. The pressure was calculated using an internal platinum metal pressure calibrant. The Birch–Murnaghan equation of state for the CAS phase obtained from the experimental unit cell parameters showed a density of ρ0 = 3.888 g/cm3 and a bulk modulus of K0 = 229 ± 9 GPa for K′0 = 4.7 ± 0.7. When the first pressure derivative of the bulk modulus was fixed at K′0 = 4, then the value of K0 = 239 ± 2 GPa. From the experimental compressibility, the density of the CAS phase was observed to be lower than the density of co-existing Al-bearing stishovite, calcium perovskite, calcium ferrite-type phases, and (Fe,Al)-bearing Mg-perovskite in subducted sediments in the lower mantle. Therefore, the density of subducted sediments in the lower mantle decreases with increasing mineral proportion of the CAS phase.  相似文献   

11.
A phase transition in pure CaSiO3 perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO3 perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al2O3 content dissolved in CaSiO3 perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO3(+ 3 wt.% Al2O3) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range.  相似文献   

12.
The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe2SiO4 olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K0 = 1.19 ± 0.10 Mbar and K0′ = 7 ± 4, and if we assume K0′ = 5: K0 = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made.  相似文献   

13.
We extended the pressure range of sound velocity measurements for liquid water to 25 GPa and 900 K along the melting curve using a laser heated diamond anvil cell with a combined system of Brillouin scattering and synchrotron X-ray diffraction. Experimental pressure and temperature were obtained by solving simultaneous equations: the melting curve of ice and the equation of state for gold. The sound velocities obtained in liquid water at high pressures and melting temperatures were converted to density using Murnaghan's equation of state by fitting a parameter of the pressure derivative of bulk modulus at 1 GPa. The results are in good agreement with the values predicted by a previously reported equation of state for water based on sound velocity measurements. The equation of state for water obtained in this study could be applicable to water released by dehydration reactions of dense hydrous magnesium silicate phases in cold subducting slabs at lower mantle conditions, although the validity of Murnaghan's equation of state for water should be evaluated in a wider pressure and temperature ranges. The present velocity data provides the basis for future improvement of the accurate thermodynamic model for water at high pressures.  相似文献   

14.
应用超声波反射-透射法,在最高压力为1.0 GPa（室温）,最高温度为700℃（1.0 GPa）的条件下对新疆东准噶尔地区的卡拉麦里花岗岩带和野马泉岩体的典型花岗岩类岩石（碱长花岗岩、碱性花岗岩、花岗闪长岩、二长花岗岩和石英闪长岩）的纵波速度（VP）和横波速度（VS）进行了测量.结果显示,在常温、压力0.4~1.0 GPa条件下,东准噶尔地区花岗岩类岩石的VP和VS均随压力呈线性增加,说明在这个压力段岩石中的微裂隙已基本闭合.室温、1.0 GPa时花岗岩类岩石的VP是5.79~6.84 km·s-1,VS是3.26~3.85 km·s-1.依据压力与VP及压力与VS的线性关系,拟合得到常温常压下花岗岩类岩石的纵波和横波压力系数分别是0.1568~0.4078 km/（s·GPa）和0.0722~0.3271 km/（s·GPa）,VP0和VS0分别是5.62~6.47 km·s-1和3.15~3.75 km·s-1.恒压1.0 GPa、室温到700℃条件下,花岗岩类岩石的VP和VS均随温度的升高呈线性降低,温度系数分别为（-3.41~-4.96）×10-4 km/（s·℃）和（-0.88~-3.22）×10-4 km/（s·℃）.利用实验获得的花岗岩类岩石的VP0、VS0及温度系数和压力系数,结合东准噶尔地区的地热资料,建立了VP和VS随深度变化的剖面.将获得的VP和VS-深度剖面与该区地球物理探测结果对比,发现东准噶尔地区的碱长花岗岩、碱性花岗岩、二长花岗岩和部分花岗闪长岩的VP和VS与该区上地壳速度吻合很好,同时这几种岩石的平均泊松比也与上地壳泊松比一致,因此我们认为这几种类型的岩石是该区上地壳的重要组成部分.另外,石英闪长岩的VP和VS均符合中地壳的速度,可能为中地壳中的一种岩石.  相似文献   

15.
The study of viscosity in sub-liquidus heterogeneous media, which includes kimberlite magma at the pressures and temperatures that prevail in the mantle, is an urgent task. We have conducted experiments in the serpentine–olivine, serpentine–CaCO3?olivine, and native kimberlite–olivine systems at a pressure of 4 GPa and temperatures of 1400?1600°С in a BARS high-pressure device using the technique of a falling Pt pellet. The samples were examined after experiments to find fine-grained chilled mass of crystals where the Pt pellet was observed at the time of chilling. The concentration of the solid phase was varied in the experiments between 10 and 50 wt %. We showed that when 50 wt % of olivine grains has been introduced, it was not possible to detect the motion of the Pt pellet, while when the concentration of olivine xenocrysts reached 10 wt %, the Pt pellet very rapidly descended to the bottom of the reaction volume. Viscosity was calculated using the Stokes method. We found that the viscosity of a homogeneous kimberlite melt at 4 GPa and 1600°С is below 2 Pa s, with the viscosity of a melt that contained up to 10 wt % of the solid phase being approximately constant. A kimberlite melt that contained 30 wt % of the solid phase had a viscosity on the order of 100 Pa s, while with 50 wt % of the solid phase the relative viscosity of an ultrabasic system increased to reach values over 1000 Pa s.  相似文献   

16.
Combining textural, petrological, chemical and isotopic (Sr, H and O) data for amphiboles and whole rocks from the Zabargad peridotite diapir allows three different events to be distinguished. During each event, which can be related to a specific tectonic process of the rifting of the Red Sea, hydrous fluids produced amphiboles.

The first and the second generations of amphiboles have characteristics consistent with the involvement of mantle-derived hydrous fluids. The first generation consists of scarce Ti-pargasites which crystallized from small amounts of fluid at temperatures of around 900–1000°C. Their growth was linked to magma percolation in the peridotites before their deformation during diapiric uplift. The second generation consists of Cr-pargasites which crystallized locally (and abundantly) during reaction between the peridotites and a sodium/potassium-bearing hydrous fluid at temperatures of around 700–800°C. These amphiboles grew synchronously with the diapiric uplift. The hydrous fluids probably originated in the sub-continental mantle and were released during the diapiric uplift of the peridotites.

The third generation consists of amphiboles (pargasitic hornblende, hornblende sensu lato and tremolite) which are localized in shear zones and veins. They crystallized at temperatures estimated between 700°C and 450°C, again from a sodium/potassium-bearing hydrous fluid. However, this fluid is extraneous to the peridotites, as shown by the Sr, H and O isotope compositions which suggest seawater penetration either during or after the final emplacement of the peridotite diapir.

Although the peridotite diapir was emplaced in granulitic gneisses of the pan-African deep continental crust, no evidence was found for a contribution of hydrous continental fluids in the production of the amphiboles present in the peridotite bodies of Zabargad Island.  相似文献   


17.
We report new metal-silicate partition coefficients for Ni, Co and P at 7.0 GPa (1650–1750°C), and Ni, Co, Mo, W and P at 0.8, 1.0 and 1.5 GPa (1300–1400°C). Guided by thermodynamics, all available metal-silicate partition coefficients, D(i), where i is Ni, Co, P, Mo and W, are regressed against 1/T, P/T, lnf(O2), ln(1 − Xs) (XS is mole fraction of S in metallic liquid) and nbo/t (non-bridging oxygen/tetrahedral cation ratio, a silicate melt compositional-structural parameter) to derive equations of the following form: ln D(i) = aln f(O2) + (b/T) + (cP/T) + d(nbo/t) + eln(1 − XS) + f. Expressions for solid metal-liquid silicate and liquid metal-liquid silicate partition coefficients are derived for S-free and S-bearing systems.

We investigate whether Earth's upper-mantle siderophile element abundances can be reconciled with simple metal-silicate equilibrium. Sulfur-free metallic compositions do not allow a good fit. However, Ni, Co, Mo, W and P abundances in the upper mantle are consistent with simple metal-silicate equilibrium at mantle pressures and temperatures (27 GPa, 2200 K, ΔIW(iron-wüstite) = −0.15, nbo/t = 2.7; XS = 0.15). Although these conditions are near the anhydrous peridotite solidus, they are well above the hydrous solidus and probably closer to the liquidus. A hydrous magma ocean and early mantle are consistent with predicted planetary accretion models. These results suggest that siderophile element abundances in Earth's upper mantle were established by liquid metal-liquid silicate equilibrium near the upper-mantle-lower-mantle boundary.  相似文献   


18.
Data in the literature and additional measurements on the thermal diffusivities of granites, granulites and ultrabasic rocks at temperatures up to 1000 K and pressures to 2 GPa, have been used to propose a new model for thermal diffusivity distribution in the crust and upper mantle.The laboratory measurements were made using a pulse method or the Angstroem method with cylindrical heat flow. After making particular assumptions about the pressure and temperature distribution within the top 60 km the pressure and temperature dependencies of diffusivity were transformed into a depth dependence.The model is characterised by a continuous decrease of diffusivity to a depth of ～30 km where there is a small but rapid increase to a nearly constant value of 7.3 × 10?3 cm2 s?1.  相似文献   

19.
We have considered the influence of ocean temperature and salinity changes, mass changes of the Greenland ice sheet (GIS) and the isostatic response of the solid earth to the most recent glacial cycle on 20th century sea-level change along the US east coast with the intention of better understanding the observed signal as well as determining the potential of the tide gauge data for constraining the recent (past 50–100 yr) mass balance of the GIS and earth viscosity structure. Our results show that the signal due to steric changes is large and displays a complex spatial variation which can account for a significant portion of the observed signal. In contrast, that due to changes in the GIS is relatively small and insensitive to the specific geometry of the mass balance model adopted. As a consequence, the tide gauge data alone are not capable of providing useful constraints on either the magnitude or form of recent GIS mass balance. Our inference of mantle viscosity structure based on the tide gauge data was affected dramatically when the steric effect was accounted for: An earth model with an upper mantle viscosity of 8 × 1019 Pa s and a lower mantle viscosity of 5 × 1022 Pa s produced the best fit to the steric-corrected data; the optimal fit to the uncorrected data was obtained for upper and lower mantle viscosities of 5 × 1020 Pa s and 1022 Pa s, respectively.  相似文献   

20.
The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO2 and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO2 and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO2 for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr2O3 and poorer in SiO2, K2O, Na2O, Al2O3 and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO2 >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO2 and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO2 and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated.  相似文献   

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