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1.
Sekiguchi  T.  Watanabe  J.  Fukushima  H.  Yamamoto  T.  Yamamoto  N. 《Earth, Moon, and Planets》1997,78(1-3):143-148
In order to monitor the various phenomena of comets, we continuously made the near-nucleus imaging observations of comets at National Astronomical Observatory, Mitaka. Here we report on the results of the observations of two spectacular comets. One is the analysis of photometry of C2 emission images in the coma of comet Hyakutake (C/1996 B2). By comparing the production rates of C2 radicals with C2H2 molecules, we conclude that the most C2 radicals were originated from C2H2, while some of them might be produced from other parents. The second item is the analysis of the morphology of C2 emission images in the coma of comet Hale-Bopp(C/1995 O1). By applying a ring masking technique, we detected asymmetrical distribution of the C2 molecules. The results of these two comets might suggest that a portion of C2 radicals were formed by the disintegration of the small organic dust grains, like the so-called CHON particles. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

2.
Emission fluxes of CN, C2 and C3 carbon-bearing molecular species observed in the coma of comets Rudnicki (1967II), Ikeya-Seki (1968I), Whitaker-Thomas (1968V), and Honda (1968VI) are analysed in the framework of Haser model. CN, C3 and C3 production rates are determined using recently derived fluorescence efficiencies. The dependence of CN, C2 and C3 production rates on the heliocentric distance and the possible correlations among these radicals is studied. It is shown that comets Ikeya-Seki (1968I) and Honda (1968VI) have the same mean color indices (B-V) and (U-B).  相似文献   

3.
Photoelectric spectrophotometric scans of Comet 1973 XII Kohoutek were made on November 25.85 and 28.85 UT, 1973. The vibrational temperature of C2, the total numbers of CN and of C2, and the production rates for CN and C2 are derived from the observed fluxes. The temperature of C2 was 4900 K on 25.85 November and 4300 K on 28.85 November. Mean abundance ratio of C2 to CN was about 2.7. From the variation of production rates with heliocentric distance, it is shown that there was an outburst on 25.85 November in both CN and C2 productions. For C2, the production rates are derived by using two coma models, i.e. the Haser's parent-daughter model and the model relevant to a proposition of Yamamoto (1981b) that C2 is formed via two-step photodissociation of its parent molecules. By comparing the production rate derived from the two models, it can be supported that C2 is formed via two-step photodissociation rather than one-step photodissociation. In consequence, it is shown that the variation of the production rate with heliocentric distance is largely modified compared with that derived from the Haser's model.  相似文献   

4.
We report photochemical studies of thin cryogenic ice films composed of N2, CH4 and CO in ratios analogous to those on the surfaces of Neptune’s largest satellite, Triton, and on Pluto. Experiments were performed using a hydrogen discharge lamp, which provides an intense source of ultraviolet light to simulate the sunlight-induced photochemistry on these icy bodies. Characterization via infrared spectroscopy showed that C2H6 and C2H2, and HCO are formed by the dissociation of CH4 into H, CH2 and CH3 and the subsequent reaction of these radicals within the ice. Other radical species, such as C2, , CN, and CNN, are observed in the visible and ultraviolet regions of the spectrum. These species imply a rich chemistry based on formation of radicals from methane and their subsequent reaction with the N2 matrix. We discuss the implications of the formation of these radicals for the chemical evolution of Triton and Pluto. Ultimately, this work suggests that , CN, HCO, and CNN may be found in significant quantities on the surfaces of Triton and Pluto and that new observations of these objects in the appropriate wavelength regions are warranted.  相似文献   

5.
Spectroscopic observations of Comet P/Brorsen-Metcalf were made on August 9–13, 1989. Spatial profiles extracted from long-slit spectra were analyzed to determine the lifetimes of C3 and NH2 radicals and their parents, as well as the tailward acceleration of these radicals. In our investigations we used a Monte Carlo model. The average lifetime for C3 has been found to be 6.3 × 104 s and that for the parent of C3 to 6 × 103 s. The spatial profiles of C3 were almost symmetric and we need only 0.1 cm s−2 as the tailward acceleration. According to our simulations, C3H4 (allene) can be considered as the parent for C3. We obtained the average value 7.6 × 104 s for the lifetime of NH2 and 1.1 × 104 s for the lifetime of the NH2 parent. The tailward acceleration of NH2 was not more than 0.1 cm s−2. This result does not exceed the latest theoretical calculations of NH2 and NH3 lifetimes by a factor of 1.4. So, NH3 may be considered as a parent for NH2 in the atmosphere of P/Brorsen-Metcalf.  相似文献   

6.
A critical analysis of CH, NH, OH, C2, and CN molecules/radicals has been made in twenty-four F- and early G-type dwarfs at different effective temperature as well as in new constructed model atmosphere. Molecular indices of bandheads ofA-X system of CH, NH, OH, C2, and CN have been obtained by using the data available in the literature (thirteen-colour and eight-colour photometry).Besides, some interesting plots of the molecular indices vs eff, molecular abundances and molecular indices vs dissociation energy, reduced equivalent widths and FCF's vs dissociation energy for respective molecules have also been enumerated. It is found that the molecular indices at bandheads ofA-X system of CH, NH, OH, C2, and CN are approximately constant (5810–6570 K). It is to be noted that the molecular indices decrease in the order OH, NH, CH, C2, and CN at a given temperature.The dissociation equilibrium of CH, NH, OH, C2, and CN is considered at 5810, 6570, and 7160 K phases in model atmosphere. At standard scale of abundance the molecular abundance and molecular index decrease in the order OH, NH, CH, C2, and CN at any given phase, however, CN abundance and index increase (eff=0.867-0.767). The amplitude of abundance and index variation decrease in the order NH, OH, CH, C2, and CN (eff=0.767-0.704).The reduced equivalent width decrease in the order OH, NH, CH, and C2 and FCF's decrease in the order CH, OH, NH, CN, and C2.The confrontation of models and observations of spectra of F- and early G-type dwarfs of parent molecules is of primary importance to investigate the physical conditions within atmospheres. Reliable excitation models are also requisite for interpreting spectroscopic observations of parent molecules and deriving molecular abundances.  相似文献   

7.
Theoretical studies were performed on seven potential interstellar and circumstellar substituted cyanoacetylenes, Y(CC)CN [Y = C2H5, C3H7, C4H9, F, Cl, Br and CN]. Geometry optimizations were carried out using the DFT/B3LYP, the CCSD and CCSD(T) levels of theory. The cc-pVTZ basis set was used for all atoms. Frequency computations were also carried out at the same level of theory as for the optimization to check the nature of the stationary points. The molecular and spectroscopic parameters of the cyanoacetylenes were computed. An analysis of these parameters is in line with the satisfactory performance of the B3LYP/cc-pVTZ level compared to the golden standard, the CCSD(T) level. The theoretical data reported in this work should facilitate future identifications of these cyanoacetylenes in extraterrestrial locations. Plausible mechanisms for the formation of these molecules have been proposed.  相似文献   

8.
Column density profiles for CN, C3, C2 and NH have been determined from a long-slit CCD spectrum of periodic comet P/Schaumasse (1992x). Comparisons of these profiles with Haser models indicate that the ratios of the CN, C3 and C2 production rates are typical for a short-period comet. Although the scale lengths for NH and its parent species are uncertain, the results indicate that the production rate for NH is much greater than for either C2 or CN.  相似文献   

9.
Emission fluxes of CN, C2 and C3 species observed in the coma of some comets are analysed in the framework of Haser model. CN, C2 and C3 production rates are determined using recently derived fluorescence efficiencies and dependence of CN, C2 and C3 production rates on the heliocentric distance is studied. Evidence for a burst type activity around January 15, 1974 in the post-perihelion period of comet Kohoutek (1973f) is observed.  相似文献   

10.
The variation with heliocentric distance of the production rates of various species in Comet West (1975n=1976 VI) is explained with a cometary model consisting of a CO2-dominated nucleus plus a halo of icy grains of H2O or clathrate hydrate. We conclude that the parents of CN and C3 are released primarily from the nucleus but that the parent of C2 is released primarily from the halo of icy grains.  相似文献   

11.
Spectrophotometric observations of Comet Austin (1982g) in the bands of CN, C2, and C3 are presented, and fit to a Haser model for the cometary brightness distribution. The lifetimes of the parent and daughter molecules, as well as the velocity of the molecules leaving the cometary surface are determined from the model fit. The absolute production rate of molecules is also determined.  相似文献   

12.
The origin of CN radicals in comets is not completely understood so far. We present a study of CN and HCN production rates and CN Haser scale lengths showing that: (1) at heliocentric distances larger than 3 AU, CN radicals could be entirely produced by HCN photolysis; (2) closer to the Sun, for a fraction of comets CN production rates are higher than HCN ones whereas (3) in the others, CN distribution cannot be explained by the HCN photolysis although CN and HCN production rates seem to be similar. Thus, when the comets are closer than 3 AU to the Sun, an additional process to the HCN photolysis seems to be required to explain the CN density in some comets.The photolysis of HC3N or C2N2 could explain the CN origin. But the HC3N production rate is probably too low to reproduce CN density profile, even if uncertainties on its photolysis leave the place for all possible conclusions. The presence of C2N2 in comets is a reliable hypothesis to explain the CN origin; thus, its detection is a challenging issue. Since C2N2 is very difficult to detect from ground-based observations, only in situ measurements or space observations could determine the contribution of this compound in the CN origin.Another hypothesis is a direct production of CN radicals by the photo- or thermal degradation of complex refractory organic compounds present on cometary grains. This process could explain the spatial profile of CN inside jets and the discrepancy noted in the isotopic ratio 14N/15N between CN and HCN. Laboratory studies of the thermal and UV-induced degradation of solid nitrogenated compounds are required to model and validate this hypothesis.  相似文献   

13.
The circumstellar envelopes of carbon-rich AGB stars show a chemical complexity that is exemplified by the prototypical object IRC +10216, in which about 60 different molecules have been detected to date. Most of these species are carbon chains of the type C n H, C n H2, C n N, HC n N. We present the detection of new species (CH2CHCN, CH2CN, H2CS, CH3CCH and C3O) achieved thanks to the systematic observation of the full 3 mm window with the IRAM 30m telescope plus some ARO 12m observations. All these species, known to exist in the interstellar medium, are detected for the first time in a circumstellar envelope around an AGB star. These five molecules are most likely formed in the outer expanding envelope rather than in the stellar photosphere. A pure gas phase chemical model of the circumstellar envelope is reasonably successful in explaining the derived abundances, and additionally allows to elucidate the chemical formation routes and to predict the spatial distribution of the detected species.  相似文献   

14.
The results of the multiaperture photometry of Comet Shoemaker-Levy 1991 T2 in the pre-perihelion and P/deVico in the post-perihelion period with the narrowband CN, C2 and Blue Continuum (BC) IHW filters are presented. A Haser model of the molecular coma was used for the determination of the parent and daughter scale-lengths and production rates of the radicals. The comets showed some substantial differences between their parent scale-lengths. The CN parent scale-length (at 1.0 AU) was 16×103 km for Comet Shoemaker-Levy and 39×103 for P/deVico, the C2 parent scale-lengths were respectively 29×103 and 54×103 km. Such divergences could be interpreted in the frame of different scenarios of emission of cometary parents, either from a nucleus or from a volume source. The daughter scale-lengths for these comets were quite similar, namely: 306×103 and 318×103 km for CN and 69×103 and 66×103 km for C2. We determined the Afρ parameter for apertures of different radii. A Monte Carlo model of the dust coma was used to obtain the dust ejection velocity. It was of the order of 0.1 km s−1 for both comets. The power index of the distribution of the β-parameter of dust particles (ratio of light pressure to the solar gravitation) was of the order of 3 for C/Shoemaker-Levy and close to 2 for P/deVico. The dependence on heliocentric distance (rh) of the radical and dust production rates for P/deVico in the range of 0.7-1.0 AU was described by the power law function with a power index equal to: 5.55±0.14 for CN, 5.70±0.24 for C2 and 5.22±0.19 for dust. Relative abundances of the dynamically new Comet Shoemaker-Levy and short-period P/deVico were quite similar with an enhancement of C2 comparing with standard values taken from A'Hearn et al. (1995).  相似文献   

15.
The results of the photoelectric photometry with the narrowband CN, C3, C2 and Blue Continuum (BC) IHW interference filters are presented. Observations were carried out with a set of diaphragms of different effective radii. On the base of the Haser model the production rates of the radicals have been obtained. The CN and C2 molecules scale lengths (3.4 × 105 km and 8.5 × 104 km respectively for 1.0 AU heliocentric distance) have been also derived. The dust continuum spectrum is negligibly low in comparison with the molecular one, which stay in agreement with the results of other observations of comet Okazaki-Levy-Rudenko.  相似文献   

16.
We investigate, neutral-neutral radiative association reactions (C2+CO) and (C2+CS) for the formation of C3O and C3S respectively by DFT. Both the reactions are spin allowed and found to be exothermic and barrierless in nature. The product of these reactions are perfectly linear and the calculated rotational transitions are in good agreement with earlier published data. At the DFT/TZ2P level, the difference between the calculated rotational constant and experimental one is 0.064 % for C3O and 0.16 % for C3S. We also discussed the intrinsic and relative stability of these molecules.  相似文献   

17.
We present a preliminary analysis of medium resolution optical spectra of comet C/2000 WM1 (LINEAR) obtained on 22 November 2001. Theemission lines of the molecules C2, C3, CN, NH2,H2O+ and presumably CO (Asundi and triplet bands) and C2 -were identified in these spectra. By analysing the brightnessdistributions of the C2, C3, CN emission lines along theslit of the spectrograph we determined some physical parameters of theseneutrals, such as their lifetimes and expansion velocities inthe coma. The Franck–Condon factors for the CO Asundi bands and C2 - bands were calculated using a Morse potential model.  相似文献   

18.
One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H2O, OH, O, CN, C2, C3, CH, and NH2. Whole-coma abundances are presented for NH2, CH, C2, C3, CN, OH, CO+, H2O+, CH+, N2+, and CO2+.  相似文献   

19.
Indirect evidence against the presence of C2 lines in umbral spectra is discussed. The dominant role of CO in the molecular equilibrium of C at umbral temperatures ensures that CN, CH and C2 lines are formed in the same atmospheric regions. Observations of CN and CH umbral lines are in good accord with predictions based on accepted umbral model atmospheres. This implies that C2 must follow the predictions and that it is too weak to contribute to the umbral spectrum. C2 lines in the photosphere and penumbrae are in excellent quantitative agreement with predictions. Additional tests are proposed.  相似文献   

20.
Laboratory investigations of CN radical formation by photodissociation of parent molecules have suggested the possibility of observing emission lines in cometary spectra from newly formed CN radicals. These laboratory studies have shown that high initial internal excitation of CN is the rule with excitation of rotational levels N up to 70. In the collisionless environment of the cometary atmosphere this initial excitation would yield a corresponding distribution for the lowest vibrational level of the ground X2Σ+ state. Our calculations show that it is feasible with present observational techniques to detect photochemically excited lines with N ~ 30 in the 0-0 band of the violet system.  相似文献   

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