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1.
Dolomitization in the Western Canadian Sedimentary Basin has been extensively researched, producing vast geochemical datasets. This provides a unique opportunity to assess the regional sources and flux of dolomitizing fluids on a larger scale than previous studies. A meta‐analysis was conducted on stable isotope, strontium isotope (87Sr/86Sr), fluid inclusion and lithium‐rich formation water data published over 30 years, with new petrographic, X‐ray diffraction, stable isotope and rare‐earth element (REE+Y) data. The Middle to Upper Devonian Swan Hills Formation, Leduc Formation and Wabamun Group contain replacement dolomite (RD) cross‐cut by stylolites, suggesting replacement dolomitization occurred during shallow burial. Stable isotope, REE+Y and 87Sr/86Sr data indicate RD formed from Devonian seawater, then recrystallized during burial. Apart from the Wabamun Group of the Peace River Arch (PRA), saddle dolomite cement (SDC) is more δ18O(PDB) depleted than RD, and cross‐cuts stylolites, suggesting precipitation during deep burial. SDC 87Sr/86Sr data indicate contributions from 87Sr‐rich basinal brines in the West Shale Basin (WSB) and PRA, and authigenic quartz/albite suggests basinal brines interacted with underlying clastic aquifers before ascending faults into carbonate strata. The absence of quartz/albite within dolomites of the East Shale Basin (ESB) suggests dolomitizing fluids only interacted with carbonate strata. We conclude that replacement dolomitization resulted from connate Devonian seawater circulating through aquifers and faults during shallow burial. SDC precipitated during deep burial from basinal brines sourced from basal carbonates (ESB) and clastic aquifers (WSB, PRA). Lithium‐rich formation waters suggest basinal brines originated as residual evapo‐concentrated Middle Devonian seawater that interacted with basal aquifers and ascended faults during the Antler and Laramide Orogenies. These results corroborate those of previous studies but are verified by new integrated analysis of multiple datasets. New insights emphasize the importance of basal aquifers and residual evapo‐concentrated seawater in dolomitization, which is potentially applicable to other regionally dolomitized basins.  相似文献   

2.
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3.
Pervasive fracture networks are common in many reservoir‐scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post‐rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km2. The carbonates have a gentle, <5?, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub‐vertical veins, and sub‐vertical as well as sub‐horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400–500 m. Deformation was accommodated by a dense network of sub‐vertical mode I and hybrid fractures associated with sub‐vertical stylolites developed in a stress field characterised by a sub‐horizontal σ1 and sub‐vertical σ2. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800–900 m entering a depth interval characterised by a sub‐vertical σ1. At this stage, sub‐horizontal stylolites developed liberating calcite which sealed the sub‐vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre‐existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures.  相似文献   

4.
ABSTRACT Inter‐ and intrabasinal correlation of Neoproterozoic carbonate successions and associated glaciogenic deposits from the Pan‐African Gariep Belt and the Kango inlier in the Saldania Belt (Namibia and South Africa) is proposed on the basis of new δ13CCarb and 87Sr/86SrI data. Highly positive δ13CCarb values (as much as + 8.65‰) and low 87Sr/86SrI ratios (0.7071–0.7077) were obtained on carbonate successions of the Hilda Subgroup between an older and a younger diamictite in the Port Nolloth Group (Gariep Belt). These results are in agreement with data elsewhere that suggest deposition between the global ～ 750 Ma Sturtian and ～ 580 Ma Marinoan glaciations. Considerably lower, positive δ13CCarb values (up to + 1.01‰) and higher 87Sr/86SrI ratios (0.7082–0.7085) mark the carbonates (Bloeddrif Member, Holgat Formation) on top of the Numees Formation diamictite and support a correlation of this diamictite with the Marinoan glaciation. In the southern extension of the Gariep Belt, correlation of the Widouw Formation limestone (Gifberg Group) with the Bloeddrif Member carbonates is proposed based on similar isotopic characteristics. In the Kango inlier of the Saldania Belt, two carbonate‐bearing members exist in the Matjies River Formation. The lower one of these two (Nooitgedacht Member) compares well with the Hilda Subgroup, whereas the upper one (Kombuis Member) shows strong similarities to the Bloeddrif Member carbonates. This implies that all younger stratigraphic units of the Kango inlier are not correlatives of the Port Nolloth Group, as previously assumed, but syn‐ to post‐orogenic with respect to the 540–580 Ma Pan‐African orogeny.  相似文献   

5.
The Ayn Formation of the Neoproterozoic Mirbat Group comprises <400 m of little‐deformed, glacially influenced basin margin deposits. These deposits are preserved in several palaeovalleys eroded in crystalline basement and overlain by a discontinuous cap carbonate. The Ayn Formation and the cap carbonate, which are superbly exposed along a 20 km SW–NE‐striking escarpment in south Oman, provide important insights into the processes operating on a basin margin during a Neoproterozoic glaciation and its demise. The Ayn Formation comprises units of glacimarine rain‐out diamictite and sediment gravity flow deposits, alternated with units of fluvial and deltaic sandstones and conglomerates, which may have formed by proglacial outwash. The stratigraphic evolution of the Ayn Formation indicates a highly active hydrological cycle during a phase of overall (glacio‐eustatic?) low stand when glaciers advanced into and receded upon bedrock valleys. The transgressive cap carbonate was deposited primarily in shallow marine or shallow lacustrine environments over palaeohighs during the deglaciation, and was partly reworked into deeper parts of the basin through sediment gravity flow processes. Locally, the cap carbonate transgresses over crystalline basement containing a network of fissures filled with carbonate originating from the cap. The δ13C isotopic composition of the cap carbonate varies systematically between ?3.5 and +5.8‰ Pee Dee Belemnite standard, in common with other older Cryogenian examples.  相似文献   

6.
A total of 20 soil samples were collected from 10 boreholes constructed in the low lying area, which included ancillary samples taken from the high elevation area. Redox processes were investigated in the soil as well as groundwater in the shallow groundwater aquifer of Manukan Island, Sabah, Malaysia. Groundwater samples (n = 10) from each boreholes were also collected in the low lying area to understand the concentrations and behaviors of Fe and Mn in the dissolved state. This study strives to obtain a general understanding of the stability behaviors on Fe and Mn at the upper unsaturated and the lower-saturated soil horizons in the low lying area of Manukan Island as these elements usually play a major role in the redox chemistry of the shallow groundwater. Thermodynamic calculations using PHREEQC showed that the groundwater samples in the study area are oversaturated with respect to goethite, hematite, Fe(OH)3 and undersaturated with respect to manganite and pyrochroite. Low concentrations of Fe and Mn in the groundwater might be probably due to the lack of minerals of iron and manganese oxides, which exist in the sandy aquifer. In fact, high organic matters that present in the unsaturated horizon are believed to be responsible for the high Mn content in the soil. It was observed that the soil samples collected from high elevation area (BK) comprises considerable amount of Fe in both unsaturated (6675.87 mg/kg) and saturated horizons (31440.49 mg/kg) compared to the low Fe content in the low lying area. Based on the stability diagram, the groundwater composition lies within the stability field for Mn2+ and Fe2+ under suboxic condition and very close to the FeS/Fe2+ stability boundary. This study also shows that both pH and Eh values comprise a strong negative value thus suggesting that the redox potential is inversely dependent on the changes of pH.  相似文献   

7.
The upper Bashkirian-Moscovian Kapp KIre Formation is well-exposed in coastal cliff sections along the west coast of Bjørnøya, Svalbard. It is composed of stacked cycles of nixed siliciclastics and carbonates in the lower Bogevika Member and of cyclic shelf carbonates in the overlying Efuglvika Member. The uppermost Kobbebukta Member consists of shelf carbonates and syntectonic conglomerates and sandy turbidites. The shift in cycle types reflects an overall transgression of the region during the Moscovian combined with renewed tectonic activity and uplift of eastern Bjørnøya during the late Moscovian. Twelve carbonate facies and 6 siliciclastic facies are distinguished. The carbonate facies range from intertidal dolomitic mudstones with pseudomorphs after gypsum to subwavebase, intensely bioturbated wackestones. Most carbonates are deeper subtidal facies and shallow marine carbonate facies are only common in the transgressive part of mixed siliciclastic-carbonate cycles of the Bogevika Member. Incorporating the effects of high amplitude, high frequency glacioeustacy and active extensional tectonism, a dynamic model is developed to explain the spatial variability of facies observed within the Kapp Kke Formation. Observations from Bjørnøya are placed within the context of the regional structural and stratigraphic framework so that significance of the study to ongoing exploration efforts in the Barents Sea can be evaluated. Most important, our observations suggest that dolomitized, porous carbonate buildups are most likely to be found in the upper Moscovian succession in areas where accommodation space increased temporarily due to local tectonism.  相似文献   

8.
Lukas Plan   《Geomorphology》2005,68(3-4):201-212
Carbonate dissolution rates were investigated by measuring the mass difference of carbonate tablets exposed to natural dissolution for 1 year. 70 tablets were distributed over 13 test sites on the north slope of the Hochschwab Massif in the Austrian Alps. The influences of altitude, subsoil vs. sub-aerial exposure, vegetation, karst morphology, soil humidity, sample lithology, and sample surface morphology were investigated. The observed dissolution rates varied between 13 and 40 μm/a for subcutaneous samples and about 11 μm/a for sub-aerial exposure. Outstandingly high rates of 48 μm/a were observed in a doline and nearly zero rates were measured at a site influenced by seeping spring water.A mass balance, using high-resolution hydrological data, was calculated for the Kläffer Spring, which has an average outflow of 4.8 m3/s. It indicated a loss of 21×106 kg of carbonate rock per year which gives an average dissolution rate of 95 μm/a for the catchment area of 83 km2. The dissolution rates of 10 μm/a from the sub-aerially exposed samples are comparable to values from limestone pedestals, which were protected from dissolution by glacial erratics for the past 15 ka.  相似文献   

9.
Studies were conducted at a Livestock Farm in an arid region of Pakistan, to determine the uptake of mineral nutrients from the food of buffaloes. Samples of feed, water, forage, soil as well as blood, milk, urine, and faeces of the animals were collected and analysed for K+, Ca2+, and Fe2+ during summer and winter. The results showed that the concentrations of K+ and Ca2+ in plants were low, whereas that of Fe2+ was high. In animals, K+ was not found in the milk in significant amounts, rather it was excreted in the urine. The calcium taken in by the animals was used for the synthesis of milk, as a result of which low Ca2+ concentrations were detected in urine. Mineral nutrient concentrations (K+ and Ca2+) in forage plants and water were lower than the optimum requirement of the animals, as a result of which blood plasma contained lower amounts of minerals (K+ and Fe2+) than that of the normal animals or critical limits. From the findings of the present study, it can be concluded that the buffaloes raised at the livestock farm had a severe deficiency of mineral nutrients, particularly K+ in lactating and Fe2+ in both lactating and non-lactating animals. Feed supplements, that can overcome these deficiencies, should be used for the optimum growth, milk production and resistance to diseases.  相似文献   

10.
四川盆地西部宫钾卤水以深层卤水形式赋存于地下４０００余ｍ的中三叠统雷口坡组四段（Ｔ２ｌ４）盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比，其中含Ｋ＋含量异常高，构成液态钾矿资源；Ｂｒ－、Ｉ－、Ｂ（３＋）、Ｌｉ＋等稀有组分也远超过综合利用工业品位，为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因，具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。  相似文献   

11.
Song  Yanchen  Wang  Enze  Peng  Yuting  Xing  Haoting  Wu  Kunyu  Zheng  Yongxian  Zhang  Jing  Zhang  Na 《Natural Resources Research》2021,30(6):4355-4377

The Paleogene upper Xiaganchaigou Formation (E32) is the most important source rock and reservoir in the Qaidam Basin. However, there are few studies on the processes of hydrocarbon accumulation in this formation; therefore, its hydrocarbon resource potential has not been estimated reasonably. This paper evaluates the hydrocarbon generation properties in light of an improved hydrocarbon generation and expulsion potential model. According to the geochemical characteristics of source rocks and the petrological features of reservoirs, the potentials of different resource types, including conventional oil, tight oil and shale oil, are quantified by combining the buoyancy-driven hydrocarbon accumulation depth (BHAD) and the lower limit for movable resource abundance. The results show that the source rocks are characterized by a large thickness (more than 1000 m), moderate organic matter content, high marginal maturity and a high conversion rate (50% hydrocarbons have been discharged before Ro?=?1%), which provide sufficient oil sources for reservoir formation. Moreover, the reservoirs in the Qaidam Basin consist mainly of low-porosity and low-permeability tight carbonates (porosity of 4.7% and permeability less than 1 mD). The maximum hydrocarbon generation, expulsion, retention and movable retention intensities at present are 350?×?104 t/km2, 250?×?104 t/km2, 130?×?104 t/km2 and 125?×?104 t/km2, respectively. The thresholds of hydrocarbon generation, expulsion and BHAD were 0.46% Ro, 0.67% Ro and 0.7% Ro, respectively. Moreover, the dynamic evolution process of hydrocarbon accumulation was divided into three evolution stages, namely, (a) initial hydrocarbon accumulation, (b) conventional hydrocarbon reservoir and shale oil accumulation and (c) unconventional tight oil accumulation. The conventional oil, tight oil and movable shale oil resource potentials were 10.44?×?108 t, 51.9?×?108 t and 390?×?108 t, respectively. This study demonstrates the good resource prospects of E32 in the Qaidam Basin. A comprehensive workflow for unconventional petroleum resource potential evaluation is provided, and it has certain reference significance for other petroliferous basins, especially those in the early unconventional hydrocarbon exploration stage.

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12.
Several lacustrine basins were formed by late Miocene tectonic processes in western Macedonia, Greece. These were occupied by a series of lakes and wetland swamps during the late Miocene and early Pliocene giving rise to diatomaceous claystones, siltstones and diatom-bearing tufa deposits. Diatoms are rare or fragmentary in sandstones and chemical sediments, and are absent in conglomerates. The Fe2+-rich phosphate minerals anapaite and vivianite are present in parts of the diatomaceous siltstones. Six major diatom groups were identified using cluster and correspondence analyses, each of which tends to be associated with a particular lithofacies. The floras are indicative of mildly acidic to alkaline water of varying depths. The dominant taxa include Aulacoseira ambigua, A. distans, Cyclotella iris and several of its varieties, C. aegeae, C. castracanei, C. elymaea, C. ocellata, and two unidentified Cyclotella. Fragilariaceae are common, consisting mainly of Fragilaria bituminosa, Pseudostaurosira brevistriata, P. zeilleri, Staurosira construens, Staurosirella leptostauron, and S. pinnata. Locally, chysophycean stomatocysts are common, suggesting more oligotrophic conditions. Nine diatom stages are recognized in the Lower Neogene Series at Kariditsa (Kozani basin), reflecting shallow swamps, small alkaline lakes, and terrestrial settings. The Upper Neogene Series rocks are characterized by Mg-rich carbonates such as hydromagnesite, huntite and magnesite. A detailed stratigraphy was developed for Mio-Pliocene deposits in the Florina basin at Klidi. Parts of this sequence show clear cyclicity in both the sediments and the diatom floras, with shallow-water diatoms repeatedly giving way to taxa indicative of deeper conditions. Larger-scale, shallow-deep cycles are also present and may be related to precession- and eccentricity-forced climate change.  相似文献   

13.
Comprehensive spectroscopic characterization of interior and exterior chips of the lherzolitic shergottite Y-984028 has been performed using results from six techniques. Data from UV–visible–near-IR reflectance spectra, thermal (mid-IR) emission spectra, attenuated total reflectance (ATR) spectra, transmission FTIR spectra, Raman microprobe spectra, and Mössbauer spectra of whole rock and mineral separates from this meteorite are integrated and compared. Five of these analytical techniques accurately determined the ～Fo65 composition of the olivine within ±10 mol%. Both transmission FTIR and ATR spectra show broad features near 3500 cm?1 indicating the presence of OH/H2O that does not arise from surface water adsorption. The brown color of the Y-984028 olivine is likely due to the presence of nanophase metallic iron particles (npFe0) dispersed throughout the olivine during a major shock event on Mars. Y-984028 olivine also contains a significant amount of Fe3+, but this cannot be distinguished from Fe3+ that is present in pyroxene and possibly clay minerals. This meteorite and the nakhlite MIL03346 are the two most oxidized of the SNC meteorites studied to date, with Fe3+ contents consistent with high-temperature equilibration near the QFM oxygen buffer.  相似文献   

14.
分形方法在庐山第四纪沉积环境研究中的应用*   总被引：6，自引：0，他引：6  
朱诚  于世永 《地理研究》1996,15(3):64-69
沉积物中Fe3+/Fe2+的值与形成时的古温度有益指数关系。假定Fe3+/Fe2+的值沿剖面的变化具有自相关性,那么它所反映的古温度变化是一条分形曲线。本文以庐山大校场剖面为例,根据孢粉和Fe3+/Fe2+的测试数据,建立了一个推算古温度的非线性公式。据此推算的古温度表明,本区中更新世以来共有3次明显的冷暖波动,最高年均温在22℃左右,最低达3℃左右,出现在末次冰期。未发现有低于0℃者。由粒度分数维的概念,推导出的计算公式可作为混杂堆积物粒度分布特征的度量指标。根据计算,该剖面主要接近于泥石流和石冰川的粒度分数维,而与冰碛物的粒度分数维有较大差别。综上得出,本区沉积物成因主要是间冰期季风气候下的山地泥石流和沟谷流水的洪-冲积及冰期干冷的冰缘环境下的冻融堆积。  相似文献   

15.
Physicochemical, mineralogical, and geochemical characteristics of 279 highly calcareous lacustrine sediment samples obtained from a 30 m drilling core in the western part of the Great Konya Basin, Turkey were studied. The sediments have a predominance of silt and clay fractions with a median diameter of 3–5 μm. Vertical changes of the amounts of water soluble components, gypsum, carbonates, and non-salt minerals such as quartz, feldspars, and layer silicates in the sediments suggest that there were climatic changes in the Konya Basin. The dominant clay mineral is smectite followed by kaolinite, illite, and palygorskite. The oxygen isotopic (δ18O) ratios of six quartz samples from the Konya sediments, a terra rossa soil beside Lake Bey ehir gölü and paleosols at the foot of Mt. Erciyes Da ranged from +18.1 to +20.6‰. The dominant clay minerals and δ18O ratios suggest that part of quartz and coexisting layer silicates is of long-range transported and/or local aeolian dust origin from arid and semi-arid regions such as North Africa, Israel, and the surroundings. The relatively high deposition rate might be due to aeolian dust input and/or the sediment input introduced by the rivers such as the Çar amba river from the Toros (Taurus) mountains. The vertical distributions of electro-conductivity, amounts of water soluble and non-salt components, and the gypsum content of the sediments suggest that gypsum-rich layers were formed under shallow, saline waters, possibly associated with warm to hot and dry environments such as the Last Interglacial epoch and the Early Holocene. The sediments characterized by relatively high amounts of non-salt sediments, in which gypsum did not accumulate, could be deeper water phases formed under the cold and/or wet environments such as the Glacial epochs.  相似文献   

16.
We used environmental tracers to provide insights into groundwater evolution and flow processes on the eastern margin of China's Tengger Desert and determine recharge sources and recharge timing along the flow paths. The chemical composition was generally Na+ enriched, with no dominant anions. The chemistry is strongly influenced by evaporation and subsequent dissolution of minerals during recharge in the rainy season. Other processes, including cation exchange and weathering, also contribute to the water composition. The median groundwater δ18O value was around −9.1‰, and most groundwater in the basin was depleted in heavy isotopes. δ13C in deep groundwater ranged from −4.73 to −9.56‰, indicating that carbonate mixing is common but that isolated carbonate still exists. Radiocarbon values in groundwater ranged from 5.4 to 63.5 pmc. We estimated a residence time of 17.9 and 19.6 kyr at two desert sites, revealing that some replenishment of desert aquifers occurred in the late Pleistocene and early Holocene, when some of the upper reaches of rivers were characterized as modern water.  相似文献   

17.
Lacustrine limestones were formerly identified by their faunistic (limnea, planorbis) and floristic (Charophytes) content. For 30 years, indications of pedogenesis have been found in many lacustrine deposits, and consequently the concept of palustrine limestone was defined.Lacustrine fabrics are not that numerous: varved, laminated, homogeneous, peloidal, brecciated, gravelly, bioturbated (burrows), bioclastic, algal, and stromatolitic. Detrital beds are sometimes present and are interpreted as bottomset deposits. Palustrine fabrics result from exposure and pedogenesis of lacustrine mud. The main processes involved in this evolution are: cracking, with planar, curved, craze and skew planes, colonization by plants resulting in root traces, marmorization (redistribution of iron due to water table fluctuation), and redistribution of carbonates (needles, subspherical or cylindrical vertical nodules, carbonate coatings, early and late diagenetic crystals, Microcodium). Carbonate palustrine features can be associated with other minerals: palygorskite, gypsum, or silica. Alternation of lacustrine sedimentation and exposure/pedogenesis leads to the pseudo-microkarst facies resulting from enlargement of the complex network of root traces and horizontal cracks. The voids in the pseudo-microkarst facies are infilled with a polyphased internal sediment composed of carbonate and vadose silt and phreatic and vadose cements. Traces of exposure and pedogenesis are less in evidence in lacustrine bioclastic sands and algal-stromatolitic limestones. Finally, under certain conditions, the surficial laminar horizon and its associated perlitic crust (ooids) develops on palustrine muds and form a desert stromatolite.  相似文献   

18.
The diagenetic evolution of Permian (Autunian and Saxonian) and Triassic (Buntsandstein) sandstones and mudrocks have been studied over 1000 m sequence from the Sigüenza 44‐3 drill core in the Iberian Range, Spain. We compare and contrast the diagenetic processes in these different lithologies and the timing of clay mineral formation. Moreover, we establish the relationship between clay mineral diagenesis and reservoir potential. Both the Permian and Triassic successions are characterised by conglomerates, sandstones and interbedded mudstones of fluvial origin that change upwards into distal deposits of a fluvio‐deltaic system. The clay minerals are illite, illite‐smectite mixed layers, kaolinite and dickite. The illite content in all sequences is not related to diminished feldspars; it is owing to the initial detrital mineralogical composition of the Autunian sandstones. The effect of feldspar alteration to kaolin minerals has a strong influence on the lost of porosity‐permeability in the Saxonian facies. In contrast, illite and mixed layers illite‐smectite are the main clay rims preserving porosity in the Buntsandstein sandstones. However, fibrous illite is the dominant pore‐filling in the Permian Autunian facies, closing porosity and permeability. Kaolinite and dickite show opposite trends: dickite increases yet kaolinite decreases from Triassic to Permian sandstones. Dickite replaced kaolinite during burial‐thermal evolution of the succession. The δD and δ18O isotopic signatures from silt and clay fractions indicate a mixture of meteoric and marine waters, and suggest a minimum temperature range between 60 and 150 °C for diagenetic pore fluids. The Permian δD values (?24‰ to ?44‰) are relatively similar to Buntsandstein values (?24‰ to ?37‰). However, the Permian δ18O values (+7.6 and +15.3, average of +13.3‰) are generally higher by ca. 6.2‰ compared to the Buntsandstein data (4.8–10.1‰, average +7.1‰). Such a variation is interpreted as the result of mesodiagenetic pore fluid changes. The extensive dickitisation of kaolinite is attributed to increased hydrogen ions resulting from maturation of organic matter. The vitrinite reflectance of organic matter and the modelled thermal history suggest a maximum burial of 3400 m, accomplished 70 Ma ago. The Permo‐Triassic reached the gas window shortly before major uplift, at 65 Ma, when further maturation and hydrocarbon expulsion ceased.  相似文献   

19.
A combination of water and sediment chemistry was used to investigate carbonate production and preservation in Lake Pumayum Co (altitude 5,030 m a.s.l.), south Tibet, China. We compared the chemical composition of lake water in various parts of the lake with that of input rivers and found that the loss of Ca2+ results from calcite sedimentation induced by evaporation and biogenic precipitation. This is supported by evaporation data from the catchment and δ18O measurements on water. Results suggest that CaCO3 is the predominant carbonate in this lake. There is a positive correlation in the sediments among concentrations of total inorganic carbon (TIC), Ca, total organic carbon (TOC), and total nitrogen, confirming that most carbonates in sediment are endogenic. The Jiaqu River is the largest inflow to Lake Pumayum Co and has a strong influence on both lake water chemistry and sediment composition. The river and lake bathymetry influence carbonate sedimentation by affecting water flow velocity and growing conditions for macrophytes. Different carbon contents and relationships between TIC and TOC in the two long cores from different depths in the lake reveal that hypolimnetic conditions also influence carbonate precipitation and preservation.  相似文献   

20.
Introducing and applying an appropriate strategy for reservoir modeling in strongly heterogeneous and fractured reservoirs is a controversial issue in reservoir engineering. Various integration approaches have been introduced to combine different sources of information and model building techniques to handle heterogeneity in geological complex reservoir. However, most of these integration approaches in several studies fail on modeling strongly fractured limestone reservoir rocks of the Zagros belt in southwest Iran. In this study, we introduced a new strategy for appropriate modeling of a production formation fractured rock. Firstly, different rock types in the study area were identified based on well log data. Then, the Sarvak Formation was divided into nine zones, and the thinner subzones were used for further fine modeling procedure. These subzones were separated based on different fracture types and fracture distribution in each zone. This strategy provided sophisticated distribution of petrophysical parameters throughout the grids of the model, and therefore, it can handle strong heterogeneity of the complex reservoir. Afterward, petrophysical parameters were used to produce an up-scaled 3D gridded petrophysical model. Subsequently, maps of petrophysical properties were derived for each zone of the Sarvak Formation. Evidences achieved in this study indicates Sarvak Formation zone 2 as the target production zone with better performance of reservoir rock and the southwestern part of the field as area of maximum porosity.  相似文献   

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