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1.
松树沟元古宙蛇绿岩Nd、Sr、Pb同位素地球化学特征   总被引:22,自引:1,他引:21       下载免费PDF全文
松树沟蛇绿岩中镁铁质岩的Sm-Nd全岩等时年龄为1030±46Ma,∈Nd(t)=+5.7,模式年龄在1422-1271Ma之间,矿物的内部等时年龄为983±140Ma。全岩等时年龄为其形成上限,矿物内部等时年龄为其变质年龄,说明该蛇绿岩形成于中元古代中、晚期。镁铁质岩的∈Nd(t)在+4.2-+6.9之间,是DMM与EMI两个地幔端元的混合产物;206Pb/204Pb在18.06-18.66之间,207Pb/204Pb和208Pb/204Pb值较高,分别在15.55-15.60和37.59-38.38之间,207Pb/204Pb和208Pb/204Pb对206Pb/204Pb的关系表明,岩浆源于具DUPAL异常的源区,(207Pb/204Pb)i相对(208Pb/204Pb)i更偏离NHRL可能是变质流体作用的反映。∈Sr(t)值较高且变化大,可与蛇绿岩类比,87Sr/86Sr比值变化大,可能与海水蚀变作用有关。据此推测,松树沟蛇绿岩代表洋壳残片。  相似文献   

2.
花岗岩可以有效示踪大陆基底物质,并区分具有不同地壳结构和演化历史的构造块体。洪镇花岗岩位于长江中下游地区江北A型花岗岩带的西延位置,距离郯庐断裂带约30 km。锆石SIMS定年表明,安庆怀宁县洪镇花岗岩形成于126.2±2.0 Ma,与长江中下游A型花岗岩以及大别造山带I型花岗岩的形成时代一致。洪镇花岗岩高硅、富钾,属于高钾钙碱性系列I型花岗岩。其富集轻稀土元素和大离子亲石元素,相对亏损中稀土元素和高场强元素,经历了角闪石为主的结晶分异。洪镇花岗岩具有较为富集的Sr—Nd—Hf同位素,和低放射性成因Pb同位素组成,其n(87Sr)/n(86Sr)(t)为0.7065~0.7066,εNd(t)值为-10.9~-12.0,锆石εHf(t)为-6.7~-13.2,n(206Pb)/n(204Pb)(t)、n(207Pb)/n(204Pb)(t)和n(208Pb)/n(204...  相似文献   

3.
陈静  陈双双  高锐  刘嘉麒 《岩石学报》2023,(8):2379-2401
沙茨基海隆(Shatsky Rise)是白垩纪早期形成的西北太平洋大火成岩省,其成因和演化过程目前仍存在较大争议。本次研究对沙茨基海隆白垩纪玄武岩进行了全岩主量、微量元素、Sr-Nd-Pb同位素的分析。沙茨基海隆玄武岩主要属于拉斑玄武岩,具有较亏损的大离子亲石元素和轻稀土元素以及较富集的重稀土元素的特征,没有明显的Eu异常(δEu=0.99~1.29),与正常洋中脊玄武岩(N-MORB)的微量元素配分模式较为相似。然而该系列玄武岩却具有相对较富集的初始87Sr/86Sr(0.702986~0.703991)和143Nd/144Nd(0.513034~0.513194)同位素比值、较富集的207Pb/204Pb(15.439~15.508)和208Pb/204Pb(37.853~38.488)同位素比值,与富集的洋岛玄武岩(OIB)和岛弧火山岩的同位素成分较为相似,且源区混入高U/Pb比值(HIMU型)的富集地幔成...  相似文献   

4.
哈毕力格铀矿床位于华北陆块北缘中段,主要受乌兰哈达—猴儿山背斜和区内断裂控制。铀矿化主要产于新太古界乌拉山群第二岩段石英岩中,一直被认为是变质成因铀矿床。在分析该矿床成矿地质背景和矿化特征的基础上,系统研究了矿石与围岩中黄铁矿的硫、铅同位素特征。数据表明,硫同位素组成变化于-4.7‰~12.9‰之间,暗示成矿流体主要来自岩浆热液,同时遭受了地层物质的混染。铅同位素组成(208Pb/204Pb=36.147~42.968,207Pb/204Pb=15.919~34.268, 206Pb/204Pb=19.488~168.032)远高于单阶段演化模式组成,不同样品的207Pb/204Pb-206Pb/204Pb线性关系良好,为典型的二阶段铅同位素演化体系,表明变质地层为成矿作用提供了铀源。通过放射性207Pb/206Pb计算,结合区域岩浆演化,认为古元古代(~1 805 Ma)区域变质作用促使乌拉山群铀发生初步富集,晚古生代(374 Ma)花岗闪长质岩浆分异出大量流体活化萃取变质地层中的铀,在有利构造空间富集成矿。  相似文献   

5.
松辽盆地徐家围子断陷营城组火山岩中含有粗面质岩石,是深层天然气重要储层之一。岩心、钻井及地震资料研究表明,粗面岩具有高位喷发、低位充填的特征,在火山口附近厚度大,远离火山口厚度小。粗面岩主量、微量及同位素地球化学显示其属于钾玄岩系列,富集稀土元素,强不相容元素Rb、Ba、Th、U质量分数较高。粗面岩的(87Sr/86Sr)i=0.704 321~0.705 395,εNd(t)为正值(3.36 ~ 3.83),Pb同位素比值相对集中,(206Pb/204Pb)i、(207Pb/204Pb)i、(208Pb/204Pb)i平均值分别为18.43、15.51和38.23。研究表明,粗面质岩浆由区域年轻地壳组分部分熔融形成,经历了一定程度的分离结晶作用,地壳混染作用不显著。粗面质岩浆多期次喷发后形成粗面岩,热液气体不断聚集发生隐蔽爆破形成角砾,未固结的角砾被岩浆期后热液“胶结”,形成隐爆角砾岩,构成了粗面质岩石重要的储层类型。  相似文献   

6.
北达巴特斑岩型铜钼矿床位于西天山造山带北部。矿区钼矿化分布于流纹斑岩体内部,铜矿化受断裂构造控制,分布于流纹斑岩与地层的接触带附近。据矿物组合特征与交代关系,将成矿过程划分为3个阶段:早期石英—辉钼矿阶段,中期黄铁矿—黄铜矿—石英阶段,晚期萤石—黄铜矿阶段。对早阶段辉钼矿与晚阶段黄铜矿分别进行了Pb同位素分析。辉钼矿的208Pb/204Pb值为38.125~38.179,207Pb/204Pb值为15.570~15.575,206Pb/204Pb值为18.293~18.311,Pb同位素构造判别投点落在地壳和地幔范围内,有向造山带线靠近的趋势,指示成矿物质主要来源于地幔,流纹斑岩提供了主要的钼来源。黄铜矿208Pb/204Pb值为38.202~38.257,207Pb/204Pb值为15.581~15.621,206Pb/204  相似文献   

7.
内蒙古东乌旗阿尔哈达铅-锌-银矿床硫和铅同位素研究   总被引:5,自引:0,他引:5  
阿尔哈达铅-锌-银矿床是近年来在内蒙古东乌珠穆沁旗境内发现的一处大型铅-锌-银矿床,其产出环境和形成机理为国内外矿床学家所关注。对该矿床代表性岩(矿)石样品进行了硫和铅同位素分析,并对其变化规律和成因意义进行了讨论。研究结果表明,围岩和矿石中硫化物δ34S值变化范围为1.2‰~8.6‰,具有混源硫特征。根据共生硫化物对所确定的温度表明,该矿床的形成可划分为高温和中-低温两个阶段。17件矿石硫化物样品206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值变化范围分别为18.153~18.431,15.370~15.602和37.653~38.213,其平均值分别为18.271、15.464和37.873;3件围岩硫化物样品206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值变化范围分别为18.281~18.293,15.470~15.484和37.874~37.909,平均值分别为18.288、15.477和37.893。硫和铅同位素研究结果表明,阿尔哈达铅-锌-银矿床成矿物质分别来自泥盆系火山-沉积岩和印支期花岗岩。  相似文献   

8.
The Hua’aobaote Pb-Zn-Ag Polymetallic orefield is situated in the southern section of the Great Xing’an Range(GXAR),which has experienced extensive magmatism.Since the Paleozoic,there are two stages of magmatism in Hua’aobaote orefield occurred in the Paleozoic and Mesozoic.The Mesozoic magmatism is of great significance for the PbZn-Ag Polymetallic mineralization in Hua’aobaote orefield.In this study,new geochemical data was obtained to discuss the timing and petrogenesis of the magmatic rocks and its geodynamic and metallogenic significance.Zircon U-Pb ages reveal that the felsic igneous rocks from the Hua’aobaote orefield were formed in the Early Permian(294.8±3.2 Ma)and Early Cretaceous(132.6±1.4 Ma).Geochemically,the Early Permian granodiorite porphyrite is characterized by high Sr/Y(42-63)ratios and Mg#(62.24-70.74)values and low heavy rare earth element(HREE)(5.09-6.79 ppm)contents.The granodiorite porphyrite is also characterized by depleted Sr-Nd initial isotopic signatures[εNd(t)=5.91-7.59,(87Sr/86Sr)i=0.7029-0.7030],exhibiting adakitic characteristics.The Early Cretaceous granite porphyry and rhyolite are A-type felsic igneous rocks,and demonstrate high SiO2,Na2O+K2O and rare earth element(REE)contents,low CaO and MgO contents,low(87Sr/86Sr)i ratios(0.7044-0.7058),and positive εNd(t)values(2.57-4.65).Whole-rock Pb isotopic compositions in granodiorite porphyrite are:206Pb/204Pb=17.631-18.149,207Pb/204Pb=15.422-15.450,and 208Pb/204Pb=37.325-37.729.The granite porphyry and rhyolite have initial 206Pb/204Pb,207Pb/204Pb,and 208Pb/204Pb ratios of 18.106-19.309,15.489-15.539,and 37.821-38.05,respectively.Sr-Nd-Pb isotopic evidence suggests that the Early Permian granodiorite porphyrite is likely to derive from slab melts and modified by peridotitic mantle wedge in the subduction tectonic setting of the Paleo-Asian Ocean.The Early Cretaceous A-type felsic igneous rocks were derived from juvenile lower crust,accompanied by limited crustal contamination and various degree of fractional crystallisation during magma emplacement.The Early Cretaceous magmatism and related mineralization were formed in a post-orogenic tectonic setting that attributed to the closure of the Mongol-Okhotsk Ocean.Pb isotopic data for the various rock units in the study area indicate that the Mesozoic magma source contributed substantial Pb,Zn,and Ag to the Hua’aobaote deposit.  相似文献   

9.
鄂东南地区程潮大型矽卡岩型铁矿区岩体成因探讨   总被引:2,自引:0,他引:2  
湖北程潮铁矿是鄂东南矿集区内最大的矽卡岩型铁矿床。为了系统研究矿区内不同侵入体的成因,对程潮矿区内不同时代的侵入体进行了矿物学、地球化学和Sr-Nd-Pb同位素研究。矿区内花岗岩、石英二长斑岩、闪长岩中的黑云母成分特征暗示它们均为壳幔物质混合成因的镁质黑云母;与成矿相关的花岗岩、石英二长斑岩中原生黑云母矿物学成分显示出原始岩浆具有高氧逸度的特征,高氧逸度为磁铁矿的形成提供了有利条件。岩石地球化学特征研究表明,不同类型的岩石都具有富钾和准铝质的特征,富集Rb、Ba、K等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti等高场强元素。矿区岩石的(87Sr/86Sr)i值为0.705 0~0.709 1,εNd(t)值为-14.16~-6.95,206Pb/204Pb值为17.636~18.919,207Pb/204Pb值为15.451~15.613,208Pb/204Pb值为37.833~39.556。矿物学、地球化学、Sr-Nd-Pb同位素特征暗示矿区岩体为富集地幔发生部分熔融并同化混染了不同比例下地壳物质的产物,早期闪长岩((140±1) Ma)比晚期花岗岩和石英二长斑岩((128±1) Ma)的源区有更多的地幔成分,花岗岩和石英二长斑岩与闪长岩具有相近的锆石饱和温度(平均值分别为783、788、765℃)。  相似文献   

10.
锶同位素已经成为全球海平面变化、造山运动、古气候和古环境等全球地质事件研究与对比的有效工具之一。本文以四川盆地东部地区早中三叠世蒸发岩的野外剖面和钻孔岩心为主要研究对象,测试了碳酸盐岩、硫酸盐岩和石盐岩的锶同位素组成,并建立了相应的锶同位素演化曲线。研究结果显示,碳酸盐岩的87Sr/86Sr值平均为0.707 895,硬石膏岩的87Sr/86Sr值平均为0.708 174,石盐岩的87Sr/86Sr值平均为0.708 177,同时碳酸盐岩的87Sr/86Sr值从早三叠世的0.707 413快速增加到中三叠世早期的0.708 515,而后呈现下降趋势。从总体上看,这些87Sr/86Sr值与全球早中三叠世同期的87Sr/86Sr值数据接近,说明四川盆地东部地区早中三叠世钾盐的物质来源大部分为海水,并沉积于海相沉积环境,同时由于火山...  相似文献   

11.
《Gondwana Research》2006,9(4):529-538
Sr, Nd and Pb isotopic compositions of the Cenozoic basalts were analyzed from Baengnyeongdo Island, Jeongok, Ganseong, and Jejudo Island of Korea. They reveal relatively enriched Sr and Nd isotopic compositions (87Sr/86Sr = 0.70330∼0.70555, 143Nd/144Nd = 0.51298∼0.51256) compared with MORB.207Pb/204Pb and 208Pb/204Pb values of all the analyzed Korean basalts lie above the Northern Hemisphere Reference Line (NHRL) defined by Hart (1984). Pb isotopic compositions of basalts from Jejudo Islands (206Pb/204Pb = 18.61∼19.12, 207Pb/204Pb = 15.54∼15.69, 208Pb/204Pb = 38.98∼39.72) are significantly more radiogenic than the rest (206Pb/204Pb = 17.72∼18.03, 207Pb/204Pb = 15.44∼15.58, 208Pb/204Pb = 37.77∼38.64). The Cenozoic Korean basalts thus can be divided into two groups based on their Sr, Nd and Pb isotopic compositions. The north group reveals mixing between DMM and EM1 while the south group displays DMM-EM2 mixing. Such a distribution is the same as Chinese Cenozoic basalts and it can be interpreted that the subcontinental lithospheric mantle under Korea represents simple lateral continuation of the South and North China Blocks. We suggest that Korean continental collision zone cross the Korean Peninsula through the region between the north and south basalt groups of Korea.  相似文献   

12.
The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs.  相似文献   

13.
We analyzed 17 fragments from a zoned allanite–epidote crystal (ca 2.2 mm × 4.0 mm), which had formed during different prograde and retrograde stages of ultra high pressure (UHP) and amphibolite facies metamorphism (240–230 Ma, Sulu Belt, E China), for the isotopic composition of Pb, Nd, and Sr and contents of Pb, U, and Th, Sr and Rb, and Nd and Sm. Since most fragments had 238U/204Pb and 232Th/204Pb values less than 1, corrections for in situ Pb growth are small and uncertainties in the recalculation of the Pb isotopic compositions to 240 Ma are insignificant. The recalculated Pb falls on a linear trend in the 206Pb/204Pb vs 207Pb/204Pb diagram with the allanite defining the low–206Pb/204Pb end (17.07) of this trend and the epidote defining its high–206Pb/204Pb end (17.56). The recalculated data scatter in the 206Pb/204Pb vs 208Pb/204Pb diagram, which implies that the initial Pb isotopic variation reflects the involvement of at least three different Pb sources. The low 87Rb/86Sr values account for a change in 87Sr/86Sr by in situ 87Sr growth of less than 0.0007, which implies that the isotopic heterogeneity of 87Sr/86Sr (0.70601–0.7200) is a primary feature. The Pb and Sr isotope data unequivocally demonstrate that contributions from different precursor minerals result in initial isotopic heterogeneity in the metamorphic reaction product. It is likely that such an initial isotopic heterogeneity also exists for Nd, but it could not be resolved in the present study. Initially heterogeneous Pb and Sr isotope compositions imply that age differences between core and rim of large crystals may result in the determination of highly arbitrary geological rates, especially for minerals with relatively low parent-to-daughter ratios.  相似文献   

14.
28 samples of Cenozoic volcanic rocks collected from Shandong Province have been dated by K-Ar method. They are mainly Neogene with an age range of 4–19 m. y. The basalts from Linqu and Yishui in west Shandong Province are Miocene and those from Penglai and Qixia in east Shandong Province are Miocene and Pliocene in age. The basalts from Wudi in north Shandong Province are Middle-Early Pleistocene in age. In each area the duration of volcanic eruption was estimated at about 2–3 m. y. Pb and Sr isotopic compositions and U, Th, Pb, Rb, Sr, and major elements in most of the samples were determined. The isotopic compositions are:206Pb/204Pb—16.92-18.48,207Pb/204Pb—15.30-15.59,208Pb/204Pb—37.83-38.54, and (87Sr/86Sr)i—0.70327-0.70632. There are some positive or negative linear correlations between206Pb/204Pb and207Pb/204Pb, Pb isotopes and Pb content, Pb isotopes and Sr isotopes, and Sr isotopes and other elements. The basaltic rocks from east and west Shandong Province have somewhat differences in isotopic composition and element content. The basalts probably are products of multi-stage evolution of the mantle. They have preserved the primary features of the source, although they were influenced, to some extent, by the contamination of crustal materials.  相似文献   

15.
Seven hundred and twenty-five Sr, two hundred and forty-three Nd and one hundred and fifty-one Pb isotopic ratios from seven different Mexican magmatic provinces were compiled in an extensive geochemical database. Data were arranged according to the Mexican geological provinces, indicating for each province total number of analyses, range and mean of values and two times standard deviation (2σ). Data from seven provinces were included in the database: Mexican Volcanic Belt (MVB), Sierra Madre Occidental (SMO), Baja California (BC), Pacific Ocean (PacOc), Altiplano (AP), Sierra Madre del Sur (SMS), and Sierra Madre Oriental (SMOr). Isotopic values from upper mantle and lower crustal xenoliths, basement outcrops and sediments from the Cocos Plate were also compiled. In the MVB the isotopic ratios range as follows:87Sr/86Sr 0.703003-0.70841;143Nd/144Nd 0.512496-0.513098;206Pb/204Pb 18.567-19.580;207Pb/204Pb 15.466-15.647;208Pb/204Pb 38.065-38.632. The SMO shows a large variation in87Sr/86Sr ranging from ∼0.7033 to 0.71387.143Nd/144Nd ratios are relatively less variable with values from 0.51191 to 0.51286. Pb isotope ratios in the SMO are as follows:206Pb/204Pb 18.060-18.860;207Pb/204Pb 15.558-15.636;208Pb/204Pb 37.945-38.625. PacOc rocks show the most depleted Sr and Nd isotopic ratios (0.70232-0.70567 for Sr and 0.512631-0.513261 for Nd). Pb isotopes for PacOc show the following range:206Pb/204Pb 18.049-19.910;207Pb/2047Pb 15.425-15.734;208Pb/204Pb 37.449-39.404. The isotopic ratios of the AP rocks seem to be within the range of those from the PacOc. Most samples with reported Sr and Nd isotopic data are spread within and around the “mantle array”. The SMO seems to have been formed by a mixing process between mantle derived magmas and continental crust. The MVB appears to have a larger mantle component, with AFC as the dominant petrogenetic process for the evolved rocks. There is still a need for Pb isotopic data in all Mexican magmatic provinces and of Nd isotopes in BC, AP, SMS, and SMOr.  相似文献   

16.
An isotopic study was systemically carried out on the granitic complex, diorite-porphyrite, ores and ore minerals of the 103 Ma Xiaoxinancha gold-rich copper deposit in Jilin province to determine the geodynamic model of diagenesis and metallogenesis. Results show that the initial Nd and Sr isotopic compositions of the granitic complex are in the range of 0.70425–0.70505 for (87Sr/86Sr)i , 0.51243–0.51264 for INd, and –1.31 to +2.64 for εNd(t); those of the diorite-porphyrite are in the range from 0.70438–0.70448 for (87Sr/86Sr)i, 0.51259–0.51261 for INd, and +1.56 to +2.09 for εNd(t). For ores and sulfides, the (87Sr/86Sr)i , INd, and εNd(t) values are in the range from 0.70440–0.70805, 0.51259–0.51279 and +1.72 to +5.56, respectively. The Pb isotopic ratios of the granitic complex range from 18.2992–18.6636 for 206Pb/204Pb, from 15.5343–15.5660 for 207Pb/204Pb, and from 38.1640–38.5657 for 208Pb/204Pb. For diorite-porphyrite, the isotopic ratios of 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb are 18.3919, 15.5794 and 38.3566, respectively, whereas those of the ores and ore sulfides vary from 18.2275–18.3770 for 206Pb/204Pb, from 15.5555–15.5934 for 207Pb/204Pb and from 38.1318–38.3131 for 208Pb/204Pb. The results indicate that the mineralization was correlated to the formation and evolution of the granitic complex and the diorite-porphyrite. Combining with the reported data in petrologic characteristics, elemental geochemistry and chronology, conclusions can be drawn that the geodynamic settings of diagenesis and metallogenesis of this deposit were consistent with the subduction of the Izanagi oceanic plate during the Early Cretaceous. The diorite-porphyrite was formed by the emplacement of the adakitic magma triggered by partial melting of the enriched mantle, which originated from the derivative continental lithospheric mantle metasomatized by dehydration fluids from the subducting oceanic crust. The granitic complex was produced by fractional crystallization of the mixture between the adakitic magma and the high-K calc-alkaline acidic magma, which were generated by the remelting of the lower crust in the course of intraplate upwelling of the adakitic magma. The ore-bearing fluid reservoir convened in a late stage of the evolution of the mixed magma chamber.  相似文献   

17.
西藏东部玉龙铜矿带,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多含矿斑岩,马牧普钾质碱性斑岩和总郭碱性火山岩等Sr、Nd、Pb同位素组成比较一致,其数据点均分布在地幔演化区,接近EMI地幔端元,暗示其物质来源于交代地幔源区。  相似文献   

18.
This study presents Sr and Pb isotopic ratios and Rb, Sr, U, Th, and Pb concentrations of an ultrapotassic basaltic suite and related rocks from the central Sierra Nevada, California. The ultrapotassic suite yields a narrow range of Sr and Pb isotopic compositions (87Sr/86Sr=0.70597–0.70653; 206Pb/ 204Pb=18.862–19.018; 207Pb/204Pb=15.640–15.686; 208Pb/ 204Pb=38.833–38.950). Associated basalts containing ultramafic nodules have less radiogenic Sr (87Sr/86=0.70430–0.70521) and generally higher Rb/Sr ratios than the ultrapotassic suite. Leucitites from Deep Springs Valley, California, contain high 87Sr/86Sr (71141–0.71240) and low 206Pb/204Pb (17.169–17.234) ratios, reflecting contamination by crustal granulite.The isotopic relationships support an origin of the ultrapotassic basaltic suite by partial melting of an enriched upper mantle source. Dehydration of a gently inclined oceanic slab beneath the Sierra Nevada may have provided Ba, K, Rb, Sr, and H2O, which migrated into the overlying upper mantle lithosphere. The end of subduction 10 m.y. ago allowed increased asthenospheric heat flow into the upper mantle lithosphere. The increased heat flow enhanced fluid movement in the upper mantle and contributed towards isotopic homogenization of the upper mantle source areas. Continued heating of the enriched upper mantle caused partial melting and subsequent eruption of the ultrapotassic lavas.  相似文献   

19.
Neodymium, Sr and Pb isotopic compositions, along with rare earth element (REE) concentrations were determined for twelve black ores and one yellow ore from twelve localities of the Kuroko deposits, Japan. The ores were generated by submarine hydrothermal activity during the Miocene age. Neodymium isotopic compositions of the ores (Nd: –4.9 to +6.5) mostly overlap with spatially associated igneous rocks. On a Nd versus Sr isotopic correlation diagram, however, 87Sr/86Sr ratios are shifted from the associated igneous rocks towards the higher contemporaneous seawater ratio. REE patterns are highly variable, ranging from light REE enriched to depleted, and show no Ce anomalies, as would be expected if they were derived from seawater. These results suggest that the REEs contained in ores were mainly derived from the associated igneous rocks, but that the ore Sr is a mixture derived from both seawater and the igneous rocks. Most Pb isotopic compositions fall within the range defined by the associated igneous rocks (206Pb/204Pb=18.35–18.84, 207Pb/204Pb=15.59–15.97 and 208Pb/204Pb=38.53–39.90), although several samples have very radiogenic compositions that were most likely derived from basement rocks. Our new Pb isotopic results display greater variation, and have a larger range of more radiogenic compositions than has been noted previously for these ores. In addition, the black ore with the most radiogenic Pb isotopic composition also has the least radiogenic Nd isotopic composition. This suggests that at least some of the Pb contained in the ores was derived mainly from older basement rocks. The large positive Eu anomalies for some black ores are consistent with a high-temperature origin for the parental fluids, irrespective of the source rock. The single yellow ore examined, however, has a small negative Eu anomaly, which may indicate derivation from a lower temperature fluid. Previous studies suggested that the Kuroko ores were formed in the presence of organic materials in an anoxic basin. Combined Nd, Sr, Pb and Os isotopic and REE abundance data indicate that multiple sources were involved in the genesis of Kuroko ores.  相似文献   

20.
The Rb-Sr and U-Pb systematics have been studied in the metasedimentary carbonate rocks from the Paleoproterozoic Kuetsjarvi Formation. Samples were taken from the borehole drilled in the northern zone of the Pechenga Greenstone Belt in the northwestern Kola Peninsula. The carbonate section of the formation is made up of three units (from the bottom to top): (I) dolomite (68 m), (II) calcareous-dolomite (9 m), and (III) clayey calcareous (1 m) ones. Dolomites (Mg/Ca = 0.55–0.61) from the lowermost unit I contain 70.3–111 ppm Sr. Initial 87Sr/86Sr ratio in them varies within 0.70560–0.70623 and characterizes the primary continental-lacustrine carbonate sediments. Calcareous dolomites (Mg/Ca = 0.39–0.59) and dolomitic limestones of units II and III (Mg/Ca = 0.02–0.36) are enriched in Sr (285–745 and 550–1750 ppm, respectively). Initial 87Sr/86Sr ratios in these rocks (0.70406–0.70486 and 0.70407–0.70431, respectively) fall within the range typical of the Jatulian seawater, which indicates that the carbonate sediments of two upper units were formed in an open marine basin. Study of dolomites from unit I showed that the Svecofennian metamorphism more significantly affected the U-Pb systems of carbonate rocks as compared to their Rb-Sr systems. In the 207Pb/204Pb-206Pb/204Pb diagram, most data points corresponding to the carbonate constituent of dolomites define isochron with an age of 1900 ± 25 Ma (MSWD = 0.5). The same samples define a positive correlation in the 208Pb/204Pb-206Pb/204Pb plot. Since sedimentary carbonates usually do not contain Th, this correlation points to secondary enrichment of the studied dolomites in Th or thorogenic 208Pb. Hence, the obtained Pb-Pb dating can be regarded as the age of the Svecofennian metamorphic event. Three samples from dolomites of unit I lack any disturbance of the initial U-Th-Pb systematics, but their trend in the 207Pb/204Pb-206Pb/204Pb diagram deviates from the 1900 Ma isochron. Based on these samples, the model U-Pb premetamorphic age of the Kuetsjarvi carbonate sediments is 2075–2100 Ma. This interval is consistent with the age range of the Lomagundi-Jatulian event, which was responsible for the formation of carbonate sediments with high positive δ13C values.  相似文献   

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