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1.
The behaviour of relative diffusion theory and Gifford’s random-force theory for long-range atmospheric diffusion is examined. When a puff scale is smaller than the Lagrangian length scale, 2KTL, an accelerative relative diffusion region exists, i.e., σy∝t3/2. While the puff diffusion enters a two-dimensional turbulence region, in which the diffusion scale is larger than 500 km, or time scale is larger than 1 day, divergence and convergence are main cause of horizontal diffusion. Between the two above-mentioned regimes, diffusion deviation is given byσy=2KTL. The large-scale horizontal relative diffusion parameters were obtained by analyzing the data of radioactive cloud width collected in air nuclear tests.  相似文献   

2.
One-dimensional Lagrangian dispersion models, frequently used to relate in-canopy source/sink distributions of energy, water and trace gases to vertical concentration profiles, require estimates of the standard deviation of the vertical wind speed, which can be measured, and the Lagrangian time scale, T L , which cannot. In this work we use non-linear parameter estimation to determine the vertical profile of the Lagrangian time scale that simultaneously optimises agreement between modelled and measured vertical profiles of temperature, water vapour and carbon dioxide concentrations within a 40-m tall temperate Eucalyptus forest in south-eastern Australia. Modelled temperature and concentration profiles are generated using Lagrangian dispersion theory combined with source/sink distributions of sensible heat, water vapour and CO2. These distributions are derived from a multilayer Soil-Vegetation-Atmospheric-Transfer model subject to multiple constraints: (1) daytime eddy flux measurements of sensible heat, latent heat, and CO2 above the canopy, (2) in-canopy lidar measurements of leaf area density distribution, and (3) chamber measurements of CO2 ground fluxes. The resulting estimate of Lagrangian time scale within the canopy under near-neutral conditions is about 1.7 times higher than previous estimates and decreases towards zero at the ground. It represents an advance over previous estimates of T L , which are largely unconstrained by measurements.  相似文献   

3.
A Eulerian-Lagrangian canopy microclimate model wasdeveloped with the aim of discerning physical frombiophysical controls of CO2 and H2O fluxes. The model couples radiation attenuation with mass,energy, and momentum exchange at different canopylevels. A unique feature of the model is its abilityto combine higher order Eulerian closure approachesthat compute velocity statistics with Lagrangianscalar dispersion approaches within the canopy volume. Explicit accounting for within-canopy CO2,H2O, and heat storage is resolved by consideringnon-steadiness in mean scalar concentration andtemperature. A seven-day experiment was conducted inAugust 1998 to investigate whether the proposedmodel can reproduce temporal evolution of scalar(CO2, H2O and heat) fluxes, sources andsinks, and concentration profiles within and above auniform 15-year old pine forest. The modelreproduced well the measured depth-averaged canopy surfacetemperature, CO2 and H2O concentrationprofiles within the canopy volume, CO2 storageflux, net radiation above the canopy, and heat andmass fluxes above the canopy, as well as the velocitystatistics near the canopy-atmosphere interface. Implications for scaling measured leaf-levelbiophysical functions to ecosystem scale are alsodiscussed.  相似文献   

4.
A second-order modelling technique is used to investigate the influence of turbulence on chemical reactions. The covariance and variance equations for the NO-O3-NO2 system are developed as a function of the ratio of the timescale of turbulence ( t ) and the timescale of chemistry (Ch): the first Damköhler number ( t /Ch). Special attention is given to the calculation of the covariance between NO and O3 normalized by the product of their means, the so-called intensity of segregation (I S ). This parameter quantifies the state of mixing of two chemical species.The intensity of segregation is calculated as a function of the flux of NO and the first Damköhler number. The model results presented illustrate the importance of taking the effect of turbulence on chemical reactions into account for higher values of the NO flux, for values of the ratio O3/NO larger than 12.5 and for values of the ratio t /CH larger than 0.1. For such cases, the effective reaction rates are slower than if the chemical species are assumed to be uniformly mixed.  相似文献   

5.
The size-segregated chemical composition of aerosol particles was investigated during 1?year at the puy de D?me (1,465?m?a.s.l.), France. These measurements aimed to a better understanding of the influence of the air mass origin on the size-segregated chemical composition of the aerosol at an altitude site. Mountain site measurements are important because they are representative of long range transport and useful for model validation. PM1 mass concentration exhibits a seasonal variability with a summer maximum. The composition of PM1 did not change significantly in terms of relative contribution of water soluble inorganic ions but is rather variable in term of total mass concentrations. For the PM10-1, a different seasonal behaviour was found with maxima concentrations in autumn-winter. Aerosols were classified into four different categories according to their air mass origin: marine, marine modified, continental and Mediterranean. The PM10 aerosol mass at 50?% relative humidity was close to 2.5???g?m?3 in the marine, 4.3???g?m?3 in the marine modified, 10.3???g?m?3 in the continental and 7.7???g?m?3 in the Mediterranean sectors. We noted that the influence of the air mass origin (on the chemical properties) could be seen especially on the PM10-1. A significant PM10-1 mode was found in marine, modified marine, and Mediterranean air masses, and PM1 dominated in the continental air masses samples. As a result, the aerosol chemical composition variability at the puy de D?me is a function of both the season and air mass type and we provide a chemical composition of the aerosol as a function of each of these environmental factors.  相似文献   

6.
The turbulent flow inside dense canopies is characterized by wake production and short-circuiting of the energy cascade. How these processes affect passive scalar concentration variability in general and their spectral properties in particular remains a vexing problem. Progress on this problem is frustrated by the shortage of high resolution spatial concentration measurements, and by the lack of simplified analytical models that connect spectral modulations in the turbulent kinetic energy (TKE) cascade to scalar spectra. Here, we report the first planar two-dimensional scalar concentration spectra (ϕ cc ) inside tall canopies derived from flow visualization experiments. These experiments were conducted within the deeper layers of a model canopy composed of densely arrayed cylinders welded to the bottom of a large recirculating water channel. We found that in the spectral region experiencing wake production, the ϕ cc exhibits directional scaling power laws. In the longitudinal direction (x), or the direction experiencing the largest drag force, the ϕ cc (k x ) was steeper than and followed an approximate at wavenumbers larger than the injection scale of wake energy, where k x is the longitudinal wavenumber. In the lateral direction (y), the spectra scaled as up to the injection scale, and then decayed at an approximate power law. This departure from the classical inertial subrange scaling (i.e., k −5/3) was reproduced using a newly proposed analytical solution to a simplified scalar spectral budget equation. Near the velocity viscous dissipation range, the scalar spectra appear to approach an approximate k −3, a tantalizing result consistent with dimensional analysis used in the inertial-diffusive range. Implications to subgrid modelling for large-eddy simulations (LES) inside canopies are briefly discussed.  相似文献   

7.
Urbanization has a substantial effect on urban meteorology. It can alter the atmospheric diffusion capability in urban areas and therefore affect pollutant concentrations. To study the effects of Hangzhou’s urban development in most recent decade on its urban meteorological characteristics and pollutant diffusion, 90 weather cases were simulated, covering 9 weather types, with the Nanjing University City Air Quality Prediction System and high-resolution surface-type data and urban construction data for 2000 and 2010. The results show that the most recent decade of urban development in Hangzhou substantially affected its urban meteorology. Specifically, the average urban wind speed decreased by 1.1 m s ?1; the average intensity of the heat island increased by 0.5°C; and the average urban relative humidity decreased by 9.7%. Based on one case for each of the nine weather types, the impact of urbanization on air pollution diffusion was investigated, revealing that the changes in the meteorological environment decreased the urban atmosphere’s diffusion capability, and therefore increased urban pollutant concentrations. For instance, the urban nitrogen oxides concentration increased by 2.1 μg m ?3 on average; the fine particulate matter (diameter of 2.5 μm or less; PM2.5) pollution concentration increased by 2.3 μg m ?3 on average; in highly urbanized areas, the PM2.5 concentration increased by 30 μg m ?3 and average visibility decreased by 0.2 km, with a maximum decrease of 1 km; the average number of daily hours of haze increased by 0.46 h; and the haze height lifted by 100–300 m. The “self-cleaning time” of pollutants increased by an average of 1.5 h.  相似文献   

8.
Analysis of profiles of meteorological measurements from a 160 m high mast at the National Test Site for wind turbines at Høvsøre (Denmark) and at a 250 m high TV tower at Hamburg (Germany) shows that the wind profile based on surface-layer theory and Monin-Obukhov scaling is valid up to a height of 50–80 m. At higher levels deviations from the measurements progressively occur. For applied use an extension to the wind profile in the surface layer is formulated for the entire boundary layer, with emphasis on the lowest 200–300 m and considering only wind speeds above 3 m s?1 at 10 m height. The friction velocity is taken to decrease linearly through the boundary layer. The wind profile length scale is composed of three component length scales. In the surface layer the first length scale is taken to increase linearly with height with a stability correction following Monin-Obukhov similarity. Above the surface layer the second length scale (L MBL ) becomes independent of height but not of stability, and at the top of the boundary layer the third length scale is assumed to be negligible. A simple model for the combined length scale that controls the wind profile and its stability dependence is formulated by inverse summation. Based on these assumptions the wind profile for the entire boundary layer is derived. A parameterization of L MBL is formulated using the geostrophic drag law, which relates friction velocity and geostrophic wind. The empirical parameterization of the resistance law functions A and B in the geostrophic drag law is uncertain, making it impractical. Therefore an expression for the length scale, L MBL , for applied use is suggested, based on measurements from the two sites.  相似文献   

9.
According to the statistical shape–slope (μ–Λ) relationship observed for the first time by several 2D-Video-Distrometers (2DVD) in southern China, a constrained gamma (C-G) model was proposed for the retrieval of rain drop size distributions (DSDs) from Guangzhou S-band polarimetric radar observations. Two typical precipitation processes were selected to verify the accuracy of the retrieval scheme. The μ–Λ relationship: Λ = 0.0241μ2 + 0.867μ + 2.453 was obtained based on the 2DVD observation results from at Huizhou Longmen station, which is a very representative location in the area. Relying on the Guangzhou polarimetric radar measurements of radar reflectivity (ZHH) and differential reflectivity (ZDR), the gamma (Γ) size distribution parameters (N0, μ, and Λ) can be retrieved by the C-G model retrieval scheme. The results show that the Guangzhou polarimetric radar retrievals of DSDs were close to the 2DVD observations at Guangzhou Maofengshan station. The rain rate, mass mean diameter, and normalized intercept parameter of radar retrievals were in good agreement with the 2DVD observations, and the relative errors were less than 10%. The overall accuracy of the retrieval scheme was high. The retrieval scheme has established the relationship between the polarimetric radar measurements and gamma size distribution parameters. It will be helpful to in-depth research and application of the dual-polarization radar data in microphysical precipitation processes analysis, as well as convection-resolved numerical model data assimilation and prediction effect evaluation.  相似文献   

10.
The inertial subrange Kolmogorov constant C 0, which determines the effective turbulent diffusion in velocity space, plays an important role in the Lagrangian modelling of pollutants. A wide range of values of the constant are found in the literature, most of them determined at low Reynolds number and/or under different assumptions. Here we estimate the constant C 0 by tracking an ensemble of Lagrangian particles in a planetary boundary layer simulated with a large-eddy simulation model and analysing the Lagrangian velocity structure function in the inertial subrange. The advantage of this technique is that it easily allows Reynolds numbers to be achieved typical of convective turbulent flows. Our estimates of C 0 is C 0=4.3±0.3 consistent with values found in the literature  相似文献   

11.
It is shown that the slope of energy spectrum obtained from the velocity solution of Kdv-Burgers equation lies between -5/3 and -2 in the dilogarithmic coordinates paper. The spectrum is very close to one of Kolmogorov’s isotropic turbulence and Frisch’s intermittent turbulence in inertial region. In this paper, the Kdv-Burgers equation to describe atmospheric boundary layer turbulence is obtained. In the equation, the 1 / Re, corresponds to dissipative coefficient v, to dispersive coefficient β, then (v/ 2β)2 corresponds to .We prove that the wave number corresponding to maximum energy spectrum decreases with the decrease of stability (i.e., the increase of in eddy-containing region. And the spectrim amplitude decreases with the increase of (i.e., the decrease of stability). These results are consistent with actual turbulence spectrum of atmospheric surface layer from turbulence data.  相似文献   

12.
This study elucidates the characteristics of ambient PM2.5 (fine) and PM1 (submicron) samples collected between July 2009 and June 2010 in Raipur, India, in terms of water soluble ions, i.e. Na+, NH 4 + , K+, Mg2+, Ca2+, Cl?, NO 3 ? and SO 4 2? . The total number of PM2.5 and PM1 samples collected with eight stage cascade impactor was 120. Annual mean concentrations of PM2.5 and PM1 were 150.9?±?78.6 μg/m3 and 72.5?±?39.0 μg/m3, respectively. The higher particulate matter (PM) mass concentrations during the winter season are essentially due to the increase of biomass burning and temperature inversion. Out of above 8 ions, the most abundant ions were SO 4 2? , NO 3 ? and NH 4 + for both PM2.5 and PM1 aerosols; their average concentrations were 7.86?±?5.86 μg/m3, 3.12?±?2.63 μg/m3 and 1.94?±?1.28 μg/m3 for PM2.5, and 5.61?±?3.79 μg/m3, 1.81?±?1.21 μg/m3 and 1.26?±?0.88 μg/m3 for PM1, respectively. The major secondary species SO 4 2? , NO 3 ? and NH 4 + accounted for 5.81%, 1.88% and 1.40% of the total mass of PM2.5 and 11.10%, 2.68%, and 2.48% of the total mass of PM1, respectively. The source identification was conducted for the ionic species in PM2.5 and PM1 aerosols. The results are discussed by the way of correlations and principal component analysis. Spearman correlation indicated that Cl? and K+ in PM2.5 and PM1 can be originated from similar type of sources. Principal component analysis reveals that there are two major sources (anthropogenic and natural such as soil derived particles) for PM2.5 and PM1 fractions.  相似文献   

13.
Following the parameterization of sheared entrainment obtained in the companion paper, Liu et al. (2016), the present study aims to further investigate the characteristics of entrainment, and develop a simple model for predicting the growth rate of a well-developed and sheared CBL. The relative stratification, defined as the ratio of the stratification in the free atmosphere to that in the entrainment zone, is found to be a function of entrainment flux ratio (A e). This leads to a simple expression of the entrainment rate, in which A e needs to be parameterized. According to the results in Liu et al. (2016), A e can be simply expressed as the ratio of the convective velocity scale in the sheared CBL to that in the shear-free CBL. The parameterization of the convective velocity scale in the sheared CBL is obtained by analytically solving the bulk model with several assumptions and approximations. Results indicate that the entrainment process is influenced by the dynamic effect, the interaction between mean shear and environmental stratification, and one other term that includes the Coriolis effect. These three parameterizations constitute a simple model for predicting the growth rate of a well-developed and sheared CBL. This model is validated by outputs of LESs, and the results show that it performs satisfactorily. Compared with bulk models, this model does not need to solve a set of equations for the CBL. It is more convenient to apply in numerical models.  相似文献   

14.
This paper reports aerosol chemical properties for the first time over a Korean Global Atmosphere Watch (GAW) supersite, Anmyeon (36°32′N; 126° 19′E), during 2003–2004 period. Total suspended Particulates (TSP) showed significant seasonal variation with consistent higher mass concentrations during spring season (average of up to 230?±?190 μg/m3). PM10 also followed similar trend with higher concentrations during spring (average of up to 170?±?130 μg/m3) and showed reduced concentrations during summer. PM2.5 showed a significant increase during summer (average of up to 60?±?25 μg/m3), which could be due to the influx of fine mode sea salt aerosols associated with the Changma front (summer monsoon). Chemical composition analysis showed enhanced presence of acidic fractions, majorly contributed by sulphates (SO 4 2- ) and nitrates (NO 3 - ) in TSP, PM10 and PM2.5 during different seasons. Enhanced presence of Calcium (Ca2+) was observed during sand storm days during spring. The high correlation obtained on matrix analysis between crustal ions and acidic ions suggests that the ionic compositions over the site are mainly contributed by terrestrial sources of similar origin. The neutralization factors has been estimated to find the extend of neutralization of acidicity by main basic components, and found to have higher value for Ammonium (up to 1.1) in different seasons, indicating significant neutralization of acidic components over the region by NH 4 + . Back trajectory analysis has been performed during different seasons to constrain the possible sources of aerosol origin and the results are discussed in detail.  相似文献   

15.
We investigated the acidity and concentrations of water-soluble ions in PM2.5 aerosol samples collected from an urban site in Beijing and a rural site in Gucheng, Hebei Province from November 2016 to January 2017 to gain an insight into the formation of secondary inorganic species. The average SO42–, NO3–, and NH4+ concentrations were 8.3, 12.5, and 14.1 μg m–3, respectively, at the urban site and 14.0, 14.2, and 24.2 μg m–3, respectively, at the rural site. The nitrogen and sulfur oxidation ratios in urban Beijing were correlated with relative humidity (with correlation coefficient r = 0.79 and 0.67, respectively) and the aerosol loadings. Based on a parameterization model, we found that the rate constant of the heterogeneous reactions for SO2 on polluted days was about 10 times higher than that on clear days, suggesting that the heterogeneous reactions in the aerosol water played an essential role in haze events. The ISORROPIA II model was used to predict the aerosol pH, which had a mean (range) of 5.0 (4.9–5.2) and 5.3 (4.6–6.3) at the urban and rural site, respectively. Under the conditions with this predicted pH value, oxidation by dissolved NO2 and the hydrolysis of N2O5 may be the major heterogeneous reactions forming SO42– and NO3– in haze. We also analyzed the sensitivity of the aerosol pH to changes in the concentrations of SO42–, NO3–, and NH4+ under haze conditions. The aerosol pH was more sensitive to the SO42– and NH4+ concentrations with opposing trends, than to the NO3– concentrations. The sensitivity of the pH was relatively weak overall, which was attributed to the buffering effect of NH3 partitioning.  相似文献   

16.
We identify and remove the main natural perturbations (e.g. volcanic activity, ENSOs) from the global mean lower tropospheric temperatures (T LT ) over January 1979 - June 2017 to estimate the underlying, potentially human-forced trend. The unaltered value is +0.155 K dec?1 while the adjusted trend is +0.096 K dec?1, related primarily to the removal of volcanic cooling in the early part of the record. This is essentially the same value we determined in 1994 (+0.09 K dec?1, Christy and McNider, 1994) using only 15 years of data. If the warming rate of +0.096 K dec?1 represents the net T LT response to increasing greenhouse radiative forcings, this implies that the T LT tropospheric transient climate response (ΔT LT at the time CO2 doubles) is +1.10 ± 0.26 K which is about half of the average of the IPCC AR5 climate models of 2.31 ± 0.20 K. Assuming that the net remaining unknown internal and external natural forcing over this period is near zero, the mismatch since 1979 between observations and CMIP-5 model values suggests that excessive sensitivity to enhanced radiative forcing in the models can be appreciable. The tropical region is mainly responsible for this discrepancy suggesting processes that are the likely sources of the extra sensitivity are (a) the parameterized hydrology of the deep atmosphere, (b) the parameterized heat-partitioning at the oceanatmosphere interface and/or (c) unknown natural variations.  相似文献   

17.
Abstract

The propagation of baroclinic Kelvin and Rossby waves in a fairly coarse‐resolution numerical reduced‐gravity ocean model is investigated using simple geostrophic adjustment experiments in a box‐like domain. Numerical experiments using three different horizontal resolutions (4° × 5°,2° × 2.5° and l° × 1.25°) with properly scaled eddy viscosity coefficients show that the phase speed of the model Kelvin waves is almost exactly proportional to the grid resolution, but is virtually independent of the model viscosity. These results are consistent with the findings of Hsieh et al. (1983) and Wajsowicz and Gill (1986). It is also shown that the two relevant parameters that govern the propagation and decay of these waves, namely the grid‐resolution parameter Δ = Δx/a (where Δx is the grid size and a is the baroclinic Rossby radius, viz. a = C/f, with C being the phase speed of inviscid internal gravity waves in a continuum) and the viscosity parameterΔ = Amλ/2πfa3 (where Am is the eddy viscosity coefficient and λ is the alongshore wavelength) can be replaced with Δ only. This is because in Munk (1950)‐type models, the viscosity parameter Δ scales with Δ3. For Δ3 >1, the Kelvin wave phase speed is cK ΔC/Δ and the alongshore decay length scale is of the order of the perimeter of the basin, viz., 0(104) km.

In contrast to the case for Kelvin waves, the phase speed of the model Rossby waves is not that much different from its value in a continuum and depends only weakly on the model resolution. This is in good agreement with the theoretical results of Wajsowicz (1986). On the other hand, the model Rossby waves are severely damped, within a distance of the order of a wavelength, by the large eddy viscosity of the model. We therefore extrapolate that for a proper simulanon of Kelvin and Rossby waves in this type of numerical ocean model, we need a grid size smaller than 1° × 1°, and a higher‐order turbulent closure scheme that will reduce the eddy viscosity coefficient.  相似文献   

18.
气溶胶质量密度是气溶胶重要的参数,它影响着大气中复杂的化学反应,也与气溶胶的传输过程和空间分布息息相关.基于MERRA-2再分析资料提供的气溶胶柱质量密度数据,研究了我国塔里木盆地1980—2018年长时间序列的沙尘气溶胶柱质量密度的时空分布特征.结果表明,沙尘气溶胶和沙尘PM2.5气溶胶柱质量密度有很大的变化范围,平均值分别为0.33和0.086 g/m2,同时具有明显的年际、月和季节变化特征.沙尘气溶胶和沙尘PM2.5气溶胶柱质量密度的年平均值在0.24~0.41和0.06~0.11 g/m2范围内变化;春季最大,其平均值分别为0.47和0.12 g/m2,冬季最小,其平均值分别为0.13和0.04 g/m2;月平均值最大出现在5月,分别为0.57和0.14 g/m2,最小在1月,分别为0.1和0.03 g/m2.  相似文献   

19.
Our long-term study provides an unequivocal evidence for near-quantitative (80–100%) depletion of chloride from sea-salts in the marine atmospheric boundary layer (MABL) of tropical Bay of Bengal. During the late NE-monsoon (Jan-Mar), continental outflow from south and south-east Asia dominate the wide-spread dispersal of pollutants over the Bay of Bengal. Among anthropogenic constituents, SO 4 2? (range: 0.6–35 μg m?3) is the most dominant. The non-sea-salt SO 4 2? (nss-SO 4 2? ) constitutes a major fraction (55–65%) of the aerosol water-soluble ionic composition (WSIC), whereas contribution of NO 3 ? is relatively minor. The magnitude of Cl-deficit (with respect to its sea-salt proportion) exhibits linear increase with the excess-nss-SO 4 2? (excess over NH 4 + ). We propose that displacement of HCl from sea-salt aerosols by H2SO4 is a dominant reaction mechanism for the chloride-depletion. These results also suggest that sea-salts could serve as a potential sink for anthropogenic SO2 in the downwind polluted marine environment. Furthermore, loss of hydrogen chloride, representing a large source of reactive chlorine, has implications to the oxidant chemistry in the MABL (oxidation of hydrocarbons and dimethyl sulphide).  相似文献   

20.
The model of Paillard and Parrenin (Earth Planet Sci Lett 227:263–271, 2004) was modified to obtain a closer fit to δ18O and CO2 time series for the last 800 kyr. The model performance can be improved if its CO2 sensitivity to I65 insolation is eliminated and if different response times are assumed for ablation/accumulation of ice. Correlations between simulated and experimental time series for CO2 and ice volume V increase from 0.59 and 0.63 to 0.79 and 0.88, respectively. According to these models, terminations are produced by I65 amplification through CO2-T and T-CO2 feedbacks, in synergy with an extra CO2 contribution from the deep ocean. This contribution is strongly dependent on ice-sheet extent and ice volume (or alternatively, CO2 concentration, which is a good proxy of Antarctic temperature) but is insensitive to Southern Ocean (SO) insolation on 21 February (I60). Change of deep SO state may be the “order parameter” for nonlinear deglacial changes. According to these models, 100 kyr periodicity of glacial cycles arises from the characteristic time of Antarctic ice sheet advance to the continental slope.  相似文献   

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