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Analysis of Re, Au, Pd, Pt and Rh in NIST Glass Certified Reference Materials and Natural Basalt Glasses by Laser Ablation ICP-MS 总被引：1，自引：0，他引：1
A new technique for the in situ analysis of Re, Au, Pd, Pt and Rh in natural basalt glass by laser ablation (LA)-ICP-MS is described. The method involves external calibration against NIST SRM 612/613 or 614/615 glass certified reference materials, internal standardisation using Ca, and ablation with a 200 μm wide beam spot and a pulsed laser repetition rate of 50 Hz. Under these conditions, sensitivities for Re, Au, Pd, Pt and Rh analyte ions are ˜ 5000 to 100,000 cps/μg g-1 . This is sufficient to make measurements precise to ˜ 10% at the 2-10 μg g-1 level, which is well within the range of concentrations expected in many basalts. For LA-ICP-MS calibration and a demonstration of the accuracy of the technique, concentrations of Re, Au, Pd, Pt and Rh in the NIST SRM 610/611 (˜ 1 to 50 μg g-1 ), 612/613 (˜ 1 to 7 μg g-1 ), 614/615 (˜ 0.2 to 2 μg g-1 ) and 616/617 (˜ 0.004 to 2 μg g-1 ) glasses were determined by solution-nebulisation (SN)-ICP-MS. Using the 612/613 or 614/615 glasses as calibration standards, LA-ICP-MS measurements of these elements in the other NIST glasses fell within ˜ 15% of those determined by SN-ICP-MS. Replicate LA-ICP-MS analyses of the 612/613 and 614/615 glasses indicate that, apart from certain anomalous domains, the glasses are homogeneous for Re, Au, Pd, Pt and Rh to better than 3.5%. Two LA-ICP-MS analyses of natural, island-arc basalt glasses exhibit large fractionations of Re, Au and Pd relative to Pt and Rh, compared to the relative abundances in the primitive mantle. 相似文献
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激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)适合于直接分析硫化物矿物中痕量元素的含量及空间分布,但硫化物矿物的激光剥蚀特性与硅酸盐及氧化物不同,受到的干扰也更严重,且由于硫化物标准物质(尤其是含铂族元素、Au、Ag等贵金属元素标准物质)极度缺乏,限制了LA-ICP-MS技术在硫化物微区分析中的广泛应用。本文以贵金属标准样品GPT-9和矿石标准物质为原料合成锍镍试金扣,并封入真空管中重熔,利用背散射电子图像和LA-ICP-MS分析元素分布的均匀性,探讨真空重熔锍镍试金扣制备硫化物原位微区分析标准样品的可行性。背散射电子图像(BSE)显示真空重熔后锍镍试金扣由单相S、Ni化合物组成。LA-ICP-MS线扫描和点扫描分析表明,锍镍试金扣中S、Ni、Cr、Co、Cu、Pb、Sb、Cd、Bi等主量及微量元素分析精密度(RSD)均小于10%,均匀分布;在镍扣制备过程中Zn相对于Cu、Pb、Sb更难进入硫化物相;贵金属元素Au、Ag、Pt均一性较好,其余贵金属元素由于含量低、仪器波动及质谱干扰等影响因素造成分析数据的RSD相对较大,但可通过提高原料中贵金属元素含量、降低熔融样品淬火温度等方法进一步提高其均匀性。锍镍试金扣的组成元素对铂族元素分析的质谱干扰研究表明,重铂族元素(Os、Ir、Pt)和Au受到的干扰可忽略不计;轻铂族元素(Ru、Rh、Pd)受金属氩化物干扰较为严重,需进行干扰校正。研究认为,真空重熔技术可有效提高锍镍试金扣中各元素(包括贵金属)的均一性,达到硫化物原位微区分析标准样品的要求,利用真空重熔锍镍试金扣制备LA-ICP-MS原位微区痕量及贵金属硫化物分析标准样品具可行性。 相似文献
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通过描述一种利用LA-ICP-MS准确测定含水硅酸盐矿物主量元素和微量元素含量的多外标、无内标分析方法.总结出该方法基于矿物化学计量式计算含水硅酸盐矿物中挥发分的相对含量,再将全部分析元素归一化到总金属氧化物含量(100%减含水量)的原理,利用多种天然成分的岩石标准玻璃(如MPI-DING玻璃和USGS玻璃)作为外标进行校正计算.利用该方法对角闪石、绿帘石、电气石和透闪石等含水硅酸盐矿物进行了分析,并与利用电子探针和微钻(直径300 μm)取样溶液-ICP-MS分析的结果进行了对比研究.研究结果表明:对于组成均一的主量元素的分析结果与电子探针分析数据一致,相对偏差集中在5%以内.除了那些分布异常不均一的元素(在300 μm尺度上),对微量元素的分析结果与溶液-ICP-MS分析结果具有很好的一致性,二者之间的相对偏差大部分集中在10%以内.研究结论为采用归一化校正策略,选择MPI-DING和USGS玻璃作为外标,利用LA-ICP-MS微区分析方法可以准确测定含水硅酸盐矿物中的主、微量元素含量. 相似文献
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Ladislav Strnad Vojtech Ettler Martin Mihaljevic Jindrich Hladil Vladislav Chrastny 《Geostandards and Geoanalytical Research》2009,33(3):347-355
We report new data on the trace element concentrations of Mg, Cr, Mn, Co, Ni, Cu, Zn, Sr, Cd, Ba, La, Ce, Nd, Pb and U in USGS carbonate reference materials (MACS-1 and MACS-2) and compare solution ICP-MS and LA-ICP-MS trace element determinations on landfill calcites using calibration to different reference materials (MACS-1 and MACS-2 carbonate and NIST SRM 612 glass). Very good agreement (differences below 10% relative) was found between laser ablation and solution ICP-MS data for MACS-1 with higher concentrations of trace elements (values between 100 and 150 μg g−1 ), with the exception of Cu and Zn. Similarly good agreement was found for MACS-2 with lower trace element concentrations (units to tens of μg g−1 ), with the exception of Cr, Co and Zn. The MACS-1 reference material for calibration of LA-ICP-MS was found to be extremely useful for in situ determination of trace elements in real-world carbonate samples (landfill calcites), especially those present in calcite in higher concentrations (Mn, Sr, Ba; < 5% RSD). Less accurate determinations were generally obtained for trace elements present at low concentrations (∼ units of μg g−1 ). In addition, good agreement was observed between the instrument calibration to MACS and NIST SRM 612 glass for in situ measurements of trace elements in landfill calcites K-2, K-3 and K-4 (differences below 15% relative for most elements). Thus, the application of MACS carbonate reference materials is promising and points to the need for the development of new carbonate reference materials for laser ablation ICP-MS. 相似文献
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William T. Perkins Nicholas J.G. Pearce John A. Westgate 《Geostandards and Geoanalytical Research》1997,21(2):175-190
This contribution presents a review of the recent developments in laser ablation inductively coupled plasma-mass spectrometry. We describe the important developments which have occurred in the laser systems used, leading to a spatial resolution of around 20 (im, and give an overview of the major instrument developments which have affected the geological applications of laser ablation ICP-MS. We describe the calibration of laser ablation for the analysis of trace elements in two different matrices: volcanic glass shards and sulfide minerals. We show how single glass shards can be analysed using the National Institute of Standards and Technology (NIST) glass certified reference materials for calibration and demonstrate the effect of using single spot analyses compared to rastering of the calibration sample. We show the importance of inter-shard variation and demonstrate that averaged single shard analyses produce data which compare well with bulk analyses. The calibration of the laser system for sulfide mineral analysis is discussed and two different strategies are proposed, one using spiked pressed powder pellets of sulfides and the other metal reference materials. We present conclusions and recommendations for the calibration of laser ablation ICP-MS instruments. 相似文献
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Meeri Suominen Esko Kontas Heikki Niskavaara 《Geostandards and Geoanalytical Research》2004,28(1):131-136
The classical lead fire assay is still the most important method for the pre-concentration and separation of Ag, Au and some of the platinum-group elements (PGE) in the analysis of geological materials. The most frequently used fire assay procedure is the determination of Au, Pd and Pt with Ag as collector. When Au is used instead of Ag as a collector, Pd, Pt, Rh and possibly Ir can also be determined. In this study the recoveries by Au and Ag collectors, also called inquarts, were compared in the fire assay analysis of Pd, Pt and Rh in geological reference materials. The amount of gold to be added was optimised. Variable recoveries were obtained with Ag inquart for Rh, but a 2 mg inquart of Au gave good recoveries for all three of these elements in the analysis of reference samples of different geological materials. A procedure, alternative to scorification, to overcome interferences caused by base metals in the cupellation step is presented. The procedure involves cutting the Pb button into pieces and analysing the pieces separately. Prior to this, a homogeneity study of the lead button was made, and it showed that Pd, Pt and Rh were evenly distributed in the Pb button. All determinations were made using inductively coupled plasma-atomic emission spectrometry (ICP-AES). 相似文献
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Sarah-Jane Barnes R. A. Cox M. L. Zientek 《Contributions to Mineralogy and Petrology》2006,152(2):187-200
Concentrations of Ag, Au, Cd, Co, Re, Zn and Platinum-group elements (PGE) have been determined in sulfide minerals from zoned sulfide droplets of the Noril’sk 1 Medvezky Creek Mine. The aims of the study were; to establish whether these elements are located in the major sulfide minerals (pentlandite, pyrrhotite, chalcopyrite and cubanite), to establish whether the elements show a preference for a particular sulfide mineral and to investigate the model, which suggests that the zonation in the droplets is caused by the crystal fractionation of monosulfide solid solution (mss). Nickel, Cu, Ag, Re, Os, Ir, Ru, Rh and Pd, were found to be largely located in the major sulfide minerals. In contrast, less than 25% of the Au, Cd, Pt and Zn in the rock was found to be present in these sulfides. Osmium, Ir, Ru, Rh and Re were found to be concentrated in pyrrhotite and pentlandite. Palladium and Co was found to be concentrated in pentlandite. Silver, Cd and Zn concentrations are highest in chalcopyrite and cubanite. Gold and platinum showed no preference for any of the major sulfide minerals. The enrichment of Os, Ir, Ru, Rh and Re in pyrrhotite and pentlandite (exsolution products of mss) and the low levels of these elements in the cubanite and chalcopyrite (exsolution products of intermediate solid solution, iss) support the mss crystal fractionation model, because Os, Ir, Ru, Rh and Re are compatible with mss. The enrichment of Ag, Cd and Zn in chalcopyrite and cubanite also supports the mss fractionation model these minerals are derived from the fractionated liquid and these elements are incompatible with mss and thus should be enriched in the fractionated liquid. Gold and Pt do not partition into either iss or mss and become sufficiently enriched in the final fractionated liquid to crystallize among the iss and mss grains as tellurides, bismithides and alloys. During pentlandite exsolution Pd appears to have diffused from the Cu-rich portion of the droplet into pentlandite. 相似文献
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Yu. A. Poltavets V. N. Sazonov Z. I. Poltavets G. S. Nechkin 《Geochemistry International》2006,44(2):143-163
Relationships between noble-metal and oxide-sulfide mineralization during the origin of the Volkovsky gabbroic pluton are discussed on the basis of geochemical data and thermodynamic calculations. The basaltic magma initially enriched in noble metals (NM) relative to their average contents in mafic rocks, except for Pt, is considered to be a source of Pd, Pt, Au, and Ag in the gabbroic rocks of the Volkovsky pluton. The ores were formed with a progressive gain of NM in the minerals during the fractionation of the basaltic magma. The active segregation of NM in the form of individual minerals (palladium tellurides and native gold) hosted in titanomagnetite and copper sulfide ore occurred during the final stage of gabbro crystallization, when the residual fluid-bearing melt acquired high concentrations of Cu, Fe, Ti, and V, along with volatile P and S. Copper sulfides—bornite and chalcopyrite—are the major minerals concentrating NM; they contain as much as 22.65–25.20 ppm Pd and 0.74–1.56 ppm Pt; 4.39–8.0 ppm Au, and 127.2–142.6 ppm Ag, respectively. The copper ore and associated NM mineralization were formed at a relatively low sulfur fugacity, which was a few orders of magnitude (attaining 5 log units) lower than that of the pyrite-pyrrhotite equilibrium. The low sulfur fugacity and the close chemical affinity of Pd and Pt to Te precluded the formation of pyrrhotite, pyrite, and PGE disulfides. The major ore minerals and NM mineralization were formed within a wide temperature range (800–570°C), under nearly equilibrium conditions. Foreign elements (Ni, Co, and Fe) affected the thermodynamic stability of Pd and Pt compounds owing to the difference in their affinity to Te and to elements of the sulfur group (S, Se, and As). The replacement of Pd with Ni and Co and, to a lesser extent, with Pt and the replacement of Te with S, As, and Se diminish the stability field of palladium telluride. Comparison of Pd tellurides from copper sulfide ores at the Volkovsky and Baronsky deposits showed the enrichment of the former in Au, Sb, and Bi, while the latter are enriched in Pt, Ni, and Ag. The enrichment of Pd tellurides at the Baronsky deposit in Ni is correlated with the analogous enrichment of the host gabbroic rocks. 相似文献
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SONG Huanbin HE Mingqin ZHANG Shangzhong YI Fenghuang 《中国地球化学学报》2008,27(1):104-108
The Jingbaoshan platinum-palladium deposit is China＇s largest independent PGM （platinum-group metals） deposit so far discovered. There are eleven kinds of useful components in the ore： Pt, Pd, Os, Ir, Ru, Rh, Au, Ag, Cu, Ni, and Co. The platinum-group elements, gold and silver occur in the form of minerals in ores. twenty-five kinds of precious metal minerals have been found, of which twenty one belong to the platinum-group minerals. The minerals are very small in grain size. Copper occurs mainly as copper sulfide with a small amount of free copper oxide, and the beneficiated copper accounts for 95.21%. Nickel occurs mainly as nickel sulfide, and some nickel silicate and nickel oxide occur in the ore. The beneficiated nickel accounts for 72.03%. Cobalt occurs mainly as cobalt sulfide, and there are some cobalt oxide and other kinds of cobalt. The beneficiated cobalt accounts for 77.58%. 相似文献
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位于华北克拉通南缘的小秦岭地区是我国仅次于胶东的大型金矿床集中区,但金矿床的成矿物质来源及成因问题一直存在较大争议.以华北南缘小秦岭矿集区东桐峪金矿床中的黄铁矿作为研究对象,在黄铁矿显微结构研究的基础上利用LA-ICP-MS对黄铁矿的微量元素进行原位分析,为进一步认识东桐峪金矿床及区内其他同类型矿床的成因提供新的资料和制约.东桐峪金矿床的黄铁矿从早到晚依次划分为3个世代(PyⅠ、PyⅡ和PyⅢ).PyⅠ主要形成于粗粒黄铁矿-石英阶段,颗粒粗大且自形程度高,呈星点状或斑点状赋存于乳白色石英脉中.PyⅡ主要形成于石英-中细粒黄铁矿阶段,呈半自形-他形结构且裂隙发育,常被晚期石英、多金属硫化物、自然金等矿物充填.PyⅢ主要形成于多金属硫化物阶段,常呈他形粒状结构与黄铜矿、方铅矿及闪锌矿等硫化物密切共生.LA-ICP-MS分析结果显示,PyⅠ中As平均含量为16.63×10-6,Au、Ag和Te含量较低且常位于检测限以下;相较而言,PyⅡ中As含量稍低,而Au、Ag和Te含量略高(其中Au含量为0.10×10-6~0.59×10-6);PyⅢ中Au、Ag和Te含量差异较大且显著升高,其中Au、Te含量最高可达35.58×10-6和79.79×10-6,而As含量较低且大部分数值低于检测限;不同世代黄铁矿的Co/Ni比值基本上都大于1,且PyⅢ的Co、Ni含量和Co/Ni比值明显低于PyⅡ和PyⅠ.以上结果表明,东桐峪金矿床的载金矿物黄铁矿中As的含量很低,金的富集与As无关;不同世代的黄铁矿中Au、Ag和Te之间存在显著且稳定的线性正相关关系,暗示金矿化与Te关系密切.另外,第3世代黄铁矿(PyⅢ)中Au、Ag及Te存在显著富集,指示Te(而不是As)在金和银的迁移、搬运、富集、沉淀等过程中具有重要作用.华北克拉通南缘小秦岭地区晚中生代大规模的金成矿作用及金矿床中普遍存在Te-Au-Ag矿物,且黄铁矿中As含量低、Te含量高等特征,暗示该区金矿床的成矿物质/成矿流体可能来自深部岩浆的脱挥发分或地幔脱气作用,而与区域变质作用的关系不大. 相似文献
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激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是一种固体微区分析新技术。用该技术来分析矿床中硫化物的微量元素组成可以为研究成矿流体特征、矿床成因及找矿勘探提供有关的科学信息。文中以安徽铜陵矿集区内新桥Cu-Au-S矿床中的黄铁矿为研究对象,在详细的野外观察和室内鉴定的基础上,将矿床中的黄铁矿分为具有沉积特征的胶状黄铁矿(PyⅠ)、具有变形重结晶和热液叠加作用特征的细粒他形黄铁矿(PyⅡ)和具热液成因特征的中—粗粒自形黄铁矿(PyⅢ)3种类型。LA-ICP-MS原位微量元素测定结果显示,PyⅠ中相对富含Ti、Co、Ni、As、Se、Te;PyⅡ继承了PyⅠ中富含Ti、Co、Ni、As、Se、Te、Bi的特征,同时还含有不均匀分布的少量成矿元素(Cu、Pb、Zn、Au、Ag);PyⅢ中成矿元素Cu、Pb、Zn、Ag、Au以及Bi元素的含量较高,Co、Ni、As的含量较低。在元素赋存状态方面,Co、Ni、As、Se和Te均以类质同象的形式进入到了黄铁矿的晶格中;Bi在PyⅡ中主要以含Bi矿物的微细包裹体形式存在,而在PyⅢ中的Bi还部分取代了Fe而占据了晶格;Cu、Pb、Zn、Au、Ag这些成矿元素中,Cu和Zn分别以黄铜矿和闪锌矿的矿物包裹体存在于黄铁矿中;PyⅡ中所含的少量Au、Ag,可能分别以自然金和自然银的形式存在,而在PyⅢ中Au可能主要以银金矿的形式存在,Ag除了以银金矿的形式存在以外还可能赋存于黄铁矿中含铋的矿物包裹体内;Pb主要赋存于黄铁矿中的方铅矿或含铋矿物的包裹体中。在综合分析黄铁矿的结构形态和微量元素组成特征的基础上认为,PyⅠ型黄铁矿可能形成于前人提出的晚古生代海底沉积或喷流沉积环境,PyⅡ和PyⅢ型黄铁矿分别形成于中生代区域构造变形-热液叠加改造的过渡环境和热液环境,PyⅡ和PyⅢ的形成时间相近。新桥矿床的形成可能经历了晚古生代海底沉积或喷流沉积期和燕山期热液期,胶黄铁矿主要形成于沉积成矿期,而矿床中成矿物质Cu、Pb、Zn、Au、Ag等主要来自燕山期岩浆侵入作用形成的热液成矿系统。 相似文献
13.
激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展 总被引：9，自引：5，他引：4
激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是目前地球科学分析领域的重要技术手段,元素微区分析标准物质研制是该分析技术发展的重要方向。本文对当前LA-ICP-MS元素微区分析标准物质的种类、元素分布以及应用上的优缺点和标准物质的制备方法进行了评述。现有的有证标准物质数量不多、种类不齐全,部分元素浓度较低,定值不确定度较大,应用上受到较大的局限性;研制标准也不成熟,均匀性检验方面尚未有统一的方法。本文参照岩石粉末标准物质均匀性检验方法提出了两步均匀性检验法,同时指出在标准物质种类方面,铂族元素及Au元素浓度适当、Pb-S等不同硫化物基体标准物质,以及化学成分不同的碳酸岩和磷酸岩基体标准物质是当前的迫切需求;在标准物质研制技术方面,纳米岩石粉末压片技术的研发、原位微区分析标准物质(固体)均匀性检验判别标准研究是亟待解决的问题。 相似文献
14.
Platinum-Group Elements and Gold Determination in NiS Fire Assay Buttons by UV Laser Ablation ICP-MS
Alexandre P.de S. Jorge Jacinta Enzweiler Elisa K. Shibuya Jorge E.S. Sarkis Ana Maria G. Figueiredo 《Geostandards and Geoanalytical Research》1998,22(1):47-55
The direct analysis of nickel sulfide fire assay buttons by UV laser ablation ICP-MS was used to determine the platinum-group elements and gold in the following reference materials: UMT-1, WPR-1, WMG-1, GPt-4, GPt-6 and CHR-Bkg. The instrument was calibrated with buttons prepared using quartz doped with the appropriate standard solutions. Analytical precision (RSD) was generally better than 10%, although occasional higher RSDs may infer local heterogeneities within nickel sulfide buttons. Good or excellent agreement was observed between analysed and reference material values except Rh in UMT-1 and WMG-1, which suffered an interference from copper. Detection limits calculated as 10 s quantitation limits were Au (1.7 ng g−1 ), Pd (3.3 ng g−1 ), Pt (8.3 ng g−1 ), Os (1.3 ng g−1 ), Rh (1 ng g−1 ), Ru (5 ng g−1 ) and Ir (0.7 ng g−1 ). 相似文献
15.
NK8310螯合树脂分离富集地质样品中痕量金银铂钯及其测定 总被引：14，自引：3，他引：14
研究了硫脲螯合树脂（NK8310）分类富集地质样品中痕量Au、Ag、Pt和Pd的实验条件。在φ=10％的王水介质中，[AuCI4]^-、[AgCI2]^-、[PtCI6]^2-和[PdCI4]^2-定量吸附于树脂上并与大量贱金属分离；用5g/L硫脲－0.12mol/L HCI溶液洗脱Au、Ag、Pt和Pd，回收率为97％－104％。用硫镍矿管理样以及国家一级标准物质进行分析验证，分析结果与推荐值及标准值吻合，表明NK8310螯合树脂适用于地质样品中Au、Ag、Pt和Pd的分离富集。 相似文献
16.
硫化物矿物中痕量元素的激光剥蚀-电感耦合等离子体质谱微区分析进展 总被引：10，自引：3，他引：7
第一行过渡金属元素及痕量贵金属元素高度富集在硫化物矿物中,常形成具有工业意义的矿床,使得硫化物具有重大的经济价值。对天然硫化物矿物中的这些痕量金属元素丰度及其分布的研究,在矿石成因学、经济地质学、环境地球化学等领域具有重要的应用价值。激光剥蚀-电感耦合等离子体质谱(LA-ICP-MS)微区分析技术是一种强大的痕量元素分析工具,非常适合直接分析硫化物矿物中痕量元素的浓度及其空间分布。由于硫化物的激光剥蚀特性与硅酸盐及氧化物不同,分析校准用的标准物质又极度缺乏,严重阻碍了这一技术在硫化物矿物微区分析中的应用。本文评述了硫化物简介、硫化物中痕量金属元素分析的意义、LA-ICP-MS微区分析技术在硫化物矿物痕量元素分析中的优势及近年来的应用进展、硫化物分析中的干扰与校准、包含铂族元素及金的硫化物标准物质的研制进展及合成硫化物标准物质最有应用前景的方法。 相似文献
17.
The distribution of trace elements in sulfide minerals from the Broken Spur hydrothermal vent field (MAR) suggests the presence
of nanomineral phases for some trace elements, including Au and Ag. 相似文献
18.
应用偏光显微镜和电子探针技术研究安徽铜官山矽卡岩型铜铁矿床伴生元素金银铂钯铀的赋存状态 总被引：4，自引：2，他引：2
安徽铜官山矽卡岩型铜铁矿床富含多种稀有贵金属金银铂钯和铀,本文应用偏光显微镜与电子探针技术对该地区贵金属和铀矿物的含量、矿物种类、赋存状态及其嵌布特征进行研究,并利用电子探针Th-U-Pb定年技术推测铀矿物的形成时期。研究表明:金主要以银金矿独立矿物存在,成色均值约为638,与铜的硫化物密切依存,金矿物形成于成矿中晚期的中低温环境;银的独立矿物有银金矿、碲银矿、辉银矿,还与铜铋铅等以类质同象形式结合形成不同种类的矿物组合,且含量在74.15%~0.12%不等;铂钯矿物以含铂碲钯矿为主;铀以晶质铀矿独立矿物存在且与磁铁矿密切依存,晶质铀矿的形成年龄约为124±14 Ma,晚于岩体形成年龄(约139 Ma),早于黄铜矿和含金银铂钯等矿物,而与磁铁矿同在燕山中晚期形成。结合镜下观察,认为铜官山矽卡岩型铜铁矿床主要矿物生成顺序依次是:石榴子石-磁铁矿、晶质铀矿,含金银铂钯矿物,黄铜矿。本研究为贵金属选矿提供了线索,同时利用晶质铀矿的年龄数据界定了伴生贵金属的形成年代。 相似文献
19.
Quantitative microanalysis of entire silicate and sulfide melt inclusions by Excimer Laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICPMS) has been applied to extrusive and shallow intrusive rocks from the andesitic Farallón Negro Volcanic Complex (northwestern Argentina). Silicate melts are trapped in pyroxene, amphibole, plagioclase and quartz, and sulfide melts are trapped in amphibole. Details of the analytical approach and the quantification procedure are given and the results are evaluated to test the accuracy of the technique and the validity of the interpretation of analytical signals. Similar compositions of silicate melt inclusions trapped in truly co-precipitating minerals show that the quantification approach of melt inclusion compositions from LA-ICPMS signals through an internal standard is valid. This correspondence also shows that melt inclusions investigated in this study are not significantly influenced by the boundary layer around a growing crystal or by post-entrapment modifications. Post-entrapment diffusive re-equilibration only affected the Fe and Mg content of melt inclusions in mafic phases. Thus, melt inclusions are representative samples of the melt from which the host mineral crystallized, with regard to most major and trace elements. Sulfide melt inclusions (present as pyrrhotite with exsolution of Au and Cu in phases separated during cooling) were analyzed for their bulk Fe, Cu and Au content, and the abundance of these elements was quantified using a silicate glass as external standard. The validity of this calibration was tested by comparing electron microprobe analyses of Fe, Cu, Ni and Co in homogeneous sulfide minerals with LA-ICPMS results. Identical results within calculated uncertainty (one standard deviation of five to nine analyses, mostly between 1 and 5 wt% RSD) demonstrate that for these elements, measured element ratios are independent of the matrix using our analytical setup.Editorial responsibility: T.L. Grove 相似文献
20.
Masanori Kurosawa Kunihiro Shima Satoshi Ishii Kimikazu Sasa 《Geostandards and Geoanalytical Research》2006,30(1):17-30
The concentrations of fifty trace elements, including relatively volatile elements and transition metal elements, in fused glasses of Geological Survey of Japan rock reference materials GSJ JR-2, JA-1, JA-2, JB-1a, JB-3, JGb-1 and JF-1 were determined by particle (proton) induced X-ray emission (PIXE) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The fused glasses were prepared by rapid fusion and subsequent quenching in welded platinum capsules and were found to be homogeneous for major elements and for trace elements with concentrations of more than 1 μg g-1 within the observed precision (± 10% mean) on a 70 μm sampling scale. The values obtained by PIXE and LA-ICP-MS for the transition elements (Cr, Mn, Fe, Ni and Cu), the relatively volatile elements (Zn, Ga, Rb and Pb) and the refractory elements (Y, Zr, Nb and Th) with concentrations greater than a few μg g-1 showed good agreement (within 10 % relative difference). The values for almost all the elements detected at concentrations higher than 1 μg g-1 as determined by LA-ICP-MS also agreed well with the reference values (mean relative difference < ± 10%), except for B and Cu. The good agreement confirmed the appropriateness of the NIST SRM 600 series glass calibration reference material for LA-ICP-MS analysis of glasses with variable major-element compositions for almost all elements. The concentrations of Cu in all the samples were lower than the reference values, which was attributed to adsorption of the transition metals onto the platinum capsule during preparation. 相似文献