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1.
Factors affecting water chemistry of alpine lakes   总被引：2，自引：0，他引：2  
During a four-year study (1988–1991), 413 lakes in the Central Alps (Italy, Switzerland and Austria) were investigated to quantify their acidification. The ionic content of the lakes was generally low: 68% of them had alkalinity values of less than 200 µeq 1–1 and were regarded as sensitive to acidification. Moreover, 36% of the lakes showed alkalinity values of less than 50 µeq 1–1. Redundancy Analysis was used to relate the hydrochemistry of 187 lakes to their catchment characteristics. Calcite weathering was the main factor influencing lake chemistry. The same analysis, applied to a subset of 101 lakes lying in watersheds exclusively composed of silicic rocks, showed that lake chemistry was influenced by silicate weathering and nitrogen uptake. These processes were found to be mainly related to lake altitude and the fraction of the watershed not covered by vegetation, i.e. controlled by temperature. The importance of these relations to explain the pH shift produced by climatic variation is also discussed.  相似文献   

2.
Alpine lakes in siliceous catchments of Tyrol and Carinthia (Austria) show signs of acidification. About 9% of the studied lakes have no alkalinity, more than 20% are below pH 6. About two thirds of all lakes have acid neutralizing capacities below 100 eq 1–1. In spite of moderate precipitation acidity, some lakes show considerable concentrations of dissolved reactive aluminum during or shortly after snowmelt. High altitude lakes of the Alps are definitely more acidic than high mountain lakes in remote areas. Large differences in water and soil chemistry of nearby situated lakes were attributed to heterogeneities of bedrock geology. Paleolimnological investigations on former pH values of five lakes, based on diatom assemblages in the sediment, showed different developments: recent and past acidification, stable conditions, and alkalinization.  相似文献   

3.
Although acidifying deposition in western North America is lower than in many parts of the world, many high‐elevation ecosystems there are extremely sensitive to acidification. Previous studies determined that the Mount Zirkel Wilderness Area (MZWA) has the most acidic snowpack and aquatic ecosystems that are among the most sensitive in the region. In this study, spatial and temporal variability of ponds and lakes in and near the MZWA were examined to determine their sensitivity to acidification and the effects of acidic deposition during and after snowmelt. Within the areas identified as sensitive to acidification based on bedrock types, there was substantial variability in acid‐neutralizing capacity (ANC), which was related to differences in hydrological flowpaths that control delivery of weathering products to surface waters. Geological and topographic maps were of limited use in predicting acid sensitivity because their spatial resolution was not fine enough to capture the variability of these attributes for lakes and ponds with small catchment areas. Many of the lakes are sensitive to acidification (summer and autumn ANC < 100 µeq L?1), but none of them appeared to be threatened immediately by episodic or chronic acidification. In contrast, 22 ponds had minimum ANC < 30 µeq L?1, indicating that they are extremely sensitive to acidic deposition and could be damaged by episodic acidification, although net acidity (ANC < 0) was not measured in any of the ponds during the study. The lowest measured pH value was 5·4, and pH generally remained less than 6·0 throughout early summer in the most sensitive ponds, indicating that biological effects of acidification are possible at levels of atmospheric deposition that occurred during the study. The aquatic chemistry of lakes was dominated by atmospheric deposition and biogeochemical processes in soils and shallow ground water, whereas the aquatic chemistry of ponds was also affected by organic acids and biogeochemical processes in the water column and at the sediment–water interface. These results indicate that conceptual and mechanistic acidification models that have been developed for lakes and streams may be inadequate for predicting acidification in less‐understood systems such as ponds. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

4.
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5.
The role of chemical weathering in the neutralization of acidic deposition   总被引：1，自引：0，他引：1  
Chemical weathering of rocks and minerals is a key factor which mitigates acidic deposition and affects water chemistry. It supplies cations and alkalinity to the surface water, groundwater, ion-exchange complex, and vegetation in the watershed. The kinetics of chemical weathering have not been determined in the field, but based on laboratory experiments, the rate of weathering has a fractional order dependency on hydrogen ion and organic ligand concentration in bulk solution. Watersheds with the greatest degree of hydrologic and geologic sensitivity can produce only 200–500 eq/ha·yr of cations or alkalinity for export. This is equivalent to 100 cm/yr of precipitation with a pH of 4.3–4.6 or an annual sulfur deposition of 1.0–2.5 g S/m2·yr. When acid and sulfur deposition are greater than these levels, extremely sensitive lakes may become acidified. To illustrate this point, a simple steady-state model is applied to lakes in regions where acidification of lakes has been reported.  相似文献   

6.
Although littoral regions in northern lakes may sustain fish spawning grounds, little is known of the temporal or spatial aspects of their thermal and chemical regimes. This shortcoming is due in part to the difficulty in properly sampling these regions throughout the year with adequate spatial resolution. This problem is especially critical in lakes affected by episodic acidification during the spring snowmelt, a period of substantial importance to fisheries recruitment. A device was constructed to alleviate the problems associated with conventional water quality sampling of littoral regions. Constructed of thick walled polyvinyl chloride and permanently installed in the nearshore regions of an Adirondack lake, the episodic event sampler (EES) provided finely resolved (0.25 m) temperature and water chemistry data during the spring snowmelt period (February to May) of 1989. Although the construction and installation of the sampler represented a significant investment in labour and materials, this was offset by the high quality of the data collected. As the samplers were relatively undamaged by freeze-thaw activity, it is expected that they will continue to provide excellent information for several years.  相似文献   

7.
Acidic atmospheric deposition has adversely affected aquatic ecosystems globally. As emissions and deposition of sulfur (S) and nitrogen (N) have declined in recent decades across North America and Europe, ecosystem recovery is evident in many surface waters. However, persistent chronic and episodic acidification remain important concerns in vulnerable regions. We evaluated acidification in 269 headwater streams during 2010–2012 along the Appalachian Trail (AT) that transits several ecoregions and is located downwind of high levels of S and N emission sources. Discharge was estimated by matching sampled streams to those of a nearby gaged stream and assuming equivalent daily mean flow percentiles. Charge balance acid-neutralizing capacity (ANC) values were adjusted to the 15th (Q15) and 85th flow percentiles (Q85) by applying the ANC/discharge slope among sample pairs collected at each stream. A site-based approach was applied to streams sampled twice or more and a second regression-based approach to streams sampled once to estimate episodic acidification magnitudes as the ANC difference from Q15 to Q85. Streams with ANC <0 μeq/L doubled from 16% to 32% as discharge increased from Q15 to Q85 according to the site-based approach. The proportion of streams with ANC <0 μeq/L at low flow and high flow decreased from north to south. Base cation dilution explained the greatest amount of episodic acidification among streams and variation in sulfate (SO42−) concentrations was a secondary explanatory variable. Episodic SO42− patterns varied geographically with dilution dominant in northern streams underlain by soils developed in glacial sediment and increased concentrations dominant in southern streams with older, highly weathered soils. Episodic acidification increased as low-flow ANC increased, exceeding 90 μeq/L in 25% of streams. Episodic increases in ANC were the dominant pattern in streams with low-flow ANC values <30 μeq/L. Chronic and episodic acidification remain an ecological concern among AT streams. The approach developed here could be applied to estimate the magnitude and extent of chronic and episodic acidification in other regions recovering from decreasing levels of atmospheric S and N deposition.  相似文献   

8.
About one third of several hundred mining lakes in Eastern Germany are highly acidified, and there is a need to restore them to neutral conditions because they constitute an environmental hazard for water resources and downstream environments. The aim of this study is to evaluate the efficiency of three different acid pit lake water remediation treatments: dilution with alkaline (river) water, limestone treatment and biological neutralization by organic carbon-driven alkalinity generation. The efficiency is evaluated for the acidic mining lake Grünewalder Lauch by adjusting input values into a geochemical model and making future projections. Current approaches, such as flooding with neutral surface water or extensive liming, are not suitable for many lakes because of a limited supply of alkaline water or high lime immobilizing potential of Fe- and Al-rich water in acidic lakes, respectively. Further treatment methods are, therefore, designed to combine water supply and biological measures with the management of water quality by the application of in-lake microbial processes. These processes are focused on the metabolic response of aquatic ecosystems to nutrient enrichment (enhancement of primary production and thereby organic carbon supply) and the microbial decomposition of organic matter and their effects on the gain or loss of alkalinity.The results and comparisons of different neutralization measures will be generalized by the application of hydrogeochemical models for alkalinity production showing
a)
the long term efficiency of the measures, depending on carbon turnover at the sediment/water interface,
b)
the development of bicarbonate buffering capacity as a consequence of biological measures,
c)
the importance of pyrite formation instead of FeS.
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9.
In high-elevation lakes of the Sierra Nevada (California), increases in phosphorus (P) supply have been inferred from changes in phytoplankton growth during summer. To quantify rates of sediment P release to high-elevation Sierran lakes, we performed incubations of sediment cores under ambient and reducing conditions at Emerald Lake and analyzed long-term records of lake chemistry for Emerald and Pear lakes. We also measured concentrations of individual P forms in sediments from 50 Sierra Nevada lakes using a sequential fractionation procedure to examine landscape controls on P forms in sediments. On average, the sediments contained 1,445 µg P g?1, of which 5 % was freely exchangeable, 13 % associated with reducible metal hydroxides, 68 % associated with Al hydroxides, and the remaining 14 % stabilized in recalcitrant pools. Multiple linear regression analysis indicated that sediment P fractions were not well correlated with soluble P concentrations. In general, sediments behaved as net sinks for P even under reducing conditions. Our findings suggest that internal P loading does not explain the increase in P availability observed in high-elevation Sierran lakes. Rather, increased atmospheric P inputs and increased P supply via dissolved organic C leaching from soils may be driving the observed changes in P biogeochemistry.  相似文献   

10.
To better understand the linkage between lake area change, permafrost conditions and intra‐annual and inter‐annual variability in climate, we explored the temporal and spatial patterns of lake area changes for a 422 382‐ha study area within Yukon Flats, Alaska using Landsat images of 17 dates between 1984 and 2009. Only closed basin lakes were used in this study. Among the 3529 lakes greater than 1 ha, closed basin lakes accounted for 65% by number and 50% by area. A multiple linear regression model was built to quantify the temporal change in total lake area with consideration of its intra‐annual and inter‐annual variability. The results showed that 80.7% of lake area variability was attributed to intra‐annual and inter‐annual variability in local water balance and mean temperature since snowmelt (interpreted as a proxy for seasonal thaw depth). Another 14.3% was associated with long‐term change. Among 2280 lakes, 350 lakes shrank, and 103 lakes expanded. The lakes with similar change trends formed distinct clusters, so did the lakes with similar short term intra‐annual and inter‐annual variability. By analysing potential factors driving lake area changes including evaporation, precipitation, indicators for regional permafrost change, and flooding, we found that ice‐jam flooding events were the most likely explanation for the observed temporal pattern. In addition to changes in the frequency of ice jam flooding events, the observed changes of individual lakes may be influenced by local variability in permafrost distributions and/or degradation. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

11.
Physical as well as biochemical processes have a significant influence on the material balance of a lake. Mathematical concepts are developed to treat transport phenomena with which a comparison of different lakes under certain systematic aspects becomes possible. A two-box model consisting of the subsystems epilimnion and hypolimnion, for lakes with one specific limiting nutrient factor (e.g., phosphorus) is employed to evaluate eutrophication processes. In particular, a theoretical basis forVollenweider's [3] empirical relation between specific phosphorus loading and the trophic state is presented. Finally, the inhomogeneous O2-consumption in the deep part of the lake during summer stagnation is calculated with diffusion theory.   相似文献   

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14.
Joshua C. Koch 《水文研究》2016,30(21):3918-3931
Arctic thaw lakes are an important source of water for aquatic ecosystems, wildlife, and humans. Many recent studies have observed changes in Arctic surface waters related to climate warming and permafrost thaw; however, explaining the trends and predicting future responses to warming is difficult without a stronger fundamental understanding of Arctic lake water budgets. By measuring and simulating surface and subsurface hydrologic fluxes, this work quantified the water budgets of three lakes with varying levels of seasonal drainage, and tested the hypothesis that lateral and subsurface flows are a major component of the post‐snowmelt water budgets. A water budget focused only on post‐snowmelt surface water fluxes (stream discharge, precipitation, and evaporation) could not close the budget for two of three lakes, even when uncertainty in input parameters was rigorously considered using a Monte Carlo approach. The water budgets indicated large, positive residuals, consistent with up to 70% of mid‐summer inflows entering lakes from lateral fluxes. Lateral inflows and outflows were simulated based on three processes; supra‐permafrost subsurface inflows from basin‐edge polygonal ground, and exchange between seasonally drained lakes and their drained margins through runoff and evapotranspiration. Measurements and simulations indicate that rapid subsurface flow through highly conductive flowpaths in the polygonal ground can explain the majority of the inflow. Drained lakes were hydrologically connected to marshy areas on the lake margins, receiving water from runoff following precipitation and losing up to 38% of lake efflux to drained margin evapotranspiration. Lateral fluxes can be a major part of Arctic thaw lake water budgets and a major control on summertime lake water levels. Incorporating these dynamics into models will improve our ability to predict lake volume changes, solute fluxes, and habitat availability in the changing Arctic. Published 2016. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

15.
A hydrochemical investigation was carried out in spring, summer, and autumn, in the years 1991–1994, in three dystrophic lakes of the Wigry National Park (NE Poland). In spite of the fertile catchment basin, the developing ombrofile peat bogs of lake environment results in the acidification of lakes, the presence of small concentrations of dissolved mineral substances (below 50 mg L–1), and exceptionally high DOC concentrations, exceeding 10 mg L–1 C. During summer, a strong thermic stratification develops in the lakes, with constant conditions of oxygen deficiency prevailing below 3 m. In the course of the spring and autumn mixing of dystrophic lakes, the deterioration of oxygen conditions occurs in the epilimnion. In spite of high TP and NH4+ concentrations, which increase from spring to autumn, the conditions developing in the lakes are unfavourable, for the functioning of aquatic organisms, on account of the strong shading. The increased direct irradiation of water bodies caused by deforestation or favourable atmospheric conditions results in an increased trophy of lakes.  相似文献   

16.
Two nanociliates of the order Prostomatida,Pseudobalanion planctonicum (12–18 µm) andUrotricha furcata (12–21 µm), were found to be the most abundant ciliates in the epilimnion of Piburger See, a small mesotrophic lake. Temperature and food availability were the main factors controlling the sudden increase in abundance, which reached a maximum of 101 cell ml–1 at the beginning of summer. During their exponential development in numbers and biomass, a strong decrease in chlorophylla and in the abundance of phytoplankton, especiallyRhodomonas, was observed. We assume, therefore, thatPseudobalanion planctonicum andUrotricha furcata together with rotifers, mainlyPolyarthra dolichoptera, are able to reduce the phytoplankton biomass in the upper epilimnion to the same level as found during the clearwater phase. Preliminary results of grazing on bacteria suggest that these nanociliates are omnivorous, although their impact on bacterial assemblages was low (3.1% of the standing stock grazed per day). Feeding on the base of the food web combined with their high abudance at certain times makes them an important link for higher trophic levels. This study constitutes the second report onPseudobalanion as an important component of the microbial food web in lakes.  相似文献   

17.
      
The investigated coal mining lakes (ML 111, ML 117, and ML 107) in the Lusatian lignite mining district are extremely acidic. The concentrations of iron in these geogenic acidified lakes are orders of magnitude higher than in acidic bog lakes and softwater lakes acidified by atmospheric deposition. For the most part ferric iron was the predominant species by a Fe(III) to Fe(II) ratio of more than 10. Density stratification of the water column leads to vertical concentration gradients of ferrous iron. Extremely high concentrations of ferrous iron were found in the anoxic layers above the sediment of ML 111 and ML 107. High concentrations of Fe(II) were correlated with high concentrations of carbon dioxide. A microbial potential to reduce ferric iron was found in the sediments. In ML 111 and ML 117 the concentrations of Fe(II) in the epilimnion were markedly higher than in the oxic hypolimnetic layers. It can be suggested that the occurence of ferrous iron in the epilimnion is of photochemical origin, as described for softwater lakes. Minimum concentrations of dissolved organic carbon in the epilimnion could be correlated to the increase of ferrous iron concentrations. Especially in springtime and summer the concentrations of Fe(II) in the epilimnion were higher than in the oxic hypolimnetic layer below.  相似文献   

18.
A genetic and evolutionary model is established for saline depressions in continental areas. These depressions are located in arid or subarid areas, and are developed on low permeability geological mediums (K<10 mm/day) with a lack of streams reaching the small lakes. The phenomenon of evaporation is fundamental, since it is the basic requirement for the presence or absence of a free water surface in the lake, and also for depression of the phreatic surface, which causes inflow of groundwater towards the lake. With these conditions, the proposed model includes the following stages: (i) initiation of the close depression; (ii) deepening of the depression; (iii) formation of the lake basin and the end of the deepening; and (iv) levelling and lateral extension of the lake basin. The combined effects of groundwater flows and aeolian action offer a coherent explanation for the origin and evolution both of the closed depressions found in the Ebro Valley, and of the salt lakes that subsequently form. The processes described form morphologies of oval shape with the main axis parallel to the direction of the wind, flat floors and evaporitic sedimentation, although they act on geological materials with different lithologies. © 1998 John Wiley & Sons, Ltd.  相似文献   

19.
Groundwater chemical data from Birkenes, southern Norway, collected during the period October 1980 to November 1993, reveal intensifying acidification in the 1990s, as evidenced by decreases in pH, acid-neutralising capacity and alkalinity, and increases in hardness/alkalinity ratio, ‘acidification’, nitrate, non-marine sulphate (SO4*), non-marine hardness (Ca* + Mg*) and dissolved aluminium. The whole monitoring period is characterised by slopes of four or more on a plot of (Ca* + Mg*) vs. alkalinity.

Owing to its proximity to the sea, the Birkenes catchment receives seasalt-influenced precipitation, which results in episodic, natural acidification of the groundwater via cation exchange of marine Na+ with soil-bound H+ and/or Al3+. However, it is uncertain whether all of the recent groundwater acidification can be attributed to intensifying seasalt deposition alone: the steep slopes on the (Ca* + Mg*) vs. alkalinity plot and the increase in groundwater SO4* suggest that strong acids, of possible anthropogenic origin, may be involved. Additionally, seasalt deposition appears not to have increased during the 1990s: Cl− content in precipitation has not increased significantly and river water pH has not decreased significantly over the period 1990–1993. The suggestion is made that the observed intensification in groundwater acidification at Birkenes partly results from the exhaustion or weakening of an acid buffering system caused by soil acidification, under persisting, even if abating, anthropogenic acid loading.  相似文献   


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