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1.
Kazuya Idemitsu Katsuhiko Ishiguro Yasuhisa Yusa Noriaki Sasaki Naomi Tsunoda 《Engineering Geology》1990,28(3-4):455-462
Measurements on plutonium diffusivity in water-saturated compacted bentonite were carried out. Representative specimens of sodium bentonite were taken from the Tsukinuno and Kuroishi mines situated in northeast Japan. Tsukinuno bentonite was divided into three types: raw type, purified Na-type, and H-type which was prepared by treating Na-type bentonite with hydrochloric acid. Kuroishi bentonite contained chlorite as impurity. H-type bentonite was used as reference for the convenience of profile measurement in bentonite, since plutonium diffusivity in H-type bentonite was considered to be larger than that in Na-type bentonite because of low pH and low swelling pressure of H-type bentonite.
Sampled bentonite was compacted into pellets of 20 mm in diameter and 20 mm in height. Bulk densities of these specimens were 1200–1800 kg/m3 for purified Na-type and H-type bentonite and 1600 kg/m3 for raw type bentonite.
Plutonium profiles obtained in H-type bentonite can be explained by diffusion equation with constant concentration source. Diffusivity ranges from 10-13 to 1012 m2/s for H-type and Kuroishi impure sodium bentonite. Diffusivity in both raw type and purified Tsukinuno bentonite was was estimated to less than 10-14 M2/s. Diffusivity in H-type bentonite showed a tendency to decrease with increasing density. Influence of in bentonite was also studied. Quartz content up to 50% or hematite content up to 1% did not influence diffusivity significantly in H-type bentonite.
The chemical species of plutonium in pore water of Na-type and H-type were estimated Pu(OH)3-; and PuO2- , respectively. 相似文献
2.
提高水价对水资源需求的影响分析——以华北地区为例 总被引：29，自引：2，他引：27
中国已决定在3年之内把目前严重偏低的供水价格提高到保本乃至微利水平,这意味着华北地区农业供水价格将从目前的0.03元/m3左右提高到0.2元/m3～0.3元/m3,工业用自来水价格将从0.50元/m3～1.50元/m3提高到3.0元/m3～4.0元/m3,生活用水价格将从0.30元/m3～1.00元/m3提高到1.00元/m3～2.50元/m3。如此大幅度地提高水价,将对华北地区的水资源需求产生强烈的抑制作用,相对于原来预测的水资源需求量,水价提升将使水资源需求量减少25%～50%,达132～250亿m3,至少相当于“南水北调”中线和东线两项工程调往黄河以北的水量。显然,理顺水价具有很大的节水潜力。 相似文献
3.
利用Phreeqc软件模拟了核废料处置库中高压实膨润土中发生的化学反应,建立了K+、Ca2+、Na+、Mg2+ 4种阳离子的离子交换和矿物溶解沉淀的一维运移反应模型。模拟了核废料处置环境中,膨润土化学组分在不同流体环境下随时间和空间的变化规律,验证了膨胀性的衰减主要是由Na基蒙脱石转变为Ca基蒙脱石引起。结合膨润土化学组分变化结果,对膨润土膨胀性衰减程度进行了评估。得到1万年后海水和地下水环境下的高庙子膨润土膨胀性衰减系数分别达到0.83和0.92,MX80膨润土达到0.79和0.90。 相似文献
4.
Research on the longevity of potential bentonite-based barrier materials is an important part of the Canadian Nuclear Fuel Waste Management Program. Valuable information on the longterm effectiveness of bentonitic barriers can be obtained by examining the properties of unprocessed bentonites from natural deposits. This study compares the swelling capacity (Ps) and hydraulic conductivity (K) of an unprocessed (clay that has not been ground and dried by the supplier) and a processed bentonite from south-central Saskatchewan, Canada. The clay deposit is 75 to 85 Ma old. At a given clay density, the processed bentonite exhibits a greater P3 and a lower K than the unprocessed clay. This can be at least partially attributed to the partial cementation of the unprocessed bentonite particles; this cementation is likely ruptured when the clay is ground during processing. Even though K for the unprocessed clay is higher than that of the processed clay, it is still low enough (< 1011m/s) to meet the permeability requirements of a barrier material in a nuclear fuel waste disposal vault. The unprocessed clay also has the has the ability to self seal: exposure to water, the normalized flow rate of water through some samples was as high as 10-5 m3/s, but the rate rapidly decreased to < 10-10m3/s the clay absorbed water and swelled. The data indicate that the unprocessed bentonite clay maintains anacceptably high swelling capacity and low permeability millions of years after deposition. 相似文献
5.
城市湖泊生态环境需水量包括:城市湖泊蒸发需水量、城市湖泊自身存在的需水量、生物栖息地的需水量、城市湖泊净化需水量、湖泊渗漏需水量、景观、娱乐需水量。需水量计算在遵循生态优先原则、兼容性原则、最大值原则和等级制原则的基础上,还应充分考虑时间性原则。计算了北京市六海各季节(冬季除外)生态环境需水量,结果表明:北京六海春、夏、秋及全年的最小生态环境需水量分别为:296.82、643.94、474.59和1415.35万m3,其中净化需水量分别占35 87%、71 23%、70 08%和63 42%。根据研究和计算结果,对改善六海生态环境提出了建议。 相似文献
6.
以天山乌鲁木齐河上游作为研究对象, 结合乌鲁木齐河上游近50 a的实测月均径流变化资料, 对未来的月均径流进行了预测. 基于对重现水平的95%置信区间进行估计的结果表明, 乌鲁木齐河上游重现期为10 a、25 a、50 a和100 a的月均径流量极大值分别约为35.4 m3·s-1、39.9 m3·s-1、43.2 m3·s-1和46.3 m3·s-1;重现期为10 a、25 a、50 a和100 a的月均径流量极小值分别约为0.60 m3·s-1、0.43 m3·s-1、0.30 m3·s-1和0.18 m3·s-1. 在当前气候变化背景下, 乌鲁木齐河上游在2058年前后枯水期时可能发生断流现象. 该研究对乌鲁木齐河径流变化预测具有重要意义. 相似文献
7.
Snehasis Tripathy Ramakrishna Bag Hywel Rhys Thomas 《Geotechnical and Geological Engineering》2014,32(4):749-763
The effects of post-compaction residual lateral stress and salt concentration in the hydrating fluid on swelling pressures of compacted MX80 bentonite is brought out in this paper. In order to release the residual lateral stresses, following the static compaction process during preparation of specimens, compacted bentonite specimens were extruded from the specimen rings and then inserted back prior to testing them for swelling pressures in isochoric condition. The swelling pressure tests were carried out at several dry densities of the bentonite with distilled water and solutions of NaCl (0.1 and 1.0 M) as the hydrating fluids. With water, the test results showed that specimens that underwent extrusion and insertion processes exhibited about 10–15 % greater swelling pressures as compared to the specimens those that were compacted and tested. The influence of saline solutions was found to reduce the swelling pressure of the bentonite, but their impact was less significant at high compaction dry densities. 相似文献
8.
G. S. Xeidakis 《Engineering Geology》1996,44(1-4):107-120
Stabilization of the swelling clay structure is attempted by intercalation of Mg(OH)2 and the development of a brucite interlayer between the clay layers. The properties of the product obtained by applying the technique, formulated as described in a previous work, are considered here. The materials used were Wyoming bentonite (USA), Fuller's Earth (UK), kaolinite, illite, lignite, and silica gels. The Mg(OH)2-clay products were examined by the methylene blue dye test, X-ray diffraction analysis (XRD), differential thermal analysis (DTA), and derivative thermogravimetry analysis (DTGA). From the results obtained it is concluded that: the Mg-hydroxide is adsorbed by swelling clays both on their external and internal surface, whereas it is adsorbed on the external surface by non-swelling clays. The internally adsorbed phase of Mg-hydroxide forms an ill-defined interlayer of brucite, retarding swelling, whereas the external phase covers the particles modifying drastically their surface properties, like the adsorption of the MB dye. The material produced after precipitation of Mg-hydroxide on swelling clays (smectites) did not re-expand on wetting or after glycolation. The adsorption of MB dye was also reduced by some 80–90%, due to coating effect, preventing the measurements of the external surface area of the clay by polar molecules. The principal forces involved in the process are believed to be physical adsorption on the external surface, along with chemisorption and some chemical bonding, mostly in the internal surface. Cementation due to crystallization and, in the long term, some pozzolanic reactions take also place. Internal adsorption of the Mg-hydroxide is postulated to be in the form of positively charged mono- and/or small polymers and it is, chiefly, diffusion controlled. Since Mg-hydroxide is internally adsorbed by swelling clays, whereas Ca-hydroxide(lime) is not, and the (Mg, Ca)-clay aggregates are more stable than the Ca-clay or the Mg-one, the combination of the two hydroxides could give better results in soil stabilization than each hydroxide alone. 相似文献
9.
This paper gives several new and strong arguments in favour of the possibility of fixation of anhydrous lithium in the interlayer space of trioctahedral potassium micas. From the chemical viewpoint Li+ can replace K+, but is located out of the alkaline cation site; it enters pseudo-octahedral cavities limited by the triangular bases of two aluminous tetrahedra of two consecutive sheets. The solubility limit of Li+ in the interlayer is a function of the AlIV content of the mica. It is given by the relation (Li/Li + K)max = 2[(Al/Si + Al)IV]2. In both micas investigated — phlogopite, KMg3(Si3Al)O10(OH)2, and eastonite, K(Mg2.5Al1.5)(Si2.5Al1.5)O10(OH)2 — there is a remarkable agreement between the calculated values of the solubility limits and those measured by exchange reactions with hydrothermal solutions, at 600°C, 2 kbar. In high-Al micas, the interlayer Li content can be very important, with about one-third of K+ replaced by Li+.
The fixation of Li+ according to this model provokes a strong flattening of the interlayer (strong decrease of the reticular distance d005) and a slight increase of the reticular distance d060. Infra-red (IR) absorption spectrometry shows that vacant K+ sites are created when Li+ enters the interlayer; one observes low-frequency OH stretching bands attributed to OH dipoles lying towards these empty sites. Fixation of Li+ does not provoke any modification of the IR spectra in the region 1200-300 cm−1, indicating that Li+ is really out of the sheet. For both cell dimensions and IR spectra, a comparison is made with “ordinary” lepidolites, having Li+ in the octahedral sheet; it provides a guide for the distinction between the two species of Li-bearing micas. 相似文献
10.
Dynamic compaction tests of bentonite-based materials (BBMs) with 100, 70 and 50% bentonite contents have been performed using five powdery bentonites with different physicochemical properties to establish the simplified evaluation method for dynamic compaction properties of BBMs. For a given bentonite content and a total compaction energy condition, the maximum dry density, ρdmax, and the optimum water content, wopt, which are well-known indexes of compaction properties, for BBMs were determined according to the type of bentonite used for BBMs. For evaluation of those values of BBMs derived in this study, the plastic limit of BBM, wpbbm, was defined as the plastic limit that was measured using the sample pulverized to a maximum grain size of less than 425 μm in the case of BBM with sand having a maximum grain size of more than 425 μm and was measured using the powdery bentonite itself in the case of BBM without sand. This study proposed equations for evaluating ρdmax and wopt of BBMs with more than 50% bentonite content under the total compaction energy conditions of 551–2755 kN-m/m3 using wpbbm. Finally, we related the equations derived in this study to the equation for evaluating hydraulic properties of compacted BBMs proposed in previous work and proposed the preparation method of BBMs with more than 50% bentonite content for constructing BBM buffer by in-situ compaction method. 相似文献
11.
探索了长江南水北调占总径流量10%情况下对长江粗颗粒悬沙(≥0.05mm)入海数量变化的可能影响。研究表明:南水北调对入海细颗粒泥沙的影响主要为南沙北调,但数量较小,在1%左右,而对粗颗粒悬沙的影响主要表现在入海流量减少导致的水体挟沙能力的降低。通过建立大通站典型枯水年(1978),平水年(1987)及洪水年(1983)月平均流量与月平均床沙质输沙率相关曲线,估算出各典型年在典型流量23000m3/s,30000m3/s与40000m3/s水平下调水流量3000m3/s时导致的入海床沙质输沙率的变化。结果表明,输沙率的相对变化在-39%至-24%之间,且在较高的流量水平下,输沙率相对变化较小,但绝对变化增大,经大通入海的床沙质数量每年约减少2350～4700万t. 相似文献
12.
河南信阳上天梯膨润土制备高效活性白土试验研究 总被引：6，自引：0，他引：6
上天梯膨润土属于钙基膨润土,主要矿物成分是钙质蒙脱石。矿石的胶体分散性较差,阳离子交换总量较低,主要的可交换阳离子是钙、镁离子。蒙脱石的晶体化学结构研究表明,蒙脱石有较高的有序度和较大的层电荷,因此,上天梯膨润土适合于制备高效活性白土。试验讨论了酸性活化、固液比及活化时间对产品质量的影响,确定了最佳工艺条件。对原矿进行捣浆提纯后,用16％～20％的硫酸溶液对膨润土进行活化,活化时间 6～8小时,固液比1∶2。制得的活性白土的脱色力达156～218,活性度大于222m.mol/100g ,其质量达到和超过了国家行业标准和同行业该产品的指标,脱色效果良好。 相似文献
13.
Giacomo D''Amato Avanzi Roberto Giannecchini Alberto Puccinelli 《Engineering Geology》2004,73(3-4):215-228
On June 19, 1996, an extremely heavy rainstorm hit a restricted area in the Apuan Alps (northwestern Tuscany, Italy). Its max intensity concentrated over an area of about 150 km2 astride the Apuan chain, where 474 mm was recorded in about 12 h (21% of the mean annual precipitation, with an intensity up to 158 mm/h). The storm caused floods and hundreds of landslides and debris flows, which produced huge damage (hundreds of millions of Euros), partially destroyed villages and killed 14 people. This paper reports the results obtained from a detailed field survey and aerial view interpretation. In the most severely involved area, 647 main landslides were investigated, mapped and related to the geologic, geomorphic and vegetational factors of the source areas. This was in order to define the influence of these factors and contribute to an evaluation of the landslide hazard in the study area. An assessment was also made of the total area and volume of material mobilised by landsliding. The study area, about 46 km2 wide, includes three typically mountainous basins, characterised by narrow, deep cut valleys and steep slopes, where many rock types outcrop. Most of the landslides were shallow and linear, referable to complex, earth and debris translational slide, which quickly developed into flow (soil slip–debris flow). Usually, they involved colluvium and started in hollows underlain by metamorphic rock (metasandstone and phyllite), often dipping downslope. Therefore, bedrock lithology and impermeability appeared to be important factors in the localisation of the landslide phenomena. The investigation of the geomorphic and land use features in the source areas also frequently highlighted a rectilinear profile of the slope, a high slope gradient (31–45°) and dense chestnut wood cover. In the area, about 985,000 m2 (2.1% of 46 km2) was affected by landsliding and about 700,000 m2 of this area was covered by chestnut forest. The landslides removed about 7000 trees. The volume of mobilised material was about 1,360,000 m3; about 220,000 m3 remained on the slopes, while the rest poured into the streams. In addition, about 945,000 m3 was mobilised by the torrential erosion in the riverbeds. 相似文献
14.
This paper presents an upscaling concept of swelling/shrinking processes of a compacted bentonite/sand mixture, which also applies to swelling of porous media in general. A constitutive approach for highly compacted bentonite/sand mixture is developed accordingly. The concept is based on the diffuse double layer theory and connects microstructural properties of the bentonite as well as chemical properties of the pore fluid with swelling potential. Main factors influencing the swelling potential of bentonite, i.e. variation of water content, dry density, chemical composition of pore fluid, as well as the microstructures and the amount of swelling minerals are taken into account. According to the proposed model, porosity is divided into interparticle and interlayer porosity. Swelling is the potential of interlayer porosity increase, which reveals itself as volume change in the case of free expansion, or turns to be swelling pressure in the case of constrained swelling. The constitutive equations for swelling/shrinking are implemented in the software GeoSys/RockFlow as a new chemo‐hydro‐mechanical model, which is able to simulate isothermal multiphase flow in bentonite. Details of the mathematical and numerical multiphase flow formulations, as well as the code implementation are described. The proposed model is verified using experimental data of tests on a highly compacted bentonite/sand mixture. Comparison of the 1D modelling results with the experimental data evidences the capability of the proposed model to satisfactorily predict free swelling of the material under investigation. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
15.
新疆开都-孔雀河流域绿洲需水量与稳定性分析 总被引：3，自引：0，他引：3
水是绿洲存在和发展的核心, 干旱区绿洲稳定性与水密切相关. 根据2000-2009年资料, 采用蒸发系数法和定额法估算开都-孔雀河流域绿洲自然生态系统和社会经济系统综合需水量, 并对水资源约束条件下的绿洲稳定性进行初步探讨. 结果表明: 2000-2009年, 绿洲年均总需水量理论值约为54.80×108 m3, 其中开都河绿洲总需水量约为20.55×108 m3, 孔雀河绿洲总需水量约为21.90×108 m3, 博斯腾湖区耗水量约为12.35×108 m3, 与绿洲10 a平均供水量相比, 供需表现出极大地不平衡性. 水资源可承载绿洲面积(不含博斯腾湖)约为3139.66 km2, 其中可承载灌溉地面积约为1395.41 km2, 与绿洲10 a平均面积5 248 km2相比, 差别较大, 绿洲处于不稳定状态, 现状绿洲面积应适当收缩. 最后, 对博斯腾湖最低生态水位进行讨论, 初步把大湖最低水位定为海拔1 045 m, 小湖最低生态水位定为海拔1 046.5 m. 相似文献
16.
目前长春市水资源匮乏,水资源危机严重。城市水资源化是解决水危机、防治水污染的有效途径之一。长春市经处理的污水量为1.843 亿m3/a, 经过深度处理后回用的污水量为423.4 万m3/a,占2.297%,污水资源化利用程度不高。所建污水处理回用工程完成后,每天可增加水量16.16 万m3。通过制定政策,拓宽融资渠道以及提高环保意识等,可提高城市污水资源化的程度,实现良好的社会效益。 相似文献
17.
以北京市延庆地区南湾道豁子泥石流沟为研究对象,通过野外泥石流沟精细调查及历史资料统计,详细了解该泥石流发育特征和形成条件,针对流域内松散堆积物补给条件进行重点分析;综合研究该泥石流的动力学特征,进行泥石流危险区预测评价,提出相应的防治措施建议。研究结果表明:该泥石流沟内松散堆积物动储量为18.47×104 m3,分为冲洪积、残坡积、人工堆积和崩滑塌等4种补给来源,其中冲洪积和残坡积所占比重最大;泥石流发展阶段处于衰退期;经动力学分析,洪峰流量值在10年一遇的降雨条件下为52.53 m3/s,20年一遇的降雨条件下为59.25 m3/s,50年一遇的降雨条件下为68.13 m3/s,100年一遇的降雨条件下为74.85 m3/s,对应的一次固体冲出总量分别为0.77×104 m3、0.87×104 m3、1.00×104 m3和1.10×104 m3;属于中型泥石流,最大危险区面积为0.238 3 km2。通过评价分析,该泥石流沟仍存在爆发中型泥石流的可能性,将对下游南湾村以及千沙公路行车和行人的生命财产安全造成威胁。研究成果可为延庆地区该类泥石流单沟预警模型研究和灾害防治提供科学依据。 相似文献
18.
1980—2017年祁连山水源涵养量时空变化特征 总被引：1，自引：0，他引：1
祁连山是中国西北地区十分重要的生态安全屏障,也是当地极为关键的水源涵养区。基于InVEST模型中的产水量模块,对祁连山水源涵养量和时空变化进行了分析并探讨其影响因素。结果表明：祁连山多年平均产水总量和水源涵养总量约为93.03×108 m3和57.83×108 m3。从时间变化来看,水源涵养量呈上升趋势,上升速率约为0.196 mm·a-1;在空间上呈“东多西少”的分布格局,与年降水量的空间分布大致相同。不同土地利用类型下的水源涵养总量依次为：草地（31.87×108 m3）>林地（16.71×108 m3）>耕地（4.92×108 m3）>其他用地（2.29×108 m3）>建设用地（0.63×108 m3）。降水量与水源涵养量在所有研究时段内均存在显著正相关性。不同时期土地利用类型的变化也会对水源涵养量产生重要影响,研究区草地面积变化对水源涵养量影响较大。根据建立的经验公式并参考已有研究成果,估算得出研究区多年冻土地下冰储量在550 km3以上,在全球气候变暖的背景下,消融趋势明显。研究可为祁连山水资源合理配置和生态系统保护提供参考。 相似文献
19.
G. S. Xeidakis 《Engineering Geology》1996,44(1-4):93-106
The damage caused to structures and other human endeavours, on or in the ground, by swelling clay soils is considered as a natural hazard. In order to mitigate this hazard an attempt was made to stabilize the swelling clay mineral structure by the addition of Mg(OH)2. This will turn the swelling minerals, like montmorillonite, into non-swelling ones, e.g., chloride. Accordingly, the various factors affecting the precipitation-adsorption of the Mg-hydroxide by clays, was investigated, and the conditions giving the best results were established. The factors examined were: the base used as precipitant (NH4OH and NaOH); the preparation of the precipitate, inside or outside the clay suspension; the sequence and the duration of the reagents addition; the OH/Mg ratio; the time of clay-chemical contact; and the drying time and temperature. The method, was applied to different clay minerals (swelling and non-swelling). The material produced after the Mg-hydroxide precipitation was examined by the methylene blue dye adsorption test, XRD, DTA and DTGA methods; the results were treated statistically by factorial analysis. From the results obtained, it is concluded that the factors affecting the Mg-hydroxide adsorption by clays are: the base used as a precipitant, the preparation of the hydroxide directly inside or outside the clay suspension, the drying temperature, and the rate of titration of the reagents. Therefore, the best conditions for the laboratory preparation of hydroxy-Mg-interlayers are a dilute (1–2%) and well-dispersed clay suspension, pH between 10–12; some 12 meq Mg2+, as Mg-salt (e.g., MgCl2) per gram of clay, added before the base and followed by the dropwise titration of 1–2 N NaOH solution into the clay suspension, to give a molar ratio OH/Mg of about 1.5; vigorous agitation of the suspension during titration of the reagents; centrifugation and decantation of the supernatant liquid, and drying the product at about 250°C. Satisfactory results are also obtained with the fast titration of the base and drying at 105°C to complete dryness. 相似文献
20.
金沙江上游巴塘—中咱河段位于青藏高原东南缘,该河段两岸岸坡发育众多的大型古滑坡,且部分古滑坡曾堵塞金沙江形成了堰塞湖,特米大型古滑坡堰塞湖是其中之一。关于特米古滑坡堰塞湖的形成与演化过程目前尚未见有过详细的报道。本文在野外调查的基础上,结合遥感影像解译和年代学测试,对特米古滑坡堰塞湖的地貌和沉积特征进行了详细研究,并对其形成与演化过程进行了分析。研究结果表明,特米古滑坡堰塞湖很可能是由该地区的古地震活动触发大型滑坡并堵塞金沙江形成的,最大湖面面积约为1.42×107 m2,库容蓄水量约为1.46×109 m3。该古堰塞湖的形成时间约为1.8 ka BP,其溃决消亡的时间约为1.4 ka BP,溃决洪峰流量约为55 858 m3/s,该滑坡堰塞湖持续稳定了约400年的时间。 相似文献