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1.
The following work aims at minimizing the environmental impact of the solid wastes (ash) that is produced after the utilization of the bituminous limestone in thermal power stations and/or retorting processes. The laboratory tests have been selected with respect to construction needs and possible post construction conditions. Utilization of the various types of ash in the production of lightweight concrete block has revealed optimum results. The compressive strength of various ash–glass sand mixes has ranged between 19 and 76 kg/cm2 at 28 days. The compressive strength of ash–tuff mixes has ranged between 54 and 63 kg/cm2 at 28 days. Ultra light mixtures using ash–polyester with a density of 0.88 kg/m3 and a compressive strength of 21 kg/cm2 at 28 days are produced at normal room curing temperature without the use of ordinary Portland cement. The high alkalinity of El-Lajjun ash is considered a disadvantage when utilized in normal concrete mixes for structural purposes. Ash only can be mixed with aggregates to produce lean concrete for blinding purposes for use in foundations.  相似文献   

2.
Clayey subgrade soil requires treatment in order to make the subgrade stable for pavement structures. Treatment of clayey soil i.e. stabilization of clayey soil by cement, lime, and fly ash are established techniques used in geotechnical and highway engineering. Stabilization by alkali activation of fly ash is reported recently but literatures are limited. Present study investigates the stress strain behavior, peak stress and ultimate strain of clayey soil stabilized by slag and slag-fly ash blending by alkali activation. The peak stress as high as 25.0 N/mm2 may be obtained at 50% slags content when 12 molar sodium hydroxide solutions were used. Peak stress, ultimate strain and slope of stress–strain curve of stabilized clay are controlled by Na/Al and Si/Al ratios. Stress–strain response and peak stress of slag and fly ash blended specimen are not governed by Na/Al and Si/Al ratios; rather the behavior is dependent predominantly on slag content.  相似文献   

3.
Limestone–marl alternations are usually directly interpreted to reflect cyclic palaeoenvironmental signals. However, uncertainty in such interpretations stems from the differential diagenesis that most limestone–marl alternations have undergone. Differential diagenesis results in markedly different alterations between limestones and marls and in the loss of comparability of many measurable parameters. For an unequivocal interpretation of the origin of rhythmic alternations, diagenetically robust parameters or parameters that clearly indicate the degree of diagenetic bias are required. The present study uses a multiproxy approach (independent biotic, sedimentary and geochemical parameters) in order to unravel the palaeoenvironmental signal recorded in Valanginian (Early Cretaceous) limestone–marl alternations from the Blake‐Bahama Basin (DSDP site 391). Using this approach, terrestrial and marine influences can be distinguished, changes in nutrient levels estimated and prediagenetic differences in the non‐carbonate fraction constrained. Surprisingly, no systematic variations in any of these parameters were observed between limestone and marl layers, implying that none of these was directly responsible for the formation of the rhythmic alternation. Hence, none of the current models of sedimentary formation of limestone–marl rhythmites is applicable here. Calcareous nannofossils are equally well preserved in limestone and marl layers, ruling out their dissolution in marl layers as a source of the calcite cement in the limestone beds. Sr values of 700–900 p.p.m. indicate that aragonite may have been present in the original, pelagic sediment. The assumption of fine‐grained sedimentary aragonite imported from nearby carbonate platforms as the source of the cement would explain a number of otherwise enigmatic features in these rhythmites, including the source of the calcite cement observed in the limestones, the equally good preservation of calcareous nannofossils in limestones and marls and the higher concentration of calcareous nannofossils in marl layers. The study demonstrates that examination of diagenetically inert parameters or parameters in which diagenetic effects can be filtered can yield unexpected results. Clearly, careful analysis of such parameters needs to be undertaken in order to make reliable palaeoenvironmental interpretations from rhythmite successions.  相似文献   

4.
Chian  S. C.  Bi  J. 《Acta Geotechnica》2021,16(4):1127-1145

In nature, soils are often composed of varying amounts of clay, silt and sand. Variation of the percentage of these compositions can affect the final strength of the soils when stabilised with cement. In this study, focus was placed on clayey soils with different gradation of sand impurities up to 40% in mass. An extensive study of such clayey soils treated with cement was investigated. For the results, it is noted that water:cement ratio was a major influence of strength development of cement-treated clayey soils. In contrast, the soil:cement ratio was found to have minor effects on the strength development. The presence of sand impurities has a significant reduction on the strength development of the cement-treated clayey soil mixture due to more free water available for hydration. The use of free-water:cement ratio is adopted which was shown to be capable of adjusting for such change in amount of free water and water holding capacity of the clay which is determined with Atterberg’s liquid limit tests. The effects of gradation (fine, coarse and well-graded) of the sand impurities were found to affect strength development minimally, owing to similarities in their liquid limits when mixed with clay. Ordinary Portland cement (OPC)-treated clayey soils produced a more rapid gain in strength but lower final strength at 28 days of curing as compared with Portland blast furnace cement (PBFC). This is found to be persistent for different gradation of sand impurities. A linear correlation can be established based on the log of the unconfined compressive strengths developed at different curing age, with slopes of these linear trends found to be similar for PBFC and OPC-treated clayey soil specimens. Finally, a strength prediction model comprising of these findings is developed. The parameters adopted in this model coincide with values proposed by past studies, thereby validating the robustness of the model. The practical benefits from this study offer a quality control scheme to forecast long-term performance of cement-treated clayey soils as well as optimise cement dosage in cement stabilisation to produce a more cost-effective and less environmental-invasive usage of the technology in geotechnical applications.

  相似文献   

5.
三峡移民安置区泥灰质岩岩溶风化灾变性分析   总被引:5,自引:2,他引:3  
张加桂 《中国岩溶》2005,24(3):239-244
三峡移民安置区三叠系巴东组( T2b )泥灰质岩的岩溶风化问题是新近发现的重大工程地质问题。泥灰质岩具有灰岩和泥岩双重特性,在灰质成分遭受溶蚀的同时,泥质成分遭受风化,由此引起岩性的复杂变化,由室内测试得出,深灰色泥质灰岩经岩溶风化后, CaCO3 含量呈降低的趋势, Fe2O3 含量和蒙脱石含量增高,演变为一系列风化岩和残坡积土,包括灰绿色泥灰岩、黄绿色泥灰岩、粉红色钙质泥岩、棕红色钙质泥岩、棕红色泥砾层、黄褐色膨胀土,在深处地下水富集带,泥灰质岩则被溶蚀成为杏黄色泥质条带。随着岩性的变化,岩石的力学强度不断降低、完整性不断弱化,并可能产生普遍的地面不均匀沉降、地裂缝、滑坡、崩塌、泥石流及地面塌陷地质灾害,这些问题必须在移民迁建以及将来城镇运行过程中引起高度重视。   相似文献   

6.
Cementitious materials will be used for the construction of the engineered barrier of the planned repositories for radioactive waste in Switzerland. Superplasticizers (SPs) are commonly used to improve the workability of concretes and, along with a set accelerator (Acc), to produce shotcrete. In this study the influence of a polycarboxylate- (PCE) and a polynaphthalene-sulphonate-based (PNS) SP on the hydration process, mineral composition and the sorption behaviour of metal cations has been investigated using an ordinary Portland cement (OPC), a low-alkali cement mix (LAC) consisting of CEM III-type cement and nanosilica, and a shotcrete-type cement mix (ESDRED) consisting of a CEM I-type cement and silica fume prepared in the presence of an alkali-free set accelerator.Both the PCE and PNS SP do not significantly influence the amount and quantity of hydrates formed during hydration. The concentration of both SPs decreased rapidly in the early stage of the hydration process for all cements due to sorption onto cement phases. After 28 days of hydration and longer, the concentration of the PNS SP in the pore fluids of all cements was generally lower than that of the PCE SP, indicating stronger uptake of the PNS SP. The formate present in the Acc sorbs only weakly onto the cement phases, which led to higher aqueous concentration of organics in the ESDRED cement than in OPC and LAC.Sorption experiments with 63Ni, 152Eu and 228Th on a cation exchange resin indicate that, at concentrations above 0.1 g L−1, the two SPs could reduce sorption of metal cations. Thermodynamic modelling further indicates that radionuclide complexation by formate at the concentration level in Acc can be excluded, suggesting that the apparent effect of Acc in the sorption measurements on the resin can be attributed to colloids formed owing to the high concentrations of Al and S in Acc. Sorption studies with the same radionuclides on hardened cement paste (HCP) in the presence of concrete admixture solutions and pore fluids squeezed from cement pastes further revealed no significant effect on sorption by either the concrete admixtures or their degradation products that were potentially present in the pore fluids. This finding suggests that the investigated concrete admixtures (PNS, PCE, Acc) and their degradation products have no significant impact on radionuclide mobilisation.  相似文献   

7.
The clay assemblages of the Late Jurassic-Early Cretaceous sediments of the Agadir Basin are affected by burial diagenesis. Apparent ages of these formations, from the K-Ar dating of fine grain size fractions (< 2 μm), decrease downward. This indicates an opening of the K-Ar isotopic system of detrital Hercynian minerals during burial. The extent of the isotopic rehomogenisation is more important in sandstones than in clayey marl facies. During burial diagenesis, a temperature of 165°C in clayey marl and 110°C in sandstone can be enough for isotopic rehomogenisation of fine-grained Hercynian illite. The migration of pore water seems to favour the diffusion of radiogenic 40Ar in sandstones.  相似文献   

8.
中国白垩纪大陆科学钻探松科1井南孔连续取青山口组一段岩心81.41m,收获率为100%。青一段沉积时期应与土仑阶对应。通过对松科1井南孔青一段岩心的精细描述,揭示其岩性-岩相-旋回的沉积序列及其过程。青一段识别出6种岩石类型(泥岩、白云岩、泥灰岩、重结晶灰岩、介形虫灰岩和火山灰)。相类型为深湖亚相以及白云岩沉积、泥灰岩沉积、灰岩沉积、深湖浊流沉积、火山灰沉积和深湖静水泥沉积共6种沉积微相。青一段中可识别的米级旋回(六级旋回)有4种类型,可划分出81个米级旋回。这些米级旋回叠加成25个五级旋回、6个四级旋回,识别出1个三级旋回界面。对青山口组一段暗色泥岩、白云岩、火山灰等特殊事件层的精细刻画对于松辽盆地的缺氧事件、烃源岩、湖海沟通事件研究具有重要意义。  相似文献   

9.
灰岩-泥灰岩韵律层的差异成岩作用   总被引:2,自引:0,他引:2  
灰岩-泥灰岩韵律层包括结核状灰岩到灰岩和泥灰岩互层,广泛分布在陆棚及深海环境中,出现于各地质时期,是研究高分辨率地层学和环境恢复的理想工具.但是成岩作用在灰岩-泥灰岩韵律层形成过程中的作用一直存在分歧,有的学者认为差异化学压实成岩作用加强了原始沉积的差异,有的学者认为成岩作用不仅能够强烈歪曲原始环境特征,还可以通过自身...  相似文献   

10.
Major geotechnical problems in construction involving silty–clayey soils are due to their low strength, durability and high compressibility of soft soils, and the swell–shrink nature of the overconsolidated swelling soils. Confronted with these problems, a suitable ground improvement technique is needed, for deep excavations in soft clays, for stability, durability and deformation control. Cement-stabilization is one of the alternatives. An increase in strength and durability, reduction in deformability are the main aims of this method. Conventional cement-stabilization methods are used mainly for surface treatment. However, the use of cement has recently been extended to a greater depth in which cement columns were installed to act as a type of soil reinforcement (deep cement–soil mixing and cement jet grouting). In situ engineering properties of these silty–clayey soils are often variable and difficult to predict. For this reason cement-stabilization methods have a basic target to control the aforementioned engineering properties of these clays so that the properties of a silty–clayey soil become more like the properties of a soft rock such as clayey shale or lightly cemented sandstone. So cement-stabilization of these soils is essential to control their engineering properties and to predict their engineering behaviour for construction. In an effort to predict, classify and study the suitability of silty–clayey soils for cement-stabilization both slaking and unconfined compressive strength tests were carried out on clayey–sand mixtures consisted of two types of clays, kaolin and bentonite. Finally diagrams were prepared to study the variation of slaking and strength due to compaction, curing time and cement percentage and also to predict areas of efficient cement-stabilization.  相似文献   

11.
Groundnut shell ash, cement and their combinations are used as soil stabilizers in various percentages to improve the strength of locally available highly compressible clay soil. The effect of stabilizer in improving the strength of the soil is evaluated through change in consistency limits, compaction characteristics, undrained cohesion and modulus of elasticity. The durability characteristics of stabilised soil were studied based on the improvement of undrained shear strength for various days of curing by increasing the percentage of cement. Stabilised soil showed satisfactory improvement in strength and consistent durability characters. Groundnut shell ash and cement increased the optimum moisture content. There was a slight decrease in the dry density and modulus of elasticity of soil. These can be used as a viable economic alternative in construction of roads and for stabilising soil acting as bearing medium. The use of groundnut shell ash, an agricultural waste, helps in waste management and promotes sustainable development of local construction industry.  相似文献   

12.
西准噶尔洪古勒楞组及泥盆-石炭系界线   总被引:18,自引:3,他引:15  
<正> 新疆西准噶尔和布克赛尔蒙古自治县的沙尔布尔提山一带,上泥盆统发育,其下部称朱鲁木特组,为陆相地层,上部为洪古勒楞组,下石炭统称为黑山头组。洪古勒楞组建于1979年(曾亚参、肖世禄1979,侯鸿飞等1979)。1985年笔者重测洪古勒楞组的命名剖面,发现它可能位于向斜构造上,地层有重复,缺失与石炭系接触的上部地层;此外发现三个泥盆—石炭系的连续剖面。  相似文献   

13.
This work examines the environmental and geochemical impact of recycled aggregate concrete produc-tion with properties representative for structural applications.The environmental influence of cement content,aggregate production,transportation,and waste landfilling is analysed by undertaking a life cycle assessment and considering a life cycle inventory largely specific for the region.To obtain a detailed insight into the optimum life cycle parameters,a sensitivity study is carried out in which supplementary cementitious materials,different values of natural-to-recycled aggregate content ratio and case-specific transportation distances were considered.The results show that carbon emissions were between 323 and 332 kgCO2e per cubic metre of cement only natural aggregate concrete.These values can be reduced by up to 17%by replacing 25%of the cement with fly ash.By contrast,carbon emissions can increase when natural coarse aggregates are replaced by recycled aggregates in proportions of 50%and 100%,and trans-portation is not included in analysis.However,the concrete with 50%recycled aggregate presented lower increase,only 0.3%and 3.4%for normal and high strength concrete,respectively.In some cases,the rel-ative contribution of transportation to the total carbon emissions increased when cement was replaced by fly ash in proportions of 25%,and case-specific transportation distances were considered.In absolute values,the concrete mixes with 100%recycled aggregates and 25%fly ash had lower carbon emissions than concrete with cement and natural aggregates only.Higher environmental benefits can be obtained when the transportation distances of fly ash are relatively short(15-25 km)and the cement replacement by fly ash is equal or higher than 25%,considering that the mechanical properties are adequate for prac-tical application.The observations from this paper show that recycled aggregate concrete with strength characteristics representative for structural members can have lower carbon emissions than conventional concrete,recommending them as an alternative to achieving global sustainability standards in construction.  相似文献   

14.
In order to determine the properties of lean Roller compacted concrete mixture of Filiatrinos Dam, a number of trial mixtures were prepared and a trial section was constructed. The results of the above tests were supplemented with laboratory measurements and in situ tests that were performed during the quality control of the dam construction. Additionally, results of trial mixtures using flysch excavation material from the dam area and limestone aggregates with clay lumps from a nearby quarry were used. This paper examines the impact of the quality of aggregates and the cementitious materials’ content on compressive strength and also the influence of other factors, such as the percentage of compaction. Certain mathematical relations are suggested that can be used in the design phase of hardfill Dams as well as in the quality control during construction. Moreover, the influence of the cement content on the compressive strength and the percentage of the replacement of cement with flying ash are studied.  相似文献   

15.
Clayey soils, especially clayey soils with high or very high liquid limits (> 60%) often present difficulties in construction operations because they usually contain expansive clay minerals. However, the engineering properties of clay soils can be enhanced by the addition of either cement or lime, thereby producing an improved construction material. In this research, slake durability was related to the liquid limit and unconfined compressive strength of clayey admixtures. Three of the most important components in clay soils, namely, kaolinite, montmorillonite and quartz, were combined to make the clayey admixtures. A slaking value of 45% is suggested as identifying satisfactory stabilization. For clayey admixtures with liquid limit between 40% and 60%, this could be achieved with the addition of between 4% and 12% cement. Clayey admixtures with liquid limits over 60% could only achieve this with large uneconomical amounts of cement (> 12%).  相似文献   

16.
This paper studied the use of burned sludge ash as a soil stabilizing agent. The sludge ash was obtained from a public wastewater treatment plant, and it was burned at 550 °C. Different percentages of burned sludge ash were mixed with three different types of clayey soil. A laboratory study consisting of Atterberg’s limits test, unconfined compressive strength test, standard proctor density test, and swelling pressure test were carried out on samples treated with burned sludge at different percentages by dry weight of the clayey soils. The results show that the addition of 7.5 % of the burned sludge ash by the dry weight of the soil will increase the unconfined compressive strength and maximum dry density and also decrease the swelling pressure and the swell potential of the soil. The addition of percentage higher than 7.5 % by dry weight of the soil decreases both the maximum dry density and the unconfined compressive strength; as a result it showed less effectiveness in stabilizing the soil. The conclusion of this research revealed that the burned sludge ash can be used as a promising material for soil stabilization.  相似文献   

17.
This paper describes a study on tropical peat soil stabilization to improve its physical properties by using different stabilizing agents. The samples were collected from six different locations of Sarawak, Malaysia, to evaluate their physical or index properties. Out of them, sample having the highest percentage of organic content has been selected for stabilization purposes. In this study, ordinary portland cement (OPC), quick lime (QL), and class F fly ash (FA) were used as stabilizer. The amount of OPC, QL, and FA added to the peat soil sample, as percentage of dry soil mass, were in the range of 5–20%; 5–20% and 2–8%, respectively for the curing periods of 7, 14, and 28 days. The Unconfined Compressive Strength (UCS) test was carried out on treated/stabilized samples with the above mentioned percentages of the stabilizer and the result shows that the UCS value increases significantly with the increase of all stabilizing agent used and also with curing periods. However, in case of FA and QL, the UCS value increases up to 15 and 6%, respectively with a curing period of 28 days but decreases rather steady beyond this percentage. Some UCS tests have been conducted with a mixture of FA and QL to study the combined effect of the stabilizer. In addition, Scanning Electron Microscope (SEM) study was carried out on original peat soil and FA, as well as some treated samples in order to study their microstructures.  相似文献   

18.
Clay soils, especially clay soils of high or very high swelling potential often present difficulties in construction operations. However, the engineering properties of these clay soils can be enhanced by the addition of cement, thereby producing an improved construction material. Higher strength loss of cement stabilized clay soils after soaking in water is attributed to water absorbing capacity of the clay fraction (e.g. montmorillonite). Kaolinite and illitic soils are largely inert and resist to water penetration. These clays generally develop satisfactory strengths resulting to low strength reduction [Croft, 1967]. The swelling clays such as bentonite soaked in water, due to environmental conditions, result to volume increase causing macro and micro-fracturing in engineering structures. These fractures accelerate water penetration and consequently cause greater strength loss [Sällfors and Öberg-Högsta, 2002]. The water intrusion during soaking creates swelling and disrupts the cement bonds. The development of internal and external force systems in soil mass, due to soaking conditions, establish the initiation of slaking. Internal force system of a stabilized clayey soil consists of the resultant stresses established by the bonding potential of a cementing agent and the swelling potential of a clay fraction. In an effort to study this influence of soaking conditions and final absorbed water content on the stabilization parameters (cement, compaction, curing time), both unconfined compressive strength and slaking (durability) tests were carried out on two different cement stabilized clayey mixtures consisted of active bentonite, kaolin and sand.  相似文献   

19.
贵州石漠化地区棕黄色粘性土团聚体稳定性研究   总被引:2,自引:0,他引:2  
 以贵州省普定县碳酸盐岩石漠化研究试验区(陈旗村)的棕黄色粘性土为研究对象,考虑了初始含水率和浸润时间两个影响因素,对研究区土体中占绝对优势的5mm的大颗粒团聚体进行了共计16组湿筛法试验。结果表明:棕黄色粘性土团聚体遇水破裂的过程主要发生在被浸润初期,初始含水率越小的土壤,经雨水浸润后,大颗粒团聚体破裂得越快越彻底;而原本就比较湿润的土体,团聚体的稳定性则较好。因此,对碳酸盐岩石地区石漠化的防治,应着重考虑气候长期干燥、蒸发量对水土流失的影响。 〖  相似文献   

20.
选取桂林典型石灰土不同发育阶段土样(黑色石灰土、棕色石灰土、黄色石灰土),对土壤中腐殖质组成、土壤钙的形态及其含量进行测定。结果显示:(1)石灰土发育过程中,黑色石灰土、棕色石灰土、黄色石灰土总碳量分别为230.15mg/g、37.49mg/g、17.94mg/g,胡敏酸所占比例分别为31.94%、9.44%、7.25%,富啡酸所占比例为1.04%、36.14%、66.16%,胡敏素为67.02%、54.41%、26.59%;(2)黑色石灰土、棕色石灰土、黄色石灰土中土壤钙全量分别为21486.66mg/kg、6913.33mg/kg、5540.17mg/kg,且三种土壤中均是酸溶态所占比例最高,分别为57.58%、74.69%、80.83%,其次为可还原态、残渣态和可氧化态;(3)相关性分析表明,土壤钙及其各形态均与土壤有机碳总量、胡敏酸、胡敏素成正相关关系,与富啡酸成负相关关系,土壤腐殖质组成及其含量在很大程度上影响着土壤钙含量及赋存形态。   相似文献   

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