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1.
《Atmospheric Research》2007,83(3-4):481-488
Gradient theory (GT), a form of density functional theory (DFT), was applied to water, methanol, and ethanol using the cubic perturbed hard body (CPHB) equation of state (EOS). Compared to the standard form of classical nucleation theory (CNT), the GT results for water showed an improved temperature dependence, but the supersaturation dependence was slightly poorer. GT and several forms of CNT were also found to be in good agreement with a single high T molecular dynamics rate for TIP4P water. The rates predicted by GT for methanol and ethanol were improved by several orders of magnitude compared to CNT, but no improvement in the predicted temperature dependence of the rates was found. 相似文献
2.
《Atmospheric Research》2009,91(2-4):303-312
Nucleation phenomena have a great importance in many areas of science. However, the main theoretical tool to analyse these phenomena, the classical nucleation theory (CNT), has known weaknesses. A decade ago a nucleation theorem based correction to CNT was developed [McGraw, R., Laaksonen, A., 1996. Scaling properties of the critical nucleus in classical and molecular-based theories of vapor–liquid nucleation. Phys. Rev. Lett. 76, 2754–2757]. We have analysed experimental nucleation rate data of two homologous series of molecular fluids in terms of this scaling relation. Our first results suggest possible universal functional form for correction to the temperature dependence of CNT. 相似文献
3.
Jussi Malila Antti-Pekka Hyvrinen Yrj Viisanen Ari Laaksonen 《Atmospheric Research》2008,90(2-4):303-ICNAA07
Nucleation phenomena have a great importance in many areas of science. However, the main theoretical tool to analyse these phenomena, the classical nucleation theory (CNT), has known weaknesses. A decade ago a nucleation theorem based correction to CNT was developed [McGraw, R., Laaksonen, A., 1996. Scaling properties of the critical nucleus in classical and molecular-based theories of vapor–liquid nucleation. Phys. Rev. Lett. 76, 2754–2757]. We have analysed experimental nucleation rate data of two homologous series of molecular fluids in terms of this scaling relation. Our first results suggest possible universal functional form for correction to the temperature dependence of CNT. 相似文献
4.
International regulations are under consideration for methyl bromide because of its high time dependent ozone depletion potential. Geocycling of the species is not well understood, and removal may occur in several types of natural water incuding the oceanic and those in soils. The hydrolysis reaction is a dominant loss pathway in environmental aqueous systems, but rate constants have generally been reported only in distilled water and at greater than room temperature. Here we present measurements in sodium chloride solutions and in seawater in addition to pure water, and at temperatures across the oceanographic range. The reaction could be followed even in solutions near the freezing point because product methanol was monitored in the method of initial rates. Time constants for methyl bromide hydrolysis fall between 10 and 1000 days over the temperatures of the sea, and are always within an order of magnitude of the fastest abiotic destruction mode, chlorination. Activation energies for the two processes are similar so that the ratio of their time scales does not vary with oceanic location. Hydrolysis rate constants are also listed for the closely related compounds methyls iodide and chloride. Solvolysis of the methyl halides in natural waters acts as a source of methanol to the ocean and atmosphere. 相似文献
5.
Sea surface temperature (SST) is a result of multiple interactions in air-sea processes. During days with strong insolation and low wind speed, there may be uneven net heating of the water layer near the surface of the ocean, when there are horizontal temperature gradients at the sea surface. Cooling of the water caused by evaporation, sensible, or longwave radiative, heat loss would be greater from warm water compared to that from relatively cold water. As a result, under low wind speed conditions and clear skies, the horizontal SST discontinuities, occurring at fronts, eddies, or in storm wakes, may diminish or even vanish. This phenomenon is illustrated here with some field and modelling results. The dependence on latitude and mean environmental conditions of the difference in warming on the cold and warm side of SST discontinuities is explored. The time dependence is important for the impact on remote sensing of SST, and it is found to be short enough that substantial masking of SST gradients can occur during the first six hours of the diurnal heating cycle, but the effect would continue to grow if calm and solar heating persist for several subsequent days. An integrated effect of this uneven net heating is seen in the seasonal masking of subsurface temperature gradients in the Gulf of Mexico and Florida Straits. 相似文献
6.
GRAPES-TCM业务试验结果分析 总被引：3，自引：2，他引：3
应用数值模式GRAPES-TCM2.1（GT2.1）的升级版GRAPES-TCM2.6（GT2.6）对2005年西北太平洋及南海热带气旋路径进行了后报试验和性能检验。在检验预报路径时考察了平均距离误差、系统偏差、距离误差的地理分布和平均移速误差,并在总体检验的基础上,根据与热带气旋路径相关的重要因素（路径类型、强度、有无登陆过程以及有无移向或移速突变）进行了分类检验。结果表明,GT2.6表现出良好的预报性能,其对所有样本的24、48和72小时平均距离误差分别为135.8、230.7和336.0km,但前12小时距离误差较大（近100km）。用系统偏差订正GT2.6对转向类样本的预报路径可获得明显的改进。GT2.6对130°E以西区域特别是靠近我国东南沿海的热带气旋路径预报表现较好。GT2.6的总体平均预报移速在48小时内都比最佳路径移速偏快,初始的12小时内偏快最多（近1m·s^-1）,在48小时后转为偏慢。GT2.6和GT2.1的前48小时路径预报性能的稳定性相当,总体误差特征相似,GT2.6对所有样本的48小时预报有显著改进,平均距离误差减小17km。初步分析表明,对GT2.6的改进应主要集中在数值预报初始场的改进方面,比如在初始化过程中采用较准确的涡旋分离方案、加入引导向量改进初始移动以及适当考虑加入非对称Bogus涡旋;扩大预报区域,并适当选取预报区域起始位置等。 相似文献
7.
H. H. Schomberg J. L. Steiner S. R. Evett A. P. Moulin 《Theoretical and Applied Climatology》1996,54(1-2):5-16
Summary The effectiveness of crop residues to protect the soil surface and reduce soil erosion decreases as residues decompose. The rate of residue decomposition is directly related to the temperature and moisture regimes of the residues. Predicting changes in residue mass, orientation, and soil cover requires the use of functions that relate changes in decomposition rates to changes in the temperature and water regimes. Temperature and water functions used in the residue decomposition submodel of the Wind Erosion Prediction System (WEPS) were evaluated for their effects on predictions of residue decomposition. A precipitation function (PC) was found to produce relatively more accurate estimates of decomposition than a near surface soil water content function (SWC) for describing water regime effects. The estimated accuracies of the two functions were similar when bias in the estimation was considered. Predictions made with PC had estimated accuracies of ± 11.4, 14.5, 13.5% for alfalfa, sorghum and wheat, respectively, while those made with SWC had estimated accuracies of ± 13.8, 16.2, and 16.9%, respectively. Three temperature functions were compared for use in predicting residue decomposition over a range of locations and crops. There was little difference between the temperature functions over all the locations but, for several locations, one function overpredicted decomposition more often than the other two functions. Accuracies ranged from ±4 to ±51% of the observed values. The highest values were obtained at one location, and all three temperature functions produced similar high values. Over most of the data, estimated accuracies were generally between ± 15 and ± 25%. The prediction intervals were similar to those observed for decomposition of surface-placed residues. This evaluation indicates that the temperature and water functions used in the WEPS decomposition submodel will give reasonable estimates of mass loss from surface residues using easy-to-obtain weather data.With 8 Figures 相似文献
8.
Mean Profiles of Moisture Fluxes in Snow-Filled Boundary Layers 总被引：1，自引：0，他引：1
Profiles of moisture fluxes have been examined for convective boundary layers containing clouds and snow, using data derived from aircraft measurements taken on four dates during the 1983/1984 University of Chicago lake-effect snow project. Flux profiles were derived from vertical stacks of aircraft cross-wind flight legs taken at various heights over Lake Michigan near the downwind shore. It was found that, if ice processes are taken into account, profiles of potential temperature and water content were very similar to those presented in past studies of convective boundary layers strongly heated from below. Profiles of total water content and equivalent potential temperature adjusted for ice were nearly invariant with height, except very near the top of the boundary layer, suggesting that internal boundary-layer mixing processes were rapid relative to the rates at which heat and vapour were transported into the boundary layer through entrainment and surface fluxes. Ice was found to play a significant, measurable role in boundary-layer moisture fluxes. It was estimated that 40 to 57% of the upward vapour flux was returned to the surface in the form of snow, converting about 45 to 64% of the surface latent heat flux into sensible heat in the snow-producing process. Assuming advective fluxes are relatively small (thought to be appropriate after the first few tens of km over the lake as suggested by past studies), the boundary layer was found to warm at a rate faster than could be explained by surface heat fluxes and latent heat releases alone, the remainder of the heating presumably coming from radiational processes and entrainment. Discussions of moisture phase change processes throughout the boundary layer and estimates of errors of these flux measurements are presented. 相似文献
9.
改进的人工增雨水滴冻结实验装置 总被引：3，自引：0，他引：3
介绍一个改进的水滴冻结实验装置,它由冷腔、冷腔温度控制、水滴冻结信号检测及记录、循环散热和冷环境箱等几部分构成.实验时,将被测水样分散为数十个均匀水滴,分布在涂有硅油的冷板上,温度控制系统使水滴温度线性降低.由于每个水滴中所含冰核引发水滴冻结的温度不同,群滴将会陆续发生冻结.利用水滴冻结释放的潜热和帕尔帖效应,在笔式记录仪上自动地连续给出水滴冻结事件的脉冲信号.对某种水样进行多次的冻结实验得到其水滴冻结温度谱,按Vali给出的方法可以推算该水样中冻结核含量.用该装置曾对北京地区各类降水做过冻滴实验,结果表明不同降水的冻结核浓度的温度谱有明显差异.如能对播云催化作业前后的雨水进行采样并在此装置中进行冻结核浓度的检测,有望为人工影响天气效果的检验提供一个新的物理判据. 相似文献
10.
The development and characteristics of coastal internal boundary layers were investigated in 28 tests. These were made at all seasons and in both gradient and sea-breeze flows but only during mid-day periods. Measurements of turbulence and temperature were taken from a light aircraft which flew traverses across Long Island at successive altitudes parallel to the wind direction. These were used to locate the boundary between modified and unmodified air as a function of height and distance from the coast. The same measurements plus tower measurements of wind, turbulence and temperature, pilot balloon soundings and measurements of land and water surface temperatures by a remote sensing IR thermometer were used to quantify the characteristics of the modified and unmodified air. The boundary layer slope was steep close to the land-water interface and became shallower with downwind distance. Growth of the boundary layer was initially slower with stable lapse rates upwind than with neutral or unstable conditions over the water. An equilibrium height was found in many tests except under conditions of free convection when the internal boundary layer merged into the mixed layer inland and with sea-breeze conditions. The equilibrium height depended on downwind conditions and was greater with low wind speeds and strong land surface heating than with stronger winds and small land-water temperature differences. Current theoretical models are not adequate to predict the height of the boundary layer at the altitudes and distances studied but reasonably good predictions were given by an empirical model developed earlier. Wind speed in the modified air averaged about 70% of that at the coast but turbulence levels were several times higher both near the surface and aloft. These findings have important implications for diffusion from coastal sites. 相似文献
11.
The development and characteristics of coastal internal boundary layers were investigated in 28 tests. These were made at all seasons and in both gradient and sea-breeze flows but only during mid-day periods. Measurements of turbulence and temperature were taken from a light aircraft which flew traverses across Long Island at successive altitudes parallel to the wind direction. These were used to locate the boundary between modified and unmodified air as a function of height and distance from the coast. The same measurements plus tower measurements of wind, turbulence and temperature, pilot balloon soundings and measurements of land and water surface temperatures by a remote sensing IR thermometer were used to quantify the characteristics of the modified and unmodified air. The boundary layer slope was steep close to the land-water interface and became shallower with downwind distance. Growth of the boundary layer was initially slower with stable lapse rates upwind than with neutral or unstable conditions over the water. An equilibrium height was found in many tests except under conditions of free convection when the internal boundary layer merged into the mixed layer inland and with sea-breeze conditions. The equilibrium height depended on downwind conditions and was greater with low wind speeds and strong land surface heating than with stronger winds and small land-water temperature differences. Current theoretical models are not adequate to predict the height of the boundary layer at the altitudes and distances studied but reasonably good predictions were given by an empirical model developed earlier. Wind speed in the modified air averaged about 70% of that at the coast but turbulence levels were several times higher both near the surface and aloft. These findings have important implications for diffusion from coastal sites. 相似文献
12.
Sanderine Nonhebel 《Climatic change》1993,24(4):311-329
A crop growth simulation model based on SUCROS87 was constructed to study the effects of temperature rise and increase of the atmospheric CO2 concentration on spring wheat yields in The Netherlands. The model simulated potential production (limited by crop characteristics, temperature and radiation but without any stress from water or nutrient shortages or pests, diseases and weeds) and water-limited production in which growth is also limited by water shortage. The model was validated for the present climatic conditions. When daily weather data from a nearby station were used, the model was well able to simulate yields obtained in field experiments.Effects of several combinations of temperature rise and atmospheric CO2 concentration on simulated yields were studied. A temperature rise resulted in a reduction in simulated yield due to shortening of the growing period. Large variations existed in the magnitude of this reduction. Increases in atmospheric CO2 concentration led to yield increases due to higher assimilation rates and to increase of the water use efficiency. Combination of temperature rise and higher CO2 concentration resulted in small yield increases in years in which water was not limiting growth and large yield increases in dry years.Change of variety or of sowing date could not reduce the negative effects of temperature rise on simulated yields. 相似文献
13.
It is found that the surface bog temperature and bog water level position are major factors that determine CO2 emission from the bog massif. The emission intensity increases with increasing temperature and with a bog water level decrease. The dependence of CO2 emission is shown to be different for each bog microlandscape. Monthly mean CO2 emissions are given for the central bog massif in the years with different water content. Based on modeling, it is shown that in the case of a low bog water level the CO2 flux is directed to the atmosphere (the emission value exceeds the gas amount consumed for photosynthesis), while in the case of a high level, it is taken up by the growing plants. 相似文献
14.
应用ATOVS资料反演大气温湿廓线 总被引：3，自引：2，他引：3
本文用牛顿迭代的方法反演NOAA-15极轨气象卫星ATOVS资料，求解大气温度廓线和水汽廓线，本文利用一阶变分原理从辐射传输方程中得到了大气温度、水汽权重函数的解析形式，并改进了传统使用的线性迭代方法，利用牛顿非线性迭代方法求解大气表层温度，大气温度廓线及大气水汽廓线，并根据大气参量的自相关性，将大气温度廓线、大气水汽廓线用经验正交函数（EOF）的线性组合表示，减少了要反演的参数，提高了反演稳定性和迭代速度。 相似文献
15.
The atmospheric katabatic flow in the foothills of the Front Range of the Rocky Mountains has been monitored by a network of towers and sodars for several years as part of the Atmospheric Studies in COmplex Terrain (ASCOT) program. We used three years of data from the network to explore the dependence on surface cooling and channeling by winds above the canyon of (1) profiles of the mean and variance of the vertical (perpendicular to the geopotential) component of motion and (2) the mean component of the wind perpendicular to the local terrain of Coal Creek Canyon. Previously we found that the magnitude of the near-surface temperature difference decreases with increasing surface cooling in light winds, apparently because of increasing turbulence caused when increasing drainage winds interact with surface topography. The variance of vertical velocity exhibits three types of vertical profiles, corresponding to different cooling rates and external wind speeds. The mean variance was found to depend strongly on a locally derived Richardson number. 相似文献
16.
通过LI-COR8100A土壤碳通量观测系统分别于2013年1月、5月、10月和11月进行了塔克拉玛干沙漠腹地塔中流沙下垫面土壤呼吸速率测定试验,并分析了相应的土壤水热因子对呼吸速率的影响。结果表明:塔克拉玛干沙漠腹地土壤呼吸速率整体偏低,但具有明显的昼夜波动性和季节变化特征。研究区流沙土壤中可能存在的无机碳过程是导致夜间及凌晨的土壤呼吸速率为负值,白天为正值的主要原因。不同时段的土壤呼吸速率(Rs)分别与土壤表层0~5 cm平均土壤温度(T)和湿度(W)间存在较为同步的昼夜变化趋势且具有良好的回归关系。相对于单因素影响的回归分析,土壤温、湿度的协同作用能够从整体角度更好地解释土壤呼吸速率的变化情况。回归方程Rs=a+bT+cW和Rs=a+bT+cW+dTW可解释不同时段土壤呼吸速率76.0%以上的变化情况。这说明土壤温、湿度是控制土壤呼吸速率的主要环境因子。沙漠腹地土壤极低的水分条件成为土壤呼吸的限制性因子,呼吸速率对于作为限制性因子的土壤湿度的变化响应则更加直接,而对于土壤温度变化的敏感性就有所下降,导致土壤呼吸速率与土壤温度回归关系出现明显的时滞环现象。 相似文献
17.
Arthur Charpentier 《Climatic change》2011,109(3-4):245-260
Extremal events are difficult to model since it is difficult to characterize formally those events. The 2003 heat wave in Europe was not characterized by very high temperatures, but mainly the fact that night temperature were no cool enough for a long period of time. Hence, simulation of several models (either with heavy tailed noise or long range dependence) yield different estimations for the return period of that extremal event. 相似文献
18.
Boundedness of Turbulent Temperature Probability Distributions,and their Relation to the Vertical Profile in the Convective Boundary Layer 总被引：3，自引：3，他引：0
Alexander Graf Dirk Schüttemeyer Heiner Geiß Axel Knaps Michael Möllmann-Coers Jan H. Schween Stefan Kollet Bruno Neininger Michael Herbst Harry Vereecken 《Boundary-Layer Meteorology》2010,134(3):459-486
Higher-order moments, minima and maxima of turbulent temperature and water vapour mixing ratio probability density functions
measured with an eddy-covariance system near the ground were related to each other and to vertical boundary-layer profiles
of the same scalars obtained through airborne soundings. The dependence of kurtosis on squared skewness showed a kurtosis
intercept below the Gaussian expectation, suggesting a compression of the probability density function by the presence of
natural boundaries. This hypothesis was corroborated by comparing actual minima and maxima of turbulent fluctuations to estimates
obtained from the first four sample moments by fitting a four-parameter beta distribution. The most sharply defined boundaries
were found for the minima of temperature datasets during the day, indicating that negative temperature fluctuations at the
sensor are limited by the availability of lower temperatures in the boundary layer. By comparison to vertical profiles, it
could be verified that the turbulent minimum of temperature near the ground is close to the minimum of potential temperature
in the boundary layer. The turbulent minimum of water vapour mixing ratio was found to be equal to the mixing ratio at a height
above the minimum of the temperature profile. This height roughly agrees with the top of the non-local unstable domain according
to bulk Richardson number profiles. We conclude that turbulence statistics measured near the surface cannot be solely explained
by local effects, but contain information about the whole boundary layer including the entrainment zone. 相似文献
19.
应用通量方差法估算戈壁绿洲下垫面湍流通量的研究 总被引：3，自引：0，他引：3
利用“绿洲系统能量与水分循环过程观测试验” 2005年绿洲、戈壁点的观测资料, 分析与讨论了温度、水汽的归一化标准差随稳定度变化的通量方差关系, 应用通量方差法对感热、 潜热通量进行了计算, 并同涡动相关系统的观测结果进行了比较。不稳定条件下, 戈壁点温度归一化标准差随稳定度变化的通量方差关系优于下垫面非均匀性更强的绿洲点, 绿洲点水汽的归一化标准差随稳定度变化的通量方差关系较温度量表现得更好。对同一站点, 归一化温度标准差的通量方差关系并不总是优于水汽的通量方差关系, 其取决于该站点的温度以及水汽的源汇分布情况; 通量方差法对两个站点的感热、 潜热通量均有较好的再现, 但戈壁点感热通量的计算效果优于非均匀性更强的绿洲点。应用通量方差法对潜热通量计算时若采用直接观测的感热通量, 则潜热通量的计算效果具有一定程度的改善。 相似文献
20.
H. Soegaard B. Hasholt T. Friborg C. Nordstroem 《Theoretical and Applied Climatology》2001,70(1-4):35-51
Summary Within the framework of the European LAPP-project (Land Arctic Physical Processes) and as part of the Danish Research Council’s
Polar Programme, studies on water- and surface energy balance in NE Greenland were conducted in 1996 and 1997. Eddy correlation
measurements of water vapour and sensible heat fluxes above the three dominant vegetation types: fen, willow snowbed, and
heath were conducted for the entire growing season. This was supplemented by measurements of evaporation from snow covered
areas and from a small pond. The evapotranspiration was found to be relatively high with the maximum from the fen (≈86 mm
per season). For the two other vegetation types the evapotranspiration was less, for heath 61 mm per season, while willow
snowbed had evaporation rates on intermediate level. By use of the Penman-Monteith equation it was possible to estimate the
altitude dependence of the evapotranspiration and calculate the annual evaporation for the whole area to 80 mm per year. By
applying a bucket model the evaporation was found to be in accordance with changes in soil moisture as monitored with TDR.
The observed surface water balance was compared to river discharge, which shows a glacio-nival regime with an early spring
flow (June), determined by the snow melt in the main valley and an July–August maximum determined by melt on higher plateau
areas. When balancing the individual hydrological components an annual deficit of 180 mm was observed, but it was found that
this deficit could be reduced by correcting for aerodynamic and altitude effects on the precipitation. Finally some of the
possible consequences of a global warming is discussed in relation to the water and energy balance in the high-arctic ecosystem.
Received November 1, 1999 Revised May 15, 2000 相似文献