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1.
Assemblages of evaporite minerals record detailed physical and chemical characteristics of ancient surficial environments. Accordingly, newly discovered regions of saline minerals on Mars are high priority targets for exploration. The chemical divide concept of evaporite mineral formation is used successfully to predict evaporite mineralogy and brine evolution on Earth. However, basaltic weathering largely controls fluid compositions on Mars and the robust predictive capabilities of terrestrial chemical divides cannot be used to interpret Martian evaporites. Here we present a new chemical divide system that predicts evaporite assemblages identified in SNC-type meteorites, ancient evaporites discovered on Meridiani Planum by the Opportunity rover, and Mars Express OMEGA data. We suggest that a common fluid type that has been buffered to different pH levels by basaltic weathering controls the variability among Martian evaporite assemblages and that evaporite mineralogy and brine evolution is essentially established by the initial composition of the dilute evaporating fluid.  相似文献   

2.
During the warm seasons of 1998–2004, the naturally-acidic (pH2.2) Lake Caviahue was sampled for conductivity, temperature, oxygen, light, nutrients, and phytoplankton (density, biomass and chlorophyll a) with a view to studying the summer phytoplankton population changes with relation to environmental factors, as well as the significance of nitrogen limitation on the phytoplankton yield. Lake Caviahue is characterized by its low transparency, CO2, and N concentration; significant P values; a distinctive vertical distribution of phytoplankton biomass with high values along the water column; and sometimes maximum meta-hypolimnion values. Biodiversity is very low as a result of extreme environmental conditions, Chlorophyceae being the prevailing algae group. Two types of bioassays were carried out to assess nitrogen limitation. For the first bioassay, a solution of ammonium–nitrogen chloride and/or wastewater (rich in ammonium and phosphorus) was used, while one of the lake's sediments was the source of nutrients for the second bioassay. Contrary to the case of acidic mining lakes, N-ammonium proved to be a significant supportive capacity limiting factor as to phytoplankton yield. The present paper provides for the first time information on phytoplankton nitrogen limitation in a naturally-acidic lake.  相似文献   

3.
The harmonic relationship between the diurnal and semidiurnal tides gives rise to an elementary mathematical relationship that has intriguing consequences for secondary waves produced by non-linear interactions between the diurnal tide and planetary waves. A speculative theory is developed which predicts that, under certain conditions, these secondary waves can be amplified by non-linear interaction with the semidiurnal tide. A peculiar feature of dynamics in the MLT region above Bulgaria is the presence of strong oscillations with periods near 20 and 30 h, especially in the zonal wind component. Observational evidence from a meteor radar at Yambol, Bulgaria suggests that the 20- and 30-h signals are produced as the result of non-linear interactions of the type proposed by the novel theory.  相似文献   

4.
Samples of a new Martian meteorite of the nakhlite family (NWA 817) contain traces of an iron-rich alteration product. Textural arguments indicate that this alteration product has been formed on the parent body of the meteorite (Mars). The chemical composition and structural data (X-ray diffraction, transmission electron microscopy and vibrational spectroscopy) show that the alteration mineral is a hydrous phase from the smectite family. Major elements and rare earth elements suggest that the formation of the alteration phase is related to the circulation of an aqueous fluid which composition is controlled by the dissolution of feldspars to account for a positive Eu anomaly, olivine and possibly apatite. Hydrogen isotope data display negative δD values ranging from −60 to −280‰ in olivine and pyroxenes and from −140 to −181‰ in the alteration phase. The values of δD for the alteration product show a small scatter with a mean value of −170±14‰. These values are lower than those previously obtained on other Martian meteorites, which give mainly positive δD values. These positive values have been interpreted as resulting from the interaction of the Martian meteorites with water from the Martian atmosphere. Ruling out the effect of terrestrial alteration, it is suggested that alteration in the NWA 817 meteorite was likely produced on Mars by the circulation of an aqueous fluid originating from a chemical reservoir, such as the Martian mantle, which has not equilibrated with a fractionated Martian atmosphere.  相似文献   

5.
Dark aeolian deposits on Mars are thought to consist of volcanic materials due to their mineral assemblages, which are common to basalts. However, the sediment source is still debated. Basaltic dunes on Earth are promising analogs for providing further insights into the assumed basaltic sand dunes on Mars. In our study we characterize basaltic dunes from the Ka'u Desert in Hawaii using optical microscopes, electron microprobe, and spectral analyses. We compare the spectra of terrestrial and Martian dune sands to determine possible origins of the Martian dark sediments. Our results show that the terrestrial sands consist primarily of medium to coarse sand‐sized volcanic glass and rock fragments as well as olivine, pyroxene, and plagioclase minerals. Grain shapes range from angular to subrounded. The sample composition indicates that the material was derived from phreatomagmatic eruptions partially with additional proportions of rock fragments from local lava flows. Grain shape and size indicate the materials were transported by aeolian processes rather than by fluvial processes. Spectral analyses reveal an initial hydration of all terrestrial samples. A spectral mineralogical correlation between the terrestrial and Martian aeolian sands shows a similarity consistent with an origin from volcanic ash and lava. We suggest that the Martian deposits may contain similar abundances of volcanic glass, which has not yet been distinguished in Martian spectral data. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

6.
The characteristics of rock varnish from the Campo de Piedra Pomez (CPP, Andes Argentina) provides new insights into the development of rock varnish under severe dusty conditions. The CPP varnish has been analysed using SEM‐EDAX and Raman techniques. The rock coating is tens of microns in thickness and under the microscope shows a micro to cryptocrystalline appearance and a general granular texture. Silica (quartz, cristobalite and amorphous silica) is the main phase forming these coverings followed by Al, K and Na compounds. Minor Fe oxides and Mn oxides are the source for the orange (Fe) and brown (Fe and Mn) hues of the coating. The results obtained for the CPP coating show that desert varnish developed under dusty circumstances does not have the appearance of typical rock varnish. Textural characteristics include high crystallinity and granular arrangement of the components. Moreover the absence of typical microlaminations is related to the presence of aeolian mineral grains which inhibit their development. The main mechanism of formation of rock varnish under such environmental circumstances is the direct incorporation of aeolian mineral grains into the varnish. However, other physicochemical processes are also required to explain the formation of varnish components such as amorphous silica or iron oxides phases. Although the development of the desert varnish may act as a protector of the underlying pyroclastic rock, the extreme and persistent windy conditions in the CPP field are high enough to weather and erode not only the rock coating but also the original ignimbrite. As other warm desert sites on Earth, the CPP area can also be considered as possible terrestrial analogue to Mars. Some environmental attributes might be similar to those expected on the Martian surface and thus, textural similarities between the CPP varnish and the rock varnish‐like coating of Mars are likely. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

7.
粤东五华河流域的化学风化与CO2吸收   总被引：1，自引：1，他引：0  
基于对粤东五华河干流和支流水体的物理、化学组成测试数据,应用质量平衡法和相关分析法探讨湿热山地丘陵地区岩石化学风化过程对大气CO2的吸收.结果表明:五华河水体的总溶解性固体含量(77.11 mg/L)接近于世界河流的平均值(65 mg/L);离子组成以Ca2+、Na+和HCO3-为主,可溶性Si次之.五华河流域化学径流组成主要源自硅酸盐矿物化学风化过程的贡献,碳酸盐矿物的贡献较少;大气和土壤CO2是流域内岩石化学风化的主要侵蚀介质.与同一气候带其他河流相比较,五华河流域岩石化学风化过程对大气CO2的吸收通量(2.14×105mol/(km2·a))较低,这主要是由于流域内缺乏碳酸盐岩所导致.  相似文献   

8.
The nutations of the planets Mars andEarth are investigated and compared. Alarge number of interior structureparameters are involved in the nutationcomputations. The comparison between the observations and the computationsprovides several constraints on these parmeters andtherefore allows a better understanding of the physics of the interior of theplanet. For the Earth, the high precision of the observations of the nutationshas led to a very good determination of interior properties of the planet. ForMars, observations of nutations are not yet available, and we review how theamplitude of the Martian nutations depends on the hypotheses consideredfor its interior. Although Mars is very similar to the Earth, its interior is not well known;for example, we don't knowif its core is liquid or solid. Only if the core is liquid,the Free Core Nutation (FCN) normal mode exists and can alter the nutationswhich are close to the resonance. From the observed geoids, it is known thatboth planets are not in hydrostatic equilibrium. The departure is larger forMars than for the Earth, and consequently, the implication of considering a convective mantle instead of a mantle in hydrostatic equilibrium described byClairaut's equation for the initial equilibrium state of the planet is largeron the Martian nutations than on the Earth nutations. The consequences of theuncertainty in the core dimensions are also examined and shown to be of a veryhigh influence for Mars if the core is liquid, due to the potential changes inthe FCN resonance. The influence of the presence of an inner core, which isknown to exist for the Earth, could be more important for Mars than for theEarth if the inner core is large. Due to the presence of Tharsis on Mars, thetriaxiality of this planet has, additionally, larger effects than on Earth.  相似文献   

9.
Impure reworked evaporitic sandstones, preserved on Meridiani Planum, Mars, are mixtures of roughly equal amounts of altered siliciclastic debris, of basaltic provenance (40 ± 10% by mass), and chemical constituents, dominated by evaporitic minerals (jarosite, Mg-, Ca-sulfates ± chlorides ± Fe-, Na-sulfates), hematite and possibly secondary silica (60 ± 10%). These chemical constituents and their relative abundances are not an equilibrium evaporite assemblage and to a substantial degree have been reworked by aeolian and subaqueous transport. Ultimately they formed by evaporation of acidic waters derived from interaction with olivine-bearing basalts and subsequent diagenetic alteration. The rocks experienced an extended diagenetic history, with at least two and up to four distinct episodes of cementation, including stratigraphically restricted zones of recrystallization and secondary porosity, non-randomly distributed, highly spherical millimeter-scale hematitic concretions, millimeter-scale crystal molds, interpreted to have resulted from dissolution of a highly soluble evaporite mineral, elongate to sheet-like vugs and evidence for minor synsedimentary deformation (convolute and contorted bedding, possible teepee structures or salt ridge features). Other features that may be diagenetic, but more likely are associated with relatively recent meteorite impact, are meter-scale fracture patterns, veins and polygonal fractures on rock surfaces that cut across bedding. Crystallization of minerals that originally filled the molds, early cement and sediment deformation occurred syndepositionally or during early diagenesis. All other diagenetic features are consistent with formation during later diagenesis in the phreatic (fluid saturated) zone or capillary fringe of a groundwater table under near isotropic hydrological conditions such as those expected during periodic groundwater recharge. Textural evidence suggests that rapidly formed hematitic concretions post-date the primary mineral now represented by crystal molds and early pore-filling cements but pre-date secondary moldic and vug porosity. The second generation of cements followed formation of secondary porosity. This paragenetic sequence is consistent with an extended history of syndepositional through post-depositional diagenesis in the presence of a slowly fluctuating, chemically evolving, but persistently high ionic strength groundwater system.  相似文献   

10.
Alpine/subalpine basins may exhibit substantial variability in solute fluxes despite many apparent similarities in basin characteristics. An evaluation of controls on spatial patterns in solute fluxes may allow development of predictive tools for assessing basin sensitivity to outside perturbations such as climate change or deposition of atmospheric pollutants. Relationships between basin physical characteristics, determined from geographical information system (GIS) tools, and solute fluxes and mineral weathering rates were explored for nine alpine/subalpine basins in Rocky Mountain National Park, Colorado, using correlation analyses for 1993 and 1994 data. Stream‐water nitrate fluxes were correlated positively with basin characteristics associated with the talus environment; i.e., the fractional amounts of steep slopes (≥ 30°), unvegetated terrain and young debris (primarily Holocene till) in the basins, and were correlated negatively with fractional amounts of subalpine meadow terrain. Correlations with nitrate indicate the importance of the talus environment in promoting nitrate flux and the mitigating effect of areas with established vegetation, such as subalpine meadows. Total mineral weathering rates for the basins ranged from about 300 to 600 mol ha?1 year?1. Oligoclase weathering accounted for 30 to 73% of the total mineral weathering flux, and was positively correlated with the amount of old debris (primarily Pleistocene glacial till) in the basins. Although calcite is found in trace amounts in bedrock, calcite weathering accounted for up to 44% of the total mineral weathering flux. Calcite was strongly correlated with steep slope, unvegetated terrain, and young debris—probably because physical weathering in steep‐gradient areas exposes fresh mineral surfaces that contain calcite for chemical weathering. Oligoclase and calcite weathering are the dominant sources of alkalinity in the basins. However, atmospherically deposited acids consume much of the alkalinity generated by weathering of calcite and other minerals in the talus environment. Published in 2001 by John Wiley & Sons, Ltd.  相似文献   

11.
We report new Sm-Nd, Lu-Hf, and Pb-Pb mineral and whole-rock isotope data for the basaltic shergottite Zagami, as well as Pb-Pb whole-rock isotope data for the basaltic shergottite Los Angeles, the lherzolitic shergottite Dar-al-Gani 476 (DaG 476), and the clinopyroxenite Nakhla. In agreement with previous findings, our new Sm-Nd and Lu-Hf mineral ages on the Martian meteorite Zagami are young (155 and 185 Ma, respectively). The 207Pb/206Pb-204Pb/206Pb compositions of the insoluble fractions of shergottites (Zagami, Los Angeles, and literature data for Shergotty and EETA79001) form an excellent alignment indicative of a 4.0 Ga crystallization age. The range of Pb isotope compositions observed in the leachates of these samples attests to negligible contamination of the shergottites by terrestrial Pb and argues against mixing relationships. The age of 4.048 ± 0.017 Ga (MSWD = 1.5) provided by the Pb isotope compositions of the Zagami whole-rock and residues is therefore taken to date the crystallization of this rock, which, so far, was believed to be only ∼ 180 Ma old. Based on this result, we argue that the lithosphere of Mars is extremely old and that most mineral ages were reset recently by acidic aqueous solutions percolating through the Martian surface. This interpretation is consistent with photographic interpretations of erosional features on Mars. It also relieves the constraint imposed by the presence of anomalies of 142Nd and 182W (both products of extinct radioactive nuclides) that the Martian mantle should have preserved primordial isotopic heterogeneities, thus allowing for the planet interior to be actively convecting.  相似文献   

12.
火星环境探测结果分析   总被引：6，自引：0，他引：6  
本文对空间飞行器所观测取得的火星环境的资料进行了分析研究，并对有关火星磁层和电离层及其与太阳风机相互作用的研究结果进行了概述。  相似文献   

13.
A hydrochemical budget is used to quantify the rate of chemical weathering and solutional denudation on Old Red Sandstone in East Twin drainage basin (0.2 km2) on the Mendip Hills for the 1972–73 Water Year. Net nutrient uptake by the biomass and precipitation inputs are subtracted from stream solute outputs to give an estimate of the solutes released to the system by weathering. The mineralogies of the sandstone and the soil are compared to predict possible weathering reactions for the primary and secondary minerals. Tentative estimates of primary mineral alteration and secondary mineral formation are then made by substituting the hydrochemical balances into the formulated weathering reactions. Finally the rate of solutional denudation (0.8 tonnes/a or 1.6 mm/100 a) is compared with other estimates of solutional and mechanical denudation at East Twin and with similarly derived results for other lithologies.  相似文献   

14.
Iron-rich spherules (> 90% Fe2O3 from electron microprobe analyses) ∼10-100 μm in diameter are found within sulfate-rich rocks formed by aqueous, acid-sulfate alteration of basaltic tephra on Mauna Kea volcano, Hawaii. Although some spherules are nearly pure Fe, most have two concentric compositional zones, with the core having a higher Fe / Al ratio than the rim. Oxide totals less than 100% (93-99%) suggest structural H2O and/or OH− 1. The transmission Mössbauer spectrum of a spherule-rich separate is dominated by a hematite (α-Fe2O3) sextet whose peaks are skewed toward zero velocity. Skewing is consistent with Al3+ for Fe3+ substitution and structural H2O and/or OH− 1. The grey color of the spherules implies specular hematite. Whole-rock powder X-ray diffraction spectra are dominated by peaks from smectite and the hydroxy sulfate mineral natroalunite as alteration products and plagioclase feldspar that was present in the precursor basaltic tephra. Whether spherule formation proceeded directly from basaltic material in one event (dissolution of basaltic material and precipitation of hematite spherules) or whether spherule formation required more than one event (formation of Fe-bearing sulfate rock and subsequent hydrolysis to hematite) is not currently constrained. By analogy, a formation pathway for the hematite spherules in sulfate-rich outcrops at Meridiani Planum on Mars (the Burns formation) is aqueous alteration of basaltic precursor material under acid-sulfate conditions. Although hydrothermal conditions are present on Mauna Kea, such conditions may not be required for spherule formation on Mars if the time interval for hydrolysis at lower temperatures is sufficiently long.  相似文献   

15.
This study presents uranium and thorium concentrations and activity ratios for all riverine phases (bedload, suspended load, dissolved load and colloids) from basaltic terrains in Iceland and the Azores. Small basaltic islands, such as these, are thought to account for ~ 25% of CO2 consumed by global silicate weathering, and for ~ 45% of the flux of suspended material to the oceans. These data indicate that [U] and [Th] in the dissolved and colloidal fractions are strongly controlled by pH, and to a much lesser extent by levels of dissolved organic carbon (which are low in these environments). At high pH, basalt glass dissolution is enhanced, and secondary mineral formation (e.g. Fe-oxyhydroxides and allophane) is suppressed, resulting in high dissolved [U], and low colloidal [U] and [Th], indicating a direct chemical weathering control on elemental abundances. When the dissolved (234U/238U) activity ratio is >~1.3 (i.e. when physical weathering, groundwater contribution or soil formation are high), there is little isotope exchange between dissolved and colloidal fractions. At lower activity ratios, the dissolved load and colloids have indistinguishable activity ratios, suggesting that when chemical weathering rates are high, secondary clay formation is also high, and colloids rapidly adsorb dissolved U. Many of the suspended sediment samples have (234U/238U) activity ratios of > 1, which suggests that uptake of U onto the suspended load is important. Identical (230Th/232Th) in suspended, dissolved and colloidal samples suggests that Th, like U, is exchanged or sorbed rapidly between all riverine phases. This particle-reactivity, combined with poorly constrained contributions from groundwater and hydrothermal water, and short-term variations in input to soils (volcanic and glacial), suggests that U-series nuclides in riverine material from such basaltic terrains are unlikely to reflect steady state erosion processes.  相似文献   

16.
Results from long term microerosion meter (MEM) studies indicate that microenvironments are characterized by different erosion rates. A complementary study, carried out on the same sites, examines the microscale morphology in each environment. Optical and scanning electron microscopy were used to identify a range of features thought to reflect different processes. Under subaerial conditions micromorphology is dominated by biological weathering features owing to the presence of microflora. Sites permanently covered by soil or stream water have only dissolution etch features, though stream sites may exhibit microfractures. Sites with periodic exposure exhibit both dissolution and biological etch features. The natural environment is more accurately reflected by allowing some microflora colonization of MEM sites rather than preventing colonization by artificial means.  相似文献   

17.
Bimodal volcanism, normal faulting, rapid sedimentation, and hydrothermal circulation characterize the rifting of the Izu-Bonin arc at 31°N. Analysis of the zigzag pattern, in plan view, of the normal faults that bound Sumisu Rift indicates that the extension direction (080° ± 10°) is orthogonal to the regional trend of the volcanic front. Normal faults divide the rift into an inner rift on the arc side, which is the locus for maximum subsidence and sedimentation, and an outer rift further west. Transfer zones that link opposing master faults and/or rift flank uplifts further subdivide the rift into three segments along strike. Volcanism is concentrated along the ENE-trending transfer zone which separates the northern and central rift segments. The differential motion across the zone is accommodated by interdigitating north-trending normal faults rather than by ENE-trending oblique-slip faults. Volcanism in the outer rift has built 50–700 m high edifices without summit craters whereas in the inner rift it has formed two multi-vent en echelon ridges (the largest is 600 m high and 16 km long). The volcanism is dominantly basaltic, with compositions reflecting mantle sources little influenced by arc components. An elongate rhyolite dome and low-temperature hydrothermal deposits occur at the en echelon step in the larger ridge, which is located at the intersection of the transfer zone with the inner rift. The chimneys, veins, and crusts are composed of silica, barite and iron oxide, and are of similar composition to the ferruginous chert that mantles the Kuroko deposits. A 1.2-km transect of seven alvin heat flow measurements at 30°48.5′N showed that the inner-rift-bounding faults may serve as water recharge zones, but that they are not necessarily areas of focussed hydrothermal outflow, which instead occurs through the thick basin sediments. The rift basin and arc margin sediments are probably dominated by permeable rhyolitic pumice and ash erupted from submarine arc calderas such as Sumisu and South Sumisu volcanoes.  相似文献   

18.
Distribution, abundance and life history characteristics of Mysis relicta were studied in the Feldberg Lake District (Lake Breiter Luzin, Lake Schmaler Luzin, Lake Zansen) located in northeastern Germany. Between July 2001 and November 2002 mysids were collected by vertical net hauls. In order to determine the impact of the current trophic conditions on the distribution of mysids in these lakes, oxygen concentration, total phosphorus, chlorophyll a and water transparency were also measured. All investigated lakes are mesotrophic at present. Lake Breiter Luzin exhibited great seasonal and spatial variations in mysid abundance. Density of adults and juveniles had a mean of 44.9 ± 57.1 and 68.7 ± 99.6 m−2, respectively. Highest abundance of adults was 110.4 ± 76.5 m−2 in summer, lowest abundances of 2.0 ± 4.0 m−2 occurred in spring. For juveniles, highest density of 218.4 ± 174.6 m−2 was detected in summer and lowest of 0.8 ± 1.8 m−2 in winter. No mysids were caught in any of the daytime hauls, but they were widely distributed throughout the water column at night. Size frequency distribution of mysids suggested that reproduction occurred year-round, the most consistent influx of juveniles occurred in early summer and a smaller second cohort in autumn. Highest mysid abundance was 189.2 ± 318.6 adults and 127.0 ± 66.3 juveniles m−2 in Lake Schmaler Luzin, and 59.6 ± 5.6 adults and 79.4 ± 11.2 juveniles m−2 in Lake Zansen. There were great spatial differences in abundance in both lakes.  相似文献   

19.
Mineral weathering rates and a forest macronutrient uptake stoichiometry were determined for the forested, metabasaltic Hauver Branch watershed in north‐central Maryland, USA. Previous studies of Hauver Branch have had an insufficient number of analytes to permit determination of rates of all the minerals involved in chemical weathering, including biomass. More equations in the mass‐balance matrix were added using existing mineralogic information. The stoichiometry of a deciduous biomass term was determined using multi‐year weekly to biweekly stream‐water chemistry for a nearby watershed, which drains relatively unreactive quartzite bedrock. At Hauver Branch, calcite hosts ~38 mol% of the calcium ion (Ca2+) contained in weathering minerals, but its weathering provides ~90% of the stream water Ca2+. This occurs in a landscape with a regolith residence time of more than several Ka (kiloannum). Previous studies indicate that such old regolith does not typically contain dissolving calcite that affects stream Ca2+/Na+ ratios. The relatively high calcite dissolution rate likely reflects dissolution of calcite in fractures of the deep critical zone. Of the carbon dioxide (CO2) consumed by mineral weathering, calcite is responsible for approximately 27%, with the silicate weathering consumption rate far exceeding that of the global average. The chemical weathering of mafic terrains in decaying orogens thus may be capable of influencing global geochemical cycles, and therefore, climate, on geological timescales. Based on carbon‐balance calculations, atmospheric‐derived sulfuric acid is responsible for approximately 22% of the mineral weathering occurring in the watershed. Our results suggest that rising air temperatures, driven by global warming and resulting in higher precipitation, will cause the rate of chemical weathering in the Hauver Branch watershed to increase until a threshold temperature is reached. Beyond the threshold temperature, increased recharge would produce a shallower groundwater table and reduced chemical weathering rates. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

20.
Carbonates capping Neoproterozoic glacial deposits contain peculiar sedimentological features and geochemical anomalies ascribed to extraordinary environmental conditions in the snowball Earth aftermath. It is commonly assumed that post-snowball climate dominated by CO2 partial pressures several hundred times greater than modern levels, would be characterized by extreme temperatures, a vigorous hydrological cycle, and associated high continental weathering rates. However, the climate in the aftermath of a global glaciation has never been rigorously modelled. Here, we use a hierarchy of numerical models, from an atmospheric general circulation model to a mechanistic model describing continental weathering processes, to explore characteristics of the Earth system during the supergreenhouse climate following a snowball glaciation. These models suggest that the hydrological cycle intensifies only moderately in response to the elevated greenhouse. Indeed, constraints imposed by the surface energy budget sharply limit global mean evaporation once the temperature has warmed sufficiently that the evaporation approaches the total absorbed solar radiation. Even at 400 times the present day pressure of atmospheric CO2, continental runoff is only 1.2 times the modern runoff. Under these conditions and accounting for the grinding of the continental surface by the ice sheet during the snowball event, the simulated maximum discharge of dissolved elements from continental weathering into the ocean is approximately 10 times greater than the modern flux. Consequently, it takes millions of years for the silicate weathering cycle to reduce post-snowball CO2 levels to background Neoproterozoic levels. Regarding the origin of the cap dolostones, we show that continental weathering alone does not supply enough cations during the snowball melting phase to account for their observed volume.  相似文献   

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