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In situ X-ray diffraction was used to measure the isothermal bulk modulus at room conditions (KT0) of synthetic olivines with different iron contents. The chemical formulae of the olivine samples were (Fex,Mg1?x)2SiO4 with x = 0.45; 0.64; 0.82; 1, with 1% standard deviation (referenced as Fa45, Fa64, Fa82 and Fa100, respectively). All experiments were performed in the multi-anvil apparatus installed at NSLS beamline X17B2, to pressures up to about 7 GPa. Unit-cell volumes under hydrostatic conditions and differential stresses present in the samples were calculated using the method developed by Singh et al. (1998), and pressures measured using NaCl as a standard were then corrected for these stresses. Using a second-order Birch–Murnaghan equation of state, we obtained the isothermal bulk modulus of each composition: KT0Fa45=131.4±2.6 GPa, KT0Fa64=132.1±3.1 GPa, KT0Fa82=136.3±1.7 GPa and KT0Fa100=134.8±1.4 GPa. These values combined with data available in the literature show that the KT0 of Fe-rich olivines increases very slowly with the Fe content, but possibly not in a simple linear trend.  相似文献   

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We studied the particle growth in a protoplanetary disk in a high-ionization environment and found that icy planet formation is inactive for a disk with an ionization rate 100 times higher than that of the present Solar System. In particular, in the case of M 10~(-7.4)M_☉yr~(-1), only rocky planet formation occurs. In such a case, all the solid materials in the disk drift inward, eventually reach the inner MRI front,and accumulate there. They form a dense, thin sub-disk of solid particles, which undergoes gravitational instability to form rocky planetesimals. The planetesimals rapidly grow into a planet through pebble accretion. Consequently, rocky planets tend to be much larger than planets formed through other regimes(tandem planet formation regime and dispersed planet formation regime), in which icy planet formation actively takes place. These rocky planets may evolve into hot Jupiters if they grow fast enough to the critical core mass of the runaway gas accretion before the dispersal of the disk gas, or they may evolve into super-Earths if the gas dispersed sufficiently early.  相似文献   

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Previous paleoenvironmental studies reported the δD values of a mixture of coeluting alkenones. Here, we present a semi-preparative normal-phase high-performance liquid chromatography–mass spectrometry (NP-HPLC–MS) method for purifying long chain (C37 and C38) unsaturated methyl and ethyl ketones (alkenones) on the basis of chain length and degree of unsaturation.The method was applied to purify alkenones in suspended particles and surface sediments from a site in Chesapeake Bay, eastern USA. The hydrogen isotopic composition of di- and triunsaturated C37 and C38 alkenones differed significantly on the basis of chain length and the degree of unsaturation, demonstrating the importance of gas chromatography–isotope ratio-mass spectrometry (GC–irMS) analysis of individual alkenones for accurate paleoenvironmental reconstruction. Constant fractionation factors between alkenones with different chain length but the same degree of unsaturation (αC37:2C38:2andαC37:3C38:3=1.01) and those with the same chain length but different degree of unsaturation (αC37:2C37:3andαC38:2C38:3=0.97) in all samples suggest that the values may represent hydrogen isotope fractionation associated with elongation and desaturation during alkenone biosynthesis.  相似文献   

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