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1.
Testing Effluents of the Textile Refining Industry with Biological Methods The environmental problems caused by the manufacture of finished textiles involve a long chain of individual processes. This “textile chain” includes very diverse enterprises of varied size and structure. The textile refiners occupy a key position in the “textile chain”. On the one hand, this is due to their use of an obscurely large number of chemicals which can end up in the wastewater as well as in the textile products. On the other hand, this key role of the textile refining industry is based on their central position between the preproduction stage and the consumers. This study dealt with the textile refining industry's wastewater. As measured by volume and contents of its wastewater, this industry can be counted among the major industrial plants which discharge into municipal wastewater treatment plants. German wastewater legislation includes the provision that substances which are toxic, persistent, capable of accumulating, carcinogenic, fetotoxic or mutagenic be kept out of natural waters as well as technically possible (Wasserhaushaltsgesetz WHG). Several biotest methods for examining the effect of the substances contained in the wastewater were incorporated into the appendix of the German wastewater regulation (Rahmenabwasser-Verwaltungsvorschrift based on § 7a WHG). The aim of this study was to show, with the aid of biotest methods, how strongly the wastewater of textile refining companies is polluted as compared to other known industrial branches and to what degree the pollution of these wastewaters is eliminated by the treatment in wastewater treatment plants. Finally, we experimented to find out which biotest methods were suited for the examination of these wastewaters. The study's results show that the ecotoxicity of the textile refining industry's wastewater was only extraordinary high in isolated cases as compared to other examined branches of industry. The textile wastewaters exhibit values of GL = 3 to GL = 96 in the luminescent bacteria test, GD = 1 to GD = 192 (with one exception of GD > 30000) in the daphnia test and GF < = 2 to GF = 32 in the fish test. It turned out though, that a large number of the samples from the textile refining companies (27%) reacted mutagenically in the Ames test in their native state. Consecutive tests for chromosomal aberrations (V79 hamster cell test) also showed mutagenic potential in five out of nine native samples. The employed testing methods with fish, daphnia and luminescent bacteria demonstrate a higher sensitivity of the luminescent bacteria and/or the daphnia as opposed to the fish in most cases. As the fish test is controversial anyway on the grounds of animal protection, a replacement of the fish test by these other tests should be aimed at: on account of the different end points of the luminescent bacteria and the daphnia test, a combination of these tests appears most sensible.  相似文献   

2.
Baker's yeast industry has significant effects on environment due to significant water consumption and high strength wastewater production. Effluents from baker's yeast industry are characterized by high concentrations of biological oxygen demand (BOD5), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), total dissolved solids (TDS), sulfate, and dark brown color. The aim of this study is to provide a detailed quantitative and qualitative identification and characterization of the wastewater sources from different processes of a baker's yeast industry. It is identified that the most polluted wastewater components of the facility are coming from rotary drum filter and evaporation process. However, the highest pollution loads is identified as tank and equipment cleaning effluent due to very high flow rate from this source. The efforts should be on the way to minimize the water usage for the tank and equipment cleaning process, and to recycle less polluted waste streams back to the process.  相似文献   

3.
Chitosan, a natural polymer, was investigated as a possible sizing agent in fabric production by appropriate modification in the textile industry. Based on recipe developments at a laboratory‐scale, the ecological and economical potential of mainly cotton yarns were demonstrated and developed. Subsequent tests within the scope of industrial production confirmed the findings of the basic developments. As an interesting alternative to the conventional sizing process involving the removal of the size after weaving, the use of appropriate processing technologies makes it possible to apply chitosan in the form of a sizing agent resistant to wash‐out processes. Therefore, the wash‐out process and the combined wastewater loading can be avoided and the properties of chitosan can be used beneficially in the later applications of the fabric. The traditional method of sizing and weaving developments as well as the analyses of material recycling showed the possibilities of using closed circuits in textile production involving sizing agent and water. It is possible that a chitosan‐specific enzyme suitable for production conditions, which facilitates the wash‐out process in combination with the biodegradation of the wastewater in a sewage plant, could be developed.  相似文献   

4.
In arid and semi-arid regions, many rivers experience extremely low flow conditions during seasonal dry periods. During these times, effluent from wastewater treatment plants can make up the majority of flow in the river. However, water quality in urban systems can also be strongly influenced by the natural or human-influenced flow regime and discharge from other anthropogenic sources such as industrial operations and runoff from impervious surfaces. In this study, we aimed to determine whether water quality was controlled primarily by wastewater discharge in an effluent-dominated river. Between May 2016–May 2019, we systematically measured water temperature, pH, dissolved oxygen, biochemical oxygen demand, and the concentrations of nitrate-N, ammonia-N, and orthophosphate in the South Platte River in the Denver metropolitan area, Colorado, USA. We found that, despite being an effluent-dominated river, wastewater treatment plant discharge was not the principal factor controlling water quality in many of the sampled areas. Non-point source pollution from impervious surfaces, delivered to the river through storm drains and minor tributary streams, also contributed to the high nutrient conditions in several locations. We also noted a strong seasonality in water quality, with higher concentrations of nutrients and higher biochemical oxygen demand in the winter months when wastewater effluent can make up more than 90% of the flow in the river. Thus, the interaction of discharge location and reduced seasonal flow produced spatio-temporal hot spots of diminished water quality. More stringent enforcement of water quality regulations may improve water quality in this system. However, a large portion of the pollution seems to be from non-point sources, which are very difficult to control.  相似文献   

5.
The integrated steel industry is considered as one of the important industrial sectors, and its outputs are inputs for other sectors including construction, engineering, medical and scientific equipment, and defence. Massive production, consumption, and export of steel signify a country's economic index. This review outlines the World's steel production quantities, the processes involved, and wastewater generation from the industry and its treatment. Wastewater generated from steel plants is highly complex and requires intensive treatment before discharge into natural water bodies. Technologies adopted for treating wastewater generated from steel industries are deliberated, focusing on coking wastewater treatment. Microbial mediated processes provide an effective means of degrading the contaminants, but the toxicity of certain compounds during higher pollutant load inhibits its further treatment. However, these processes can be integrated with either electrochemical technologies or advanced oxidation processes (AOPs), which can reduce the toxicity level. Hence, when a highly concentrated and complex mixture of contaminants is considered, an integrated approach is a resourceful option in terms of cost-effectiveness and treatment efficiency.  相似文献   

6.
The tannery industry influences the gross domestic product/economic activity of any country, but the uncontrolled release of tannery effluents causes environmental degradation and increases health risks to human. The reason for the toxicity of tannery effluents is the presence of high concentrations of organic and inorganic chemicals used in the production of leather goods. Untreated or partially treated effluents discharged into surface water results in an increase in both chemical and biological oxygen demand as well as in an increase in the levels of total suspended solids, dissolved solids, and toxic metals in environmental bodies, especially in soil, water bodies, and water sediments. Various treatment techniques, such as physicochemical, biological, and advanced oxidation methods, which include chemical precipitation, electrocoagulation, aerobic or anaerobic treatment, wetland construction, and Fenton, electro-Fenton, and photo-Fenton processes are also described. This review also discusses the technical appropriateness and economic feasibility of reducing the effluent pollution load and solid waste emanating from the tannery industry. Considering the enhanced health risks in the tannery waste treatment and management regime, some green and advanced technologies should be explored. A sustainable green technology that avoids the use of toxic chemicals in the tanning process is seen well for ecological health.  相似文献   

7.
The gel-permeation chromatography system with multicomponent detection of organic carbon, organic nitrogen, organic halogen, and UV/vis absorption measurement is shown to be a useful tool for characterization of industrial wastewaters and wastewater treatment processes. The proposed system was used to investigate biologically treated wastewater from chemical industry, whereby one branch stream was identified to be the main source of persistent halogenated organics. Various treatment processes of pulp mill wastewater were also evaluated revealing that precipitation with aluminium is very effective for the removal of the high molecular fraction whereas the biological treatment is generally less selective. In the biological treatment of tannery wastewaters, it has been shown that the aerobic treatment, in contrast to anaerobic step, causes evident alterations of the composition of the polar DOC fraction. The nitrogen containing compounds are also better decomposed in the aerobic step compared to the anaerobic one.  相似文献   

8.
In the carpet industry of the investigated area in 1980 there were used 100 t of different chemicals, especially dyes and textile auxiliaries. This quantity is to be increased 2.6 times till 1985. This industry does not have any closed-cycle drainage systems for the dyeing and washing plants. Thus, during eight months of the year the effluents infiltrate in the soil or evaporate from pools. The accumulations of wastewater originating contain up to 60 mg/l chromium, so that 1… 10 mg/l chromium occur in the wells of the area. In the few central water-supply plants till now chromium has not been detected. The annual variation of the groundwater shows pronounced maxima of contamination during July to September, which clearly agree with the maxima of the wastewater concentrations. The possible ecological impacts of this uncontrolled spread of substances contained in water also in the nutrient chain are discussed.  相似文献   

9.
We assessed short-term ecological and potential human health effects of wastewater treatment plant (WTP) effluent by measuring δ15N‰ and microbial concentrations in oysters and suspended particulate matter (SPM). We also tested male-specific bacteriophage (MSB) as an alternative to fecal coliforms, to assess potential influence of wastewater contamination on shellfish. WTP effluent did not affect oyster growth or survival, but SPM and oysters acquired wastewater-specific δ15N‰. δ15N values were depleted near the WTP, typical of low-level processed wastewater. Fecal coliform and MSB concentrations were higher in samples taken closest to the WTP, and MSB values were significantly correlated with δ15N‰ in oyster tissues. Overall, oysters demonstrated relatively rapid integration and accumulation of wastewater-specific δ15N‰ and indicator microorganisms compared to water samples. These data suggest oysters were superior sentinels compared to water, and MSB was a more reliable indicator of wastewater influence on shellfish than fecal coliforms.  相似文献   

10.
The performance of a constructed wetland for wastewater treatment was examined for four months (December 1995 to March 1996). The study area, hereby referred to as the Splash wetland, is approximately 0·5 ha, and is located in the southern part of Nairobi city. Splash wetland continuously receives domestic sewage from two busy restaurants. Treated wastewater is recycled for re‐use for various purposes in the restaurants. Both wet and dry season data were analysed with a view of determining the impact of seasonal variation on the system performance. The physical and chemical properties of water were measured at a common intake and at series of seven other points established along the wetland gradient and at the outlet where the water is collected and pumped for re‐use at the restaurants. The physico‐chemical characteristics of the wastewater changed significantly as the wastewater flowed through the respective wetland cells. A comparison of wastewater influent versus the effluent from the wetland revealed the system's apparent success in water treatment, especially in pH modification, removal of suspended solids, organic load and nutrients mean influent pH = 5·7 ± 0·5, mean effluent pH 7·7 ± 0·3; mean influent BOD5 = 1603·0 ± 397·6 mg/l, mean effluent BOD5 = 15·1 ± 2·5 mg/l; mean influent COD = 3749·8 ± 206·8 mg/l, mean effluent COD = 95·6 ± 7·2 mg/l; mean influent TSS = 195·4 ± 58·7 mg/l, mean effluent TSS = 4·7 ± 1·9 mg/l. As the wastewater flowed through the wetland system dissolved free and saline ammonia, NH4+, decreased from 14·6 ± 4·1 mg/l to undetectable levels at the outlet. Dissolved oxygen increased progressively through the wetland system. Analysis of the data available did not reveal temporal variation in the system's performance. However, significant spatial variation was evident as the wetland removed most of the common pollutants and considerably improved the quality of the water, making it safe for re‐use at the restaurants. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

11.
Industrial park wastewater (IPWW) includes complex non‐biodegradable organic compounds. A wastewater treatability study using biodegradability assessment approach was carried out for an industrial park housing mainly textile and machinery sectors. Biodegradable and inert chemical oxygen demand (COD) fractions with soluble and particulate counterparts were experimentally estimated by implementing respirometric methods. Aerobic batch test methods and oxygen uptake rate profiles were used to map kinetic parameters and COD fractions. Denitrification potential was also determined by application of anoxic batch tests. Relevant kinetic constants, stoichiometric, and design parameters were determined for biological processes. Tests were carried out for raw and physico‐chemically pre‐treated IPWW. Hence, it was aimed to assess the effects and necessity of pre‐treatment on biological processes. Biological mineralization, nitrification, and denitrification processes were also designed and tested using a bench scale continuous treatment model for pre‐treated IPWW. The sum of initial inert soluble COD fraction and production of soluble microbial products decreased about 25% for the case of pre‐treated IPWW as compared to raw IPWW. Eighty‐three percent total COD and 89% total Kjeldahl nitrogen removal efficiencies were attained for the modeling experiments of pre‐treated IPWW. Results showed the significance of pre‐treatment if complex strength industrial wastewaters are to be biologically treated.  相似文献   

12.
The objective of this study was to investigate the effect of salt concentration on performance of a membrane bioreactor (MBR) for treating an olefin plant wastewater. For this purpose, a lab‐scale submerged MBR with a flat‐sheet ultrafiltration membrane was used for treatment of synthetic wastewater according to oxidation and neutralization unit of olefin plant. The synthetic wastewater was adjusted to have 500 mg/L chemical oxygen demand (COD). Trials on different concentrations of sodium sulfate (Na2SO4) (0–20 000 ppm) in the feed were conducted under aerobic conditions in the MBR. The results showed that increasing the salt concentrations causes an increase in the effluent COD, phenol, and oil concentrations. These results are due to reduction of the membrane filtration efficiency and also decline in the microbial activity that it is indicated by decreasing the sOUR in MBR. But in all the trials, the effluent COD and oil concentration was well within the local discharge limit of 100 and 10 mg/L, respectively. These results indicate that the MBR system is highly efficient for treating the olefin plant wastewater, and although high salt concentrations decreased organic contaminant removal rates in the MBR, the effluent still met the discharge limits for treating the olefin plant wastewater.  相似文献   

13.
An eco‐friendly and inexpensive technique for wastewater treatment originated from inductively coupled plasma‐optical emission spectrometry (ICP‐OES) is presented within this paper. The proposed process comprised of loading waste crab shells in packed column for adsorption of heavy metal ions, followed by desorption using 0.01 M HCl. An exhaustive physical and chemical characterization of ICP‐OES wastewater revealed the complex nature of effluent, including the presence of 15 different metals and metalloid under strong acidic condition (pH 1.3). Based on the preliminary batch experiments, it was identified that solution pH played a major role in metal sequestration by crab shell with pH 3.5 identified as optimum pH. Rapid metal biosorption kinetics along with complete desorption and subsequent reuse for three cycles was possible with crab shell‐based treatment process. Continuous flow‐through column experiments confirmed the high performance of crab shell towards multiple metal ions with the column able to operate for 22 h at a flow rate of 10 mL/min before outlet concentration of arsenic reached 0.25 times of its inlet concentration. Other metal ions such as Cu, Cd, Co, Cr, Pb, Ni, Zn, Mn, Al, and Fe were only in trace levels in the treated water until 22 h. The performance of the treatment process was compared with trade effluent discharge standards, and the process flow diagram along with cost analysis was suggested.  相似文献   

14.
In the present investigation, treatment of textile effluent using an electrochemical technique was designed and analyzed using the Box-Behnken method. The influence of individual parameters on electro-oxidation of textile effluent has been critically examined using the response surface method (RSM), and a quadratic model for chemical oxygen demand (COD) reduction has been developed. It has been observed from the present analysis that the predicted values are in good agreement with experimental data with a correlation coefficient of 0.945.  相似文献   

15.
Disposal of wastewater treatment plant (WWTP) effluent into sea, a typical anthropogenic disturbance, may influence many environmental factors and change the coastal microbial community structure. In this study, by setting up coastal sediment microcosms perturbed by WWTP effluent, the changes of microbial community structure under different degree of disturbances were investigated. Quantitative PCR (qPCR) and terminal restriction fragment length polymorphism (T-RFLP) were used to analyzed the biomass and biodiversity. High throughput sequencing analysis was used to identify the classification of the microorganisms. Our study suggested that low ratio of WWTP effluent may stimulate dominant species, which increase the biomass but decrease the biodiversity; while high ratio of WWTP effluent may depress all species, which decrease the biomass but increase the biodiversity. In other words, the impact was dose-dependent. The changes of microbial community structure may provide a metric for water environmental assessment and pollution control.  相似文献   

16.
A pilot plant study and a full scale plant study were conducted to determine the feasibility of using contact oxidation followed by activated carbon adsorption process in textile wastewater treatment, and to determine the effects of types of packing media in the contact oxidation tank and types of aeration process on the treatment performance. Results indicated that contact oxidation followed by activated carbon adsorption process was effective in removing organics and color from textile wastewaters. Types of packing media and types of aeration processes had little effect on the treatment performance. The pilot plant performance was found to perform slightly better than the performance of the full scale plant.  相似文献   

17.
The European Water Framework Directive (WFD) and the Urban Wastewater Treatment Directive (UWWTD) aim to improve water quality and reduce the environmental impact of wastewater, by requiring member states to introduce better treatment levels. This study was carried out in order to detect the most suitable treatment type or flow level for reducing benthic environmental impact. Therefore, soft-bottom polychaete assemblages affected by discharges of six treatment plants, with different treatment technologies and flow rates, were analysed over three consecutive years. Polychaete assemblages changed as a result of sewage discharge. These changes were related to treatment level and flow rates. Both disposal quality and quantity are important since changes in soft-bottom assemblages in stations affected by pre-treated sewage with medium and high flow rates are observed. However, the location with a low-flow pre-treated effluent has similar polychaete assemblages with regard to locations with biological treatment or controls.  相似文献   

18.
Population growth in urban areas is putting pressure on sewage treatment plants. The improper treatment of sewage entering the aquatic ecosystems causes deterioration of the water quality of the receiving water body. The effect of sewage effluent on the Sand River was assessed. Eight sampling sites were selected, site 1 and 2 were upstream of the sewage treatment plant along the urbanised area of Polokwane, whilst sites 3, 4, 5, 6, 7 and 8 were downstream. The physico-chemical parameters and coliform counts in the water samples were determined. The suitability of the water for irrigation was also determined. Hierarchical average linkage cluster analysis produced two clusters, grouping two sites above the sewage treatment works and six sites downstream of the sewage effluent discharge point. Principal component analysis (PCA) identified total nitrogen, total phosphorus, conductivity and salinity as the major factors contributing to the variability of the Sand River water quality. These factors are strongly associated with the downstream sites. Canonial correspondence analysis (CCA) indicated the macroinvertebrates, Chironomidae, Belastomatidae, Chaoborus and Hirudinea being strongly associated with nitrogen, phosphorus, conductivity and temperature. Escherichia coli levels in the Polokwane wastewater treatment works maturation ponds, could potentially lead to contamination of the Polokwane aquifer. The Sodium Adsorption Ratio was between 1.5 and 3.0 and residual sodium carbonate was below 1.24 Meq/l, indicating that the Sand River water is still suitable for irrigation. The total phosphorus concentrations fluctuated across the different site. Total nitrogen concentrations showed a gradual decrease downstream from the point of discharge. This shows that the river still has a good self-purification capacity.  相似文献   

19.
Breeding ornamental fish in wastewater was a successful solution not only to decrease sanitary risks but also to encourage fish growth. In fact, the secondary treated effluent was used to grow a walking catfish (Clarias batrachus), a western mosquitofish (Gambusia affinis; Poeciliidae), and a leopard pleco (Glyptoperichthys gibbiceps). The growth rate of fish reared in final treated wastewater was significantly higher than of treated effluent (25 and 50%) and the relative growth rate during 2 months reached 2, 4, and 2.5, respectively. Bacterial loads were important in the gills compared to other fish organs (intestine, skin, and edible muscles). However, the total aerobic germs ranged between 2 × 103 and 3.4 × 103 cfu/g in the edible fish species cultured in secondary treated effluent. The pathogenic bacteria Aeromonas hydrophila was absent in all examined fish muscles. However, the presence of tested fishes did not prevent the reduction of the treatment biological parameter (BOD and COD) at half, in the three treated wastewater proportions (25, 50, and 100%) and thereafter, they clearly participated to the tertiary biological treatment of used water. Further bacteriological and physico‐chemical analyses indicated that the use of treated wastewater in aquaculture is safe and risks to human health are reduced.  相似文献   

20.
The coral reef at Kahekili, Maui is located ~300 m south of the Lahaina Wastewater Reclamation Facility which uses four Class V injection wells to dispose of 3-5 million gallons of wastewater effluent daily. Prior research documented that the wastewater effluent percolates into the nearshore region of Kahekili. To determine if the wastewater effluent was detectable in the surface waters offshore, we used algal bioassays from the nearshore region to 100 m offshore and throughout the water column from the surface to the benthos. These algal bioassays documented that significantly more wastewater effluent was detected in the surface rather than the benthic waters and allowed us to generate a three-dimensional model of the wastewater plume in the Kahekili coastal region. Samples located over freshwater seeps had the highest δ(15)N values (~30-35‰) and the effluent was detected in surface samples 500 m south and 100 m offshore of the freshwater seeps (~8-11‰).  相似文献   

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