共查询到20条相似文献，搜索用时 31 毫秒
1.
Sergio Castro Heriban Soto Jorge Goldfarb Janusz Laskowski 《International Journal of Mineral Processing》1974,1(2):151-161
The rate of consumption of sulphide in the sulphidizing reactions of malachite and chrysocolla has been measured. The oxidation of sulphide ions at the surface of sulphidized chrysocolla was shown to take place. The influence of thiosulphate anions on the xanthate flotation of sulphidized malachite and chrysocolla was investigated and it was shown to depress the flotation of chrysocolla strongly.The result suggest, that the presence of thiosulphate as a product of simultaneous oxidation can be one of the reasons for the more difficult flotation of sulphidized chrysocolla. 相似文献
2.
Jonathan M. Horlick W. Charles Cooper Alan H. Clark 《International Journal of Mineral Processing》1981,8(1):49-59
Chrysocolla in the Cuajone ores appears to be microcrystalline and to exhibit a fibrous structure.Sulphuric acid leaching of the chrysocolla is facilitated by a microcracked surface structure. A marked surface structural change is evidenced as hydrogen ions replace the copper. The end result is a noncontinuous surface layer of silica from which the copper has been essentially completely removed.The results of this study provide confirmatory evidence for the structure and hydrometallurgy of chrysocolla. 相似文献
3.
黔西北海相、海陆过渡相页岩孔隙分形特征对比研究 总被引：1，自引：0，他引：1
本文以黔西北地区海相页岩层系牛蹄塘组、龙马溪组及海陆过渡相页岩层系龙潭组为研究对象,在孔隙特征分析和低温氮气吸附-脱附实验的基础上,对比研究深海陆棚相、浅海陆棚相以及潮坪-泻湖相泥页岩的孔隙分形维数特征,结果显示：深海陆棚相泥页岩D1适中,D2较大;浅水陆棚相D1偏小,D2适中;潮坪-泻湖相D1、D2均较大。通过将分形维数D1、D2与主要地质参数进行相关关系研究认为：D1能够较好的区别各种沉积相孔隙结构的整体特征,能够表征泥页岩的均值性、孔隙体积、吸附能力等宏观特征,D2则能够较好表征泥页岩结构复杂程度等微观特征。综合研究成果认为：浅海陆棚相泥页岩岩石均质性较好,吸附能力一般,微孔不很发育,不利于页岩气富集,资源潜力较小;潮坪-泻湖相泥页岩岩石非均质性强,吸附能力强,微孔发育,有利于游离态、吸附态页岩气富集,孔隙结构复杂,但开采难度最大;深海陆棚相泥页岩均质性较好,吸附能力适中,微孔发育,有利于游离态页岩气富集,但孔隙结构复杂,开采难度偏大。深海陆棚相为目前研究价值最高,经济开发潜力最高的层系。 相似文献
4.
运用分形理论对汶南煤矿红层的微孔隙发育规律进行了研究,结果表明,该岩层的孔隙分布具有自相似性,分维值是真实地反映孔隙特征的一个综合指标,分形统计方法是岩石孔隙定量描述的有效途径。有关方法、结论等可供进一步探讨。 相似文献
5.
M. Barbaro R. Herrera Urbina C. Cozza D. Fuerstenau A. Marabini 《International Journal of Mineral Processing》1997,50(4):275-287
A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation. 相似文献
6.
The heterogeneous reaction between natural and sulphidized chrysocolla and potassium amyl xanthate in solution is investigated.It is found that, together with the consumption of large amounts of xanthate, particles composed of the reaction products are spontaneously released from the surface of chrysocolla giving rise to a colloidal dispersion. In principle the mechamism is related to the peptizing effect of the excess xanthate ions that are found when Cu2+ and X? ions are made to react in a homogeneous phase.In sulphidized chrysocolla this phenomenon is markedly reduced, showing that Na2S has a stabilizing effect on the collector coating.Flotation experiments performed with aqueous amyl dixanthogen emulsions show that stable adhesion occurs only on properly sulphidized chrysocolla. It is believed that the mechanism controlling adhesion in this case is similar to that which determines the stability of the collector layer. 相似文献
7.
页岩孔隙结构及差异性是页岩含气性和产能评价的基础性问题.针对川东南彭水地区五峰组与龙马溪组页岩的孔隙结构已有若干研究成果,然而在页岩孔隙结构差异性和有机孔定量特征方面还缺乏研究.利用低温低压氮气吸附测定和氩离子抛光-场发射扫描电镜（FE-EM）技术,对页岩样品纳米孔隙进行了二维观察与统计以及分形特征计算,研究了3nm至几百nm页岩孔径范围的孔隙结构及其差异性.研究区五峰组-龙马溪组页岩有机孔十分发育;氮气吸附测定页岩孔隙形状包含开放型圆筒状、层状结构狭缝状和墨水瓶状等;扫描电镜观察有机孔形态主要有近圆形、椭圆形和多角形等.五峰组和龙马溪组页岩孔隙结构具有明显的差异性,主要体现在孔径大小、形态和数量上.氮气吸附测定表明,五峰组页岩孔隙比表面积和总孔容较龙马溪组大,微孔所占总孔的比例也较高;五峰组页岩孔径相对龙马溪组更细窄.扫描电镜二维图像观察与统计结果表明,五峰组有机孔径以小于3nm为主,形态以多角形为主;龙马溪组有机孔径以小于0nm为主,形态多呈近圆形和椭圆形.五峰组页岩的分形维值大于龙马溪组页岩,说明前者孔隙复杂程度较高. 相似文献
8.
研究煤复杂发育的孔隙结构对揭示煤层气体赋存机理及扩散运移规律有重要意义.为了研究煤的纳米孔隙结构,利用SEM、液氮吸附、小角X射线研究了不同煤阶煤的纳米孔隙在形式和分布上的非均匀性.实验煤样煤基质中的孔呈多峰分布,且孔径范围主要集中在2~10 nm.煤样低温液氮吸附实验测得煤样的吸附量为3.676 cm3/g,煤样的比表面积为1.416 m2/g.以最可几孔径作为研究对象,在实验压力范围内,吸附压力越大,最可几孔径变大的越多;瓦斯气体在纳米级孔隙结构中的扩散模式以过渡型扩散为主,微孔更发达的煤样中,扩散更接近Knudsen型扩散,中孔更发达的煤样中,扩散更接近Fick型扩散;Knudsen数与温度呈负相关关系,温度高于250 K后,Knudsen数趋于稳定,与压强呈正相关关系,压强越大,扩散越容易. 相似文献
9.
The quantitative analysis of the pore characteristics of granular materials has been often challenging due to arbitrarily shaped geometry of pores despite its significant implications. In this study, we investigate the size distribution and orientation of pores in dilative and contractive assemblies in the direct shear test by performing 3D discrete element simulations in conjunction with image processing of pore geometry. We quantitatively define unit pores by the Delaunay Tessellation followed by pore mergence and fitting them with ellipsoids. It is observed that the evolution of pore size distribution depends on the dilatancy of assemblies. Results also show that the direction of principal stresses governs the orientations of pores during shearing, with respect to the size of pores. This study highlights that the dominant factors of the pore characteristics upon shearing are stress anisotropy and particle mobilization to make the internal structure stable. 相似文献
10.
目前关于自生粘土矿物对深层孔隙结构及油气运聚的影响方面的研究十分薄弱.综合利用铸体薄片、全岩XRD、扫描电镜、恒速压汞等测试手段,分析自生粘土矿物对孔隙连通性、孔喉直径及其分布的影响,并结合埋藏史和生烃史探讨了低渗透砂岩不同孔隙结构类型的油气差异富集条件.珠海组深部储层压实作用较强,自生粘土矿物含量较高.碎屑颗粒以线接触-凹凸接触为主,识别出"孔隙+粗喉道"和"喉道主控"2种孔隙结构类型,前者孔隙体积和粗喉道占比较高,后者主要以细喉道为主;自生粘土矿物分割占据大量孔喉空间,自生伊利石主要为孔喉充填型,自生绿泥石主要为颗粒包壳型;珠海组储层与下渐新统恩平组烃源岩不整合接触形成纵向"下生上储"、横向连续分布的有利源储组合,烃源岩持续生烃.珠海组是典型的深埋藏碎屑岩低渗储层,仍具备良好的储集条件,储层发育受机械压实作用和自生粘土矿物共同控制;压实作用是原生孔隙损失的初始因素,以绿泥石和伊利石为代表的自生粘土矿物高度发育是制约优质储层发育的关键因素. 相似文献
11.
莺歌海盆地东方-乐东区已获得商业气田发现,但针对气田盖层研究,尤其是泥岩盖层岩石学特征及孔喉结构特征方面研究较少.利用岩石薄片、地球化学、XRD、元素分析等资料,深入分析研究区泥岩矿物组成、地球化学、成岩演化以及孔隙结构特征.结果表明:莺歌海盆地东方-乐东区中新统黄一段和黄二段泥岩盖层分布最为稳定,泥岩盖层封盖性受陆源碎屑供给与钙质化石碎片影响较大,研究区优质盖层中陆源碎屑颗粒与钙质化石碎片含量较低,次生溶蚀孔隙与微裂缝不发育;埋藏成岩过程中的粘土矿物转化脱水与有机质热演化排烃是低速泥岩的主要成因;泥岩盖层以微孔喉和超微孔喉为主,此类喉道不利于气体的渗流,对油气向上逸散起明显阻碍,盖层整体封盖性较好. 相似文献
12.
13.
以CTMABr、TPABr为介、微孔模板剂, Na2SiO3为硅源, Al2(SO4)3为铝源, La2O3的H2SO4溶液为La供体, 在水热条件下, 通过La离子导入、预置晶种、二步晶化等手段, 首次合成出La杂原子ZSM-5/MCM-41复合分子筛.XRD、N2吸附脱附结果表明, 样品共存ZSM-5和MCM-41两种物相, 两种结构、孔径在介、微孔范围都有分布, 且La可取代分子筛骨架的少量Si.SEM照片显示, 样品晶粒局部聚集成不规则的团块, 构成团块的颗粒大小不一但结合紧密, 与ZSM-5、MCM-41形貌明显不同.IR曲线中不存在La2O3的特征吸收谱, 样品特征骨架振动峰向高波位移的现象, 以及样品微分热失重峰向高温方向偏移, 加之DTA曲线肩峰的出现进一步说明La杂原子ZSM-5/MCM-41复合分子筛的合成. 相似文献
14.
Micro-CT and FIB–SEM imaging and pore structure characterization of dolomite rock at multiple scales
Rajakumar S. Devarapalli Amina Islam Titly Farhana Faisal Mohamed Sassi Mustapha Jouiad 《Arabian Journal of Geosciences》2017,10(16):361
With improvements of imaging techniques and computational power, Digital Rock Physics (DRP) has been increasingly used to determine transport and elastic properties of reservoir core plugs. Since numerical computations highly rely on accurate 3D representations of the porous microstructure of the rocks, the imaging technique and the scale at which the imaging is performed is a critical parameter. In this paper, we introduce a multiscale imaging workflow that uses both micro-X-ray tomography (micro-XCT) and focused ion beam combined with scanning electron microscope (FIB–SEM) to characterize a dolomite rock from the microscale to the nanoscale. This allows for the accurate capture of the different heterogeneities that exist in the carbonate (texture, mineralogy, pore size). The reconstructed microporous structures were then used to successfully predict elastic and permeability properties of selected carbonate. 相似文献
15.
为了揭示鄂尔多斯盆地东缘海陆过渡相页岩微观孔隙结构特征及其主控因素,丰富对该区块海陆过渡相煤系页岩孔隙发育特征与孔隙结构的认识,对临兴地区页岩进行扫描电镜、高压压汞和液氮吸附分析以表征微观孔隙结构特征,同时结合孔隙率、TOC含量、岩石矿物含量、黏土相对含量、有机质成熟度测试结果对页岩孔隙结构发育主控因素进行研究。结果表明:研究区页岩发育粒内孔、粒间孔、溶蚀孔和微裂缝,有机质内部偶见孔隙、可见微裂隙,与矿物伴生时周边发育微裂隙;页岩总孔容介于0.001 46~0.010 81 mL/g,介孔占比81.9%,比表面积介于0.35~ 3.65 m2/g,孔径分布以单峰型为主,分布范围主要在200 nm以内,主峰孔径在45 nm左右,本溪组、太原组页岩孔隙连通性优于山西组,太原组宏孔占比优于本溪组、山西组;页岩总有机碳含量对页岩孔隙发育的影响复杂,对宏孔发育具有一定的积极作用,脆性矿物含量对总孔、介孔发育有积极作用,黏土矿物含量对总孔和介孔发育起消极作用,其中,脆性矿物和黏土矿物通过影响介孔的发育来控制页岩中孔隙的发育程度。基于页岩孔隙结构多尺度定性–定量表征及其控制因素研究对临兴区块海陆过渡相页岩气资源量评价、甜点优选与开发具有重要指导意义,丰富了对海陆过渡相页岩储层的地质认识。 相似文献
16.
绿松石是一种多孔材料,其孔隙特征直接影响其颜色、光泽、硬度、耐久性等性质,进而影响其市场价值,电化学处理的主要目的是降低绿松石孔隙度从而使其耐久、保色。采用全自动比表面仪、X射线显微CT(Micro-CT)等测试分析手段,对电化学处理前后绿松石的孔隙特征进行了对比研究。比表面仪研究发现,电化学处理后的绿松石总孔隙度、总孔体积、平均孔径及比表面积均有一定程度的变化;吸附-脱附曲线高压区域天然绿松石吸附曲线斜率变大,而电化学处理绿松石吸附曲线斜率变小;天然绿松石孔径分布曲线为类抛物线,而电化学处理绿松石孔径分布曲线呈内凹曲线状。Micro-CT研究结果表明:天然绿松石中出现的由表面贯穿至内部的大孔洞,经电化学处理后孔洞被不完全充填;天然绿松石存在“流纹状”结构,孔隙沿“流纹”分布,而电化学处理绿松石的“流纹状”结构消失,孔隙分布杂乱无章。本研究首次从孔隙特征角度入手,发现天然绿松石与电化学处理绿松石在高压区域吸附曲线特征、50 nm孔径以上孔隙分布曲线、孔隙充填情况和内部结构等方面存在明显差异。通过检测绿松石的钾(K)含量,并结合孔隙特征差异,可以有效地对绿松石是否经过电化学处理进行检验判定。 相似文献
17.
为揭示不同变质程度煤岩纳米级孔隙特征,运用小角X射线散射方法(SAXS),采集镜质体反射率Rmax在0.31%~6.24%的15个样品,基于散射数据获取的煤岩孔隙率、孔径分布、比表面积和分形维数,讨论了煤化过程对煤岩纳米孔隙(0.3~100 nm)结构的影响,并用低温CO2和N2吸附DFT模型结果对孔径分布进行了验证。结果表明:在Rmax < 0.5 %时,煤岩孔隙率和比表面积随着变质程度的增加而增加,微孔(< 2 nm)含量增长较少,介孔(2~50 nm)和大孔(50~100 nm)含量大幅增加,煤岩表面逐渐光滑;在Rmax=0.5%~1.4%时,孔隙率和比表面积减小,各类孔隙含量均减少,煤岩表面逐渐光滑;在Rmax=1.4%~4.0%时,煤岩孔隙率和比表面积增大,微孔含量大幅增加,介孔和大孔含量近乎稳定,煤岩表面逐渐粗糙;在Rmax > 4.0%后,煤岩孔隙率和比表面积缓慢增加,微孔增长幅度变缓,煤岩表面逐渐光滑。SAXS在0.3~100 nm孔径分布(本次实验范围)中用球形形状因子与低温CO2和N2吸附结果契合度较高,煤中纳米级孔隙率及比表面积主要由微孔贡献。 相似文献
18.
应用常规物性、铸体薄片、扫描电镜、常规压汞、核磁共振等实验,着重分析姬塬地区长6油层组微观孔隙结构类型划分及其对可动流体饱和度的影响。研究表明:该区的储集空间主要为原生粒间孔、其次为长石溶孔;根据毛管压力曲线形态以及相应的参数,将储层孔隙结构分为Ⅰ类、Ⅱ类、Ⅲ类、Ⅳ类,四类孔隙结构对应储集空间不同,其储集性能和渗流能力依次变差;核磁共振测得T_2谱图形态与其所对应孔喉半径进汞饱和度分布形态相似,T_2值大小与孔喉半径大小呈正相关性,孔喉半径是影响可动流体分布的主要因子,渗透率与可动流体饱和度呈较好的正相关性,是表征孔隙结构渗流能力的直观参数。 相似文献
19.
天然硅藻土的应力水平与孔隙空间分布的关系 总被引：4，自引：1，他引：3
采用压汞法研究了不同固结压力作用下具有强结构性的天然沉积硅藻土的微观孔隙入口孔径分布与应力水平的关系。研究结果表明：当应力水平小于固结屈服应力时,具有强结构性的天然沉积硅藻土的微观孔隙入口孔径分布几乎与应力水平无关,而当外加应力水平达到固结屈服压力时,虽然总体孔隙空间体积几乎与天然沉积状态时一样,但其微观孔隙入口孔径分布则发生显著变化。在屈服后阶段,随着应力水平的增大硅藻土的孔隙空间体积逐渐减少,最大孔隙变小,整体孔隙空间的孔径趋于均匀。并对微观结构变化与宏观力学特性的内在联系也进行了初步探讨。 相似文献
20.
《Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy》2000,25(2):169-174
A simple cutoff approach based on the capillary bundle model has become an industrial standard method to quickly obtain the irreducible water saturation from NMR T2 distribution. However this approach is not always valid. To overcome the shortcoming of the capillary bundle model that ignores pore-pore connectivity, we have conducted a two-phase flow simulation in a CT-based pore network. The CT -based pore network is a representation of a real rock pore structure that is described by a binary X-ray tomographic data set. Simulation on such network mimics a process of the porous plate measurement. The generated capillary curve is quite reasonable. The oil accession distributions at different water saturations plotted as a function of pore size provide an insight for the immiscible displacement process in the real rock pore structure. Water is trapped not only in dead ends but also in the well-connected pores due to a pore level by-pass mechanism. At the capillary end point pressure, a plot of the trapped water distribution as a function of pore size has the same lognormal distribution as the pore size distribution, which is much different from what the simple capillary bundle model suggests. 相似文献