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1.
Red mud (RM), the solid waste of alumina industry, is high in silicon, calcium, aluminum and iron oxides. In this study, RM was activated by heat treatment at different temperatures and characterized with BET nitrogen gas sorption, scanning electron microscopy analysis and X-ray diffraction analysis. Immobilization of phosphorus, copper, zinc, and arsenic in swine manure by activated RM was studied as a function of RM dosage, pH and time. The immobilization efficiency of phosphorus, copper, zinc and arsenic increased with the increase in RM dosage, reaching 77, 39, 42, and 78 % when the proportion of RM to swine manure was 20 %. The pH of the solution had a significant impact on the immobilization and it was found that the efficiency increased with the increase in pH. During the 24-h immobilization, the efficiency increased with time and achieved equilibrium after 12 h. Chemical variations of phosphorus, copper, zinc, and arsenic during the immobilization process were investigated with sequential chemical extraction method and the results showed that the contents of non-labile fractions of phosphorus, heavy metals and arsenic increased obviously, whereas the contents of labile fractions decreased.  相似文献   

2.
Concentrations and vertical distributions of total nitrogen (TN), total phosphorus (TP) and their different forms in sediments obtained from nine locations of Lake Dalinouer in September 2008 were analyzed. The results demonstrated that TP in surface sediments ranged from 0.493 to 0.904 g/kg, and inorganic phosphorus was the main fraction of total phosphorus, ranging from 335 to 738 mg/kg. Simultaneously, the autogenetic calcium phosphorus (ACa-P) was the main fraction of inorganic phosphorus, ranging from 145.4 to 543.2 mg/kg. Vertical distribution of different phosphorus forms in different sediment cores was distinguishing, and most of them tended to increase toward the surface sediment, indicated that the phosphorus concentration was related to the humanity with a certain extent. The relationships between TP and occluded phosphorus and ACa-P were significant. Nitrogen in the sediment was composed mainly of organic nitrogen, accounting for grater than 80 % of TN. NO3 ?-N was the dominate fraction of inorganic nitrogen in the surface sediment, ranging between 51 and 346 mg/kg (151.1 ± 104.4 mg/kg), and accounting for between 2.2 and 17.7 % of total sediment nitrogen (6.2 ± 5.6 %). The ratio of organic carbon and TN in sediment was in range of 6.0–25.8 and presented a tendency of lake centre >lake sides, indicating that nitrogen accumulated in the sediments from lake sides came mainly from terrestrial source and nitrogen was mainly autogenetic in lake centre. Ratio of N:P in all sampling sites was below 14, indicated that N was the limiting nutrient for algal growth in this lake.  相似文献   

3.
Monitoring general variability of soil attributes is a fundamental requirement from the point of view of understanding and predicting how ecosystems yield. In order to monitor impact of different land use types on the combination of morphological, clay mineralogical and physicochemical characterizes, 42 soil samples (0–30 cm) were described and analyzed. Soil samples belonging to Cambisols and Vertisols reference soil groups collected from three neighboring land use types included cropland (under long-term continuous cultivation), grassland, and forestland. The soils were characterized by high pH (mean of 7.1–7.5) and calcium carbonate equivalent (CCE) (mean of 35–97 g kg?1) in the three land use types. The weakening in soil structure, hardening of consistency, and lighting of soil color occurred for the cropland under comparable condition with grassland and forest. Changes in land use types produced a remarkable change in the XRD patterns of clay minerals containing illite and smectite due the dynamic and removal of potassium. Continuous cultivation resulted in an increase in sand content up to 35 % while silt and clay content decreased up to 22 and 18 %, respectively, as compared to the adjoining grassland and forest mainly as a result of the difference of dynamic alterational and erosional process in the different land use. Long-term cultivation caused a negative and degradative aspects on soil heath as is manifested by the increasing in soil pH (a rise of 0.3–0.46 unit), electrical conductivity (EC) (a rise of 1.78–5.5 times), sodium absorption ration (SAR) (a rise of 10–51 %), exchangeable sodium percentage (ESP) (a rise of 3–46 %), and the decrease in soil organic C (a drop of 12–41 %), along with soil fertility attributes. Overall, the general distribution of soil organic C, total N, available P and K, cation exchange capacity (CEC), and exchangeable cations (Ca, Mg, and K) followed the order: forestland > grassland > cropland. The general distribution of EC, SAR, ESP, and exchangeable Na, however, followed the order: cropland > grassland > forestland. Soil quality index (SQI), calculated based on some physicochemical properties, specified that cultivation led to a negative effect in SQI for both Cambisols (a drop of 10–17 %) and Vertisols (a drop of 17 %) as compared to those of under grassland and forestland.  相似文献   

4.
Based on the analysis of the enrichment characteristics of Hg and MeHg in bird feathers from Caohai National Nature Reserve in Guizhou, the risks of Hg pollution to the birds from Caohai wetland have been evaluated. The total Hg content of bird feathers ranges from 40 to 5058 ng/g with an average of 924 ng/g. The content of MeHg is significantly correlated with total Hg (r = 0.68, p < 0.01), and the content are among 0.75 and 113 ng/g. The total Hg content in the birds feathers is significantly dependent on their feeding habits, which is mainly in accordance with the following rule: carnivorous birds > omnivorous birds that are mainly carnivorous > omnivorous birds that are mainly herbivorous. There are also differences in the Hg enrichment ability in the different parts of bird feathers, and the total Hg and MeHg content in the wing feathers are significantly higher than that in the other parts of feathers. The bioaccumulation coefficients of aqueous Hg and MeHg by bird feathers are 0.9 × 104–112.13 × 104 (mean value is 20.47 × 104) and 0.47 × 104–70.4 × 104 (mean value is 9.52 × 104), respectively. Although the whole Hg level in Caohai bird feathers is not too high, the Hg content in some carnivorous birds exceeds over or approaches the abnormal threshold when birds are breeding (5 μg/g), which indicates that the birds in Caohai wetland are faced with some risks of ecological Hg pollution.  相似文献   

5.
This study examines the phosphorus attenuation capacity of acid mine drainage (AMD) floc (also called ocher or sludge)—generated by neutralizing AMD with ammonia, lime, and sodium hydroxide—in the face of competition from two major organic companions, citrate and oxalate, of phosphorus in manure. Lime-treated floc (LF) was the least effective of the three flocs in attenuating both inorganic phosphorus and organic phosphorus (OP: represented by inositol hexaphosphate or phytate). Out of the remaining two flocs, ammonia-treated floc (AF) attenuated more inorganic phosphorus and less organic phosphorus than did sodium hydroxide-treated floc (SF). Increasing citrate:phosphorus molar ratio in the solution from 0:1 to 1:1 decreased the inorganic P attenuation capacity (IPAC) from 53 to 29 % in AF, 33 to 16 % in LF, and from 49 % to 27 % in SF at pH 4. The corresponding figures for organic P attenuation capacity (OPAC) were from 73 to 54 % in AF, 58 to 45 % in LF, and from 76 to 58 % in SF. Increasing oxalate:phosphorus molar ratio from 0:1 to 1:1 decreased IPAC and OPAC similarly, but to a lesser extent. The competitive influence of citrate and oxalate went on weakening with increase in pH. A likely increase in pH following prolonged manure application may undermine the competitive ability of citrate and oxalate. The study shows that manure P attenuation potential of waste of AMD treatment, notwithstanding the peer anion competition to P, warrants its effectiveness in controlling buildup of P in heavily manured soils.  相似文献   

6.
This study was conducted to evaluate the efficiency of low-cost adsorbents including bentonite, kaolinite and zeolite saturated with calcium and potassium, potato and wheat residues, and three metal oxide nanoparticles functionalized with an acidic extract of potato residues in improving the quality of sodic waters. The optimization of factors such as pH, contact time, and adsorbent dosage was investigated using a solution containing sodium, calcium, magnesium, and potassium. The optimal pH and contact time were 7.0 and 24 h, respectively. The optimal dosage for using functionalized nanoparticles was 0.1 g and for using other adsorbents was 1.0 g. The sodium exchange isotherms were conducted in binary sodium–calcium and sodium–potassium and quaternary sodium–calcium–magnesium–potassium systems. Zeolite saturated with potassium was the most effective adsorbent in removing sodium from aqueous solutions with an average removal efficiency of 69.2 and 66.5 % in binary and quaternary systems, respectively. Freundlich and Langmuir equations fitted well to experimental data in both binary and quaternary systems. Cation selectivity coefficients calculated based on the Gaines–Thomas convention varied with changing pH and adsorbent dosage. Graphical and statistical evaluations confirmed that the mechanistic cation exchange model using average Gaines–Thomas selectivity coefficients in geochemical PHREEQC program was able to successfully simulate the sodium exchange on different adsorbents in both systems. The Gaines–Thomas selectivity coefficient values greater than unity and as a consequence, the negative values of the Gibbs free energy change of adsorption indicated that sodium exchange reactions in the presence of different adsorbents used is this study were exergonic and spontaneous.  相似文献   

7.
This study investigated the leaching of radium-226 from phosphogypsum (PG) waste produced from the fertilizer industry by synthetic solutions that replicate water that may contact the waste in natural conditions. The results indicated that the activity concentration of Ra-226 in the PG was 461 ± 12 Bq kg?1 and compared with other studies carried out worldwide. The leached percentage of Ra-226 represents the exchangeable fraction loosely bounded in the matrix of the PG waste. The leached fraction of Ra-226 was 6.5 ± 0.6 and 9.0 ± 0.5% when the waste was exposed to rainwater and saline solution, respectively. It is also found that the leaching fraction increased 10–12 ± 0.4% when the waste was exposed to the admixture of saline solution containing Sr2+ or Ba2+ cations, whereas it was lowered to 4–5 ± 0.5% in the presence of carbonate or sulfate anions. When the PG is used as an economic fertilizer, the irrigation water can leach 7.8 ± 0.6% of Ra-226 that could contribute to plant uptake, thereby to animal and/or human consumption. The primary tests of the drinking water (well and tap resources) consumed by the populations surround the PG facility showed that the activity concentration of Ra-226 was below the minimum detectable activity.  相似文献   

8.
In present study a turbocharged, medium duty compression ignition engine was alternatively fuelled with biodiesel to investigate the changes in particulate matter composition, relative to that taken with diesel fuel. The engine was operated on an AC electrical dynamometer in accordance with an 8-mode, steady-state cycle. The numbers of particles were estimated through electrical low pressure impactor, while sulfates and trace metals were analyzed by ion chromatography and inductively coupled plasma-atomic emission spectroscopy, respectively. Nitric oxides and nitrogen dioxides were measured separately using SEMTECH-DS. Experimental results revealed that, on account of elevated ratios of nitrogen dioxide to nitrogen oxides, mean accumulation mode particles were 42 % lower with biodiesel. On the other hand, nuclei mode particles were higher with biodiesel, owing to heterogeneous nucleation and accounting for an increase in sulfate emissions up to 8 % with biodiesel as compared to diesel. On the average, trace metal emissions were significantly reduced showing 65–85.4 % reduction rates with biodiesel, relative to its counterpart. Further to this, individual congeners such as iron, calcium, and sodium were the predominant elements of the trace metals emitted from engine. The mean relative decrease in iron and calcium was 89–97.8 and 77.6–87 %, respectively, while the relative rise in sodium was in the range of 29–46 % with biodiesel. Further, elements such as zinc, chromium, and aluminum showed substantial abatement, whereas potassium, magnesium, and manganese exhibited irregular trends on account of variable engine loads and speeds during the various modes of cycle.  相似文献   

9.
Biochar has been considered a safe soil additive to enhance soil fertility and agronomic traits of different crops. This study was conducted to explore the impacts of sugarcane waste straw biochar on soil characteristics and some agronomic traits of okra. The experiment was carried out with four treatments, i.e., control, sugarcane waste straw biochar (10 ton ha?1), farmyard manure (FYM, 10 ton ha?1), and chemical fertilizers (NPK; 120:100:80 kg ha?1) having three replications of each treatment. Soil samples were tested for texture, bulk density, particle density, pH, electrical conductivity (EC), organic matter content, nitrate nitrogen (NO3-N), and extractable-P. The sugarcane waste straw biochar was characterized for plant major nutrient elements. The impact of various treatments was observed on soils and agronomic traits of okra like plant height, fruit size, fruit length, and yield of okra. Results revealed that sugarcane waste straw biochar expressed higher EC value and noticeable amounts of nitrogen (N), phosphorus (P), potassium (K), sulfur (S), and magnesium (Mg). The sugarcane waste straw biochar, in comparison with FYM and NPK, significantly improved the NO3-N, extractable-P, OM and EC of the calcareous soil, and reduced the soil bulk density. Furthermore, plant growth and yield parameters were significantly improved under biochar application over the control, FYM and NPK. Overall, sugarcane waste straw biochar proved to be a good alternative to conventional organic and inorganic fertilizers under calcareous soil conditions.  相似文献   

10.
The removal of colour and organic compounds from vinasses derived from the wine distillery industry was studied using boron-doped diamond-based electrodes and dimensionally stable anodes. The maximum reduction of organic compounds and colour was attained with the use of boron-doped diamond-based electrode after 10 h of operation at a current density of 6.6 mA cm?2. The current efficiency obtained was about 90% with a specific energy consumption (measured in terms of removal of chemical oxygen demand) of 17 kWh kg?1 COD removed. The dimensionally stable anodes were capable of removing 6–47% of the organic material and reached 60% decolourisation but with a lower current efficiency (between 85 and 10%) and much higher specific energy consumption values. The anaerobic digestion of vinasse after 1 h of treatment using boron-doped diamond-based electrode showed an effective mineralisation of the organic matter contained in the sample leading to an increase in methane production during anaerobic digestion.  相似文献   

11.
In the present study, the waste coral was utilized as a source of calcium oxide for transesterification of soybean oil into biodiesel (methyl esters). Characterization results revealed that the main component of the waste coral is calcium carbonate which transformed into calcium oxide when calcined above 700 °C. The Box–Behnken design of experiment was carried out, and the results were analyzed using response surface methodology. Calcination temperature, methanol– soybean oil molar ratio and catalyst concentration were chosen as variables. The methyl ester content (wt%) was response which must be maximized. A second-order model was obtained to predict methyl ester content as a function of these variables. Each variable was placed in the three low, medium and high levels (calcination temperature of 700, 800 and 900 °C; catalyst concentration of 3, 6 and 9 wt%; methanol-to-oil ratios of 12:1, 18:1 and 24:1). The optimum conditions from the experiment were found that the calcination temperature of 900 °C, catalyst concentration of 6 wt% and methanol-to-oil ratio of 12:1. Under these conditions, methyl ester content reached to 100 wt%. The waste catalyst was capable of being reused up to 4 times without much loss in the activity.  相似文献   

12.
Goodenough Spring (Texas, USA) is a large spring near the border of the American state of Texas and the Mexican state of Coahuila, discharging into the international Amistad Reservoir on the river Rio Grande (Rio Bravo). Discharge was routinely measured from 1928 until 1968 to partition the flow of the river between the two countries in accordance with water-use treaties. Samples were analyzed for water-quality parameters in 1967–1968 prior to inundation under 45 m of Amistad Reservoir in 1968. Subsequently, discharge has been estimated indirectly by the International Boundary and Water Commission (IBWC). For the first direct measurements of the spring in 37 years, velocity and cross-sectional measurements were made and water samples collected in the summer of 2005 using advanced self-contained underwater breathing apparatus (SCUBA) techniques. Spring discharge was calculated at 2.03 m3 s–1, approximately one-half of the historical mean of 3.94 m3 s–1. In situ and laboratory analyses of samples for temperature, pH, dissolved oxygen, specific conductance, alkalinity, nitrate-nitrogen, dissolved solids, chloride, sulfate, fluoride, phosphorus, calcium, sodium, potassium, magnesium, and iron showed the water quality to be very good for human consumption and crop irrigation. Measurement values are relatively unchanged from those reported 37 years prior.  相似文献   

13.
Petroleum coke (PC) is a waste by-product generated during the oil upgrading processes by the petroleum industry. The continuing accumulation of large quantities of PC requires the development of innovative strategies for the effective utilization of this carbon-rich material. In this study, PC was used for the removal of naphthenic acids (NAs) and acid-extractable fraction (AEF) from oil sands process-affected water (OSPW), generated during the oil refining process. A systematic study on the adsorption of organic fractions, vanadium leaching from PC, adsorption mechanisms, and the effect of physico-chemical characteristics of the PC on adsorption process was performed. Physico-chemical properties of PC were determined by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy, and Brunauer–Emmett–Teller surface area analysis. AEF and NAs removals of 60 and 75 %, respectively, were achieved at PC dose of 200 g/L after 16 h of contact. FT-IR and TGA analysis of PC suggested the physisorption of organic compounds onto the surface of PC. The calculated mean free energy of adsorption (E < 8 kJ/mol) also indicated the physisorption of organics to the PC surface. The hydrophobic interactions between the NAs and the PC were suggested as the dominant adsorption mechanisms. The vanadium release occurred when PC was mixed with OSPW and vanadium concentration increased with an increase in the PC dose. Speciation analysis indicated that the vanadium leached was predominantly vanadium (V) and insignificant amount of vanadium (IV) was also detected.  相似文献   

14.
Liners are commonly used in engineered waste disposal landfill to minimize the potential contamination of the aquatic environment. The adsorption behavior of Cu(II) from aqueous solution onto clay admixed with various mix ratios of quarry fines was investigated. The amount of Cu(II) adsorption increases with increase in contact time. The copper removal efficiencies of the composite mixture gradually decrease from 94.53 % (raw clay) to 85.59 % (20 % of quarry fines with clay), and appreciable decrease in percent removal 75.61 % was found with 25 % of quarry fines with clay. The kinetic adsorption data were analyzed by pseudo-first-order, pseudo-second-order, Bhattacharya–Venkobachar and Natarajan–Khalaf kinetic models to classify adsorption process mechanisms. Kinetic experimental data were good agreement with pseudo-second-order kinetic model with the degree of fitness of the data (R 2) 0.9999 for the adsorption of Cu(II). The results revealed that quarry fines can be used with optimum of 20 % replacement of natural clay for removal of Cu(II) as a liner material in landfills.  相似文献   

15.
This literature review surveys the previous and current researches on the co-digestion of anaerobic processes and examines the synergies effect of co-digestion with cattle manure. Furthermore, this review also pays attention to different operational conditions like operating temperature, organic loading rate (OLR), hydraulic retention time (HRT), chemical oxygen demand (COD) and volatile solid (VS) removal efficiency and biogas or methane production. This review shows that anaerobic mono-digestion of cattle manure usually causing poor performance and stability. Anaerobic studies were generally performed under mesophilic conditions maintained between 35 and 37 °C. Organic waste loading rate generally ranges from 1 to 6 g VS–COD L?1 day?1 stable condition in anaerobic digester. Generally, studies show that HRT for co-digestion of fruit–vegetables waste and industrial organic waste appears to exceed 20 days. However, the anaerobic co-digestion process is generally operated at HRT of between 10 and 20 days. VS and COD removal efficiency usually reaches up to 90 % due to co-digestion with different type organic waste. Methane–biogas production is generally obtained between 0.1 and 0.65 L CH4–biogas g?1 VS.  相似文献   

16.
The behavior of the Gimpo #2 landfill, which is an active landfill and the largest in Korea, is analyzed using field measurement data obtained from various field instruments installed within the landfill. The data included in this analysis are the leachate head within the landfill, waste load data using soil pressure plate and settlement data from settlement plate on the surface of the waste of each stage fill including the settlement of the soft foundation clay soil. Landfill blocks are selected both near the embankment and in the center area of the landfill. The analysis of the field-monitored data showed that the leachate head increase was negligible near the embankment. It was significant in the central block as the waste loads increase and reached 15 m at the fourth stage of waste disposal. The reason that the leachate head is higher in the central block than near the embankment is due to the long drainage path and the loss of gradient of drain pipes. The range of unit weight of the waste converted from the measurement data of earth pressure cell was 0.91–1.24 t/m3 and the average value was 1.05 t/m3. The values reflect well the waste compositions recently buried in GML #2, since from 1998 the waste disposed in GML #2 did not contain food waste. The magnitude of final settlements that occurred in each stage loading of 5 m thickness in the peripheral block was very close to 120 cm. The settlement rate of the waste by dividing the thickness of waste was 24 %. This rate can be divided into 10 % by waste loading and 14 % by waste decomposition. The delay of settlements is recognized in each waste layer for second and third loading in the central block due to the accumulation of leachate within the landfill.  相似文献   

17.
Treated wastewater is a valuable resource, particularly in countries facing water shortage such as Jordan. Nevertheless, excess nutrients, especially phosphorus, may have detrimental impacts on receiving waterbodies. Treated wastewater in Jordan often exceeds the recommended levels set by the Jordanian Standards for wastewater reuse and discharge. Therefore, it is important to reduce phosphorus loads to acceptable levels before discharge. Biofiltration is a low-cost technology that has shown good potential for wastewater treatment. The performance of biofilters largely depends on the media used. In this study, local sand and sand augmented with biochar prepared from the olive oil processing waste (SBC) were used as filter media for phosphorus removal from clarified secondary treated wastewater. The two media types were tested under different hydraulic and phosphorus loading conditions to simulate shock, flooding, and inundation conditions. The results showed that sand media was more effective in removing phosphorus (90.8 ± 2.6%) than sand amended with biochar (83.3 ± 3.2%). Both media showed resilience under extreme loading conditions. Although phosphorus removal efficiency was negatively affected following the extreme loading events, the observed effects were temporary. The simulated inundation event further showed that the media was able to retain the adsorbed phosphorus. Furthermore, the phosphorus concentration in the effluent remained within the prescribed discharge guidelines at all times.  相似文献   

18.
Adsorptive separation of Pb(II) and Cu(II) using modified waste Lyocell fiber adsorbent was investigated in this research. The waste Lyocell fiber was functionalized through carboxymethylation of the hydroxyl moieties using sodium chloroacetate as modifying agent and was crosslinked with epichlorohydrin to provide water stability. The maximum equilibrium batch uptake in single metal system was 353.45 mg/g for Pb(II) and 98.33 mg/g for Cu(II), according to the Langmuir isotherm model. The adsorption rates were very fast and reached equilibrium within 3 and 5?10 min for Cu(II) and Pb(II), respectively. In competitive binary metal system, the uptake of Cu(II) largely decreased to 38.40 mg/g, and Pb(II) selectivity was observed. Elemental and functional characterization suggested that the adsorption proceeded by ion exchange between the adsorbent and metal ions. In a flow-through column system, adsorption followed by desorption aided in effectively eluting ~260 mg of Pb(II) (out of ~300 mg total adsorbed) from the Pb(II)–Cu(II) binary solution. Finally, the adsorbent was very effective in four successive adsorption–desorption cycles with over 99 % uptake and 94 % desorption efficiencies. The present study may provide an alternative option for waste fiber recycling and could be useful in recovering heavy metal ions from aqueous sources to complement their depleting reserves.  相似文献   

19.
There is an urgent need for characterization of leachate arising from waste disposal to ensure a corresponding effective leachate management policy. Field and laboratory studies have been carried out to investigate the impact of municipal landfill leachate on the underlying groundwater at a site in West Malaysia. The solid waste was disposed of directly onto an unprotected natural soil formation. This situation was made worse by the shallow water table. The hydrochemical composition of groundwater in the vicinity of the site (background) is a dilute mixed cation, bicarbonate water. The high ionic balance error of ~13.5% reveals that the groundwater body underneath the site was a highly contaminated leachate rather than contaminated groundwater. Elevated concentration of chloride (355.48 mg/L), nitrate (10.40 mg/L as NO3), nitrite (14.59 mg/L), ammoniacal-N (11.61 mg/L), sodium (227.56 mg/L), iron (0.97 mg/L), and lead (0.32 mg/L) measured downgradient indicate that the contamination plume has migrated further away from the site. In most cases, the concentration of these contamination indicators, together with the ranges of sodium percentage (66.3–89.9%) and sodium adsorption ratio (10.1–19.7%), were found to be considerably higher than the limit values of safe water for both domestic and irrigation purposes, respectively.  相似文献   

20.
A combined ABR–MBR process consisting of an anaerobic baffled reactor (ABR) combined with an aerobic membrane bioreactor (MBR) treating municipal wastewater was investigated at controlled pH range 6.5–8.5 and at constant temperature 25 ± 1 °C. Total nitrogen (TN), ammonia (NH4 +–N), total phosphorus (TP), and chemical oxygen demand (COD) removal performances were evaluated by analyzing the mechanism for efficient nutrient removal. The results showed that the average removal rates of COD, NH4 +–N, TN, and TP reached 93, 99, 79, and 92 %, respectively, corresponding with the COD, NH4 +–N, TN, and TP effluent of 24 (18–31), 0.4 (0–0.8), 10.6 (8.8–12.9), and 0.31 (0.1–0.5) mg/L under the operational condition of hydraulic retention time (HRT) 7.5 h, recycle ratio 200 %, and dissolved oxygen 3 mg/L. The MBR enhanced NH4 +–N, TN, and TP removal rates of 13, 10, and 18 %, respectively, and the membrane retention reduced TP 0.17 mg/L. The process was able to maintain a stable performance with high-quality effluent. Analysis of the results by fluorescence in situ hybridization showed that the abundance of ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, and phosphorus accumulating organisms as percentages of all bacteria in each compartment was stable. The enriched microorganisms in the system appear to be the main drivers of the process efficient for nutrient removal.  相似文献   

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