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1.
Three types of paramagnetic radiation-induced defects (RID), namely A, A′ (Si-O?-centers) and B (Al-O?-Al center), had been identified in natural kaolinites by means of electron paramagnetic resonance spectroscopy. The A-center, stable at the scale of geological periods, was thought to be of particular relevance to quantify past transits of radionuclides in the geosphere. Alpha radiation being likely the main source of RID in kaolinite, the objective of this paper is to define the role of α-particles on the creation of RID and to test the use of A-centers for an α-dosimetry. Three kaolinites with different crystalline order and containing other clays as impurities were irradiated with He+ ion beams. The radiation dose range (0–750 MGy) was consistent with natural radioactivity in environments from the Earth's surface. Irradiation drastically enhanced the original signals due to RID. An important increase of concentration of the unstable B-center, partly due to unrealistic dose rate provided by accelerator ion beam, was observed from the lower doses. The most stable defects remained of the Atype all along experimental irradiations. The contribution of ancillary phyllosilicates to EPR spectra was negligible. The concentration of the three types of RID was related to radiation doses up to 30 MGy. Dosimetry growth curves for the A-centers exhibited variable efficiencies and saturation levels that were related to the structural order and the chemical purity of the kaolinites: the more ordered and purer the kaolinite, the higher the efficiency and the lower the saturation plateau. Moreover, these results are of geochemical significance: dosimetry based on A-centers could be directly used to quantify past migrations of radioelements in the geosphere, by determination of the naturally-cumulated doses (paleodose) of kaolinites.  相似文献   

2.
伍皓  李小刚  吴晨  夏彧  周恳恳  熊国庆  姚雪婷 《地质论评》2021,67(3):67040008-67040008
为尝试利用锆石来初步探索地球内部铀、钍的丰度，通过搜集秦岭造山带加里东期岩浆岩体锆石U-Th-Pb同位素测年文献，掌握了3件超基性岩、52件基性岩、46件中性岩、90件酸性岩，共计191件样品，6979个（铀含量数据3552个，钍含量数据3427个）锆石定年数据。数据分析指示铀和钍在同一类型岩浆岩锆石中含量均相差悬殊，可在不同类型岩浆岩锆石中富集或亏损，不具有从超基性岩到基性岩到中性岩再到酸性岩总体增加的趋势。在所有样品锆石铀、钍平均值2倍以上的45件高富集样品中的34件呈现“局部长期”分布的特征，表现为：10件在451.0~422.1 Ma期间的以OIB型基性、中基性岩为主的样品约29 Ma时间集中产出在南秦岭大巴山地区，岩浆多来自由HIMU，EMII和EMI三个富集地幔端元组分混合而成的复杂地幔区；24件在495.9~413.6 Ma期间的以I型、S-I型酸性岩为主的样品约82 Ma时间集中产出于北秦岭商丹（商南—丹凤）地区，岩浆可来自地幔、壳幔混合和地壳源区。结合华南金属铀（0价）的发现等前人研究成果初步分析认为，加里东期大巴山和商丹地区可能分别存在地幔柱和大陆型热点，地核中大量铀、钍沿地幔柱和大陆型热点上升致使地幔和地壳局部熔体中铀、钍长期富集，其超高含量可能被熔体中锆石结晶部分记录，这一元素迁移过程可能是两区域产出高锆石铀、钍含量样品和商丹地区生成铀矿的主要原因。支持铀、钍可在地核和地幔柱富集的认识。  相似文献   

3.
Ion microprobe U-Th-Pb isotopic analyses of zircons from a granodioritic orthogneiss from the Napier Complex, Mount Sones, Enderby Land, Antarctica, have identified an unambiguous example of unsupported radiogenic Pb in a 3,950 Ma-old crystal. At one 40 m spot on the crystal an unusually large heterogeneity in Pb content was found, the concentration of radiogenic Pb ranging from 5 to 50 percent higher than could have been generated in 3,950 Ma by radioactive decay of the co-existing U and Th. This relative excess of radiogenic Pb is attributed to Pb gain rather than to U and Th loss because first, the Pb content varied by more than the U or Th contents and secondly, changes in the Pb/U, Pb/Th and Pb isotopic composition correlated directly with changes in the Pb concentration. The individual 207Pb/206Pb apparent ages ranged from 4,000 Ma to 4,145 Ma, all greater than the inferred age of the crystal. A correlation between 207Pb/206Pb and Pb/U shows that the Pb excess has not resulted from recent Pb movement. The spot apparently gained radiogenic Pb about 2,500 Ma ago, at the same time as the majority of the other zircons in the rock suffered substantial Pb loss. The Pb movement occurred in response to a discrete geologic event. Reverse discordance is a phenomenon that must be considered when interpreting zircon U-Pb ages, especially 207Pb/206Pb ages of single crystals or portions of crystals. Decay constants. Ages in this paper are calculated using the decay constant convention recommended by the Subcommission on Geochronology (Steiger and Jaeger 1977).  相似文献   

4.
为尝试利用锆石来初步探索地球内部铀、钍的丰度,通过搜集秦岭造山带加里东期岩浆岩体锆石U-Th-Pb同位素测年文献,掌握了3件超基性岩、52件基性岩、46件中性岩、90件酸性岩,共计191件样品,6979个（铀含量数据3552个,钍含量数据3427个）锆石定年数据。数据分析指示铀和钍在同一类型岩浆岩锆石中含量均相差悬殊,可在不同类型岩浆岩锆石中富集或亏损,不具有从超基性岩到基性岩到中性岩再到酸性岩总体增加的趋势。在所有样品锆石铀、钍平均值2倍以上的45件高富集样品中的34件呈现“局部长期”分布的特征,表现为：10件在451.0~422.1 Ma期间的以OIB型基性、中基性岩为主的样品约29 Ma时间集中产出在南秦岭大巴山地区,岩浆多来自由HIMU,EMII和EMI三个富集地幔端元组分混合而成的复杂地幔区;24件在495.9~413.6 Ma期间的以I型、S-I型酸性岩为主的样品约82 Ma时间集中产出于北秦岭商丹（商南—丹凤）地区,岩浆可来自地幔、壳幔混合和地壳源区。结合华南金属铀（0价）的发现等前人研究成果初步分析认为,加里东期大巴山和商丹地区可能分别存在地幔柱和大陆型热点,地核中大量铀、钍沿地幔柱和大陆型热点上升致使地幔和地壳局部熔体中铀、钍长期富集,其超高含量可能被熔体中锆石结晶部分记录,这一元素迁移过程可能是两区域产出高锆石铀、钍含量样品和商丹地区生成铀矿的主要原因。支持铀、钍可在地核和地幔柱富集的认识。  相似文献   

5.
《Applied Geochemistry》1998,13(6):751-765
The origin of 3 types of point defects (A-, A′- and B-centers) in kaolinite, due to natural irradiation and detected by electron paramagnetic resonance spectroscopy (EPR), has been demonstrated by artificial irradiation. The potential use of tracing the dynamics of the transfer of radionuclides through A-centers (i.e. the most stable centers) was qualitatively tested on different low-temperature alteration systems, some associated with U-concentrations. This paper proposes a quantitative approach to the reconstruction of the past migration of radionuclides by dosimetry of A-centers. With this aim in mind, the efficiency of α- and γ-radiations to produce A-centers was determined by experimental irradiation. Parameters extracted from A-center growth curves, together with their relationship with a parameter describing the degree of order of kaolinite, permitted (i) a definition to be made of the dose range in which a given kaolinite could be used as a dosimeter and (ii) the quantitative derivation of U-concentration from the cumulative dose (paleodose) of kaolinites. This was achieved by a formalism that accounted for the contribution of natural radiosources to the production of A-centers. The formalism was applied to the Nopal I U-deposit (Chihuhua, Mexico), considered as a natural analogue of a high level nuclear waste repository. Irrespective of the scenario considered, in terms of kaolinite age and of degree of isotopic disequilibrium in the system, A-center dosimetry permitted the determination of past occurrences of U which were several orders of magnitude higher than the present-day measured U-concentrations. Furthermore, this approach also provided evidence for several previous episodes of U-migration. EPR spectroscopy is thus a unique tool for the quantitative, indirect assessment of past radionuclide migration in the geosphere and kaolinite is a reliable in-situ dosimeter.  相似文献   

6.
We present the results of a comparative study of several geochronometer minerals (baddeleyite, zircon, apatite, phlogopite and tetraferriphlogopite) and isotopic systems (U-Pb, Th-Pb and Rb-Sr) from phoscorites (magnetite-forsterite-apatite-calcite rocks) and carbonatites of the Kovdor ultramafic-alkaline-carbonatite massif, Kola Peninsula, Russia. Uranium, thorium and their decay products are extremely fractionated by minerals that crystallise from carbonatite and phoscorite magma. We obtain high-precision ages from different chronometers, compare their accuracy, and evaluate the role of geochronological pitfalls of initial radioactive disequilibrium, differential migration of radiogenic isotopes, and inaccurate decay constants.Apatite yielded concordant U-Th-Pb ages between 376 and 380 Ma. The accuracy of the apatite 238U-206Pb ages is, however, compromised by uncertainty in the amount of radiogenic 206Pb produced from initial excess 230Th. The 235U-207Pb ages are relatively imprecise due to large common Pb correction and the uncertainty in the initial Pb isotopic composition. The Th-Pb system yields a more precise age of 376.4 ± 0.6 Ma.Zircon from two carbonatite samples is characterised by moderate to low U contents, high Th contents, and very high Th/U ratios up to 9000. The 206Pb*/238U systems in the zircon are strongly affected by the presence of excess 206Pb*, produced by decay of initial 230Th. The 208Pb*/232Th ages of zircon from both carbonatite samples are uniform and yield a weighted average of 377.52 ± 0.94 Ma.Baddeleyite U-Pb analyses are 3 to 6% normally discordant and have variable 207Pb*/206Pb* apparent ages. Eleven alteration-free baddeleyite fractions from three samples with no evidence for Pb loss yield uniform 206Pb*/238U ages with a weighted average of 378.54±0.23 Ma (378.64 Ma after correction for initial 230Th deficiency), which we consider the best estimate for age of the phoscorite-carbonatite body of the Kovdor massif. The 206Pb*/238U ages of baddeleyite fractions from five other samples spread between 378.5 and 373 Ma, indicating a variable lead loss up to 1.5%. The anomalously old 207Pb/235U and 207Pb/206Pb ages are consistent with the presence of excess radiogenic 207Pb* in the baddeleyite. We interpret this as a result of preferential partitioning of 231Pa to baddeleyite.Fifteen phlogopite and tetraferriphlogopite fractions from five carbonatite and phoscorite samples yielded precise Rb-Sr isochron age of 372.2 ± 1.5 Ma, which is 5 to 7 m.y. younger than our best estimate based on U-Th-Pb age values. This difference is unlikely to be a result of the disturbance or late closure of Rb-Sr system in phlogopite, but rather suggests that the accepted decay constant of 87Rb is too high.Comparative study of multiple geochronometer minerals from the Kovdor massif has revealed an exceptional complexity of isotopic systems. Reliable ages can be understood through systematic analysis of possible sources of distortion. No single geochronometer is sufficiently reliable in these rocks. Th-Pb and Rb-Sr can be a very useful supplement to U-Pb geochronometry, but the routine use of these geochronometers together will require more precise and accurate determination of decay constants for 232Th and 87Rb.  相似文献   

7.
内蒙古中部苏尼特左旗地区大石寨组酸性火山岩SHRIMP锆石U-Pb测年结果显示,2件流纹岩样品的206Pb/238U年龄加权平均值分别为272.1±3.1Ma和271.4±1.7Ma,说明大石寨组流纹岩喷发于早二叠世。锆石Hf同位素分析结果表明,εHf(t)值为+10.8~+13.1;Hf-Nd同位素耦合关系计算显示,其与同期形成的大石寨组玄武岩Nd同位素组成特点非常相似。全岩地球化学分析表明,该流纹岩高Si O_2,贫Ca O、Fe_2O_3*和Mg O,大部分样品属于过铝质、钙碱性流纹岩;富集轻稀土元素,轻、重稀土元素分馏中等,具明显的负Eu异常,富集Cs、Rb、Th、U和Zr,亏损Ba、Sr、Nb、Ta、P和Ti,指示其是富水的钙碱性基性地幔岩浆分离结晶作用的产物。结合区域地质资料,认为苏尼特左旗流纹岩形成于大陆岛弧背景。  相似文献   

8.
毕力赫金矿位于中亚造山带东南段华北克拉通北缘白乃庙早古生代弧增生杂岩带内,该矿床为一个斑岩型矿床,成矿岩体为早中二叠世花岗闪长岩。文中对成矿岩体进行了主微量元素地球化学以及锆石U-Pb年代学和Lu-Hf同位素研究。毕力赫花岗闪长岩具有安第斯型陆缘弧岩浆岩的地球化学亲缘性：岩体SiO2含量(质量分数)介于61.3%~64.4%,K2O/Na2O值介于0.52~0.87,A/CNK值介于0.82~0.95,属准铝高钾钙碱性系列岩石;岩体相对富集Rb、Th、U等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti等高场强元素和重稀土元素,显示负Eu异常(δEu=0.50~1.03)。岩体浅部(zk086-53)与深部(zkI005-105)两个样品的锆石206Pb/238U加权平均年龄分别为(268.1±1.8) Ma(MSWD=1.17,1σ)和(267.7±4.1) Ma(MSWD=1.06,1σ);继承锆石除外,样品中锆石εHf(t)值分别为3.2~8.7和-0.6~8.3,二阶段模式年龄TDM2分别为1 085~737 Ma和1 330~762 Ma。成矿岩体可能源于洋壳俯冲脱水导致的新生地壳部分熔融而产生的底侵中基性岩浆与由底侵导致的古老基底物质部分熔融形成的长英质岩浆的混合。  相似文献   

9.
塔里木北部二叠纪长英质火山岩年代学及地球化学特征   总被引：5，自引：2，他引：3  
大面积分布于塔里木盆地的二叠纪玄武岩构成了面积250000km2的大火成岩省(LIP),长英质火山岩的发现为塔里木二叠纪火山作用的研究打开了新的窗口。本文从塔北地区约5000m深的钻井中收集了4件二叠纪长英质火山岩的样品。通过对其进行锆石U-Pb同位素测试,得出其形成时代为274~282Ma,为塔里木大火成岩省晚期岩浆作用的产物。岩石具有高钾的特征K2O+Na2O=7.29%~8.34%,K2O/Na2O>1,大部分属于高钾钙碱性系列,且属于过铝质(A/CNK=1.32~1.53)。具有富集LREE和Zr、Hf、Y,亏损Sr、P、Ti、Nb、Ta等特征,微量元素分布曲线形态与地壳相近,具有右倾的稀土元素配分曲线,且显示出一定的负铕异常。通过Sr-Nd-Pb同位素的分析得出其源区有大量地壳物质,这与其具有较高的Th、U含量和与地壳平均值相似的Nb/La、Nb/U、Th/Ta相一致。综合年代学、地球化学特征及构造环境的判断,认为塔北地区二叠纪长英质火山岩形成于地幔柱活动背景下的地壳物质的部分熔融。  相似文献   

10.
目前应用LA-MC-ICPMS分析熔体包裹体Pb同位素,由于没有同时测试U和Th的信号,导致熔体包裹体Pb同位素的研究仅局限于中生代以来的样品。本文应用LA-MC-ICPMS分析了玻璃样品以及存在显著U-Th衰变影响的古老熔体包裹体的Pb同位素组成,评价了U/Pb和Th/Pb分析误差对初始Pb同位素比值校正的影响。实验中以国际玻璃标样NKT-1G为外部标样,采用"标样-样品-标样法"进行仪器漂移和质量歧视校正,结果表明,国际玻璃标样BHVO-2G、TB-1G的208Pb/206Pb和207Pb/206Pb分析精度优于0.30%(2RSD),与推荐值的偏差小于0.30%,然而232Th/206Pb和238U/206Pb分析结果显示了较大分散性(外精度约5.0%)。根据误差传递计算,样品的年龄对初始铅的误差有很大影响。对于古生代以来的样品(年龄小于540 Ma),即使测试的232Th/206Pb和238U/206Pb与真值偏差达到10%,经过U-Th衰变校正后的Pb同位素比值与真值的偏差依然小于0.80%。因此本方法可以将熔体包裹体等地质样品的Pb同位素研究由新生代样品(年龄小于65 Ma)扩展到古生代样品。  相似文献   

11.
ABSTRACT

This article presents new zircon U–Pb geochronology, Hf isotopic, and whole-rock major- and trace-element geochemical data that provide insights into the petrogenesis and tectonic history of the Riwanchaka granodiorite porphyries of Central Qiangtang, Tibet. Zircon U–Pb ages of 236–230 Ma indicate an early Late Triassic age of emplacement of the porphyries, and zircon Hf isotopic data yield εHf(t) values of – 7.0 to – 1.5 and ancient zircon Hf crustal model ages (TDMC) of 1524–1220 Ma. The granodiorite porphyries are characterized by low K2O contents, high Mg# values, and relatively high Cr and Ni contents. They are classified as I-type calc-alkaline granite and are considered to have formed through the anatexis of ancient mafic crustal rocks with contributions from mantle-derived components. The geochemistry and isotopic compositions of all samples are similar to those of magmatic rocks that originated in the South Qiangtang crust. However, field observations indicate that the pluton intrudes the North Qiangtang crust, and we propose that the granodiorite porphyries were derived by partial melting of subducted continental crust of the South Qiangtang terrane. These new data have been integrated with data from previous studies to construct a new model of slab rollback during northward subduction of the Southern Qiangtang continental crust at ca. 245–226 Ma, thereby improving our understanding of magmatic processes involved in continental subduction in collision settings.  相似文献   

12.
阿尔金奇克山地区侵入于地层中的斜长角闪岩原岩为辉长岩,岩石地球化学组成显示斜长角闪岩的SiO_2和Al_2O_3含量较高为49.29%~51.03%和12.27%~14.49%,Na_2O+K_2O含量低为2.35%~4.37%,MgO和Mg~#值为6.48%~10.12%和48.7~59.6,具Eu负异常,样品的MgO对SiO_2、Al_2O_3、TiO_2及Cr-Rb和Rb/Nb-Rb/Zr关系图显示明显相关性,表明其为地幔岩浆经分异演化形成。岩石富集Rb、Th和U,亏损Nb、Sr和P,且Th/Ta为1.05~2.771,Nb/La为0.88~1.02,多小于1,显示岩石在演化过程中受到了地壳轻微混染,推断岩石形成于板内伸展环境。利用LA-ICP-MS微区原位定年获得斜长角闪岩~(206)Pb/~(238)U-~(207)Pb/~(235)U谐和年龄503±5 Ma和~(206)Pb/~(238)U加权平均年龄为479±6 Ma,该年龄段为阿尔金峰期变质阶段,指示岩石形成于479 Ma以前。  相似文献   

13.
Detailed geochemical mapping of superficial lateritic formations is compared with recent high-resolution SPOT satellite images in the Dagadamou prospect in southern Mali.The two main landscape features standing out in SPOT images are expressed by thematic indices derived from multispectral data. They reflect the distribution of vegetation cover and the distinction between silty clay soils in the valleys and ferruginous duricrust exposed on the plateaus. Geochemical differentiation factors are closely related to the nature of sampled materials and reflect the relative amounts of major constituent minerals estimated by normative calculation.Duricrust samples with high Fe and Al content are also enriched in trace elements, P, V, Cr, As, Mo, Nb and Cu, immobilized in the weathering profile with secondary oxihydroxide minerals.Soils of flats are composed mainly of quartz and kaolinite; they also concentrate heavy minerals characterized by high contents of Zr, Ti, Ce and Y.Accumulation of detrital material at the periphery of duricrust plateaus is marked by a geochemical halo of higher contents in Zr and quartz at their periphery. This feature is clearly visible on SPOT imagery as a zone of high reflectance, devoid of vegetation.The density of vegetation on duricrust is related to its kaolinite content. Its distribution is characterized by a striped pattern, which is probably controlled by bedrock lithological structures preserved in the lateritic cover.This study shows the relationships, both direct and indirect, existing between spectral reflectance and geochemical composition of superficial lateritic formations. Many other landscape features identified with high resolution on SPOT images provide complementary information, which could be very helpful at various stages of geological and mineral exploration in lateritic terrain.  相似文献   

14.
Abstract

The Jurassic–Cretaceous Great Artesian Basin is the most extensive, and largest volume, sedimentary feature of continental Australia. The source of its mud-dominated Cretaceous infill is attributed largely to contemporary magmatism along the continental margin to the east, but the source of its Jurassic infill, dominated by quartz sandstone, remains unconstrained. This paper investigates the question of a Jurassic sediment source for the northern part of the basin. Jurassic uplift and exhumation of the continental margin crustal sector to the east provided the primary Jurassic sediment source. (U–Th)/He data are presented for zircon and apatite from Pennsylvanian to mid Permian granitoids of the Kennedy Igneous Association distributed within the northern Tasmanides between the Townsville and Cairns regions and for coeval granites of the Urannha batholith from the Mount Carlton district (N Bowen Basin), also within the northern Tasmanides. The data from zircon indicate widespread Jurassic exhumation of a crustal tract located to the east of the northern Great Artesian Basin and largely occupied by rocks of the Tasmanides. Detrital zircon age spectra for samples of the Jurassic Hutton and Blantyre sandstones from the northeastern margin of the Great Artesian Basin show their derivation to be largely from rocks of the northern Tasmanides. In combination, the detrital age spectra and (U–Th)/He data from zircon indicate exhumation owing to uplift generating appreciable physiographic relief along the north Queensland continental margin during the Jurassic, shedding sediment westward into the Great Artesian Basin during its early development. A portion of (U–Th)/He data for zircon are consistent with late Permian–mid Triassic exhumation within the Tasmanides, attributable to the influence of the Hunter--Bowen Orogeny. Evidence of Cretaceous and Paleocene exhumation episodes is also indicated for some samples, mainly by apatite (U–Th)/He analysis, consistent with data previously published from fission track studies. Overall, new data from the present study reveal that the exhumation related to Jurassic regional uplift and the subsequent erosional reworking of the northeast Australian continental margin is critical for the evolution and development of the northern side of the Great Artesian Basin in eastern Australia. Apart from this, another two previously suggested Permian–Triassic and Cretaceous exhumation and uplift episodes along the northeast Australian continental margin are also confirmed by the dataset of this study.
  1. KEY POINTS

  2. U–Pb detrital zircon ages of sandstone samples from the northeastern Eromanga Basin reveal Paleozoic (480–280 Ma) and Proterozoic (1800–1400 Ma) age clusters.

  3. (U–Th)/He zircon and apatite dating results of granitoids samples from Cairns, Townsville and the Mount Carlton districts are dominated by Jurassic (198–164 Ma) and Permian–Triassic (272–238 Ma) age clusters.

  4. Combination of above two datasets proves the regional uplift-driving Jurassic exhumation episode in the northeast Australian continental is vital for the development of the northern Great Artesian Basin.

  相似文献   

15.
《Geochimica et cosmochimica acta》1999,63(23-24):4013-4035
The effect of organic matter during soil/water interaction is still a debated issue on the controls of chemical weathering in a tropical environment. In order to study this effect in detail, we focused on the weathering processes occurring in a small tropical watershed (Nsimi-Zoetélé, South Cameroon). This site offers an unique opportunity to study weathering mechanisms in a lateritic system within a small basin by coupling soil and water chemistry.The lateritic cover in this site can reach up to 40 m in depth and show two pedological distinct zones: unsaturated slope soils on the hills and/or elevated areas; and water-saturated soils in the swamp zone which represent 20% of the basin surface. The study present chemical analysis performed on water samples collected monthly from different localities between 1994–1997 and on soil samples taken during a well drilling in December 1997. The results suggest the existence of chemical and spatial heterogeneities of waters in the basin: colored waters flooding the swamp zone have much higher concentrations of both organic matter (i.e., DOC) and inorganic ions (e.g., Ca, Mg, Al, Fe, Th, Zr) than those from springs and groundwater from the hills. Nevertheless, these organic-rich waters present cation concentrations (Na, Ca, Mg, K) which are among the lowest compared to that of most world rivers. The main minerals in the soils are secondary kaolinite, iron oxi-hydroxides, quartz, and accessory minerals (e.g., zircon, rutile). We mainly focused on the mineralogical and geochemical study of the swamp zone soils and showed through SEM observations the textural characterization of weathered minerals such as kaolinite, zircon, rutile, and the secondary recrystallization of kaolinite microcrystals within the soil profile. Water chemistry and mineralogical observations suggest that hydromorphic soils of the swamp zone are responsible for almost all chemical weathering in the basin. Thus, in order to explain the increase of element concentration in the organic-rich waters, we suggest that organic acids enhance dissolution of minerals such as kaolinite, goethite, and zircon and also favors the transport of insoluble elements such as Al, Fe, Ti, Zr, and REE by chemical complexation. SiO2(aq) concentrations in these waters are above saturation with respect to quartz. Dissolution of phytholithes (amorphous silica) may be responsible for this relatively high SiO2(aq.) concentration. Al/Mg ratios obtained for the soil and the Mengong river waters show that a significant amount of Al does not leave the system due to kaolinite recrystallisation in the swamp zone soils. Geochemical data obtained for this watershed show the important contribution of vegetation and organic matter on chemical weathering in the swamp zone. Quantitatively we propose that the increasing amount in total dissolved solid (TDS) due to organic matter and vegetation effect is about 35%. In summary, this interaction between soils and waters occurs mostly in soils that are very depleted in soluble elements. Thus, the low concentration of major elements in these water is a direct consequence of the depleted nature of the soils.  相似文献   

16.
LA-MC-ICP-MS独居石微区原位U-Pb同位素年龄测定   总被引：7，自引：0，他引：7  
独居石富含U、Th, 同时具有较低的初始普通Pb含量, 是U-Pb和Th-Pb同位素定年的理想对象。由于普遍存在于多种岩石中, 独居石的U-Th-Pb定年具有广阔的应用前景。本文报道利用193 nm ArF准分子激光剥蚀系统和NEPUNE多接收器电感耦合等离子体质谱仪, 对独居石进行微区原位U-Pb同位素年龄测定的新方法。运用这一新方法对独居石样品AL01、BL02和CL03进行微区原位U-Pb同位素年龄测定, 获得AL01和BL02号样品的206Pb/238U年龄加权平均值分别为(288.3±1.1) Ma (n=19)和(446.8±2.3) Ma (n=41); CL03号样品的U-Pb等时线年龄为(396.8±8.8) Ma (n=55), 取得了令人满意的结果。  相似文献   

17.
Nepheline-bearing gneisses from the 75 km2 Tambani body in the Mozambique Belt of southern Malawi, are miaskitic biotite-nepheline monzodiorites, reflecting an absence of K-feldspar, alkali amphiboles or pyroxenes, and contain euhedral zircon megacrysts up to 5 cm across. The zircons contain U = 1–1,860 ppm, Th = 0–2,170 ppm and Y = 400–1,100 ppm, and very low concentrations of all other measured trace elements except Hf (HfO2 = 0.53–0.92 wt. %). Cathodoluminescence images reveal oscillatory sector growth zoning and no evidence for xenocrystic cores, indicating that the zircons represent primary magmatic crystallization products that have survived amphibolite grade metamorphism. U-Pb isotopic analyses (by TIMS) yield an upper intercept age of 730 ± 4 Ma (MSWD = 1.7), which we interpret as the time of magmatic crystallization of the zircons. This is coincident with 11 SHRIMP spot analyses, which yield a mean age of 729 ± 7 Ma (MSWD = 0.37). Metamorphism, at 522 ± 17 Ma as suggested by monazite, caused partial Pb-loss during local recrystallization of zircon. Lu-Hf isotopic data for three whole-rock samples of nepheline-bearing gneiss are collinear with those for zircon megacrysts, and correspond to an age of 584 ± 17 Ma (MSWD = 0.37. We interpret the Lu-Hf array to represent a mixing line defined by the Hf isotopic signature of primary zircon and that of the rock-forming minerals reset during metamorphic (re-)crystallization; hence the 584 Ma age is likely geologically meaningless. Given the well-defined association of nepheline syenites (and phonolitic volcanic equivalents) with continental rifting, we suggest that the Tambani body represents a magmatic product formed at 730 Ma during the break-up of the Rodinia supercontinent. The 522 Ma age is akin to other Pan-African metamorphic ages that record collisional suturing events during the final assembly of Gondwana. Zircon-bearing nepheline gneisses thus preserve a record of intra-continental rifting and of continental collision in southern Malawi.  相似文献   

18.
The Qinling–Dabie–Sulu belt is the world's largest ultrahigh pressure (UHP) metamorphic belt. The UHP metamorphism is well dated at 220–245 Ma in the Dabie–Sulu belt but at 507 Ma in the Qinling belt. The Tongbaishan is located between the Qinling orogenic belt to the west and the Dabie–Sulu UHP metamorphic belt to the east. It is the key area for studying the tectonic relation between the Qinling and Dabie–Sulu belts and the diachronous UHP metamorphism. The Jigongshan granitic pluton (t=128 Ma) with a total area of 1200 km2, composed of monzogranite, was mostly emplaced into the Tongbai complex, an exposed basement in the Tongbaishan. The Jigongshan granites have SiO2=69.85–72.35%, K2O/Na2O=0.87–1.13, A/CNK=0.91–1.03, Rb/Sr=0.14–0.25 and Th/U=3.3–12. Their REE compositions show strongly fractionated patterns with (La/Yb)N=14–58 and Eu*/Eu=0.79–1.05. The granites are characterized by low radiogenic Pb isotopic composition. The present-day whole-rock Pb isotopic ratios are 206Pb/204Pb=16.707–17.055, 207Pb/204Pb=15.239–15.326 and 208Pb/204Pb=37.587–37.853, which are similar to that of the continental lower crust. Their Nd(t) values range from −16 to −20, and depleted-mantle Nd model ages (TDM) from 1.8 to 2.2 Ga. The above evidence indicates that the magma of the Jigongshan granites was derived from the partial melting of the continental crust. The Pb and Nd isotopic compositions of the Jigongshan granites resemble those of the Dabie core complex in the Dabieshan but are distinct from those of the Tongbai complex in the Tongbaishan. Thus, the Dabie core complex would be the magma source of the Jigongshan granites. The result implies that the Dabie core complex is extended to the west and constitutes the unexposed basement underlaying the Tongbai complex in the Tongbaishan.  相似文献   

19.
滇中玉溪—昆阳一带广泛出露的中元古界昆阳群是一套与晋宁运动密切相关的浅变质火山-沉积岩系,其形成时代、沉积充填序列及大地构造属性一直存在争议。出露于峨山县美党地区的昆阳群黑山头组富良棚段发育有厚近百米的安山质熔结凝灰岩、晶屑凝灰岩、玄武岩及岩屑凝灰岩。对样品D0121-1及D0121-2进行同位素年代学研究,分别获得LA-ICP-MS锆石U-Pb年龄加权平均值为1007±13Ma和1005±18Ma;同时,样品D0121-2中还获较多的2200±15Ma继承性锆石,推测滇中地区应存在古元古代的地质体。2件样品锆石的Th/U值均大于0.3,均具清晰的振荡环带结构,均为岩浆成因的锆石,表明黑山头组富良棚段形成于中元古代晚期,属于与造山作用相关的火山岩系,可能是罗迪尼亚超大陆事件在扬子陆块的响应,是全球格林维尔期造山过程的组成部分。  相似文献   

20.
金柳滩韧性剪切带位于北祁连构造带东端山门镇,是陇山岩群与葫芦河岩群拼贴的构造边界.通过陇山岩群的黑云角闪斜长片麻岩和金柳滩韧性剪切带内的花岗质糜棱岩LA-ICP-MS锆石U-Pb定年分析发现:陇山岩群的黑云角闪斜长片麻岩形成于461.9±7.0 Ma;金柳滩韧性剪切带内的花岗质糜棱岩获得了～460 Ma,～420 Ma...  相似文献   

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