共查询到20条相似文献，搜索用时 15 毫秒
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Denis Lavoie Nicolas Pinet Mathieu Duchesne Andrée Bolduc Richard Larocque 《Marine and Petroleum Geology》2010
Nearly 2000 pockmarks with diameters ranging from a few tens of meters up to 700 m are present on the seafloor of the St. Lawrence Estuary in eastern Canada. Coring of some pockmarks resulted in the recovery of various-sized and shaped carbonate concretions in a predominantly silty mud matrix. Petrographic and geochemical data on four authigenic carbonate concretions are reported as well as data from shell material in the unconsolidated sediment. Video observations and echo-sounder images indicate that the sampled pockmarks are actively gas venting. The video images show significant look-alike microbial mats in areas where gas is venting. The carbonate concretions are primarily made up of carbonate cements with varying percentage of shell fragments, micrite particles and fine-grained clastics. Orthorhombic crystal morphology and diagenetic fabrics including isopachous layers and botryoids characterize the aragonite cement. Oxygen isotopes ratios for the cement crusts do not record any thermal anomaly at the site of precipitation with δ18OVPDB ratios (+3‰) in equilibrium with cold (5 °C) deep marine waters, whereas significant negative δ13CVPDB ratios (−9.9 to −33.5‰) for cement and shell material within concretions indicate that the carbonates largely derive from the microbial oxidation of methane. The δ13CVPDB ratios of aragonite shells (−2.7 to −5.6‰) taken from unconsolidated sediments at some distance from the concretions/vents show variable dilution of HCO3− with negative δ13CVPDB ratios derived from microbial oxidation of methane with isotopically normal (0‰) marine bicarbonate. These results are in agreement with other lines of evidence suggesting that pockmarks formed through the recent and still active release of gas from a reservoir within the Paleozoic sedimentary succession. 相似文献
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Mollusk shells contain many isotopic clues about calcification physiology and environmental conditions at the time of shell formation. In this review, we use both published and unpublished data to discuss carbon isotopes in both bivalve and gastropod shell carbonates. Land snails construct their shells mainly from respired CO2, and shell δ13C reflects the local mix of C3 and C4 plants consumed. Shell δ13C is typically >10‰ heavier than diet, probably because respiratory gas exchange discards CO2, and retains the isotopically heavier HCO3 ?. Respired CO2 contributes less to the shells of aquatic mollusks, because CO2/O2 ratios are usually higher in water than in air, leading to more replacement of respired CO2 by environmental CO2. Fluid exchange with the environment also brings additional dissolved inorganic carbon (DIC) into the calcification site. Shell δ13C is typically a few ‰ lower than ambient DIC, and often decreases with age. Shell δ13C retains clues about processes such as ecosystem metabolism and estuarine mixing. Ca2+ ATPase-based models of calcification physiology developed for corals and algae likely apply to mollusks, too, but lower pH and carbonic anhydrase at the calcification site probably suppress kinetic isotope effects. Carbon isotopes in biogenic carbonates are clearly complex, but cautious interpretation can provide a wealth of information, especially after vital effects are better understood. 相似文献
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Seismic characterization of Eocene-Oligocene heterozoan carbonate strata from the Browse Basin, Northwest Shelf of Australia, defines marked progradation of nearly 10 km. Stratal terminations and stacking subdivide the succession into mappable seismic units. Stratal architecture and seismic geomorphology varies systematically through the succession.Individual surfaces, discerned by toplap, onlap, and truncation, outline sigmoidal to tangential oblique clinoforms with heights of ranging from 350 to 650 m and maximum gradients between 8 and 18°. Sigmoidal clinoforms can include aggradation in excess of ∼200 m, prograde more than 500 m, and have slopes characterized by inclined, wavy to discontinuous reflectors that represent ubiquitous gullies and channels. In contrast, the overlying tangential oblique clinoforms include downstepped shelf margins, limited on-shelf aggradation (<100 m) and toplap, subdued progradation (<500 m), and continuous parallel inclined reflectors on the slope. Wedges of basinally restricted reflectors at toe of slope onlap surfaces of pronounced erosional truncation or syndepositional structural modification. The succession includes repeated patterns of seismic units that onlap, aggrade, and prograde, interpreted to represent sequence sets and composite sequences.The associations of shelf aggradation, shelf-margin progradation, and slope channeling within sigmoidal seismic units and the less marked progradation and channeling within tangential oblique seismic units contrast with the classic sequence model in which sediment delivery to the slope and pronounced progradation is favored by limited shelf accommodation. This distinct divergence is interpreted to reflect the prolific heterozoan production across the shelf during periods of rising and high base level when the shelf is flooded, perhaps enhanced by downwelling. Comparison with purely photozoan systems reveals similarities and contrasts in seismic stratigraphic heterogeneity and architecture, interpreted to be driven by distinct characteristics of heterozoan sedimentary systems. 相似文献
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Extensive areas of methane-derived authigenic carbonate (MDAC) have been mapped in the Irish Sea. In the Irish Sector, 23
seabed mounds associated with the Codling Fault Zone were identified by multi-beam echo sounder mapping. Inspection by ROV-mounted
video showed that these mounds are rocky features rising 5–10 m above the normal seabed; sampling showed that they are comprised
of quartz grains bound together by carbonate cement, probably MDAC. Two separate locations have been mapped in the UK Sector.
At Texel 11, seabed mounds and a 6–8 m high cliff were mapped geophysically (MBES, SSS and seismic profiler surveys). Video
surveys showed that both the mounds and the cliff are rocky reefs colonised by a prolific fauna. Samples proved to be carbonate-cemented
sediments, and carbon isotope analysis (δ13C −41 to −46% PDB) showed that the cement was MDAC. Similar surveys of the Holden’s Reefs area proved the presence of similar
rocky reefs which are also cemented by MDAC. The total area covered by these two MDAC occurrences is estimated to be >500,000 m2. These MDAC occurrences are comparable in nature and formation to the ‘bubbling reefs’ of the Kattegat. As the bubbling reefs
are “seabed features formed by leaking gas”, one of the marine habitats identified by the European Commission’s Habitats Directive
as being sensitive and worthy of protection, it is suggested that the Irish Sea carbonate reefs should also be considered
as special habitats. 相似文献
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Authigenic carbonates are frequently associated with methane cold-seep systems, which extensively occur in various geologic settings worldwide. Of interest is the relation between the fluids involved in their formation and the isotopic signals recorded in the carbonate cements. Along the Northern Apennines foothills (Italy), hydrocarbons and connate waters still seeping nowadays are believed to be the primary sources for the formation of fossil authigenic carbonate found in Plio-Pleistocene marine sediments. Four selected outcrops of dolomitic authigenic carbonates were analysed to compare signature of seeping fluids with fractionation of stable carbon and oxygen isotopes recorded in the carbonate.Along the foothills, deep methane-rich fluids spontaneously rise to the surface through mud volcanoes or are exploited in wells drilled nearby to the fossil Plio-Pleistocene authigenic carbonates. The plumbing system providing fluids to present-day cold seeps was structurally achieved in Late Miocene and Plio-Pleistocene. δ13C values of methane, which vary from −51.9 to −43.0‰ VPDB, indicate that gas composition from the deep hydrocarbon reservoirs is relatively uniform along the foothills. On the contrary, δ13C in fossil authigenic carbonates strongly varies among different areas and also within the same outcrop.The different carbon sources that fed the investigated carbonates were identified and include: thermogenic methane from the deep Miocene reservoirs, 13C-enriched CO2 derived from secondary methanogenesis and microbial methane from Pliocene successions buried in the Po Plain. The δ13C variability documented among samples from a single outcrop testifies that the authigenic carbonates might represent a record of varying biogeochemical processes in the hydrocarbon reservoirs. The sources of stable oxygen isotopes in authigenic carbonates are often ascribed to marine water. Oxygen isotopic fractionation in the dolomite cements indicates that marine pore water couldn't be the sole source of oxygen. δ18O values provide a preliminary evidence that connate waters had a role in the carbonates precipitation. The concomitant occurrence of active cold seepages and fossil record of former plumbing systems suggests that generation and migration of hydrocarbons are long-lasting and very effective processes along the Northern Apennines foothills. 相似文献
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The Upper Cretaceous carbonates cropping out in the Murge Plateau are good analogues of the fractured and faulted carbonate oil reservoirs of southern Italy. For this reason, a detailed field analysis focused on structural architecture of fault and fracture networks has been carried out in the Murge Plateau. The well-bedded carbonates exposed there are crosscut by a set of bed-parallel stylolites and two sets of bed-perpendicular cross-orthogonal joints/veins. These structural elements were likely formed under vertical loading during burial diagenesis and flexure of the Apulian foreland of the Southern Apennines fold-and-thrust belt. Bed-parallel stylolites and bed-perpendicular cross-orthogonal joints/veins represent the background deformation that was overprinted by the fault-related localized deformation. The fault sets documented in the study area are arranged in two kinematically-compatible fault networks. The first one is made up of WNW-ESE and NNW-SSE oriented strike-slip faults, right- and left-lateral, respectively, and NW–SE oriented normal faults. The second fault network consists of WNW-ESE oriented left-lateral strike-slip faults, and NE–SW oriented normal faults.First, both architecture and dimensional parameters of the fault and fracture networks have been characterized and computed by means of statistical analysis. Then, the permeability structures associated to the aforementioned networks have been assessed in order to determine the role exerted by fault architecture and dissolution/cementation processes on the fluid storage and migration pathways within the studied platform carbonates. Network 1 faults show a quite variable fluid behavior, in which the fluid flow is strongly affected by inherited structural elements and karst dissolution, whereas network 2 faults show a more uniform, fluid conduit behavior. 相似文献
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Stable carbon isotope values of authigenic carbonate rocks in the Miocene terrigenous sediments of Piedmont indicate a methane-related origin. Some of these methane-derived carbonates (Lucina limestone) are characterized by the presence of abundant lucinid remains. Carbonate dissolution/precipitation and development of lucinid communities were related to bacterial methane oxidation, both aerobic and anaerobic. Anaerobic oxidation led to carbonate precipitation and production of sulfide, which sustained lucinid communities through chemosynthetic symbiotic bacteria. Aerobic oxidation of methane likely resulted in dissolution of carbonate skeletal grains. Several phases of carbonate precipitation, characterized by slightly different isotopic compositions, are recognizable in the limestones. 相似文献
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通过分析研究琼东南盆地北部边缘三亚组碳酸盐岩稀土元素地球化学特征,结果表明：稀土元素含量低于1μg／g,呈明显的Ce负异常特征;沉积物沉积于氧化环境;垂向上Ce异常的波动曲线与海平面升降的变化曲线相一致。 相似文献
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Catherine Pierre Marie-Madeleine Blanc-Valleron Jér?me Demange Omar Boudouma Jean-Paul Foucher Thomas Pape Tobias Himmler Noemi Fekete Volkhard Spiess 《Geo-Marine Letters》2012,32(5-6):501-513
The southwest African continental margin is well known for occurrences of active methane-rich fluid seeps associated with seafloor pockmarks at water depths ranging broadly from the shelf to the deep basins, as well as with high gas flares in the water column, gas hydrate accumulations, diagenetic carbonate crusts and highly diverse benthic faunal communities. During the M76/3a expedition of R/V METEOR in 2008, gravity cores recovered abundant authigenic carbonate concretions from three known pockmark sites—Hydrate Hole, Worm Hole, the Regab pockmark—and two sites newly discovered during that cruise, the so-called Deep Hole and Baboon Cluster. The carbonate concretions were commonly associated with seep-benthic macrofauna and occurred within sediments bearing shallow gas hydrates. This study presents selected results from a comprehensive analysis of the mineralogy and isotope geochemistry of diagenetic carbonates sampled at these five pockmark sites. The oxygen isotope stratigraphy obtained from three cores of 2–5?m length indicates a maximum age of about 60,000–80,000?years for these sediments. The authigenic carbonates comprise mostly magnesian calcite and aragonite, associated occasionally with dolomite. Their very low carbon isotopic compositions (–61.0?<?δ13C ‰ V-PDB?<?–40.1) suggest anaerobic oxidation of methane (AOM) as the main process controlling carbonate precipitation. The oxygen isotopic signatures (+2.4?<?δ18O ‰ V-PDB?<?+6.2) lie within the range in equilibrium under present-day/interglacial to glacial conditions of bottom seawater; alternatively, the most positive δ18O values might reflect the contribution of 18O-rich water from gas hydrate decomposition. The frequent occurrence of diagenetic gypsum crystals suggests that reduced sulphur (hydrogen sulphide, pyrite) from sub-seafloor sediments has been oxidized by oxygenated bottom water. The acidity released during this process can potentially induce the dissolution of carbonate, thereby providing enough Ca2+ ions for pore solutions to reach gypsum saturation; this is thought to be promoted by the bio-irrigation and burrowing activity of benthic fauna. The δ18O–δ13C patterns identified in the authigenic carbonates are interpreted to reflect variations in the rate of AOM during the last glacial–interglacial cycle, in turn controlled by variably strong methane fluxes through the pockmarks. These results complement the conclusions of Kasten et al. in this special issue, based on authigenic barite trends at the Hydrate Hole and Worm Hole pockmarks which were interpreted to reflect spatiotemporal variations in AOM related to subsurface gas hydrate formation–decomposition. 相似文献
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This paper presents a detailed seismic analysis of a hitherto undescribed Permian succession interpreted to consist of interbedded anhydrite and carbonate from the northern flank of the Loppa High, western Barents Sea. The Fafner succession forms a locally restricted transgressive unit down-dip on the rotated Loppa High. It is subdivided into four seismic sequences each interpreted to be composed of a basal transgressive anhydrite overlain by highstand carbonates. Fafner seismic sequences 2 and 3 include well-developed buildup complexes which in map view form polygonal patterns.Analysis of attribute maps indicates that the Fafner succession is overprinted by two dissolution systems related to two prominent events of subaerial exposure, creating numerous paleo-sinkholes, breccia-pipes, and collapsed composite cavern systems.The stratigraphical position of the Fafner succession, below the Mid Sakmarian – Artinskian Bjarmeland Group and above the Top Ørn unconformity, resembles that of the Lower Permian Gipshuken Formation on Spitsbergen, and the Fafner succession is thus regarded as its offshore equivalent. 相似文献
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M.A. López-Horgue E. Iriarte S. Schröder P.A. Fernández-Mendiola B. Caline H. Corneyllie J. Frémont M. Sudrie S. Zerti 《Marine and Petroleum Geology》2010
Shallow marine carbonate sedimentation dominated during the Albian in the western part of the Basque Cantabrian Basin in Northern Spain, forming the large Ramales Platform. This platform originated on a less subsiding tectonic block facing deeper and more subsiding areas to the south and east, which were created by tectonic activity in the Basin. Fracture-related hydrothermal dolomites hosted in these Albian carbonates are well exposed in the Asón valley area. Mapping in the studied area revealed several dolomite bodies related to main faults that cut the stratification almost at right angles. The bodies show a vertical development along fault-strike up to 900 m thick from which kilometre-scale branches expand following the stratification. Dolomitization is pervasive and independent of the limestone facies. Main dolomite facies are fine replacive, sucrosic and saddle. Petrography, C, O and Sr isotopes and fluid-inclusion analysis support a polyphase hydrothermal dolomitization at fluid temperatures between 75 °C and 240 °C and highly variable salinity of up to 22 wt.% NaCl. Fine dolomite replaced limestone first and then, sucrosic and saddle dolomites replaced part of the first dolomite and cemented newly created fracture porosity together with different calcite cements. Zebra dolomites and hydroclastic breccias are products of this later stage. Burial analysis of the host rock supports maximum burial temperatures of 80 °C and intense tectonic activity from the Albian to Turonian with a latest Albian peak subsidence. Albian stretching of the crust and subsequent ascent of the isotherms in the area is suggested to have produced sufficient heat to the dolomitizing fluids. The structural analysis indicates a strong transtensional tectonic activity in the studied area during Albian to Turonian time with the creation of an overstep between W–E trending and N–S trending faults. Fluids moved from subsiding areas to fractured uplifted parts of the Ramales Platform, enhanced by diapiric activity. 相似文献
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The circulation of methane-rich fluids at cold seeps often leads to the precipitation of seep carbonates close to the seafloor along continental margins, which can be used as records of past fluid seepage. Rare earth element (REE) concentrations in seep carbonates have been used to trace fluid sources and provide information on associated biogeochemical processes at cold seeps. The REE concentrations of a series of carbonates collected from cold seeps in the southwestern Dongsha area of the northern South China Sea are analyzed in this study. The total REE contents (ΣREE) of the seep carbonates analyzed show a wide variation from 17 ppm to 523 ppm with an average ΣREE value of 54 ppm, which are higher than the typical marine carbonate values of ∼28 ppm commonly reported and also higher than those of the carbonates from other cold seep areas. A positive correlation between Fe–Mn content and ΣREE was observed. These results suggest that the seep carbonates of this study were primarily controlled by the methane-derived fluid from which they precipitated. The Fe-rich dolomite and siderite, which are the main components of the carbonates, are responsible for the enrichment of the REE. A slight positive Ce anomaly observed in the shale-normalized REE patterns of the studied seep carbonates suggests that they formed in anoxic conditions, and the correlations between Ce/Ce* and LaN/SmN, Ce/Ce* and DyN/SmN, Ce/Ce* and ΣREE further reveal that the REE characteristics of most seep carbonate samples preserve the original redox conditions in which they precipitated and late diagenesis has had little effect on the REE. However, the REE characteristics of sub-samples DS2-2B, DS1-6A and DS1-7A are very different from those of the other sub-samples, indicating a greater impact of late diagenesis and post-oxidation favored REE enrichment. 相似文献
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Submersible investigations with the ROV Victor 6000 of some pockmark structures on the seafloor of the Congo deep-sea fan
have shown that they are active venting sites of methane-rich fluids, associated with abundant fauna and carbonate crusts.
Moreover, methane hydrates have been observed both outcropping and deep in the sediments in the centre of the “Regab” giant
pockmark. Authigenic carbonates, mostly calcite sometimes mixed with aragonite, are cementing the sedimentary matrix components
and fauna; diatoms are abundant but only as moulds, indicating that biogenic silica dissolution occurred in situ synchronous
with carbonate precipitation. The occurrence of diagenetic barite and pyrite in some carbonate crusts demonstrates that they
can be formed either within the sulphate/methane transition zone or deeper in sulphate-depleted sediments. The oxygen isotopic
compositions of the diagenetic carbonates (3.17–6.01‰ V-PDB) indicate that precipitation occurred with bottom seawater mixed
with a variable contribution of water from gas hydrate decomposition. The very low carbon isotopic compositions of the diagenetic
carbonates (−57.1 to −27.75‰ V-PDB) demonstrate that carbon derives mostly from the microbial oxidation of methane. 相似文献
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A stable isotopic study, focused on calcite cements, vein-fill calcite and various bioclasts was conducted on variably deformed and thrusted Lower and Middle Permian carbonates of the Saraburi Group. Samples were collected in quarry faces across 3 areas in the Saraburi–Lopburi region of central Thailand. Stable isotope crossplots (carbon and oxygen), using texture-aware isotope samples, defined variable, but related, fluid-cement histories, which are tied to regional burial and then orogenic overprints driven by the Indosinian (Triassic) orogeny. This was followed by telogenetic overprints, driven by late Cenozoic uplift. The studied carbonates were deposited along the western margin of the Indochina Block, where they were deposited as isolated calcareous algal, sponge and fusilinid-rimmed platforms on highs bound by extensional faults. The platform areas passed laterally and vertically into more siliciclastic dominated sequences, deposited in somewhat deeper waters within probable fault-bound lows. Regional post-depositional mesogenetic fluid-rock re-equilibration of the isotope values in ongoing calcite precipitates occurred until the matrix permeability was occluded via compaction and pressure solution. This regional burial regime was followed by collision of the Indochina and Sibumasu blocks during the Indosinian (Triassic) blocks, which drove a set of structurally focused (thrust-plane related) increasingly warmer set of fluids through the studied sequences. The final diagenetic overprint seen in the isotopic values of the latest calcite cements occurs in a telogenetic (uplift) setting driven by Cenozoic tectonics and isostatic uplift. Integration of isotope data with its structural setting establishes a clear separation in fluid events related to two time-separate tectonic episodes; its fluid chemistry defines the Permo-Triassic closure of the Paleotethys and its subsequent reactivation during the Tertiary collision of India and Asia. The C–O covariant plot fields in the Permian carbonates of central Thailand are so distinct that it is possible to use their signatures to separate burial from meteoric cements in drill cuttings and hence recognise equivalent subsurface unconformities and likely zone of porosity development in possible “buried hill plays in Thailand. 相似文献
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采用稳定加液一反应系统对5、15和25 ° C下镁方解石沉淀在海水中的形成过程进行了研究.结果表明镁方解石的沉淀速率(R)对过饱和度(Ω)的响应均可通过R=k(Ω-1)°或Log(R)=nLog(Ω-1)+Log(k)形式的动力学方程加以表达.pCO2的变化会显著改变过饱和度进而影响到镁方解石沉淀速率,但这一变化并不会对镁方解石沉淀形成过程的动力学表达产生影响.相比之下,不同温度下镁方解石沉淀形成的动力学方程存在明显差异,表明这一动力学过程同时还具有强烈的热力学相关性. 相似文献
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Thick Upper Cambrian-Lower Ordovician carbonates were deposited on a shallow marine platform in the northern Tarim Basin, which were extensively dolomitized, particularly for the Upper Cambrian carbonates. The resulting dolomite rocks are predominantly composed of matrix dolomites with minor cement dolomites. Based on petrographic textures, matrix dolomites consist of very finely to finely crystalline, nonplanar-a to planar-s dolomite (Md1), finely to medium crystalline, planar-e(s) dolomite (Md2), and finely to coarsely crystalline, nonplanar-a dolomite (Md3). Minor cement dolomites include finely to medium crystalline, planar-s(e) dolomite (Cd1) and coarsely crystalline, nonplanar saddle dolomite (Cd2), which partially or completely fill dissolution vugs and fractures; these cements postdate matrix dolomites but predate later quartz and calcite infills. Origins of matrix and cement dolomites and other diagenetic minerals are interpreted on the basis of petrography, isotopic geochemistry (O, C and Sr), and fluid inclusion microthermometry. Md1 dolomite was initially mediated by microbes and subsequently precipitated from slightly modified brines (e.g., evaporated seawater) in near-surface to very shallow burial settings, whereas Md2 dolomite was formed from connate seawater in association with burial dissolution and localized Mg concentration (or cannibalization) in shallow burial conditions. Md3 dolomite, however, was likely the result of intense recrystallization (or neomorphism) upon previously-formed dolomites (e.g., Md1 or Md2 dolomite) as the host carbonates were deeply buried, and influenced by later hydrothermal fluids. Subsequent cement dolomite and quartz crystals precipitated from higher-temperature, hydrothermal fluids, which were contributed more or less by the extensive Permian large igneous province (LIP) activity in Tarim Basin as evidenced by less radiogenic Sr in the cement and parts of matrix dolomites. This extensive abnormal hydrothermal activity could also have resulted in recrystallization (or neomorphism) on the previous matrix dolomites. Faults/fractures likely acted as important conduit networks which could have channeled the hydrothermal fluids from depths. However, the basin uplift triggered by the Late Hercynian Orogeny from the Late Permian would have facilitated downward infiltration of meteoric water and dilution of hydrothermal fluids, resulting in precipitation of later calcites in which lighter C and more radiogenic Sr components demonstrate such a switch of fluid properties. This study provides a useful analogue to understand the complicated dolomitizing processes and later hydrothermal alteration intimately related to the Permian LIP activity within Tarim Basin and elsewhere. 相似文献