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1.
《Marine pollution bulletin》2012,65(12):2849-2856
In this study, the state of the five stations’ quality was assessed on the basis of determination of temporal and spatial variability of nutrients with physicochemical variables. Besides this, organic matter of sediment, secchi disc depth and suspended solids were also determined. The samples were collected seasonally from different areas such as harbor and important touristic marinas along the eastern Aegean during June 2008–2009. As a result, the nutrients ranged between NH4: 0.10–25.6, NO2: 0.01–1.5, NO3: 0.19–7.0, o.PO4: 0.17–6.8, TPO4: 0.32–9.6 and Si: 0.30–13.8 μM, respectively. Precipitation leads to large changes in temperature, salinity, dissolved oxygen and nutrients. The highest nutrient values in this study were observed during the rainy season except o.PO4-P and TPO4-P. However, the physico-chemical variables have exhibited considerable temporal variations while nutrients showed spatial differences. The relatively high nutrient increase in the sampling stations coupled with surface runoff events during rainy period and pollution arising from both point and non-point sources.  相似文献   

2.
Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NOx), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NOx have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

3.
《Marine pollution bulletin》2009,58(6-12):313-324
This study investigated the seasonal and spatial dynamics of nutrients and phytoplankton biomass at 12 stations in Hong Kong (HK) waters during a three year period from 2004 to 2006 after upgraded sewage treatment and compared these results to observations before sewage treatment. Pearl River estuary (PRE) discharge significantly increased NO3 and SiO4 concentrations, particularly in western and southern waters when rainfall and river discharge was maximal in summer. Continuous year round discharge of sewage effluent resulted in high NH4 and PO4 in Victoria Harbour (VH) and its vicinity. In winter, spring and fall, the water column at all stations was moderately mixed by winds and tidal currents, and phytoplankton biomass was relatively low compared to summer. In summer, the mean surface phytoplankton chl biomass was generally >9 μg L−1 in most areas as a result of thermohaline stratification, and high nutrients, light, and water temperature. In summer, the potential limiting nutrient is PO4 in the most productive southern waters and it seldom decreased to limiting levels (∼0.1 μM), suggesting that phytoplankton growth may be only episodically limiting. The mean bottom dissolved oxygen (DO) remained >3.5 mg L−1 at most stations, indicating that the eutrophication impact in HK waters was not as severe as expected for such a eutrophic area. After the implementation of chemically enhanced primary sewage treatment in 2001, water quality in VH improved as indicated by a significant decrease in NH4 and PO4 and an increase in bottom DO. In contrast, there were an increase in chl a and NO3, and a significant decrease in bottom DO in southern waters in summer, suggesting that hypoxic events are most likely to occur in this region if phytoplankton biomass and oxygen consumption keep increasing and exceed the buffering capacity of HK waters maintained by monsoon winds, tidal mixing and zooplankton grazing. Therefore, future studies on the long-term changes in nutrient loading from PRE and HK sewage discharge will be crucial for developing future strategies of sewage management in HK waters.  相似文献   

4.
Nutrients are important building blocks for healthy aquatic ecosystems and are generally nontoxic; but they can change with alteration in environmental parameters. The main objective of this study was to consider the seasonal variability of NO 3 , PO 4 3– and total suspended solids (TSS) concentrations in water. The study sites, stream crossings (L30, L15) and river (R), are located in the hyrcanian forests, district 1 of Darabkola forest. The sampling was conducted in winter and spring. Water samples were taken into plastic bottles, labeled, and carried out to the laboratory for NO 3 , PO 4 3– and TSS analysis. T-test results showed that there was a seasonal change in nutrient concentrations (p < 0.05) except for NO 3 concentration at L30. Also, there was no significant seasonal change in TSS concentrations at all stations. Pearson correlation analysis did not reveal the same trend. Further analysis showed that the effect of road age on water quality parameters was statistically significant for PO 4 3– in spring and winter. Atmospheric precipitation plays vital role in nutrient loss and increasing concentration of suspended sediment. To prevent soil erosion from activities and discharge of wastes in the vicinity of river and stream an effective management should be planned and enforced.  相似文献   

5.
Cluster analysis (CA), discriminant analysis (DA) and principal component analysis (PCA) were comprehensively coupled to explore and identify the spatial and temporal variation and potential pollution sources in coastal water quality along Macau peninsula. The results show that the 12 months could be grouped into two periods, June–September and the remaining months, and the entire area divided into two clusters, one located at the western sides, and the other on the southeast and southern sides of the Macau peninsula. Through backward stepwise DA, pH, Cl, TSS, Color and TP, Chloride, Color, NH4 +, DO, COD were discriminant variables of spatial and temporal variation, with 84.82 and 76.54% correct assignments, respectively. Fecal pollution, organic pollution and soil weathering are among the major sources for coastal water quality deterioration along Macau peninsula. This study illustrates that application of multivariate statistical techniques was beneficial to gain knowledge for further optimizing the monitoring network and controlling coastal water quality along Macau peninsula.  相似文献   

6.
In this paper, cluster analysis (CA), principal component analysis (PCA) and the fuzzy logic approach were employed to evaluate the trophic status of water quality for 12 monitoring stations in Daya Bay in 2003. CA grouped the four seasons into four groups (winter, spring, summer and autumn) and the sampling sites into two groups (cluster DA: S1, S2, S4-S7, S9 and S12 and cluster DB: S3, S8, S10 and S11). PCA identified the temporal and spatial characteristics of trophic status in Daya Bay. Cluster DB, with higher concentrations of TP and DIN, is located in the western and northern parts of Daya Bay. Cluster DA, with the low Secchi, is located in the southern and eastern parts of Daya Bay. The fuzzy logic approach revealed more information about the temporal and spatial patterns of the trophic status of water quality. Chlorophyll a, TP and Secchi may be major factors for deteriorating water quality.  相似文献   

7.
《Marine pollution bulletin》2013,76(1-2):291-300
Surface water samples were collected from substations along Sheva creek and Dharamtar creek mangrove ecosystems of Uran (Raigad), Navi Mumbai, west coast of India. Water samples were collected fortnightly from April 2009 to March 2011 during spring low and high tides and were analyzed for pH, Temperature, Turbidity, Total solids (TS), Total dissolved solids (TDS), Total suspended solids (TSS), Dissolved oxygen (DO), Biochemical oxygen demand (BOD), Carbon dioxide (CO2), Chemical oxygen demand (COD), Salinity, Orthophosphate (O-PO4), Nitrite–nitrogen (NO2–N), Nitrate–nitrogen (NO3–N), and Silicates. Variables like pH, turbidity, TDS, salinity, DO, and BOD show seasonal variations. Higher content of O-PO4, NO3–N, and silicates is recorded due to discharge of domestic wastes and sewage, effluents from industries, oil tanking depots and also from maritime activities of Jawaharlal Nehru Port Trust (JNPT), hectic activities of Container Freight Stations (CFS), and other port wastes. This study reveals that water quality from mangrove ecosystems of Uran is deteriorating due to industrial pollution and that mangrove from Uran is facing the threat due to anthropogenic stress.  相似文献   

8.
三峡大坝上下游水质时空变化特征   总被引:6,自引:2,他引:4  
为探索三峡大坝上下游(坝上99.9 km、坝下63.0 km、全长162.9 km)水质时空变化特征,运用主成分分析和方差分析对2016年近坝段水质时空变化特征进行了分析.主成分分析表明,水文因子流量(Q)、气温(T)、水位(Z)和水质因子(水温(WT)、pH、电导率(EC)、溶解氧(DO)、悬浮物(SS)、高锰酸盐指数(CODMn)、硫酸盐(SO42-)、氟化物(F-)、总硬度(T-Hard)、硝态氮(NO3--N)、总氮(TN)和硒(Se))的变化主导着研究区域水质变化;各采样点主成分得分和双因素方差分析结果显示研究区域水质因子时间变化主要呈现出季节和不同水库运行时期的差异.消落期(2-5月),T-Hard、F-、SO42-和EC是影响河流水质变化的主导因子;汛期(7-8月),Q、SS、CODMn、NO3--N、TN和Se是影响河流水质变化的主导因子;T和WT主导着汛末(9月)河流水质变化,并引起了DO等理化特性的变化;高水位运行期(12月),Cl-是影响河流水质变化的主导因子.现阶段,DO、有机污染物(CODMn)、无机盐(SO42-和F-)、营养盐类(NO3--N和TN)、类金属元素(Se)和水体的矿化程度(T-Hard)的变化主导着区域水质的变化,是三峡大坝近坝段水域水质的控制因子.方差分析表明,河流的理化特性(DO、pH和SS)、营养盐组分构成(NH3-N和NO3--N)、无机盐类(EC和Cl-)、石油类有机污染物及粪大肠菌群(FC)等指标在坝上与坝下断面存在显著性差异.气温、水温、降雨、含沙量的季节性影响因素和水库调度运行模式是影响近坝段水质时间差异的主要因子;空间差异主要受城区污染排放和三峡水库调度引起的坝上和坝下水文和水动力学条件差异影响.因此控制研究区域因人类活动等造成的外源性污染,并针对不同类污染物质的季节变化特征实施合理的水库运行方式是近坝段水质提升的关键.  相似文献   

9.
胡维平  濮培民  李万春 《湖泊科学》1998,10(S1):507-518
A model on a physico-biological engineering experiment for purifying water in Wulihu Bay of Lake Taihu by using Trapa natans var. bispinosa was constructed. The state variables in water in the physico-biological engineering were ammonium nitrogen (NH4+-N); nitrate nitrogen (NO3--N); nitrite nitrogen (NO2--N); phosphate phosphorus (PO43--P); dissolved oxygen (DO); nitrogen (N) and phosphorus (P) in detritus; biomass density, N and P in phytoplankton and in Trapa natans var. bispinosa, N and P in the substance adsorbed by the membrane of the engineering and the rootstocks of Trapa natans var. bispinosa. The state variables in bottom mud layer were PO43--P in the core water,exchangeable P and N. The external forcing functions were solar radiation, water temperature, NH4+-N; NO3--N; NO2--N; PO43--P; N and P in detritus; DO; phytoplankton concentrations in inflow water and the retention time of the water in physico-biological engineering channel. The main physical, chemical and biological processes considered in the model were:growth of Trapa natans var. bispinosa and phytoplankton; oxidation of NH4+-N and NO2--N, of detritus break down; N and P sorption by the enclosure cloth of the experimental engineering and by the rootstocks of Trapa natans var. bispinosa in water; reaeration of water; uptake of P, NH4+-N, NO3--N by phytoplankton and Trapa natans var. bispinosa:mortality of the phytoplankton and Trapa natans var. bispinosa:settling of detritus; and nutrient release from sediment. Comparison of calculated results and observed results showed that the model was constructed reasonably for the experiment. The mechanism of purifying lake water in the experiment engineering was discussed by the use of the model.  相似文献   

10.
夏季短期调水对太湖贡湖湾湖区水质及藻类的影响   总被引:1,自引:0,他引:1  
贡湖湾作为"引江济太"工程长江来水进入太湖的第一站,湖湾水体生态环境的变化是对调水工程净水效果的最好响应,因此本文针对贡湖湾一次夏季短期调水展开调查研究,分别取2013年7月24日(调水前)和2013年8月18日(短期调水后)两次监测水样的水体理化指标和浮游藻类群落数据进行了对比分析,并对浮游藻类群落与环境因子做了相关性分析.结果表明:受来水影响,短期调水后监测区水体的p H略有下降,溶解氧、浊度、硝态氮、总氮、总磷以及高锰酸盐指数等水体理化指标浓度均较调水前有所升高;其中受调水影响最为显著的区域为望虞河的入湖口区、湾心区.两次监测调水前后湖区水体优势藻种属未发生变化,仍以微囊藻为主,但蓝藻种属比例有所下降,绿藻和硅藻等种属比例则有所上升.望虞河入湖口区和贡湖湾湾心区的Shannon-Wiener多样性指数和Pielou均匀度指数受调水的影响升高.同时,浮游藻类群落结构与受水水体理化参数的冗余分析结果表明,此次监测的短期调水后,太湖贡湖湾监测湖区水体p H、溶解氧、硝态氮、总氮、总磷、高锰酸盐指数等环境因子与浮游藻类的群落分布呈显著相关,是影响受水水体中藻类群落的主要环境因子.  相似文献   

11.
2010年10月-2011年9月在太湖梅梁湾围隔内研究了改性当地土壤絮凝除藻及其对水质改善的应急和长期效果,并结合室内实验研究了该技术防控底泥再悬浮和减少底泥二次污染的长效机制.现场围隔实验结果表明,改性当地土壤除藻30 min后,TN、NO3--N、NH4+-N、TP、PO34--P和Chl.a的去除率分别为66%、57%、60%、93%、92%和98%;长期监测结果表明,与对照区域相比,围隔内的TN、NH4+-N、NO3--N、TP和PO34--P在处理后11个月内的平均值分别降低了39.83%、52.30%、48.53%、18.75%和60.00%.室内再悬浮实验结果表明,改性土壤和沙子抗再悬浮能力较未改性土壤分别提高了3和5倍.室内柱培养结果表明改性土壤絮凝除藻和沙土覆盖相结合可有效提高表层沉积物-水界面的氧化还原电位和溶解氧,使沉积物向水体的TP和TN通量从源逆转成汇,PO34--P和NH4+-N通量大幅度降低.改性土壤技术在利用絮凝除藻快速改善水质后,可通过改性沙/土分层底泥调控分别达到对藻絮体再悬浮的物理控制和营养盐再释放的化学控制,通过将亚表层底泥中的藻细胞分解并被沉水植物根系吸收,可实现对底泥中水华蓝藻复苏和水体富营养化的长效生态控制.  相似文献   

12.
Spatial patterns of planktonic ciliate communities for assessment of marine environmental status were studied from June 2007 to May 2008 in Jiaozhou Bay, Qingdao, northern China. Ciliate communities were sampled biweekly at five sampling sites with a spatial gradient of environmental stress. Multivariate/univariate analyses demonstrated that: (1) the planktonic ciliate community structures represented significant differences among the five sites; (2) spatial patterns of the ciliate communities were significantly correlated with environmental variables, especially the nutrients nitrate nitrogen (NO3-N) and soluble reactive phosphates (SRP); (3) five dominant species (e.g., Rimostrombidium veniliae, Strombidium capitatum, Mesodinium pupula and Strombidinopsis acutum) were significantly correlated with nitrogen and/or SRP; and (4) both species richness and species diversity indices were correlated with NO3-N and salinity. These results suggest that planktonic ciliated protozoa might be used as a robust bioindicator of marine water quality.  相似文献   

13.
Riparian zones are highly-dynamic transition zones between surface water (SW) and groundwater (GW) and function as key biogeochemical-reactors for solutes transitioning between both compartments. Infiltration of SW rich in dissolved oxygen (DO) into the riparian aquifer can supress removal processes of redox sensitive compounds like NO3, a nutrient harmful for the aquatic ecosystem at high concentrations. Seasonal and short-term variations of temperature and hydrologic conditions can influence biogeochemical reaction rates and thus the prevailing redox conditions in the riparian zone. We combined GW tracer-tests and a 1-year high-frequency dataset of DO with data-driven simulations of DO consumption to assess the effects of seasonal and event-scale variations in temperature and transit-times on the reactive transport of DO. Damköhler numbers for DO consumption (DADO) were used to characterize the system in terms of DO turnover potential. Our results suggest that seasonal and short-term variations in temperature are major controls for DO turnover and the resulting concentrations at our field site, while transit-times are of minor importance. Seasonal variations of temperature in GW lead to shifts from transport-limited (DADO > 1) to reaction-limited conditions (DADO < 1), while short-term events were found to have minor impacts on the state of the system, only resulting in slightly less transport-limited conditions due to decreasing temperature and transit-times. The data-driven analyses show that assuming constant water temperature along a flowpath can lead to an over- or underestimation of reaction rates by a factor of 2–3 due to different infiltrating water temperature at the SW–GW interface, whereas the assumption of constant transit-times results in incorrect estimates of NO3 removal potential based on DADO approach (40%–50% difference).  相似文献   

14.
休伦湖Saginaw湾沉积物反硝化率的测定及其时空特征   总被引:9,自引:2,他引:7  
用N2生成法测定了北美休伦湖Saginaw湾1995年夏季7、8月份沉积物反硝化率,Saginaw湾内湾的沉积物反硝化率为16.0-39.6μmolN2/(m2·h),外湾沉积反硝化率为22.7 -26.1μmolN2/(m2·h),比较了不同湖泊沉积物反硝化率数值大小,指出休伦湖Saginaw湾水体现阶段的营养状况为贫-中营养水平.内外湾沉积物反硝化率数值波动大小与Saginaw河及休伦湖的影响有关;N2:TIN通量比值有不随采样时间的变化而变更等特性.在反硝化率测定过程中,反硝化率与O2消耗率之间有明显的正相关关系;沉积物上覆水中NH+4与NO-3之间通量值在变化趋势上有明显的负相关关系。  相似文献   

15.
Techniques to predict temporal variations in concentrations and loads of suspended solids from highway runoff are required to estimate impacts on receiving water ecology and to inform the design of interception/treatment devices. A recent UK study included the collection of rainfall, highway runoff rates and sediment load and quality data from six different sites where motorway runoff drained directly into a receiving watercourse. This data set is used to critically evaluate a previously-published model (Kim et al. 2005) aimed at predicting temporal variations in runoff quality. The comparisons, based on discrete samples collected during 21 storm events, suggest that a simplification of the model, requiring just two parameters, provides a robust estimate of temporal variations in total suspended solids (TSS). Generic parameter values are provided, and the model’s application is illustrated. The model captures first flush effects well, but the identified generic parameters fail to fullypredict the variation in absolute TSS values that are observed in practice.  相似文献   

16.
浮游细菌群落对河流变化具有高度响应性,并可能影响河流生境的生物地球化学过程.因此,了解浮游细菌群落的时空特征,阐明其在河流生态系统中的生态功能具有重要科学意义.于2016年6月和12月对珠江下游浮游细菌群落结构的时空特征进行调查研究,并采用16S rRNA高通量测序技术对样品组分进行分析.结果表明细菌群落主要由变形菌门(Proteobacteria)、放线菌门(Actinobacteria)、拟杆菌门(Bacteroidetes)、厚壁菌门(Firmicutes)、抗微菌门(Verrucomicrobia)和蓝细菌门(Cyanobacteria)组成.其中变形菌门相对丰度最高,主要包括β-变形菌纲(Betaproteobacteria)、α-变形菌纲(Alphaproteobacteria)和γ-变形菌纲(Gammaproteobacteria).季节上,丰水期Shannon-Wiener和Chao 1多样性指数高于枯水期其中芽孢杆菌纲(Bacilli)和黄杆菌纲(Flavobacteriia)差异显著;空间上,珠江下游可分为西江沿线、珠三角河网中部和广州市周边3个区域.采用RDA分析表明水温(WT)、溶解氧(DO)、磷酸盐(PO_4~(3-)-P)、硅酸盐(SiO_4--Si)、总磷(TP)和透明度(SD)是驱动细菌群落变化最显著的环境因子,可影响细菌的增殖代谢.其中WT和SD是影响季节差异的重要因素将丰水期和枯水期区分开;而DO、化学需氧量(COD)和营养盐(PO_4~(3-)-P、SiO_4~(2-)-Si、TP)是影响空间差异的重要因素将西江沿线、珠三角河网中部和广州市周边区分开.PICRUSt功能预测分析表明,转运体(Transporters)、ABC转运体(ABC transporters)、DNA修复和重组蛋白(DNA repair and recombination proteins)等是珠江下游浮游细菌群落所表达的主要功能其中转运体和ABC转运体功能丰水期明显高于枯水期.研究结果可为珠江下游生态环境保护提供科学参考依据.  相似文献   

17.
Although riparian zones are well known to reduce nitrogen (N) and phosphorus (P) runoff to streams, they also have the potential to affect greenhouse gas (CO2, N2O, and CH4) fluxes to the atmosphere. Following large storms, soil biogeochemical conditions often become more reduced, especially in oxbow depressions and side channels, which can lead to hot moments of greenhouse gas production. Here, we investigate the impact of the remnants of Hurricane Irene and Tropical Storm Lee on riparian zone hydrology (water table: WT), and biogeochemistry (oxidation‐reduction potential [ORP], dissolved oxygen [DO], NO3?, PO43?, CO2, N2O, CH4). Results indicate that large storms have the potential to reset WT levels for weeks to months. Overbank flooding at our site following Irene and Lee led to the infiltration of well‐oxygenated water at depth (higher DO and ORP) while promoting the development of anoxic conditions within soil aggregates near the soil surface (increased N2O and CH4 fluxes). A short‐term increase in CO2 emission was observed following Irene at our site where aerobic respiration was water‐limited. Over a 2‐year period, an oxbow depression exhibited higher WT, higher N2O and CH4 fluxes (hot moment), higher CO2 fluxes (seasonal), and lower NO3? concentrations (seasonal) than the rest of the riparian zone. However, neither Irene, nor Lee, nor the oxbow depression significantly impacted PO43?. Dissolved organic carbon, ORP, and DO data illustrate the time‐lag (>20 years) between the creation of an oxbow depression and the development of reducing conditions despite clear differences in riparian zone and oxbow WT dynamics.  相似文献   

18.
Excessive terrestrial nutrient loadings adversely impact coral reefs by primarily enhancing growth of macroalgae, potentially leading to a phase‐shift phenomenon. Hydrological processes and other spatial and temporal factors affecting nutrient discharge must be examined to be able to formulate effective measures for reducing nutrient export to adjacent reefs. During storm events and baseflow periods, water samples were obtained from the tropical Todoroki River, which drains an intensively agricultural watershed into Shiraho coral reef. In situ nutrient analyzers were deployed for 6 months to hourly measure dissolved nutrient (NO3‐N and PO43−‐P) concentrations. Total phosphorus (TP) and suspended solid concentration (TSS) were increased by higher rainfall intensity (r = 0·94, p < 0·01) and river discharge Q (r = 0·88, p < 0·01). In contrast, NO3‐N concentration tends to decrease drastically (e.g. from 3 to 1 mg l−1) during flood events. When base flow starts to dominate afterwards, NO3‐N manifested an increasing trend, but decreases when baseflow discharge becomes low. This counter‐clockwise hysteresis for NO3‐N highlights the significant influence of groundwater discharge. N delivery can therefore be considered a persistent process compared to sediment and P discharge, which are highly episodic in nature. Based on GIS analysis, nutrient concentration along the Todoroki River was largely affected by the percentage of sugarcane/bare areas and bedrock type. The spatial distribution of N concentration in the river reflects the considerable influence of subsurface geology—higher N levels in limestone‐dominated areas. P concentrations were directly related to the total length of artificial drainage, which enhances sediment transport. The use of high‐resolution monitoring data coupled with GIS‐based spatial analysis therefore enabled the clarification of control factors and the difference in the spatio‐temporal discharge characteristics between N and P. Thus, although erosion‐reduction schemes would reduce P discharge, other approaches (e.g. minimize fertilizer) are needed to reduce N discharge. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

19.
徐闯  刘广州  陈晓宏 《湖泊科学》2022,34(5):1540-1549
溶解氧是水生生态系统健康程度的重要度量指标,研究溶解氧时空变化及其影响因素对揭示河流溶解氧动态过程和理解水体生物地球化学循环具有重要意义. 当前,许多河流均存在溶解氧偏低问题,严重影响河流水质. 基于此,收集了珠江流域东江(东莞段)上游桥头、中游樟村和下游沙田泗盛3个水质监测站的实测资料,采用折线图和箱型图分析溶解氧在月、季节和年际时间尺度下的变化规律及其空间差异; 采用最大信息系数、交叉小波转换和多元线性回归3种方法解析溶解氧时空变化的影响因素. 结果表明:空间分布上,溶解氧浓度从上游到下游逐渐降低,低值区分布在入海口处的沙田泗盛站,多年平均溶解氧浓度仅为3.11 mg/L. 时间变化上,2011—2019年溶解氧主要在11.64个月的周期下循环变化. 溶解氧展现出明显的季节性. 3个站点丰水期溶解氧浓度比枯水期分别降低1.68、2.03和1.77 mg/L. 驱动因素上,溶解氧的时空变化受到多个因素的综合作用. 桥头站和樟村站水质较好,水温是这两个站点溶解氧时空变化的主要影响因素. 其主要在8~16个月的周期上调控溶解氧变化,在两个站点分别可以解释溶解氧整体变化的70%和57%. 沙田泗盛站受多条支流汇入的影响,水体中硝化和氧化作用耗氧增强,加之悬浮物遮光效应,使得该处的溶解氧浓度降低.  相似文献   

20.
Synoptic water sampling at a fixed site monitoring station provides only limited ‘snap‐shots’ of the complex water quality dynamics within a surface water system. However, water quality often changes rapidly in both spatial and temporal dimensions, especially in highly polluted urban rivers. In this study, we designed and applied a continuous longitudinal sampling technique to monitor the fine‐scale spatial changes of water quality conditions, assess water pollutant sources, and determine the assimilative capacity for biochemical oxygen demand (BOD) in an urban segment of the hypoxic Wen‐Rui Tang River in eastern China. The continuous longitudinal sampling was capable of collecting dissolved oxygen (DO) data every 5 s yielding a ~11 m sampling interval with a precision of ±0.1 mg L?1. The Streeter and Phelps BOD‐DO model was used to calculate: (1) the oxygen consumption coefficient (K1) required for calibration of water quality models, (2) BOD assimilative capacity, and (3) BOD source and load identification. In the 2014 m river segment sampled, the oxygen consumption coefficient (K1) was 0.428 d?1 (20°C), the total BOD discharge was 916 kg d?1, and the BOD assimilative capacity was 382 kg d?1 when the minimum DO level was set to 2 mg L?1. In addition, the longitudinal analysis identified eight major drainage outlets (BOD point sources), which were verified by field observations. This new approach provides a simple, cost‐effective method of evaluating BOD‐DO dynamics over large spatial areas with rapidly changing water quality conditions, such as urban environments. It represents a major breakthrough in the development and application of water quality sampling techniques to obtain spatially distributed DO and BOD in real time. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

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