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1.
The composite Oberkirch pluton consists of three compositionally different units of peraluminous biotite granite. The northern unit is relatively mafic (SiO2∼64%) and lacks cordierite. The more felsic central and southern units (SiO2=67.8 to 70.4%) can only be distinguished from each other by the occurrence of cordierite in the former. Mafic microgranular enclaves of variable composition, texture and size occur in each of these units and are concentrated in their central domains. Most abundant are large (dm to m) hornblende-bearing enclaves with dioritic to tonalitic compositions (SiO2=50.8 to 56.3 wt%; Mg#=63 to 41) and fine grained doleritic textures that suggest chilling against the host granite magma. Some of these enclaves are mantled by hybrid zones. Less common are microtonalitic enclaves containing biotite as the only primary mafic phase (SiO2=53.7 to 64.4%) and small hybrid tonalitic to granodioritic enclaves and schlieren. Synplutonic dioritic dikes (up to 6 m thick) with hybrid transition zones to the host granite occur in the southern unit of the pluton. In chemical variation diagrams, samples from unmodified hornblende-bearing mafic enclaves and dikes form continuous trends that are compatible with an origin by fractionation of olivine, clinopyroxene, hornblende and plagioclase. Chemical and initial isotopic signatures (e.g. high Mg#, low Na2O, ɛNd=−1.2 to −5.1, 87Sr/86Sr=0.7055 to 0.7080, δ18O=8.0 to 8.8‰) exclude an origin by partial melting from a mafic meta-igneous source but favour derivation from a heterogeneous enriched lithospheric mantle. Samples from the granitic host rocks do not follow the chemical variation trends defined by the diorites but display large scatter. In addition, their initial isotopic characteristics (ɛNd=−4.5 to −6.8, 87Sr/86Sr=0.7071 to 0.7115, δ18O=9.9 to 11.9‰) show little overlap with those of the diorites. Most probably, the granitic magmas were derived from metapelitic sources characterized by variable amounts of garnet and plagioclase. This is suggested by relatively high molar ratios of Al2O3/(MgO+FeOtot) and K2O/Na2O, in combination with low ratios of CaO/(MgO+FeOtot), variable values of Sr/Nd, Eu/Eu*[=Eucn/(Smcn × Gdcn)0.5] and (Tb/Yb)cn (cn=chondrite-normalized) as well as variable abundances of Sc and Y. Whole-rock initial isotopic signatures of mafic microtonalitic enclaves (ɛNd=−4.6 to −5.2; 87Sr/86Sr=0.7060 to 0.7073; δ18O ∼8.1‰) are similar to those of the low ɛNd diorites. Plagioclase concentrates from a granite sample and a mafic microtonalitic enclave are characterized by initial 87Sr/86Sr ratios that are significantly higher than those of their bulk rock systems suggesting incorporation of high 87Sr/86Sr crustal material into the magmas. Field relationships and petrographic evidence suggest that the Oberkirch pluton originated by at least three pulses of granitic magma containing mafic magma globules. In-situ hybridization between the different magmas was limited. Late injection of dioritic magma into the almost solidified granitic southern unit resulted in the formation of more or less continuous synplutonic dikes surrounded by relatively thin hybrid zones. Received: 30 April 1999 / Accepted: 6 August 1999  相似文献   

2.
An early Cretaceous (135 ± 2 Ma) felsic volcanic suite of dacite and rhyolite from Huolinhe, NE China is characterized by large ion lithophile element and light REE enrichment and high field strength element (HFSE, e.g., Nb and Ta) and Ti–P depletion, and bulk silicate earth-like Sr [87Sr/86Sr(i) = 0.70409–0.70481], quite radiogenic Nd [ε Nd(t) = +3.98 to +5.88], Pb [e.g., 206Pb/204Pb(i) = 18.46–18.55] and Hf [ε Hf(t) ~+9.2] isotope compositions. Compared with contemporaneous mafic rocks in the region, these felsic rocks have even higher Nd and Hf isotopic ratios, precluding an origin through differentiation of coeval mantle-derived magmas. Isotope calculation results suggest that these magmas were derived from a preexistent mixture composed of mainly juvenile crust (70–80%), and a subordinate recycled crustal component (20–30%) having highly radiogenic Sr and Pb and unradiogenic Nd and Hf. About 25–30% melting of such a mixed source produced the primary dacitic magma. The rhyolites, which have relatively low MgO, FeO*, Al2O3, CaO, TiO2, P2O5, Na2O, Ba, Sr, REE, HFSE and Y, were differentiates of the dacites after removal of a fractional assemblage of hornblende + plagioclase + K-feldspar + apatite + zircon. Considering the prolonged events (from 262 to 130 Ma) that produced such highly positive ε Nd felsic igneous rocks in the region, we prefer a pre-Mesozoic crustal growth model related to arc accretion associated with the Paleo-Asian Ocean subduction.  相似文献   

3.
A critical study of 311 published WR chemical analyses, isotopic and mineral chemistry of anorthosites and associated rocks from eight Proterozoic massif anorthosite complexes of India, North America and Norway indicates marked similarities in mineralogy and chemistry among similar rock types. The anorthosite and mafic-leucomafic rocks (e.g., leuconorite, leucogabbro, leucotroctolite, anorthositic gabbro, gabbroic anorthosite, etc.) constituting the major part of the massifs are characterized by higher Na2O + K2O, Al2O3, SiO2, Mg# and Sr contents, low in plagioclase incompatible elements and REE with positive Eu anomalies. Their δ 18O‰ (5.7–7.5), initial 87Sr/86Sr (0.7034–0.7066) and ɛ Nd values (+1.14 to +5.5) suggest a depleted mantle origin. The Fe-rich dioritic rocks occurring at the margin of massifs have isotopic, chemical and mineral composition more close to anorthosite-mafic-leucomafic rocks. However, there is a gradual decrease in plagioclase content, An content of plagioclase and XMg of orthopyroxene, and an increase in mafic silicates, oxide minerals content, plagioclase incompatible elements and REE from anorthosite-mafic-leucomafic rocks to Fe-rich dioritic rocks. The Fe-rich dioritic rocks are interpreted as residual melt from mantle derived high-Al gabbro melt, which produced the anorthosite and mafic-leucomafic rocks. Mineralogically and chemically, the K-rich felsic rocks are distinct from anorthosite-mafic-leucomafic-Fe-rich dioritic suite. They have higher δ 18O values (6.8–10.8‰) and initial 87Sr/86Sr (0.7067–0.7104). By contrast, the K-rich felsic suites are products of melting of crustal precursors.  相似文献   

4.
The major elements, trace elements and Nd-Sr isotopic composition of Cenozoic high-K igneous rocks and mafic deep-derived enclaves from the Liuhe-Xiangduo area, eastern Tibet, indicate the high-K igneous rocks are characterized as being enriched in Ca (CaO= 1.20% - 8.80% ), alkali (Na2O K2O= 3.47% - 10.65% ), especially K (K2O up to 5.96% ) and depleted in Ti (TiO2= 0.27% - 1.50% ). Their REE contents are very high (REE= 91.29 - 231.11 μg/g). Their REE distribution patterns are of the right-inclined type, characterized by intense LREE enrichment [(La/Yb)N= 7.44 - 15.73 ]. The rocks are distinctly enriched in Rb, Sr and Ba ( 46.3 -316 μg/g, 349-1220 μg/g and 386-2394 μg/g, respectively), high in U and Th ( 1.17 - 8.10 μg/g and 2.58 - 27.0 μg/g, respectively), moderate in Zr and Hf ( 87.5 -241 μg/g and 2.83 - 7.52 μg/g, respectively), and depleted in Nb and Ta ( 4.81 - 16.8 μg/g and 0.332 - 1.04 μg/g, respectively). In the primitive mantle-normalized incompatible element spidergram, U, K, Sr and Hf show positive anomalies, whereas Th, Nb, Ta, P, and Ti show negative anomalies. The rocks are strongly depleted in Cr and Ni ( 21.4 -1470 μg/g and 7.79 -562 μg/g, respectively), and their transition element distribution curves are obviously of type-W. The ( 87 Sr/ 86 Sr)i ratios range from 0.704184 to 0.707539 ; ( 143 Nd / 144 Nd)i from 0.512265 to 0.512564 ; and ε Nd (t) from -6.3 to -0.4 . These geochemical features might suggest that the potential source of the high-K igneous rocks in the Liuhe-Xiangduo area is similar to the EM2, which may be similar to the material enriched K that is located under the crust-mantle mixed layer. The mafic deep-derived enclaves in the high-K igneous rocks belong to chance xenoliths. Their ( 87 Sr/ 86 Sr)i ratios range from 0.706314 to 0.707198 ; ( 143 Nd / 144 Nd)i from 0.512947 to 0.513046 ; and ε Nd (t) from 7.0 to 9.0 . These geochemical features might indicate that the enclaves probably came from the depleted mantle. The P-T conditions of the enclaves also showed that the enclaves are middle-lower crust metamorphic rocks, which were accidentally captured at 20-50 km level by rapidly entrained high-K magma, whose source is over 50 km in depth.  相似文献   

5.
Granitoids from the central Mawson Escarpment (southern Prince Charles Mountains, East Antarctica) range in age from Archaean to Early Ordovician. U–Pb dating of zircon from these rocks indicates that they were emplaced in three distinct pulses: at 3,519 ± 20, 2,123 ± 12 Ma and between 530 and 490 Ma. The Archaean rocks form a layer-parallel sheet of limited extent observed in the vicinity of Harbour Bluff. This granitoid is of tonalitic-trondhjemitic composition and has a Sr-undepleted, Y-depleted character typical of Archaean TTG suites. εNd and TDM values for these rocks are −2.1 and 3.8 Ga, respectively. Subsequent Palaeoproterozoic intrusions are of granitic composition (senso stricto) with pronounced negative Sr anomalies. These rocks have εNd and TDM values of −4.8 and 2.87 Ga, indicating that these rocks were probably melted from an appreciably younger source than that tapped by the Early Archaean orthogneiss. The remaining intrusions are of Early Cambrian to Ordovician age and were emplaced coincident with the major orogenic event observed in this region. Cambro–Ordovician intrusive activity included the emplacement of layer-parallel pre-deformational granite sheets at approximately 530 Ma, and the intrusion of cross cutting post-tectonic granitic and pegmatitic dykes at ca. 490 Ma. These intrusive events bracket middle- to upper-amphibolite facies deformation and metamorphism, the age of which is constrained to ca. 510 Ma—the age obtained from a syn-tectonic leucogneiss. Nd–Sr isotope data from the more felsic Cambro–Ordovican intrusions (SiO2 > 70 wt%), represented by the post-tectonic granite and pegmatite dykes, suggest these rocks were derived from Late Archaean or Palaeoproterozoic continental crust (TDM ∼ 3.5–2.3 Ga, εNd ∼ −21.8 to −25.9) not dissimilar to that tapped by the Early Proterozoic intrusions. In contrast, the compositionally more intermediate rocks (SiO2 < 65 wt%), represented by the metaluminous pre-tectonic Turk orthogneiss, appear to have melted from a notably younger lithospheric or depleted mantle source (TDM = 1.91 Ga, εNd ∼ −14.5). The Turk orthogneiss additionally shows isotopic (low 143Nd/144Nd and low 87Sr/86Sr) and geochemical (high Sr/Y) similarities to magmas generated at modern plate boundaries—the first time such a signature has been identified for Cambrian intrusive rocks in this sector of East Antarctica. These data demonstrate that: (1) the intrusive history of the Lambert Complex differs from that observed in the adjacent tectonic provinces exposed to the north and the south and (2) the geochemical characteristics of the most mafic of the known Cambrian intrusions are supportive of the notion that Cambrian orogenesis occurred at a plate boundary. This leads to the conclusion that the discrete tectonic provinces observed in the southern Prince Charles Mountains were likely juxtaposed as a result of Early Cambrian tectonism.  相似文献   

6.
Summary The Tyrrhenian border of the Italian peninsula has been the site of intense magmatism from Pliocene to recent times. Although calc-alkaline, potassic and ultrapotassic volcanism overlaps in space and time, a decrease of alkaline character in time and space (southward) is observed. Alkaline ultrapotassic and potassic volcanic rocks are characterised by variable enrichment in K and incompatible elements, coupled with consistently high LILE/HFSE values, similar to those of calc-alkaline volcanic rocks from the nearby Aeolian arc. On the basis of mineralogy and major and trace element chemistry two different arrays can be recognised among primitive rocks; a silica saturated trend, which resulted in formation of leucite-free mafic rocks, and a silica undersaturated trend, charactrerised by leucite-bearing rocks. Initial 87Sr/86Sr and 143Nd/144Nd values of Italian ultrapotassic and potassic mafic rocks range from 0.70506 to 0.71672 and from 0.51173 to 0.51273, respectively. 206Pb/204Pb values range between 18.50 and 19.15, 207Pb/204Pb values range between 15.63 and 15.70, and 208Pb/204Pb values range between 38.35 and 39.20. The general εSr vs. εNd array, along with crustal lead isotopic values, clearly indicates that a continental crustal component has played an important role in the genesis of these magmas. The main question is where this continental crustal component has been acquired by the magmas. Volcanological and petrologic data indicate continental crustal contamination to be a leading process along with fractional crystallisation and magma mixing. Considering, however, only the samples thought to represent primary magmas, which have been in equilibrium with their mantle source, a clearer picture emerges. A large variation of εSr vs. εNd is still observed, with εSr from −2 to +180 and εNd from + 2 to −12. A bifurcation of this array is observed in the samples that plot in the lower right quadrant, with mafic leucite-bearing Roman Province rocks buffered at εSr = + 100 whereas the mafic leucite-free potassic and ultrapotassic rocks point to strongly radiogenic Sr compositions. We may argue that mafic leucite-bearing Roman Province rocks point to εSr and εNd values similar to those of Miocene carbonate sediments whereas mafic leucite-free potassic and ultrapotassic rocks point to a silicate upper crust end-member. Lead isotopes plot well inside the field of island arcs, overlapping the values of pelagic sediments as well, but bifurcation between the samples north and south of Rome is observed. The main characteristic for the mantle source of Italian potassic and ultrapotassic magmas is the clear upper crustal signature acquired prior to partial melting through metasomatic agents released by the subducted slab. In addition, one lithospheric mantle source in the north and an asthenospheric mantle source, pointing to an HIMU reservoir, in the south were recognised. The chemical and isotopic differences observed between the northern and southern sectors of the magmatic region were possibly due to the presence of a carbonate-rich component in the crustal enriching agent in the south. One crustal component might have been generated by melting of silicate metasedimentary rocks or sediments from an ancient subducted slab. The second one might reflect the activity of mostly CO2-rich fluid released more recently by the incipient subduction of carbonate sedimentary rocks. Received February 16, 2000; revised version accepted September 6, 2001  相似文献   

7.
Summary The oxygen and strontium isotope compositions of the Cambro-Ordovician granitoids cropping out in the Wilson Terrane (Granite Harbour Intrusives–GHI) constrain the petrological evolution of the magmatism in Antarctica, related to the Ross Orogeny. The measured δ18OWR values of these intrusives define three different compositional groups: the metaluminous rocks (MAG), with δ18OWR ranging from 6.9 (olivine gabbro) to 11.4‰ (monzogranite); the unaltered peraluminous granites (PAG), having δ18OWR values ranging from 10.6 to 13.2‰, and the foliated peraluminous leucogranites (SKG), characterised by δ18OWR values above 14‰. The analysis of equilibrium mineral assemblages indicates that the high δ18OWR values are magmatic and unaffected by low-temperature processes. A few peraluminous granites sampled in the vicinity of Cenozoic intrusions show anomalously low δ18OWR, due to meteoric-hydrothermal alteration. The isotopic data indicate that the coeval and spatially related metaluminous mafic and felsic intrusives forming the GHI were not comagmatic: the mafic and intermediate rocks were likely derived from lower crustal contamination of a pristine basaltic magma; their δ18OWR values were also increased during emplacement, due to the interaction with the adjacent 18O-rich hydrous felsic magmas (mixing). Oxygen isotope data indicate that the crustal sources producing the Granite Harbour intrusives were not homogeneous: the felsic metaluminous intrusives were produced by partial melting of fertile rock with possible igneous origin, whereas partial melting of a metapelitic source rock is claimed for the genesis of the peraluminous granites. Received February 9, 2001; revised version accepted August 10, 2001  相似文献   

8.
Petrogenesis of high Mg# adakitic rocks in intracontinental settings is still a matter of debate. This paper reports major and trace element, whole-rock Sr–Nd isotope, zircon U–Pb and Hf isotope data for a suite of adakitic monzogranite and its mafic microgranular enclaves (MMEs) at Yangba in the northwestern margin of the South China Block. These geochemical data suggest that magma mixing between felsic adakitic magma derived from thickened lower continental crust and mafic magma derived from subcontinental lithospheric mantle (SCLM) may account for the origin of high Mg# adakitic rocks in the intracontinental setting. The host monzogranite and MMEs from the Yangba pluton have zircon U–Pb ages of 207 ± 2 and 208 ± 2 Ma, respectively. The MMEs show igneous textures and contain abundant acicular apatite that suggests quenching process. Their trace element and evolved Sr–Nd isotopic compositions [(87Sr/86Sr)i = 0.707069–0.707138, and εNd(t) = −6.5] indicate an origin from SCLM. Some zircon grains from the MMEs have positive εHf(t) values of 2.3–8.2 with single-stage Hf model ages of 531–764 Ma. Thus, the MMEs would be derived from partial melts of the Neoproterozoic SCLM that formed during rift magmatism in response to breakup of supercontinent Rodinia, and experience subsequent fractional crystallization and magma mixing process. The host monzogranite exhibits typical geochemical characteristics of adakite, i.e., high La/Yb and Sr/Y ratios, low contents of Y (9.5–14.5 ppm) and Yb, no significant Eu anomalies (Eu/Eu* = 0.81–0.90), suggesting that garnet was stable in their source during partial melting. Its evolved Sr–Nd isotopic compositions [(87Sr/86Sr)i = 0.7041–0.7061, and εNd(t) = −3.1 to −4.3] and high contents of K2O (3.22–3.84%) and Th (13.7–19.0 ppm) clearly indicate an origin from the continental crust. In addition, its high Mg# (51–55), Cr and Ni contents may result from mixing with the SCLM-derived mafic magma. Most of the zircon grains from the adakitic monzogranite show negative εHf(t) values of −9.4 to −0.1 with two-stage Hf model ages of 1,043–1,517 Ma; some zircon grains display positive εHf(t) of 0.1–3.9 with single-stage Hf ages of 704–856 Ma. These indicate that the source region of adakitic monzogranite contains the Neoproterozoic juvenile crust that has the positive εHf(t) values in the Triassic. Thus, the high-Mg adakitic granites in the intracontinental setting would form by mixing between the crustal-derived adakitic magma and the SCLM-derived mafic magma. The mafic and adakitic magmas were generated coevally at Late Triassic, temporally consistent with the exhumation of deeply subducted continental crust in the northern margin of the South China Block. This bimodal magmatism postdates slab breakoff at mantle depths and therefore is suggested as a geodynamic response to lithospheric extension subsequent to the continental collision between the South China and North China Blocks.  相似文献   

9.
The Early Devonian Gumeshevo deposit is one of the largest ore objects pertaining to the dioritic model of the porphyry copper system paragenetically related to the low-K quartz diorite island-arc complex. The (87Sr/86Sr)t and (ɛNd)t of quartz diorite calculated for t = 390 Ma are 0.7038–0.7045 and 5.0–5.1, respectively, testifying to a large contribution of the mantle component to the composition of this rock. The contents of typomorphic trace elements (ppm) are as follows: 30–48 REE sum, 5–10 Rb, 9–15 Y, and 1–2 Nb. The REE pattern is devoid of Eu anomaly. Endoskarn of low-temperature and highly oxidized amphibole-epidote-garnet facies is surrounded by the outer epidosite zone. Widespread retrograde metasomatism is expressed in replacement of exoskarn and marble with silicate (chlorite, talc, tremolite)-magnetite-quartz-carbonate mineral assemblage. The 87Sr/86Sr ratios of epidote in endoskarn and carbonate in retrograde metasomatic rocks (0.7054–0.7058 and 0.7053–0.7065, respectively) are intermediate between the Sr isotope ratios of quartz dioritic rocks and marble (87Sr/86Sr = 0.70784 ± 2). Isotopic parameters of the fluid equilibrated with silicates of skarn and retrograde metasomatic rocks replacing exoskarn at 400°C are δ18O = +7.4 to +8.5‰ and δD = −49 to −61‰ (relative to SMOW). The δ13C and δ18O of carbonates in retrograde metasomatic rocks after marble are −5.3 to +0.6 (relative to PDB) and +13.0 to +20.2% (relative to SMOW), respectively. Sulfidation completes metasomatism, nonuniformly superimposed on all metasomatic rocks and marbles with formation of orebodies, including massive sulfide ore. The δ34S of sulfides is 0 to 2‰ (relative to CDT);87Sr/86Sr of calcite from the late calcite-pyrite assemblage replacing marble is 0.704134 ± 6. The δ13C and 87Sr/86Sr of postore veined carbonates correlate positively (r = 0.98; n = 6). The regression line extends to the marble field. Its opposite end corresponds to magmatic (in terms of Bowman, 1998b) calcite with minimal δ13C, δ18O, and 87Sr/86Sr values (−6.9 ‰, +6.7‰, and 0.70378 ± 4, respectively). The aforementioned isotopic data show that magmatic fluid was supplied during all stages of mineral formation and interacted with marble and other rocks, changing its Sr, C, and O isotopic compositions. This confirms the earlier established redistribution of major elements and REE in the process of metasomatism. A contribution of meteoric and metamorphic water is often established in quartz from postore veins.  相似文献   

10.
Isotopic (Nd and Sr) and chemical compositions of the 177 Ma Kirkpatrick Basalt and Ferrar Dolerite from north Victoria Land, Antarctica, are examined in order to address the role of crustal assimilation and the characteristics of their mantle source. Results for the Scarab Peak chemical type (SPCT) that constitutes the flow unit capping the lava sequence [Mg-number, Mg/(Mg+Fe+2)=24, MgO=2.4%, SiO2=57.1%, initial87Sr/86Sr=0.7087–0.7097, (εNd=−4.3) conform previous reports that attribute variations in the concentrations of the more mobile elements and calculated initial87Sr/86Sr to mid-Cretaceous alteration and elevated δ18O to low-temperature interaction with meteoric water. The underlying lavas and the sills that are of the Mt. Fazio chemical type (MFCT) display a much wider range of both chemical and isotopic compositions (Mg-number=40–65, MgO=3.7 7.5%; SiO2=52.6–58.3%, initial87Sr/86Sr=0.7087–0.7117, εNd=−5.6 to −4.8). The effects of rock alteration on apparent initial87Sr/86Sr are demonstrated by large differences between the initial ratio of mineral separates or leached fractions and whole rocks. Cretaceous alteration produced Rb and Sr redistribution within the lava sequence that results in erroneous calculated initial87Sr/86Sr ratios. These effects are responsible for the large initial87Sr/86Sr variations previousl7 proposed which, combined with the large range in whole-rock δ18O, were purported to show very large degrees of crustal assimilation. The variations in εNd are restricted and indicate much smaller degrees of assimilation. The least altered of the MFCT rocks show good chemical and isotopic correlations that can be integrated into a model involving fractionation of pyroxene and plagioclase coupled with assimilation of material similar to early Paleozoic basement. The lower87Sr/86Sr and higher εNd of the SPCT suggest that they were derived by extensive fractionation of a more primitive, less contaminated, precursor of the MFCT. The most isotopically primitive Ferrar rocks from the region still have a high initial87Sr/86Sr and low initial143Nd/144Nd; this may reflect either earlier assimilation or an enriched source. The chemical and isotopic similarities, as well as the close geographic correspondence of the Ferrar Group to granitoids produced during the early Paleozoic Ross Orogeny suggest that in either case Ross-type material may have been involved in the development of the enriched isotopic signature. Editorial responsibility: I. Parsons  相似文献   

11.
 Nd, Sr and O isotope systematics were used to investigate the petrogenesis of two adjacent plutons of the Bethlehem Gneiss (BG) and the Kinsman Quartz Monzonite (KQM), exposed within the Central Maine Terrane (CMT) of New England. Both are Acadian-aged (≈413 Ma) synmetamorphic and syntectonic members of the New Hampshire Plutonic Series (NHPS). Potential source rocks analyzed for this study include Silurian and Devonian metasedimentary rocks of the CMT, and Ordovician metasedimentary rocks and granitic gneisses of the Bronson Hill Anticlinorium (BHA), which border the CMT to the west. The ɛSr(413),  ɛNd(413) and δ18O values for the KQM range from 56.3 to 120.0, 2.8 to −6.4, and 7.6‰ to 12.9‰, respectively; values for the BG range from 7.4 to 144.7, 0.6 to −9.3, and 8.3‰ to 11.3‰, respectively; and values for possible source rocks range from 38.1 to 654.2, −10.7 to 5.4, and 6.2‰ to 14.1‰, respectively. Both the BG and KQM have extremely heterogeneous initial isotopic compositions consistent with mixing of multiple crustal source rocks, and neither contains a volumetrically significant (i.e., ≥10%) mantlederived component. Overlapping values of ɛNd(413),  ɛSr(413) and δ18O values for both the BG and KQM samples resemble values for metasedimentary host rocks of the CMT and BHA. We observe no systematic correlations between ɛNd and ɛSr values for either the BG or the KQM. The ɛSr and δ18O values for the BG do not form any simple mixing trends, nor is there any direct correlation between the isotopic compositions of contact BG samples and their adjacent host rocks, in contrast to our observations for the KQM (Lathrop et al. 1994). We propose that the KQM and BG magmas were generated through anatexis of metasedimentary rocks from both the BHA and CMT in response to crystal thickening during the Acadian orogeny. Melting may have been initiated within CMT metasediments in response to high heat production in these mid-crustal rocks combined with crustal thickening, whereas melting of BHA rocks with normal crustal heat production, which were located at lower-crustal levels than CMT rocks, is likely to have been driven by crustal thickening alone. Following upward advection of mobile BHA magmas, BHA- and CMT-derived magmas may have mingled during complex Acadian deformation in the CMT, thus accounting for the isotopic similarities we observe between the BG and the KQM. Received: 13 September 1994/Accepted: 31 January 1996  相似文献   

12.
Peraluminous granitoids provide critical insight as to the amount and kinds of supracrustal material recycled in the central Sierra Nevada batholith, California. Major element concentrations indicate Sierran peraluminous granitoids are high-SiO2 (68.9–76.9) and slightly peraluminous (average molar Al2O3/(CaO + Na2O + K2O)=1.06). Both major and trace element trends mimic those of other high-silica Sierran plutons. Garnet (Grt) in the peraluminous plutons is almandine–spessartine-rich and of magmatic origin. Low grossular contents are consistent with shallow (<4 kbar) depths of garnet crystallization. Metasediments of the Kings Sequence commonly occur as wallrocks associated with the plutons, including biotite schists that are highly peraluminous (A/CNK=2.25) and have high whole rock (WR) δ18O values (9.6–21.8‰, average=14.5±2.9‰, n=26). Ultramafic wallrocks of the Kings–Kaweah ophiolite have lower average δ18O (7.1±1.3‰, n=9). The δ18O(WR) of the Kings Sequence is variable from west to east. Higher δ18O values occur in the west, where quartz in schists is derived from marine chert; values decrease eastward as the proportion of quartz from igneous and metamorphic sources increases. Peraluminous plutons have high δ18O(WR) values (9.5–13‰) consistent with supracrustal enrichment of their sources. However, relatively low initial 87Sr/86Sr values (0.705–0.708) indicate that the supracrustal component in the source of peraluminous magmas was dominantly altered ocean crust and/or greywacke. Also, plutons lack or have very low abundances (<1% of grains) of inherited zircon (Zrc) cores. Average δ18O(Zrc) is 7.9‰ in peraluminous plutons, a higher value than in coeval metaluminous plutons (6–7‰). Diorites associated with peraluminous plutons also have high δ18O(Zrc), 7.4–8.3‰, which is consistent with the diorites being derived from a similar source. Magmatic garnet has variable δ18O (6.6–10.5‰, avg.=7.9‰) due to complex contamination and crystallization histories, evidenced by multiple garnet populations in some rocks. Comparison of δ18O(Zrc) and δ18O(Grt) commonly reveals disequilibrium, which documents evolving magma composition. Minor (5–7%) contamination by high δ18O wallrocks occurred in the middle and upper crust in some cases, although low δ18O wallrock may have been a contaminant in one case. Overall, oxygen isotope analysis of minerals having slow oxygen diffusion and different times of crystallization (e.g., zircon and garnet), together with detailed textural analysis, can be used to monitor assimilation in peraluminous magmas. Moreover, oxygen isotope studies are a valuable way to identify magmatic versus xenocrystic minerals in igneous rocks. Electronic Supplementary Material Supplementary material is available for this article at  相似文献   

13.
Mafic complexes in the central Sierra Nevada batholith record valuable geochemical information regarding the role mafic magmas play in arc magmatism and the generation of continental crust. In the intrusive suite of Yosemite Valley, major and trace element compositions of the hornblende-bearing gabbroic rocks from the Rockslides mafic complex and of the mafic dikes in the North America Wall are compositionally similar to high-alumina basalt. Of these rocks, two samples have higher Ni and Cr abundances as well as higher εNd values than previously recognized for the intrusive suite. Plagioclase crystals in rocks from the North America Wall and the Rockslides have prominent calcic cores and sharply defined sodic rims, a texture commonly associated with mixing of mafic and felsic magmas. In situ analyses of 87Sr/86Sr in plagioclase show no significant isotopic difference from the cores to the rims of these grains. We propose that the high 87Sr/86Sr (~0.7067) and low εNd (~?3.4) of bulk rocks, the homogeneity of 87Sr/86Sr in plagioclase, and the high δ18O values of bulk rocks (6.6–7.3 ‰) and zircon (Lackey et al. in J Petrol 49:1397–1426, 2008) demonstrate that continental crust was assimilated into the sublithospheric mantle-derived basaltic precursors of the mafic rocks in Yosemite Valley. Contamination (20–40 %) likely occurred in the lower crust as the magma differentiated to high-alumina basalt prior to plagioclase (and zircon) crystallization. As a consequence, the isotopic signatures recorded by whole rocks, plagioclase, and zircon do not represent the composition of the underlying lithospheric mantle. We conclude that the mafic and associated felsic members of the intrusive suite of Yosemite Valley represent 60–80 % new additions to the crust and include significant quantities of recycled ancient crust.  相似文献   

14.
In situ zircon U–Pb and Hf-isotopic data have been determined for mafic microgranular enclaves and host granitoids from the Early Cretaceous Gudaoling batholith in the Liaodong Peninsula, NE China, in order to constrain the sources and petrogenesis of granites. The zircon U–Pb age of the enclaves (120 ± 1 Ma) is identical to that of the host monzogranite (120 ± 1 Ma), establishing that the mafic and felsic magmas were coeval. The Hf isotopic composition of the enclaves [ε Hf(t) = +4.5 to −6.2] is distinct from the host monzogranite [ε Hf(t) = −15.1 to −25.4], indicating that both depleted mantle and crustal sources contributed to their origin. The depleted mantle component was not previously revealed by geochemical and Nd and Sr isotopic studies, showing that zircon Hf isotopic data can be a powerful geochemical tracer with the potential to provide unique petrogenetic information. Some wall-rock contamination is indicated by inherited zircons with considerably older U–Pb ages and low initial Hf isotopic compositions. Hafnium isotopic variations in Early Cretaceous zircons rule-out simple crystal–liquid fractionation or restite unmixing as the major genetic link between enclaves and host rocks. Instead, mixing of mantle-derived mafic magmas with crustal-derived felsic magmas, coupled with assimilation of wall rocks, is compatible with the data. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.  相似文献   

15.
Extensive Permo-Carboniferous volcanism has been documented from the Bohemian Massif. The late Carboniferous volcanic episode started at the Duckmantian–Bolsovian boundary and continued intermittently until Westphalian D to Stephanian B producing mainly felsic and more rarely mafic volcanics in the Central Bohemian and the Sudetic basins. During the early Permian volcanic episode, after the intra-Stephanian hiatus, additional large volumes of felsic and mafic volcanics were extruded in the Sudetic basins. The volcanics of both episodes range from entirely subalkaline (calc-alkaline to tholeiitic) of convergent plate margin-like type to transitional and alkaline of within-plate character. A possible common magma could not be identified among the Carboniferous and Permian primitive magmas, but a common geochemical signature (enrichment in Th, U, REE and depletion in Nb, Sr, P, Ti) in the volcanic series of both episodes was recognized. On the other hand, volcanics of both episodes differ in intensities of Nb, Sr and P depletion and also, in part, in their isotope signatures. High 87Sr/86Sr (0.707–0.710) and low εNd (−6.0 to −6.1) are characteristic of the Carboniferous mafic volcanics, whereas low 87Sr/86Sr (0.705–0.708) and higher εNd ranging from −2.7 to −3.4 are typical of the Permian volcanics. Felsic volcanics of both episodes vary substantially in 87Sr/86Sr (0.705–0.762) and εNd (−0.9 to −5.1). Different depths of magma source or heterogeneity of the Carboniferous and Permian mantle can be inferred from variation in some characteristic elements of the geochemical signature for volcanics in some basins. The Sr–Nd isotopic data with negative εNd values confirm a significant crustal component in the volcanic rocks that may have been inherited from the upper mantle source and/or from assimilation of older crust during magmatic underplating and ascending of primary basic magma. Two different types of primary magma development and formation of a bimodal volcanic series have been recognized: (i) creation of a unique magma by assimilation fractional crystallization processes within shallow-level reservoirs (type Intra-Sudetic Basin) and (ii) generation and mixing of independent mafic and felsic magmas, the latter by partial melting of upper crustal material in a high-level chamber (type Krkonoše Piedmont Basin). A similar origin for the Permo-Carboniferous volcanics of the Bohemian Massif is obvious, however, their geochemical peculiarities in individual basins indicate evolution in separate crustal magma chambers.  相似文献   

16.
Extensional-tectonic processes have generated extensive magmatic activity that produced volcanic/plutonic rocks along an E-W-trending belt across north-western Turkey; this belt includes granites and coeval volcanic rocks of the Ala?amdağ volcano-plutonic complex. The petrogenesis of the Early Miocene Ala?amdağ granitic and volcanic rocks are here investigated by means of whole-rock Sr–Nd isotopic data along with field, petrographic and whole-rock geochemical studies. Geological and geochemical data indicate two distinct granite facies having similar mineral assemblages, their major distinguishing characteristic being the presence or absence of porphyritic texture as defined by K-feldspar megacrysts. I-type Ala?amdağ granitic stocks have monzogranitic-granodioritic compositions and contain a number of mafic microgranular enclaves of monzonitic, monzodioritic/monzogabbroic composition. Volcanic rocks occur as intrusions, domes, lava flows, dykes and volcanogenic sedimentary rocks having (first episode) andesitic and dacitic-trachyandesitic, and (second episode) dacitic, rhyolitic and trachytic-trachydacitic compositions. These granitic and volcanic rocks are metaluminous, high-K, and calc-alkaline in character. Chondrite-normalised rare earth element patterns vary only slightly such that all of the igneous rocks of the Ala?amdağ have similar REE patterns. Primitive-mantle-normalised multi-element diagrams show that these granitic and volcanic rocks are strongly enriched in LILE and LREE pattern, high (87Sr/86Sr)i and low ε Nd(t) ratios suggesting Ala?amdağ volcano-plutonic rocks to have been derived from hybrid magma that originated mixing of co-eval lower crustal-derived more felsic magma and enriched subcontinental lithospheric mantle-derived more mafic magmas during extensional processes, and the crustal material was more dominant than the mantle contribution. The Ala?amdağ volcano-plutonic complex rocks may form by retreat of the Hellenic/Aegean subduction zone, coinciding with the early stages of back-arc extension that led to extensive metamorphic core-complex formation.  相似文献   

17.
Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼ 0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; (ΣHREE)N ∼ 2–3 times chondrite, (Gd/Yb)N ∼ 1). The εNd(t) values vary from +1.23 to -3.27 whereas δ18O values vary from +3.16‰ to +5.29‰ (average +3.97‰±0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (± silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable εNd, low Sri(0.702) and low δ18O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.  相似文献   

18.
We show here that the Amalaoulaou complex, in the Pan-African belt of West Africa (Gourma, Mali), corresponds to the lower and middle sections of a Neoproterozoic intra-oceanic arc. This complex records a 90–130-Ma-long evolution of magmatic inputs and differentiation above a subducting oceanic slab. Early c. 793 Ma-old metagabbros crystallised at lower crustal or uppermost mantle depths (25–30 km) and have geochemical characteristic of high-alumina basalts extracted from a depleted mantle source slightly enriched by slab-derived sedimentary components ((La/Sm)N < 1; εNd: +5.4–6.2; 87Sr/86Sr: 0.7027–0.7029). In response to crustal thickening, these mafic rocks were recrystallised into garnet-granulites (850–1,000°C; 10–12 kbar) and subject to local dehydration–melting reactions, forming trondhjemititic leucosomes with garnet–clinopyroxene–rutile residues. Slightly after the granulitic event, the arc root was subject to strong HT shearing during partial exhumation (detachment faults/rifting or thrusting), coeval with the emplacement of spinel- and garnet-pyroxenite dykes crystallised from a high-Mg andesitic parental magma. Quartz and hornblende-gabbros (700–660 Ma) with composition typical of hydrous volcanic rocks from mature arcs ((La/Sm)N: 0.9–1.8; εNd: +4.6 to +5.2; 87Sr/86Sr: 0.7028–0.7031) were subsequently emplaced at mid-arc crust levels (~15 km). Trace element and isotopic data indicate that magmas tapped a depleted mantle source significantly more enriched in oceanic sedimentary components (0.2%). Exhumation occurred either in two stages (700–660 and 623 Ma) or in one stage (623 Ma) with a final exhumation of the arc root along cold P-T path (550°C, 6–9 kbar; epidote–amphibolite and greenschist facies conditions) during the main Pan-African collision event (620–580 Ma). The composition of magmas forming the Cryogenian Amalaoulaou arc and the processes leading to intra-arc differentiation are strikingly comparable to those observed in the deep section of exposed Mezosoic oceanic arcs, namely the Kohistan and Talkeetna complex. This evolution of the Amalaoulaou oceanic arc and its accretion towards the West African craton belong to the life and closure of the Pharusian Ocean that eventually led to the formation of the Greater Gondwana supercontinent, a similar story having occurred on the other side of the Sahara with the Mozambique Ocean.  相似文献   

19.
A garnet-bearing tonalitic porphyry from the Achiq Kol area, northeast Tibetan Plateau has been dated by SHRIMP U-Pb zircon techniques and gives a Late Triassic age of 213 ± 3 Ma. The porphyry contains phenocrysts of Ca-rich, Mn-poor garnet (CaO > 5 wt%; MnO < 3 wt%), Al-rich hornblende (Al2O3 ~ 15.9 wt%), plagioclase and quartz, and pressure estimates for hornblende enclosing the garnet phenocrysts yield values of 8–10 kbar, indicating a minimum pressure for the garnet. The rock has SiO2 of 60–63 wt%, low MgO (<2.0 wt%), K2O (<1.3 wt%), but high Al2O3 (>17 wt%) contents, and is metaluminous to slightly peraluminous (ACNK = 0.89–1.05). The rock samples are enriched in LILE and LREE but depleted in Nb and Ti, showing typical features of subduction-related magmas. The relatively high Sr/Y (~38) ratios and low HREE (Yb < 0.8 ppm) contents suggest that garnet is a residual phase, while suppressed crystallization of plagioclase and lack of negative Eu anomalies indicate a high water fugacity in the magma. Nd–Sr isotope compositions of the rock (εNdT = −1.38 to −2.33; 87Sr/86Sri = 0.7065–0.7067) suggest that both mantle- and crust-derived materials were involved in the petrogenesis, which is consistent with the reverse compositional zoning of plagioclase, interpreted to indicate magma mixing. Both garnet phenocrysts and their ilmenite inclusions contain low MgO contents which, in combination with the oxygen isotope composition of garnet separates (+6.23‰), suggests that these minerals formed in a lower crust-derived felsic melt probably in the MASH zone. Although the rock samples are similar to adakitic rocks in many aspects, their moderate Sr contents (<260 ppm) and La/Yb ratios (mostly 16–21) are significantly lower than those of adakitic rocks. Because of high partition coefficients for Sr and LREE, fractionation of apatite at an early stage in the evolution of the magma may have effectively decreased both Sr and LREE in the residual melt. It is suggested that extensive crystallization of apatite as an early phase may prevent some arc magmas from evolving into adakitic rocks even under high water fugacity.  相似文献   

20.
The post-collisional Saraycık granodiorite intruded into a late Paleocene to early Eocene nappe pile that formed during collision of the Pontides in the North and the Anatolide-Tauride platform in the South, leading to the formation of the İzmir-Ankara-Erzincan suture. A relatively shallow pluton intrusion depth (∼5 to 8 km) was estimated from Al-in-hornblende geobarometry and contact metamorphic assemblages. The emplacement age is tightly constrained to ∼52 Ma by two Ar–Ar plateau and total fusion ages on biotite. The main mass of the pluton consists of metaluminous to peraluminous biotite granodiorite and hornblende-biotite granodiorite. In addition, up to 10-m thick dacitic and <25-cm thick aplitic dikes occur. Granodiorites and dacites show many close compositional similarities to high-silica adakites from supra-subduction zone settings, but tend to be slightly more felsic and to have a higher aluminium saturation index. Chondrite-normalized (cn) rare earth element patterns are characterized by high ratios of (La/Yb)cn, concave-upward shapes of the HREE and a lack of significant Eu anomalies. In conjunction with relatively high abundances of Ba and Sr as well as low abundances of Y, HREE and Sc, these patterns suggest a feldspar-poor, garnet ± amphibole-rich fractionating mineral assemblage (residue). All samples have very similar Nd–Sr isotopic characteristics, regardless of rock type. Initial εNd values range from −0.3 to −1.2 and initial 87Sr/86Sr ratios from 0.70491 to 0.70529. It is suggested that the magmas formed by partial melting of mafic lower crust at elevated pressures (∼1 to 2 GPa).  相似文献   

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