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1.
板内火山活动是板内下方深部物质组成的重要视窗,而中国东北是研究板内火山的热点场所.中国东北火山活动主要沿大兴安岭及松辽盆地周缘分布,隐匿在大兴安岭内的各火山群落鲜有地球物理观测.本研究聚焦于大兴安岭北部的诺敏河火山群,利用围绕诺敏河火山布设的43个流动台站记录到的17个远震事件数据,通过时间域波形匹配法计算了300条直达P波震相的Δt*,并进一步采用贝叶斯蒙特卡洛方法反演得到了研究区的二维Δt*模型,为约束诺敏河火山地区的深部结构提供了新的观测证据.结果显示研究区高衰减区域与火山活动在空间位置上有很好的一致性.诺敏河火山与研究区北端临近小古里河火山区域均观测到高Δt*值,可能由区域下方热地幔物质上涌导致.诺敏河火山东部、科洛河火山西部区域观测到低Δt*值,与高衰减区域最大Δt*差值达约0.3±0.05 s,可能由两部分原因导致:该区域下方残留未被侵蚀的岩石圈,以及局部区域或存在的部分熔融导致的残留地幔矿物脱水.  相似文献   

2.
Takemi  Ishihara  Keita  Koda 《Island Arc》2007,16(3):322-337
Abstract   Crustal thickness of the northern to central Philippine Sea was gravimetrically determined on the simple assumption of four layers: seawater, sediments, crust and lithospheric mantle, with densities of 1030, 2300, 2800 and 3300 kg/m3, respectively. As for the correction of the regional gravity variation, a 15 km difference of the lithospheric thickness with a density difference of 50 kg/m3 against the asthenosphere below between both sides of the Kyushu-Palau Ridge was taken into consideration. Mantle Bouguer anomalies were calculated on the assumption of constant crustal thickness of 6 km, and then the crustal thickness was obtained by three-dimensional gravity inversion method. The results show occurrence of thin crust areas with a thickness of approximately 5 km in the southern part and at the western margin of the Shikoku Basin and also of thick crust areas in the northwestern and northeastern parts of the Parece Vela Basin. We suggest that these are because of the variation of magma supply at the time of sea floor spreading in the Shikoku and Parece Vela Basins, which is possibly related to the variation of spreading rate and enhanced magmatism near the past arc volcanic fronts. The results further show the occurrence of crust thinner than 5 km in the northeastern part of the West Philippine Basin, of crust thicker than 15 km in the Amami Plateau, the Daito and Oki-Daito Ridges, and also in the northern part of Kyushu-Palau Ridge, whereas the southern part of the Kyushu-Palau Ridge the crust is thicker than 10 km. It was also inferred that small basins in the Daito Ridge province have the thinnest oceanic crust of less than 5 km in the Kita-Daito Basin.  相似文献   

3.
Benthic foraminiferal magnesium/calcium ratios were determined on one hundred and forty core-top samples from the Atlantic Ocean, the Norwegian Sea, the Indian Ocean, the Arabian Sea and the Pacific Ocean, mostly at sites with bottom water temperatures below 5 °C. Mg/Ca ratios are consistently lower, by  0.2 mmol/mol, in samples cleaned using oxidative and reductive steps than using oxidative cleaning. Differences between Cibicidoides species have been identified: Mg/Ca of Cibicidoides robertsonianus > Cibicidoides kullenbergi > Cibicidoides wuellerstorfi. Comparison with bottom water temperatures support observations of lowered Mg/Ca of C. wuellerstorfi at temperature below  3 °C compared with values predicted by published calibrations and from other Cibicidoides species. Hydrographic data shows that carbonate ion saturation (Δ[CO32−]) decreases rapidly below this temperature. An empirical sensitivity of Δ[CO32−] on Mg/Ca has been established for C. wuellerstorfi of 0.0086 ± 0.0006 mmol/mol/μmol/kg. A novel application using modern temperatures and Last Glacial Maximum temperatures derived via pore fluid modelling supports a carbonate ion saturation state effect on Mg incorporation. This may significantly affect calculated δ18Oseawater obtained from foraminiferal δ18O and Mg/Ca temperature.  相似文献   

4.
In this study, three receiver function stacking methods are used to study the detailed crust and upper mantle structure beneath south-central Alaska. We used teleseismic waveform data recorded by 36 stations in the Broadband Experiment Across the Alaska Range (BEAAR) and 4 permanent stations in Alaska. H − κ stacking method using P-to-S converted wave and its multiply reflected waves between the Earth's surface and the Moho discontinuity is adopted to estimate the crustal thickness (H) and average crustal VP/VS ratio (κ) in this region. The receiver function results for 24 stations show that the crustal thickness under Alaska ranges from 26.0 to 42.6 km with an average value of 33.8 km, and the VP/VS ratio varies from 1.66 to 1.94 with an average value of 1.81 which corresponds to an average Poisson's ratio of 0.277 with a range from 0.216 to 0.320. High Poisson's ratios under some stations are possibly caused by partial melting in the crust and the uppermost mantle. Common converted point (CCP) stacking results of receiver functions along three lines show clear Moho and slab images under this subduction zone. The depths of the slab from our CCP stacking images are consistent with those estimated from the Wadati–Benioff Zone (WBZ). In the area between two stations DH2 (147.8°W, 63.3°N) and DH3 (147.1°W, 63.0°N), a Moho depth offset of about 10 km is found by both the H − κ and CCP stacking techniques. Common depth point (CDP) stacking of receiver functions shows not only the 410-, 520- and 660-km discontinuities, but also significant variations (−30 to 15 km) in the transition zone thickness under the southwest and southeast parts of the study region. The transition zone becomes thinner by 20–30 km, indicating that the temperature there is 150–200 K higher than that of the normal mantle.  相似文献   

5.
Values of bulk modulus (K), shear modulus (G) and mechanical quality factor (Q) have been determined for polycrystalline samples across the CaTiO3 (CST0)–SrTiO3 (CST100) solid solution by resonant ultrasound spectroscopy. Because of similarities with low frequency elastic and anelastic anomalies due to twin wall motion reported in previous studies, a working hypothesis is developed in which dissipation processes are interpreted in terms of twin wall displacements. At high temperatures in CST50 the stability field of the I4/mcm structure is marked by the disappearance of all resonance peaks (superattenuation). This is attributed to anelastic domain wall sliding. At room temperature the I4/mcm phase of CST70 and CST80 has values of G which are lower than those of cubic or orthorhombic phases, and a concomitant drop in Q is interpreted as implying that the domain wall pinning process reported elsewhere to occur below 400–450 K is only partial. A similar drop in G and Q was found in CST95 below the transition at 238 K. The I4/mcm ↔ Pbcm transition in CST70 at 230 K is marked by an abrupt increase in Q, suggesting that mobile twins in crystals with the I4/mcm structure become effectively immobile in antiferroelectric crystals with the Pbcm structure. The I4/mcm ↔ Pnma transition in CST50 is marked by a similarly abrupt increase in Q, consistent with twin walls becoming effectively immobile also in crystals with the Pnma structure. A fall in Q below 800 K in CST0, however, could imply that a degree of twin wall mobility might develop in Pnma crystals if the tetragonal spontaneous strain departs significantly from zero. The remarkable attenuation behaviour of crystals with the I4/mcm structure at the relatively low stress conditions which apply during resonances of a parallelepiped with edge dimensions of 2–4 mm, is consistent with the view that a characteristic signature for tetragonal CaSiO3 in the Earth's lower mantle should be a marked attenuation of seismic waves.  相似文献   

6.
We investigated the physical properties in the upper mantle beneath the Philippine Sea using a theoretical relation derived by Karato [Mapping water content in the upper mantle. Subduction factory, AGU Monograph, in press]. From the attenuation model of Shito and Shibutani [Phys. Earth Planet. Interact., in press] and the velocity model of Widiyantoro et al. [Earth Planet. Sci. Lett. 173 (1999) 91], observed attenuation and velocity anomalies were evaluated to explain the temperature, water content, and chemical heterogeneities in the target area. The results indicate that the observed anomalies in the shallower regions (50–200 km) may be due to chemical composition effects (e.g., concentration of iron), in addition to the temperature and water content anomalies. In contrast, for the deep upper mantle (300–400 km), the observations can be explained by only the effects of high water content (10–50 times higher than the average mantle). These inferred properties of the mantle are consistent with the tectonic history of the Philippine Sea region, which has had a long history of subduction and active magmatism.  相似文献   

7.
为了研究海沟型巨大地震发生机制及其构造动力学特征,详细研究了地震活动与震源机制结果,根据地震俯冲带几何形状及其内应力场区域特征,南海海槽下的俯冲带可划分为两段: 东部的四国-纪伊半岛段和西部的九州段. 东部的菲律宾海板块地震俯冲带呈现出低角度俯冲(10°~22°),且俯冲深度相当浅(60~85km)的特征;而西部九州段的俯冲带为高角度俯冲(40°),且俯冲深度较深(160km). 东、西部俯冲带内部应力场也截然不同. 东部的四国大部分地区和纪伊半岛的俯冲带内表现为俯冲压缩型应力场, 而西部的九州段则为明显的俯冲拉张型应力场. 本文在综合分析了重力异常、GPS、热流量等地球物理观测结果后指出,南海海槽东部, 即四国-纪伊半岛以南的海槽区域, 具有与智利海沟极其相似的地震发生板块构造动力学背景和高应力积累等特征, 属于年轻活动俯冲带的高应力型俯冲. 而西部的九州段,虽然也是海沟型地震活动区, 但不具有大地震发生的构造动力学背景和高应力积累, 不属于年轻活动俯冲带的高应力型俯冲. 俯冲带年龄的不同很可能是造成南海海槽东、西段板块构造动力学以及应力场不同的根本原因之一.  相似文献   

8.
选取2016年3月—2019年6月内蒙古地震监测台网记录的925条内蒙古东北部及邻近地区地震数据,从中挑选133次M_L≥2.0且记录清晰、信噪比较高的地震事件,利用Sato模型、Aki模型,分别计算该区域地震尾波平均Q值,并拟合得到Q值对频率的依赖关系,其中:(1)Sato模型:Q_C(f)=(64.11±29.15)f~((0.8914±0.0772));(2)Aki模型:Q_C(f)=(258.4±65)f~((0.6815±0.1435))。结果表明,利用2种模型计算的该区域地震尾波Q值分布具有一致性,且Q值与依赖指数η成反比关系,分析认为,尾波Q值高低分布与地震活动性及地质构造有关。  相似文献   

9.
使用纵波震相及同台同源纵波和横波震相的走时资料及层析成像反演方法,分别给出了菲律宾海板块(PHP)和南海地区的纵波速度Vpf及同台同源的纵波和横波速度Vp和Vs结构. 结果表明,(1) PHP与欧亚板块(EUAP)的俯冲接触关系随地段而异,在琉球海沟,PHP向EUAP之下俯冲深达400 km;在台湾岛,EUAP先近陡直地俯冲到深度400 km,然后折向PHP之下达到660 km左右;在马尼拉海沟北段,俯冲板片几乎垂直达到660 km附近;在菲律宾海沟,PHP向EUAP之下的俯冲深度超过660 km.(2)南海地区之下是一个深达300~400 km的宽阔低速区,并且大致在莺琼海盆与700 km深处另一低速区曲折相通;在该宽阔低速区内部,有两个小而明显的低速区分别在海口火山和珠江口盆地下方.(3)对Vp和Vs及据其算出的容声速度Vb作分析发现,Vs和Vb的平均扰动量对深度的变化在一些深度范围内是反向的;年龄较大的太平洋板块俯冲体的Vs相对扰动量的平均值大于Vb的,而在较年轻的PHP俯冲体中则正好相反.  相似文献   

10.
现代地震学展现出了一个复杂的地球内核内部和表面结构.地球内核内部结构的主要特征表现为其地震波速度和衰减呈现各向异性,且各种结构(速度、衰减和各向异性)均呈现东西半球差异,而内核表面的新发现则包括其局部区域存在起伏的地形和固液并存的糊状层.地球内核压缩波速度和衰减均呈现以地球旋转轴为轴的柱对称各向异性,沿地球旋转轴方向传播的压缩波比沿赤道方向传播的压缩波传播更快且衰减更强烈.同时,内核各向异性结构随深度而变化:内核顶部约100~400 km接近各向同性,而在内核最深处300~600 km内则可能存在一个具有不同各向异性特征的内内核.地球内核的东西半球差异表现在多方面:在内核顶部~100 km厚度内,东半球的各向同性速度比西半球快约0.8%,东半球具有较强的衰减(Q=250),而西半球则具有较弱的衰减(Q=600);西半球的顶部各向同性层厚度约为100 km,而东半球顶部各向同性层厚度则约为400 km;在各向同性层底下,西半球具有较强的各向异性(~4%),而东半球则具有较弱的各向异性(~0.7%).地球内核边界在菲律宾海、黄海、西太平洋以及中美洲下方存在1~14 km高的地形起伏,在鄂霍次克海西南部下方存在4~8 km厚的糊状层.地球内核的这些新发现引发了对许多可能的新物理机制的探讨,也促使我们重新评估我们对外核成分、外核热化学对流、内核凝固过程和地球磁场驱动力的认识.这些结果表明内核凝固过程和地球磁场的热和化学驱动力远比传统观念认为的横向均匀分布复杂得多.内核西半球可能不断凝固并释放潜热和轻元素,而东半球则可能不断熔化并吸收潜热和轻元素,外核对流的驱动力在东西半球可能截然不同,甚至呈现相反方向.这些凝固与熔化交替过程也发生在局部地形起伏区域.在糊状层区域,地球内核凝固释放潜热和化学能,而在大部分无糊状地区,内核凝固只释放潜热.  相似文献   

11.
Magnitude dependent differences between estimates of local magnitude, ML (Richter12.13) based on strong motion data and on the response of Wood-Anderson Seismometer are analyzed. It is suggested that the principal cause for differences for intermediate and small magnitudes (M < 5.5) could be associated with anelastic attenuation; indicating Q values between 100 and 200 in Southern California. For large magnitudes the observed differences are interpreted to result from saturation of strong-motion amplitudes relative to other long period estimates of magnitude.  相似文献   

12.
基于五大连池火山区域地方震资料,选取信噪比高、定位准确且震中位于火山区域的39个地震,根据地震波传播的三段几何衰减模型,使用地震记录位移谱,去除仪器响应、背景噪声,反演求取各频点f的S波Q值,拟合获得火山区体波Q值与f的关系为Qf)=221.7f0.452,计算得到老黑山、火烧山附近区域Q值与f的关系为Qf)=152f0.600,与国内外其他区域体波Q值进行对比,并结合火山区地质构造活动,分析五大连池火山区体波Q值特征。  相似文献   

13.
One of the more prominent architectural elements of the Nankai subduction margin, offshore southwest Japan, is an out‐of‐sequence thrust fault (megasplay) that separates the inner accretionary prism from the outer prism. The inner prism (hanging wall of the megasplay) is dominated by mudstone, which is enigmatic when the sedimentary facies is compared to coeval deposits in the Shikoku Basin (i.e. inputs from the subducting Philippine Sea plate) and to coarser‐grained turbidite sequences from the Quaternary trench wedge. Clay mineral assemblages amplify the mismatches of sedimentary facies. Mudstones from the inner prism are uniformly depleted in smectite, with average bulk values of 23–24 wt%, whereas the Shikoku Basin deposits show progressive decreases in proportions of smectite over time, from averages of 46–48 wt% at 10 Ma to 17–21 wt% at 1 Ma. Plate‐boundary reconstructions for the Philippine Sea region provide one solution to the conundrum. Between 15 Ma and 10 Ma, the Pacific plate subducted near the NanTroSEIZE transect, and a trench‐trench‐trench triple junction migrated to the northeast. Accretion during that period involved sediments that had been deposited on the Pacific plate. Motion of the Philippine Sea plate changed from 10 Ma to 6 Ma, resulting in sinistral slip along the proto‐Nankai Trough. Sediments accreted during that period probably had been deposited near the triple junction, with a hybrid detrital provenance. Renewed subduction of the Philippine Sea plate at 6 Ma led to reorganization of watersheds near the Izu–Honshu collision zone and gradual incision of large submarine canyons on both sides of the colliding Izu arc. Accreted Pliocene mudstones share more of an affinity to the triple junction paleoenvironment than they do to Shikoku Basin. These differences between subducting Shikoku Basin strata and accreted Pacific plate sediments have important implications for interpretations of frictional properties, structural architecture, and diagenetic fluid production.  相似文献   

14.
The Fukuoka District Meteorological Observatory recently logged three possible deep low-frequency earthquakes (LFEs) beneath eastern Kyushu, Japan, a region in which LFEs and low-frequency tremors have never before been identified. To assess these data, we analyzed band-pass filtered velocity seismograms and relocated LFEs and regular earthquakes using the double-difference method. The results strongly suggest that the three events were authentic LFEs, each at a depth of about 50 km. We also performed relocation analysis on LFEs recorded beneath the Kii Peninsula and found that these LFEs occurred near the northwest-dipping plate interface at depths of approximately 29–38 km. These results indicate that LFEs in southwest Japan occur near the upper surface of the subducting Philippine Sea (PHS) plate. To investigate the origin of regional differences in the occurrence frequency of LFEs in western Shikoku, the Kii Peninsula, and eastern Kyushu, we calculated temperature distributions associated with PHS plate subduction. Then, using the calculated thermal structures and a phase diagram of water dehydration for oceanic basalt, the water dehydration rate (wt.%/km), which was newly defined in this study, was determined to be 0.19, 0.12, and 0.08 in western Shikoku, the Kii Peninsula, and eastern Kyushu, respectively; that is, the region beneath eastern Kyushu has the lowest water dehydration rate value. Considering that the Kyushu–Palau Ridge that is subducting beneath eastern Kyushu is composed of tonalite, which is low in hydrous minerals, this finding suggests that the regionality may be related to the amount of water dehydration associated with subduction of the PHS plate and/or differences in LFE depths. Notable dehydration reactions take place beneath western Shikoku and the Kii Peninsula, where the depth ranges for dehydration estimated by thermal modeling agree well with those for the relocated LFEs. The temperature range in which LFEs occur in these regions is estimated to be 400–500 °C.  相似文献   

15.
Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys   总被引:3,自引:0,他引:3  
Many of the heaviest and lightest natural zinc (Zn) isotope ratios have been discovered in hydrothermal ore deposits. However, the processes responsible for fractionating Zn isotopes in hydrothermal systems are poorly understood. In order to better assess the total range of Zn isotopes in hydrothermal systems and to understand the factors which are responsible for this isotopic fractionation, we have measured Zn isotopes in seafloor hydrothermal fluids from numerous vents at 9–10°N and 21°N on the East Pacific Rise (EPR), the TAG hydrothermal field on the Mid-Atlantic Ridge, and in the Guaymas Basin. Fluid δ66Zn values measured at these sites range from + 0.00‰ to + 1.04‰. Of the many physical and chemical parameters examined, only temperature was found to correlate with fluid δ66Zn values. Lower temperature fluids (< 250 °C) had both heavier and more variable δ66Zn values compared to higher temperature fluids from the same hydrothermal fields. We suggest that subsurface cooling of hydrothermal fluids leads to precipitation of isotopically light sphalerite (Zn sulfide), and that this process is a primary cause of Zn isotope variation in hydrothermal fluids. Thermodynamic calculations carried out to determine saturation state of sphalerite in the vent fluids support this hypothesis with isotopically heaviest Zn found in fluids that were calculated to be saturated with respect to sphalerite. We have also measured Zn isotopes in chimney sulfides recovered from a high-temperature (383 °C) and a low-temperature (203 °C) vent at 9–10°N on the EPR and, in both cases, found that the δ66Zn of chimney minerals was lighter or similar to the fluid δ66Zn. The first measurements of Zn isotopes in hydrothermal fluids have revealed large variations in hydrothermal fluid δ66Zn, and suggest that subsurface Zn sulfide precipitation is a primary factor in causing variations in fluid δ66Zn. By understanding how chemical processes that occur beneath the seafloor affect hydrothermal fluid δ66Zn, Zn isotopes may be used as a tracer for studying hydrothermal processes.  相似文献   

16.
A summary of results based mainly on the inversion of available surface-wave dispersion data is given for the Mediterranean area both for crustal and upper mantle structure. The results are presented on maps outlining the regionalization of the crust and the lithosphere-asthenosphere system in the area. It is possible to distinguish several types of crust with average S-wave velocities in the range 2.8–3.8 km s−1 and thickness varying from a minimum of about 10–16 km, in the Western Mediterranean, to a maximum of about 50 km (including a possible transitional layer) beneath the Ionian Sea. The average properties of the crust and of the lithospheric part of the mantle indicate a possible continuous structure extending from North Africa through the Ionian Sea to the Adriatic Sea, characterized by the presence of a transitional layer at the crust-mantle boundary. Strong lateral variations are present in the lithosphere-asthenosphere system both in thickness, from 30 km in the Western Mediterranean, to about 130 km, under the Alps, and in S-wave velocity, from 4.1–4.2 km s−1 up to 4.7 km s−1. The relatively high position of low resistivity material that seems to characterize the Mediterranean area agrees fairly well with the shallower average top of the asthenosphere found in this area from the study of the elastic properties. The usefulness of combining seismological and electromagnetic studies is stressed.  相似文献   

17.
Stable isotope values of Costa Rican surface waters   总被引:3,自引:0,他引:3  
Stable isotope data of surface waters from the humid tropics in general, and Costa Rica in particular, are scarce. To improve our understanding of the spatial distribution of stable isotopes in surface waters, we measured δ18O and δD in river and lake (n=63) and precipitation (n=3) samples from Costa Rica. We also present data from the IAEA/WMO isotopes in precipitation network as context for our study. Surface water isotope values do not strongly correlate with elevation, stream head elevation, stream length, distance from Caribbean Sea, or estimated mean annual precipitation for the country as a whole. However, the data show distinct regional trends. The δ18O and δD values downwind of mountain ranges are inversely related to the altitude of the ranges the air masses traverse. In the lee of the high Talamanca Range, δ18O values are 6–8‰ lower, while in the lee of the lower Tilarán Range δ18O values are 2–3‰ lower than upwind sites along the Caribbean Slope. An altitude effect of −1.4‰ δ18O/km is present on the Pacific slope of southern Costa Rica, equivalent to a temperature effect of −0.3‰/°C. The Nicoya and Osa Peninsulas have higher values than upwind sites, suggesting input of Pacific-sourced moisture, evaporative enrichment, or decreased condensation temperatures. Elevated and increasing d-excess values inland along the Nicaragua Trough suggest a recycled component may be an important contributor to the water budget. These data provide preliminary stable isotope information for Costa Rica, and will benefit paleoclimatic research in the region. More detailed studies would be beneficial to our understanding of the controls on stable isotope composition of tropical waters.  相似文献   

18.
基于Sato模型,采用2016年3月至2018年6月内蒙古东北部及临近地区发生的526次地震事件,挑选ML ≥ 2.0、记录清晰且信噪比较高的102次地震事件,拟合得到内蒙古东北部地区尾波Q值,得到QCf)=(64.74 ±29.09)f(0.8925 ±0.0765);Q值与依赖指数η成反比,且该区北部Q值偏高,南部Q值偏低,可能与地质构造及地震活动性有关。  相似文献   

19.
High-precision in-situ ion microprobe (SIMS) oxygen isotope analysis of zircons from two diorite intrusions associated with the late Caledonian Lochnagar pluton in Scotland has revealed large differences in the degree of heterogeneity in zircon δ18O between the diorites. Zircon crystals from the Cul nan Gad diorite (CnG) show a unimodal distribution of oxygen isotope values (δ18O = 6.0 ± 0.6‰ (2σ)) and no or only minor grain-scale variation. Those from the Allt Darrarie diorite (AD1) show a large range in δ18O and an apparent bimodal distribution with modes of 6.6 ± 0.4‰ and 7.3 ± 0.4‰. Variations of up to 1.2‰ occur between and within grains; both an increase and decrease in δ18O with zircon growth has been observed. The δ18O composition of growing zircon can only change if open-system processes affect the magma composition, i.e. if material of contrasting δ18O composition is added to the magma. The variability in AD1 is interpreted to represent a cryptic record of magma mixing. A ‘deep crustal hot zone’ is a likely site for generation of the dioritic magmas which developed by mixing of residual melts and crustal partial melts or by melting of mafic lower crustal rocks. The overall small number of zircons with mantle-like δ18O values (5.3 ± 0.6‰ (2σ)) in the Lochnagar diorites is largely the product of crustal differentiation rather than crustal growth.

The δ18O of quartz from the CnG and AD1 diorites shows only minor variation (CnG: 10.9 ± 0.5‰ (2σ), AD1: 11.7 ± 0.6‰ (2σ)) within single populations, with no evidence of mixing. Quartz–zircon isotopic disequilibrium is consistent with later crystallisation of quartz from late magmatic fluids, and in case of the AD1 diorite after the inferred magma mixing from a homogenised, higher δ18O melt.

High-precision SIMS oxygen isotope analysis of zircon provides a new approach to identifying and resolving previously undetected early-stage magma mixing and constraining the compositions and origins of the component magmas. A combination of zircon, quartz and whole-rock data has proven to be a powerful tool in reconstructing the petrogenetic evolution of diorite from early crystallisation to late alteration.  相似文献   


20.
In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g−1 lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g−1 lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d−1. The critical concentration in water Wc for positive substrate cooperativity was found to be 2.4 ppb. Below Wc, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g−1 lipid ppb−1 d−1. Above Wc, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form RQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g−1 lipid ppb−1 d1 and δ≈200 μg g−1 lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g−1 lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g−1 lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.  相似文献   

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