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1.
Tenerife is the largest of the seven Tertiary to Recent volcanic islands that make up the Canary Archipelago. The island is composed of volcanics belonging to the basanitetrachyte-phonolite assemblage that characterises many Atlantic islands. The most voluminous development of intermediate and salic volcanics has been in the centre of the island where the Las Canadas volcanoes arose upon a basement shield composed mainly of basanite and ankaramite flows, tuffs and agglomerates. The initial post-shield activity built the Vilaflor volcanic complex (Lower and Upper Canadas Series) that originally covered much of the underlying shield volcanics. A vast collapse of the complex, probably during post-Pleistocene times, in the centre of the island has left a large semi-circular wall, and provides an excellent vertical section through the complex. Quaternary volcanism within the collapsed area has built the twin, central-type volcanoes, Viejo and Teide, both of which have attendant satellite vents. That part of the Vilaflor Complex exposed in Las Canadas, together with the Viejo and Teide volcanoes, comprise the Las Canadas volcanoes.Four distinct rock types can be recognised in these volcanoes, basanite, trachybasanite, plagioclase phonolite, and phonolite. Each rock type can be recognised chemically and mineralogically, but there is essentially a gradational series from basanite to phonolite that includes both aphyric and glomerophyric rocks. The volcanics are strongly undersaturated and sodic, and some of the phonolites are mildly peralkaline. Variations in degree of undersaturation, and trace element abundances indicate a number of cycles of activity which would be consistent with the known field relations.Forsteritic olivine occurs in the basanites and trachybasanites but is not a stable phase in the more salic volcanics. Clinopyroxene is ubiquitous, varying in composition from titanaugite in the basanites to slightly sodic augite in the phonolites. Strongly sodic pyroxene is restricted to the groundmass of the microcrystalline phonolites along with aenigmatite and a kataphoritic amphibole. Plagioclase is found only in the groundmass of the basanites, but andesine and potash-oligoclase are common phenocryst minerals in the trachybasanites and plagioclase phonolites respectively, whereas the characteristic feldspar of the phonolites is anorthoclase.The relatively smooth curves of major and trace element variation, the presence of accumulative volcanics at all stages of differentiation, zoning of the mineral phases, and the clustering of the phonolites around the low temperature trough in Petrogeny's Residua System, all indicate that the descent from basanite to phonolite has resulted from fractional crystallisation of a basanite parent magma. The trend of pyroxene crystallisation, and the fairly constant FeO/Fe2O3 ratio during fractionation indicate crystallisation under low PO2 conditions.  相似文献   

2.
K-Ar dating on a suite of volcanic rocks from the island of Principe gives the following chronology.
  1. Basal palagonite breccia (30.6 ± 2.1 Ma).
  2. Older Lava Series (OLS) basalt (23.6±0.7 Ma) and hawaiite (19.1±0.5 Ma).
  3. Younger Lava Series (YLS) nephelinite (5.60±0.32 Ma) and basanite (3.51 ±0.15).
  4. Intrusive phonolite (5.32±0.17 Ma, 5.48±0.19 Ma), tristanite (4.89±0.15 Ma) and trachyphonolite (6.93±0.68 Ma) plugs.
Phonolites and YLS samples plot on a 5.9±0.3 Ma Rb-Sr isochron. The tristanite-trachy-phonolite suite samples also lie on this isochron. This lends support to the suggestion that the YLS basanite magmas were parental to the phonolites but rules out a similar relationship between the OLS magmas and the tristanite-trachyphonolite suite. The mean initial 87Sr/86Sr ratio for the YLS nephelinites and basanites is 0.70297. The basalts and hawaiites of the OLS show a positive 87Sr/86Sr vs. Rb/Sr correlation which may be interpreted as a 244±43 Ma pseudoisochron. This could be the result of a large-scale heterogeneity generated in the mantle during the early stages in the break-up of Gondwanaland. The mean initial 87Sr/ 86Sr ratio (at 21 Ma) for the OLS (0.70326) is significantly higher than that for the YLS and implies an isotopically distinct mantle source.  相似文献   

3.
The volcanic rocks of the South Atlantic Ocean islands of Fernando de Noronha and Trindade comprise a diverse magmatic series ranging from nephelinites and basanites to phonolites and, on Fernando de Noronha, trachytes. All rock types are highly silica undersaturated with the exception of Fernando de Noronha trachytes_, and have high abundances of incompatible trace elements and strongly LREE (light rare earth element)-enriched REE patterns. Crystal fractionation of parental basanitic magmas produced evolved phonolites and trachytes which display severe trace-element fractionation, even among trace elements (Nb, Ta, Zr, Hf) which normally behave highly incompatibly during crystallisation of alkaline magmas. Moderately to highly evolved compositions develop strongly MREE (middle REE)-depleted REE patterns, and become increasingly depleted in elements such as Nb and, in particular, Ta. Ratios of Nb/Ta and Zr/Hf are highly fractionated in phonolites (60–65, 64–77 respectively in Fernando de Noronha phonolites) compared to ratios in basanites (14, 45 respectively). The compatibility of Nb, Ta, and the REE, and the strong fractionation of Nb/Ta and Zr/Hf ratios and the MREE, during crystallisation from basanite to phonolite are attributable to the crystallisation of small amounts (<5%) of sphene. Trace-element behaviour is relatively insensitive to the major phenocryst phases, and is controlled by minor phases in highly undersaturated alkaline suites. Incompatible trace-element ratios (e.g. La/Nb, Th/Ta) in nephelinites and basanites from Fernando de Noronha and Trindade are generally comparable with those in basaltic and hawaiitic OIB (ocean island basalt) lavas from other South Atlantic islands, but are distinct from those of Gough and Tristan da Cunha OIB. The mantle source for the highly undersaturated volcanism on Fernando de Noronha and Trindade is similar in trace-element characteristics to the typical OIB source which produces alkaline lavas with significant relative enrichment in Nb and Ta compared to other trace elements (as expressed by low La/Nb, Ba/Nb and Th/Ta ratios). The highly undersaturated nature of the magmas and the slight fractionation of some incompatible-element ratios (elevated Ba/Nb, Ba/Rb, Ba/Th etc.) is consistent with a smaller degree of melting of a typical OIB source, but with residual phlogopite in the source to account for significant K depletion and LIL-element fractionation.  相似文献   

4.
Fernando de Noronha archipelago presents an older Remédios Formation with subvolcanic intrusions, belonging to two different alkaline series, the sodic (undersaturated: basanites, tephrites, essexites, tephriphonolites, phonolites), and potassic ones (mildly undersaturated to silicic, with alkali basalts, basaltic trachyandesites, trachyandesites, trachytes), and lamprophyres. The upper Quixaba Formation presents nephelinite flows and basanites. A third minor unit, São José, is constituted by basanites carrying mantle xenoliths. Magnesian olivines occur in the Remédios basanites and alkali basalts, and in nephelinites. Melilites are present as groundmass grains in melilite melanephelinites (MEM). Clinopyroxenes (cpx) are mostly salites to titaniferous salites (Remédios sodic series), grading into aegirines in the differentiated aphyric phonolites. Cpx in the lamprophyres show disequilibrium textures. In the Quixaba flows, cpx are salites, enriched in Mg (especially in MEM). Amphiboles, remarkably, are common in tephriphonolites and phonolites and in basaltic trachyandesites, sometimes with disequilibrum zoning textures, and a conspicuous phase in lamprophyres. Dark micas are present as groundmass plates in MEM, OLM and PYM (olivine and pyroxene melanephelinites), with compositional variety (enriched in Ti, Ba, Sr) depending on the composition of the parent rock; BaO can be as high as 16–19%. Feldspars crystallize as calcic plagioclases, sanidines and anorthoclases, depending on the rock types, as phenocrysts and in groundmass, both in Quixaba and Remédios rocks; they are absent in nephelinites. Nephelines are found in Remédios sodic series types and Quixaba rocks. Haüyne and noseane are rarely observed in Remédios rocks.  相似文献   

5.
New 40Ar/39Ar age data are determined for Cenozoic basaltic rocks from the Thuringian Rhön and Heldburg Gangschar (area also referred to as Grabfeld), integral parts of the Central European Volcanic Province. Applying the incremental heating technique on groundmass and plagioclase separates provided data which considerably specify our knowledge on the eruption ages in these volcanic fields and narrow down the duration of volcanic activity compared to earlier studies. All data but one outlier range between 20 and 14 Ma, being thus similar to those of the neighbouring Vogelsberg volcanic complex. The spectrum of ages is clearly divided into two distinct subsets: the Rhön ages are between 20 and 18 Ma, those of the Heldburg Gangschar are between 16 and 14 Ma. Thus, the present data clearly indicate a striking regional and temporal division of the Thuringian Miocene volcanism. The composition of the volcanic rocks in the two volcanic fields is remarkably diverse, ranging from tholeiitic basalts over alkali basalts and basanites to nephelinites. However, radiometric ages do not correlate with geochemical or petrological characteristics of the volcanics within each volcanic field, indicating that the different magma types erupted broadly contemporaneously.The outlier in age (29 Ma) is from a volcanic dyke of the NE Rhön area close to the NW end of the Thuringian Forest. However, more data are required to approve the significance of this age value, in particular since the rock showed isotopic age disturbance.  相似文献   

6.
On the basis of the first systematic mapping of Ua Pou, longknown for its exceptionally abundant phonolites, we estimatethat these rocks cover 65% of the surface of the island whereasmafic lavas cover 27% and intermediate ones 8%. The silica-undersaturatedsuite was erupted in a restricted time span (2·9–2·35Myr), following the emplacement of tholeiites derived from ayoung HIMU-type source at c. 4 Ma. Primitive basanites, derivedfrom a heterogeneous mantle source with a dominant EM II + HIMUsignature, represent likely parental magmas. The series is characterizedby a Daly gap defined by a lack of phonotephrites. We considerthat the most likely model for the origin of evolved lavas ispartial melting at depth of primitive basanites, leaving anamphibole-rich residuum and producing tephriphonolitic magmas.These tephriphonolitic magmas may have evolved by closed-systemfractional crystallization towards Group A phonolites. Threeother groups of phonolites could have been derived from tephriphonoliticmagmas by open-system fractional crystallization processes,characterized respectively by seawater contamination (GroupB), assimilation of nepheline syenite-type materials (GroupC) and extreme fractionation coupled with assimilation of theunderlying oceanic crust (Group D). The prominence of evolvedlavas is a consequence of their origin from partial meltingof mafic precursors followed by crustal contamination. KEY WORDS: Marquesas; French Polynesia; phonolite; partial melting; contamination  相似文献   

7.
Neogene (N 1 2 -N 2 1 ?) K-Na alkaline rocks were found in western Kamchatka as a subvolcanic basanite body at Mount Khukhch. The basanites have a microphyric texture with olivine phenocrysts in a fine-grained doleritic groundmass. The olivine contains inclusions of Al-Cr spinel. The microlites consist of clinopyroxene, plagioclase, magnetite, and apatite, and the interstitial phases are leucite, nepheline, and analcime. The Mount Khukhch basanites are characterized by elevated concentrations of MgO, TiO2, Na2O, and K2O, high concentrations of Co, Ni, Cr, Nb, Ta, Th, U, LREE (LaN/YbN = 10.8?12.6, DyN/YbN = 1.4?1.6) at moderate concentrations of Zr, Hf, Rb, Ba, Sr, Pb, and Cu. The values of indicator trace-element ratios suggest that basanites in western Kamchatka affiliate with the group of basaltoids of the within-plate geochemical type: Ba/Nb = 10?12, Sr/Nb = 17?18, Ta/Yb = 1.3?1.6. The basanites of western Kamchatka show many compositional similarities with the Miocene basanites of eastern Kamchatka, basanites of some continental rifts, and basalts of oceanic islands (OIB). The geochemistry of these rocks suggests that the basanite magma was derived via the ～6% partial melting of garnet-bearing peridotite source material. The crystallization temperatures of the first liquidus phases (olivine and spinel) in the parental basanite melt (1372–1369°C) and pressures determined for the conditions of the “mantle” equilibrium of the melt (25–26 kbar) are consistent with the model for the derivation of basanite magma at the garnet depth facies in the mantle. The geodynamic environment in which Neogene alkaline basaltic magmas occur in western Kamchatka was controlled by the termination of the Oligocene—Early Miocene subduction of the Kula oceanic plate beneath the continental margin of Kamchatka and the development of rifting processes in its rear zone. The deep faulting of the lithosphere and decompression-induced magma generation simultaneous with mantle heating at that time could be favorable for the derivation of mantle basite magmas.  相似文献   

8.
Mantle xenoliths (lherzolites, clinopyroxene dunites, wehrlites, and clinopyroxenites) in the Early Cretaceous volcanic rocks of Makhtesh Ramon (alkali olivine basalts, basanites, and nephelinites) represent metasomatized mantle, which served as a source of basaltic melts. The xenoliths bear signs of partial melting and previous metasomatic transformations. The latter include the replacement of orthopyroxene by clinopyroxene in the lherzolites and, respectively, the wide development of wehrlites and olivine clinopyoroxenites. Metasomatic alteration of the peridotites is accompanied by a sharp decrease in Mg, Cr, and Ni, and increase of Ti, Al, Ca contents and 3+Fe/2+Fe ratio, as well as the growth of trace V, Sc, Zr, Nb, and Y contents. The compositional features of the rocks such as the growth of 3+Fe/2+Fe and the wide development of Ti-magnetite in combination with the complete absence of sulfides indicate the high oxygen fugacity during metasomatism and the low sulfur concentration, which is a distinctive signature of fluid mode during formation of the Makhtesh Ramon alkali basaltic magma. Partial melting of peridotites and clinopyroxenites is accompanied by the formation of basanite or alkali basaltic melt. Clino- and orthopyroxenes are subjected to melting. The crystallization products of melt preserved in the mantle rock are localized in the interstices and consist mainly of fine-grained clinopyroxene, which together with Ti-magnetite, ilmenite, amphibole, rhenite, feldspar, and nepheline, is cemented by glass corresponding to quartz–orthopyroxene, olivine–orthopyroxene, quartz–feldspar, or nepheline–feldspar mixtures of the corresponding normative minerals. The mineral assemblages of xenoliths correspond to high temperatures. The high-Al and high-Ti clinopyroxene, calcium olivine, feldspar, and feldspathoids, amphibole, Ti-magnetite, and ilmenite are formed at 900–1000°. The study of melt and fluid inclusions in minerals from xenoliths indicate liquidus temperatures of 1200–1250°C, solidus temperatures of 1000–1100°C, and pressure of 5.9–9.5 kbar. Based on the amphibole–plagioclase barometer, amphibole and coexisting plagioclase were crystallized in clinopyroxenites at 6.5–7.0 kbar.  相似文献   

9.
Parental magmas of the Cape Verde Islands are high-Mg foidites, picrobasalts, and basanites. The rocks can be classified into the following two differentiated series: (1) a high-alkali series, which includes picrites, high-Mg foidites, low-Mg-foidites, and phonolites; and (2) a series of moderate alkalinity, which includes picrobasalts, basanites, tephrites, tephrophonolites, phonotephrites, phonolites, and trachytes.The differentiation of both series is associated with a decrease in the concentrations of Mg, Fe, Ti, and Ca and an increase in the contents of Al, Si, K, and Na. Rare lithophile elements (REE, Zr, Nb, Th, Rb, and U) progressively enrich younger derivatives. The Sr and Ba concentrations pass through a maximum, as is typical of alkaline series, which are characterized by broad crystallization fields of plagioclase and melilite, minerals that have high distribution coefficients of these elements. The analysis of the composition of volcanic rocks from the Cape Verde Islands within the scope of the system olivine-diopside-nepheline shows that the evolution of the parental magmas was controlled by crystallization differentiation in shallow-depth intermediate chambers. This conclusion finds further support in data on inclusions in minerals and a simulated crystallization model in a magmatic chamber.  相似文献   

10.
江南古陆中段沧水铺群锆石U-Pb年龄和构造演化意义   总被引：5，自引：2，他引：3       下载免费PDF全文
江南古陆中段湖南益阳地区沧水铺群发育在冷家溪群和板溪群之间,其在地层柱中的位置一直是中国地质学家解疑江南造山带何时启动的关键层位。笔者在沧水铺群中的火山集块岩中获得锆石SHRIMP U-Pb年龄(821±13)Ma,再次验证了沧水铺群中的火山岩是820 Ma武陵运动之前的火山事件的产物,与武陵运动的启动有关,也说明该期火山岩与冷家溪群中大量的火山凝灰岩为同一构造运动的产物。  相似文献   

11.
 This paper uses the geochemistry of primitive mafic lavas from the Rungwe volcanic province (southwestern Tanzania) to infer the source mineralogy and melting history. Post-Miocene mafic lavas from Rungwe include alkali basalts, basanites, nephelinites and picrites with up to 18.9 wt% MgO; nephelinites (>13.5% normative nepheline) are restricted to Kiejo volcano in the southern portion of the province. Rungwe lavas differ from most Western Rift volcanics in that they are not unusually potassic (K2O/Na2O ca. 0.40). Sparsely phyric mafic lavas contain phenocrysts and xenocrysts of plagioclase (An82–90), clinopyroxene (4.5–9.5 wt% Al2O3), and olivine (Fo79–88); one basanite contains a 1 mm xenocryst of apatite included in magnesian clinopyroxene. All samples have high abundances of incompatible elements (e.g., 0.7–2.2 wt% P2O5) and are enriched in REE relative to HFSE (Hf, Zr, Ti, Y), Cs, Ba, and K. Some incompatible element ratios are constant throughout the Rungwe suite (e.g., Zr/Nb, Sr/Ce, K/Rb), but other ratios are extremely variable and exceed the range measured in global Ocean Island Basalts (OIB) (e.g., Ba/Nb, Sm/Zr, La/Nb, Pb/Ce, Nb/U). The range in degree of silica saturation, and its excellent correlation with P2O5/Al2O3, indicate that the Rungwe suite records variable degrees of melting. Variations of individual incompatible trace element abundances in nephelinite and basanite samples suggest that the source contains metasomatic amphibole, ilmenite, apatite, and zircon. The Rungwe suite is interpreted as a series of low-percentage melts of CO2-rich peridotite at pressures that span the garnet-spinel transition. A geochemical comparison of Rungwe samples to lavas from other Western Rift volcanic centers requires that the source mineralogy varies along the rift axis, although each province is underlain by metasomatized peridotite. The incompatible trace element signatures of Western Rift lavas indicate that the source area is typically homogeneous on the scale of individual volcanoes, although lavas from each volcano reflect a range in degree of melting. Significantly, volcanoes with distinct geochemistry are always separated by major rift faults, suggesting that volcanic and tectonic surface features may correspond to metasomatic provinces within the subcontinental lithospheric mantle. Received: 30 May 1994 / Accepted: 5 April 1995  相似文献   

12.
The Honolulu Volcanics comprises small volume, late-stage (post-erosional)vents along rifts cutting the older massive Koolau tholeüticshield on Oahu, Hawaii. Most of these lavas and tuff of theHonolulu Volcanics have geochemical features expected of near-primarymagmas derived from a peridotite source containing Fo87–89olivine; e. g. 100 Mg/(Mg + Fe2+) >65, >250 p. p. m. Ni,and presence of ultramafic mantle xenoliths at 18 of the 37vents. Consequently, the geochemistry of the alkali olivinebasalt, basanite, nephelinite and nepheline melilitite lavasand tuff of the Honolulu Volcanics have been used to deducethe composition of their mantle source and the conditions underwhich they were generated by partial melting in the mantle. Compositional trends in 30 samples establish that the magmaswere derived by partial melting of a garnet (<10 per cent)Iherzolite source, which we infer to have been carbon-bearing,from analogy with experimental results. This source was isotopicallyhomogeneous (Sr, Lanphere & Dalrymple, 1980; Pb, Sun, 1980;Nd, Roden et al., 1981), and we infer that the source was compositionallyuniform in all major-element oxides except TiO2, in compatibletrace elements (Sc, V, Cr, Mn, Co and Ni), and in highly incompatibletrace elements (P, Th, La, Ce). However, the source appearsto have been heterogeneous in TiO2, Zr, Hf, Nb, and Ta, elementsthat were not strongly incompatible during partial melting.Some nepheline melilitite samples may be derived from a sourcewith distinct Sc and heavy-rare-earth-elements (REE) abundances,or which had a phase or phases controlling the distributionof these elements. The relatively limited abundance range for several elements,such as Ti, Zr, Nb, is partly a consequence of the low degreesof melting inferred for the series (2 per cent for nephelinemelilitite, 11 per cent for alkali olivine basalt), which failedto exhaust the source in minor residual phases. We infer thatthese residual phases probably included phlogopite, amphibole,and another Ti-rich phase (an oxide?), but not apatite. In comparison with estimates of a primordial mantle compositionand the mantle source of mid-oceanic-ridge basalt the garnetperidotite source of the Honolulu Volcanics was increasinglyenriched in the sequence heavy REEs, Y, Tb, Ti, Sm, Zr, andHf all <P <Nd <Sr Ce <La <Nb Ta. A multi-stagehistory for the source of the Honolulu Volcanics is requiredbecause this enrichment was superimposed on a mantle that hadbeen previously depleted in incompatible elements, as indicatedby the relatively low 87Sr/86Sr ratio, high 143Nd/144Nd ratioand low contents of K, Rb, Ba, and Th. The composition of thesource of the Honolulu Volcanics differs from the source ofthe previously erupted tholeiitic shield. The modal mineralogyof the source of the Honolulu Volcanics is not represented inthe upper-mantle xenoliths, e. g. the garnet pyroxenite andolivine-poor garnet Iherzolite included within the lavas andtuff of the unit.  相似文献   

13.
We report major and trace element X-ray fluorescence (XRF) datafor mafic volcanics covering the 15-Ma evolution of Gran Canaria,Canary Islands. The Miocene (12–15 Ma) and Pliocene-Quaternary(0–6 Ma) mafic volcanics on Gran Canaria include picrites,tholeiites, alkali basalts, basanites, nephelinites, and melilitenephelinites. Olivineclinopyroxene are the major fractionatingor accumulating phases in the basalts. Plagioclase, Fe–Tioxide, and apatite fractionation or accumulation may play aminor role in the derivation of the most evolved mafic volcanics.The crystallization of clinopyroxene after olivine and the absenceof phenocrystic plagioclase in the Miocene tholeiites and inthe Pliocene and Quaternary alkali basalts and basanites withMgO>6 suggests that fractionation occurred at moderate pressure,probably within the upper mantle. The presence of plagioclasephenocrysts and chemical evidence for plagioclase fractionationin the Miocene basalts with MgO<6 and in the Pliocene tholeiitesis consistent with cooling and fractionation at shallow depth,probably during storage in lower-crustal reservoirs. Magma generationat pressures in excess of 3•0–3•5 GPa is suggestedby (a) the inferred presence of residual garnet and phlogopiteand (b) comparison of FeO1 cation mole percentages and the CIPWnormative compositions of the mafic volcanics with results fromhigh-pressure melting experiments. The Gran Canaria mafic magmaswere probably formed by decompression melting in an upwellingcolumn of asthenospheric material, which encountered a mechanicalboundary layer at {small tilde}100-km depth.  相似文献   

14.
相山火山盆地主体岩石为一套由熔结凝灰岩、流纹英安岩、流纹英安斑岩、碎斑熔岩、粗斑花岗斑岩及似斑状花岗岩组成的酸性火山-侵入杂岩体, 构成了两个完整的喷发-溢流(侵出)-侵入的岩浆活动亚旋回。本文在野外地质调查的基础上, 采用SIMS、LA-ICP-MS技术对主要岩类进行了高精度的锆石U-Pb年代学研究, 并建立了火山-侵入杂岩体的演化序列。结果表明, 打鼓顶组熔结凝灰岩代表了相山火山-侵入活动的最早期产物, 其锆石U-Pb年龄为140.7±2.7 Ma、140.1±1.8 Ma和138.2±1.6 Ma, 第一亚旋回主体流纹英安岩的锆石U-Pb年龄135.0±1.8 Ma。鹅湖岭组熔结凝灰岩代表了火山-侵入活动的第二亚旋回的开始, 其U-Pb年龄为135.6±1.2 Ma, 第二亚旋回主体碎斑熔岩的锆石U-Pb年龄133.6±1.3 Ma, 沙洲单元的粗斑花岗斑岩和似斑状花岗岩属于该亚旋回最晚期的侵入岩, 其锆石U-Pb年龄代表了相山火山-侵入活动的结束时间(分别为133.4±1.2 Ma和133.9±1.1 Ma)。相山早白垩世火山-侵入活动延续时间较短, 整体上呈现一个连续的过程, 初始时间在141 Ma附近, 结束时间在132 Ma左右。概言之, 第一亚旋回(141~135 Ma)以形成熔结凝灰岩、流纹英安岩和流纹英安斑岩为主, 第二亚旋回(135~132 Ma)以熔结凝灰岩、碎斑熔岩、粗斑花岗斑岩和似斑状花岗岩为主。岩石地球化学和野外地质特征也与两个亚旋回火山-侵入岩浆活动相吻合。  相似文献   

15.
塔尔气地区满克头鄂博组火山岩主要为流纹岩、流纹质凝灰熔岩和流纹质晶屑凝灰岩,主量元素分析结果表明该火山岩具有准铝-弱过铝质（Al2O3=11.55%~14.76%,A/CNK=1.01~1.35）、富碱（Na2O+K2O=4.56%~8.79%）、贫钙镁的岩石化学特点.稀土元素分析结果表明火山岩ΣREE含量较高（平均为168.69×10-6）,稀土元素配分模式图均呈右倾型,LREE为轻度富集型,HREE分布相对较为平坦,铕负异常明显（δEu=0.29~0.72）,岩石Rb/Sr=0.3~11.4,微量元素明显富集LILE （Rb、Ba、K）而亏损HFSE （Nb、Ta、Ti）.结合地球化学特征及前人研究资料,认为塔尔气地区满克头鄂博组火山岩具有壳源岩浆的典型特征,岩浆源区有斜长石残留或岩浆经历了斜长石的分离结晶作用;满克头鄂博组火山岩属于A型火山岩,可能是蒙古-鄂霍次克洋闭合后的岩石圈伸展体制下的产物.  相似文献   

16.
Six crystalline mixtures, picrite, olivine-rich tholeiite, nepheline basanite, alkali picrite, olivine-rich basanite, and olivine-rich alkali basalt were recrystallized at pressures to 40 kb, and the phase equilibria and sequences of phases in natural basaltic and peridotitic rocks were investigated.The picrite was recrystallized along the solidus to the assemblages (1) olivine+orthopyroxene+ clinopyroxene +plagioclase+spinel below 13 kb, (2) olivine+orthopyroxene+clinopyroxene+spinel between 13 kb and 18 kb, (3) olivine+orthopyroxene+clinopyroxene+ garnet+spinel between 18 kb and 26 kb, and (4) olivine+clinopyroxene+garnet above 26 kb. The solidus temperature at 1 atm is slightly below 1,100° and rises to 1,320° at 20 kb and 1,570° at 40 kb. Olivine is the primary phase crystallizing from the melt at all pressures to 40 kb.The olivine-rich tholeiite was recrystallized along the solidus into the assemblages (1) olivine+ clinopyroxene+plagioclase+spinel below 13 kb, (2) clinopyroxene+orthopyroxene+ spinel between 13 kb and 18 kb, (3) clinopyroxene+garnet+spinel above 18 kb. The solidus temperature is slightly below 1,100° at 1 atm, 1,370° at 20 kb, and 1,590° at 40 kb. The primary phase is olivine below 20 kb but is orthopyroxene at 40 kb.In the nepheline basanite, olivine is the primary phase below 14 kb, but clinopyroxene is the first phase to appear above 14 kb. In the alkali-picrite the primary phase is olivine to 40 kb. In the olivine-rich basanite, olivine is the primary phase below 35 kb and garnet is the primary phase above 35 kb. In the olivine-rich alkali basalt the primary phase is olivine below 20 kb and is garnet at 40 kb.Mineral assemblages in a granite-basalt-peridotite join are summarized according to reported experimental data on natural rocks. The solidus of mafic rock is approximately given by T=12.5 P Kb+1,050°. With increasing pressure along the solidus, olivine disappears by reaction with plagioclase at 9 kb in mafic rocks and plagioclase disappears by reaction with olivine at 13 kb in ultramafic rocks. Plagioclase disappears at around 22 kb in mafic rocks, but it persists to higher pressure in acidic rocks. Garnet appears at somewhat above 18 kb in acidic rocks, at 17 kb in mafic rocks, and at 22 kb in ultramafic rocks.The subsolidus equilibrium curves of the reactions are extrapolated according to equilibrium curves of related reactions in simple systems. The pyroxene-hornfels and sanidinite facies is the lowest pressure mineral facies. The pyroxene-granulite facies is an intermediate low pressure mineral facies in which olivine and plagioclase are incompatible and garnet is absent in mafic rocks. The low pressure boundary is at 7.5 kb at 750° C and at 9.5 kb at 1,150° C. The high pressure boundary is 8.0 kb at 750° C and 15.0 kb at 1,150° C. The garnet-granulite facies is an intermediate high pressure facies and is characterized by coexisting garnet and plagioclase in mafic rocks. The upper boundary is at 10.3 kb at 750° C and 18.0 kb at 1,150° C. The eclogite facies is the highest pressure mineral facies, in which jadeite-rich clinopyroxene is stable.Compositions of minerals in natural rocks of the granulite facies and the eclogite facies are considered. Clinopyroxenes in the granulite-facies rocks have smaller jadeite-Tschermak's molecule ratios and higher amounts of Tschermak's molecule than clinopyroxenes in the eclogite-facies rocks. The distribution coefficients of Mg between orthopyroxene and clinopyroxene are normally in the range of 0.5–0.6 in metamorphic rocks in the granulite facies. The distribution coefficients of Mg between garnet and clinopyroxene suggest increasing crystallization temperature of the rocks in the following order: eclogite in glaucophane schist, eclogite and granulite in gneissic terrain, garnet peridotite, and peridotite nodules in kimberlite.Temperatures near the bottom of the crust in orogenic zones characterized by kyanitesillimanite metamorpbism are estimated from the mineral assemblages of metamorphic rocks in Precambrian shields to be about 700° C at 7 kb and 800° C at 9 kb, although heat-flow data suggest that the bottom of Precambrian shield areas is about 400° C and the eclogite facies is stable.The composition of liquid which is in equilibrium with peridotite is estimated to be close to tholeiite basalt at the surface pressure and to be picrite at around 30 kb. The liquid composition becomes poorer in normative olivine with decreasing pressure and temperature.During crystallization at high pressure, olivine and orthopyroxene react with liquid to form clinopyroxene, and a discontinuous reaction series, olivine orthopyroxene clinopyroxene is suggested. By fractional crystallization of pyroxenes the liquid will become poorer in SiO2. Therefore, if liquid formed by partial melting of peridotite in the mantle slowly rises maintaining equilibrium with the surrounding peridotite, the liquid will become poorer in MgO by crystallization of olivine, and tholeiite basalt magma will arrive at the surface. On the other hand, if the liquid undergoes fractional crystallization in the mantle, the liquid may change in composition to alkali-basalt magma and alkali-basalt volcanism may be seen at a late stage of volcanic activity.Publication No. 681, Institute of Geophysics and Planetary Physics, University of California, Los Angeles.  相似文献   

17.
The development of the Cretaceous-early Eocene basin of northwestern Argentina can be divided into three main magmatic phases on the basis of preliminary petrologic data. The oldest phase (130-100 Ma) is divided into an early stage of anorogenic plutonism, with subalkaline, alkaline, and minor peralkaline granitic intrusives, and a volcanic stage in which alkaline rocks characterized by trachytes, basanites and foidites prevail. The second phase (80-75 Ma) is characterized by an alkaline suite with basanites, hawaiites and tephriphonolites. The last phase (65-60 Ma) consists of lamproitic sills and basic lava flows. The two first phases correspond, respectively, to prerifting and initial rifting stages. According to the magmatic, tectonic, and sedimentary features observed, it is suggested that this basin is a foreland paleorift, of low volcanicity type, that developed along the western side of South America from the Early Cretaceous to the Eocene—at which time the rift basin was closed by the Incaic diastrophic phase.  相似文献   

18.
The western side of the Paranà Basin of Brazil extends to central Paraguay, where repeated and widespread magmatic activity developed from Lower Cretaceous to Oligocene, associated with late Mesozoic crustal extension trending NE-SW. In central Paraguay this trend is characterized by a zone of NW-SE normal faults which formed the Asunciòn-Sapucai graben, up to 45 km wide and 200 km long, where alkaline rocks occur as volcanic domes, complexes, lava-flows and dykes. These rocks, 128 Ma aged, are dominantly potassic and ne-normative.

A swarm of at least 200, mainley NW-SE trending, dykes occurs in the Sapucai region and seems to be formed by two main lineages: tephrite to phonolite (and peralkaline phonolite) and alkali basalt to trachyphonolite. They are characterized by ubiquitous diopside to ferrosalite, consistently yielding Al enrichment trends; common olivine, Fo81-69 in tephrites and alkaline basalts, and up to Fo65 in phonolites; zoned megacrysts of hastingsitic hornblende (core) to kaersutite (rim), associated with accessory groundmass pargasite in tephrites and phonotephrites; K-rich hastingsite and K-rich ferroan pargasite in the phonolites. Accessory groundmass mica falls in the annite-phlogopite range, and consistently yields insufficient (Si + Al) to satisfy the expected T site occupancy of 8.00 a.f.u. Fe---Ti oxides are Ti-magnetite, rarely ilmenite or haematite. Phenocrystal, i.e. xenocrystal plagioclase is An70-20, and An74-42 in the tephrites and phonolites, respectively; coexisting groundmass microlites are An22-14, associated with sodasanidine and sanidine. Feldspathoids include analcimized leucite and nepheline; accessories Ti-andradite and sphene.

The two main lineages, recognized by distinctive mineralogical variations, are consistent with the petrochemical variations. Complex interaction of discrete and independently evolving magma batches are indicated by intra- and/or interphase chemical variations, suggesting multiple equilibrations of the crystallizing phases under shallow level, volcanic pressure regime. The observed geochemical trends are quite similar to those of “Roman Region type magma” with the same negative anomalies of Ta, Nb, Zr and Ti. The most likely mantle source is a garnet-peridotite characterized by different enrichment in incompatible elements and which suffered low degree of partial melting (3–7%), which has geochemical and isotopic features distinct from those of the adjoining tholeiitic basalts (130 Ma) and nephelinites (61-39 Ma).

The similarities of the Sapucai dyke suite with Barton's “Roman Region type magma” supports the view that this magma type may not be formed as a result of orogenic and/or subduction-driven activity in this region. Therefore, a causal relationship of the latter activity with “Roman Region type magma” is not supported and remains questionable.  相似文献   


19.
华南东部内陆地区在侏罗纪处于陆内伸展背景已逐渐成为学术界共识,但对于该时期东部陆缘的构造环境仍存在争议。本文以浙东南毛弄组火山岩为对象,开展了岩石学、SHRIMP锆石U-Pb年代学、锆石微量元素、全岩元素地球化学和Sr-Nd同位素等研究,为认识华南东部陆缘构造背景提供制约。浙江侏罗纪火山岩以松阳毛弄剖面较具代表性,总体上是一套以英安质晶屑凝灰岩和流纹质玻屑凝灰岩为主的火山岩组合。本次研究在毛弄组下段获得的流纹质玻屑凝灰岩的SHRIMP锆石U-Pb年龄为153±2Ma。综合前人研究表明,毛弄组火山岩主要形成于180～148Ma。毛弄组火山岩属于镁质钙碱性系列,且表现出明显的轻稀土元素富集特征,其中早侏罗世毛弄英安质凝灰岩Eu负异常不明显,而晚侏罗世毛弄流纹质凝灰岩具有显著的Eu负异常;两组凝灰岩均富集K、Rb和Th等大离子亲石元素,亏损Nb、Ta、Zr和Hf等高场强元素。毛弄英安质火山岩的源区残留相组合可能为"斜长石+石榴石+角闪石",而毛弄流纹质凝灰岩则可能为"斜长石+角闪石",这一差异可能代表它们具有不同的源区深度。毛弄组火山岩的Sr-Nd-Hf同位素特征与华夏陆块古元古代基底岩体相似,其可能主要起源于基底地壳物质的部分熔融,并有少量地幔新生物质的加入。结合构造背景分析认为,毛弄组火山岩等陆缘岩浆岩形成环境为相对低温的"安第斯型"俯冲环境。通过不同时代区域岩体锆石氧逸度计算发现,早侏罗世东南海域岩浆岩的氧逸度比大陆陆缘更高,且大陆陆缘岩浆岩的氧逸度从晚三叠世至晚侏罗世不断升高,可能标志着陆缘地区俯冲流体的影响有着从东南海域向大陆陆缘扩散的趋势。综合分析认为,在侏罗纪华南东部陆缘可能发育一个与古太平洋俯冲有关的"安第斯型"陆缘岩浆弧,其时代可能最早可以追溯到早侏罗世早期,并持续扩大到中-晚侏罗世。这一时期浙闽沿海地区总体处于弧后挤压主导的构造环境,与同期内陆地区构造伸展背景形成鲜明对比。  相似文献   

20.
Middle Miocene (17-9 Ma) volcanism in northeast Israel migrated from eastern Lower Galilee (Poria, west of the Sea of Galilee) to the southwest (Yizre'el Valley) in association with the development of an extensional basin in that area. The Yizre'el Valley magmas are highly undersaturated in silica (basanites and nephelinites), while those of Poria are alkali-basaltic. Scarce Middle Miocene basalts from the Golan, further to the east, are also alkali-basaltic. Magmas from Kaukab (southeastern Lower Galilee) show a range of compositions from alkali-basalts to basanites. The patterns defined by ratios versus concentrations of incompatible elements in Kaukab basalts (e.g. versus La), as well as the scatter observed in Sr isotope ratios, are interpreted in terms of binary mixing. It is suggested that the Kaukab magmas were derived from veined lithospheric peridotites, melts of the veins and of the peridotites being the two end-members. Accordingly, alkali-basaltic- and basanite-dominated areas are underlain by vein-poor and vein-rich lithosphere, respectively. It is also suggested that melting during the Middle Miocene mainly occurred in response to extension, and that it followed the propagation of the Yizre'el-Galilee Basin from northeast to southwest.  相似文献   

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