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1.
Improvements in the joint inversion of seismic and marine controlled source electromagnetic data sets will require better constrained models of the joint elastic‐electrical properties of reservoir rocks. Various effective medium models were compared to a novel laboratory data set of elastic velocity and electrical resistivity (obtained on 67 reservoir sandstone samples saturated with 35 g/l brine at a differential pressure of 8 MPa) with mixed results. Hence, we developed a new three‐phase effective medium model for sandstones with pore‐filling clay minerals based on the combined self‐consistent approximation and differential effective medium model. We found that using a critical porosity of 0.5 and an aspect ratio of 1 for all three components, the proposed model gave accurate model predictions of the observed magnitudes of P‐wave velocity and electrical resistivity and of the divergent trends of clean and clay‐rich sandstones at higher porosities. Using only a few well‐constrained input parameters, the new model offers a practical way to predict in situ porosity and clay content in brine saturated sandstones from co‐located P‐wave velocity and electrical resistivity data sets.  相似文献   

2.
Ultrasonic compressional‐ and shear‐wave velocities have been measured on 34 samples of sandstones from hydrocarbon reservoirs. The sandstones are all of low clay content, high porosity, and cover a wide range of permeabilities. They were measured dry and brine‐saturated under hydrostatic effective stresses of 10, 20 and 40 MPa. For eight of the sandstones, ultrasonic velocity measurements were made at different partial water saturations in the range from dry to fully saturated. The Gassmann–Biot theory is found to account for most of the changes in velocities at high effective stress levels when the dry sandstones are fully saturated with brine, provided the lower velocities resulting when the dry sandstone initially adsorbs small amounts of moisture are used to determine the elastic properties of the ‘dry’ sandstone. At lower effective stress levels, local flow phenomena due to the presence of open microcracks are assumed to be responsible for measured velocities higher than those predicted by the theory. The partial saturation results are modelled fairly closely by the Gassmann–Biot theory, assuming heterogeneous saturation for P‐waves.  相似文献   

3.
We have studied 56 unfractured chalk samples of the Upper Cretaceous Tor Formation of the Dan, South Arne and Gorm Fields, Danish North Sea. The samples have porosities of between 14% and 45% and calcite content of over 95%. The ultrasonic compressional‐ and shear‐wave velocities (VP and VS) for dry and water‐saturated samples were measured at up to 75 bar confining hydrostatic pressure corresponding to effective stress in the reservoir. The porosity is the main control of the ultrasonic velocities and therefore of the elastic moduli. The elastic moduli are slightly higher for samples from the South Arne Field than from the Dan Field for identical porosities. This difference may be due to textural differences between the chalk at the two locations because we observe that large grains (i.e. filled microfossils and fossil fragments) that occur more frequently in samples from the Dan Field have a porosity‐reducing effect and that samples rich in large grains have a relatively low porosity for a given P‐wave modulus. The clay content in the samples is low and is mainly represented by either kaolinite or smectite; samples with smectite have a lower P‐wave modulus than samples with kaolinite at equal porosity. We find that ultrasonic VP and VS of dry chalk samples can be satisfactorily estimated with Gassmann's relationships from data for water‐saturated samples. A pronounced difference between the VP/VS ratios for dry and water‐saturated chalk samples indicates promising results for seismic amplitude‐versus‐offset analyses.  相似文献   

4.
The effect of clay distribution on the elastic properties of sandstones   总被引:1,自引:0,他引:1  
The shape and location of clay within sandstones have a large impact on the P‐wave and S‐wave velocities of the rock. They also have a large effect on reservoir properties and the interpretation of those properties from seismic data and well logs. Numerical models of different distributions of clay – structural, laminar and dispersed clay – can lead to an understanding of these effects. Clay which is located between quartz grains, structural clay, will reduce the P‐wave and S‐wave velocities of the rock. If the clay particles become aligned or form layers, the velocities perpendicular to the alignment will be reduced further. S‐wave velocities decrease more rapidly than P‐wave velocities with increasing clay content, and therefore Poisson's ratios will increase as the velocities decrease. These effects are more pronounced for compacted sandstones. Small amounts of clay that are located in the pore space will have little effect on the P‐wave velocity due to the competing influence of the density effect and pore‐fluid stiffening. The S‐wave velocity will decrease due to the density effect and thus the Poisson's ratio will increase. When there is sufficient clay to bridge the gaps between the quartz grains, P‐wave and S‐wave velocities rise rapidly and the Poisson's ratios decrease. These effects are more pronounced for under‐compacted sandstones. These general results are only slightly modified when the intrinsic anisotropy of the clay material is taken into account. Numerical models indicate that there is a strong, nearly linear relationship between P‐wave and S‐wave velocity which is almost independent of clay distribution. S‐wave velocities can be predicted reasonably accurately from P‐wave velocities based on empirical relationships. However, this does not provide any connection between the elastic and petrophysical properties of the rocks. Numerical modelling offers this connection but requires the inclusion of clay distribution and anisotropy to provide a model that is consistent with both the elastic and petrophysical properties. If clay distribution is ignored, predicting porosities from P‐wave or S‐wave data, for example, can result in large errors. Estimation of the clay distribution from P‐wave and S‐wave velocities requires good estimates of the porosity and clay volume and verification from petrographic analyses of core or cuttings. For a real data example, numerical models of the elastic properties suggest the predominance of dispersed clay in a fluvial sand from matching P‐wave and S‐wave velocity well log data using log‐based estimates of the clay volume and porosity. This is consistent with an interpretation of other log data.  相似文献   

5.
利用Metravib热机械分析仪, 在天然地震的频率和温度范围内, 首次对泵油和甘油饱和两种孔隙度的彭山砂岩的衰减和速度频散进行了实验研究. 结果表明, ① 泵油饱和彭山砂岩对频率和温度的依赖呈热激活弛豫规律; ② 杨氏模量和弹性波速度与孔隙度、 温度呈负相关, 与饱和液体的黏滞系数、 频率呈正相关; ③ 频散效应因频率上升而增强, 因温度增高而减弱. 这一规律性的结果为地震波理论研究提供了实验基础.   相似文献   

6.
We measured in the laboratory ultrasonic compressional and shear‐wave velocity and attenuation (0.7–1.0 MHz) and low‐frequency (2 Hz) electrical resistivity on 63 sandstone samples with a wide range of petrophysical properties to study the influence of reservoir porosity, permeability and clay content on the joint elastic‐electrical properties of reservoir sandstones. P‐ and S‐wave velocities were found to be linearly correlated with apparent electrical formation factor on a semi‐logarithmic scale for both clean and clay‐rich sandstones; P‐ and S‐wave attenuations showed a bell‐shaped correlation (partial for S‐waves) with apparent electrical formation factor. The joint elastic‐electrical properties provide a way to discriminate between sandstones with similar porosities but with different clay contents. The laboratory results can be used to estimate sandstone reservoir permeability from seismic velocity and apparent formation factor obtained from co‐located seismic and controlled source electromagnetic surveys.  相似文献   

7.
The link between the stress sensitivity of shaley sandstones and their porosity and clay content is investigated. This is achieved by firstly fitting a compliance‐based stress‐sensitivity law to laboratory measurements of ultrasonic velocity taken from four sets of reservoir sandstones, extracted from a variety of depositional settings. Correlations are then sought between the independent parameters of this law and the porosity or clay fraction of the rocks, which are then subsequently interpreted in terms of framework or pore‐space‐related microstructural clay models. The general conclusion drawn from the results is that both of the parameters defining the stress‐sensitivity law (the asymptotic modulus and the stress‐dependent excess compliance) clearly vary with porosity. However, only the asymptotic modulus shows a convincing trend with clay and there is little observed variation of the stress‐dependent compliance with clay. There is therefore a resultant variation of stress sensitivity with clay, but it is controlled only by the asymptotic modulus. The analysis also concludes that all four data sets fall into a framework‐related category of clay model.  相似文献   

8.
We design a velocity–porosity model for sand-shale environments with the emphasis on its application to petrophysical interpretation of compressional and shear velocities. In order to achieve this objective, we extend the velocity–porosity model proposed by Krief et al., to account for the effect of clay content in sandstones, using the published laboratory experiments on rocks and well log data in a wide range of porosities and clay contents. The model of Krief et al. works well for clean compacted rocks. It assumes that compressional and shear velocities in a porous fluid-saturated rock obey Gassmann formulae with the Biot compliance coefficient. In order to use this model for clay-rich rocks, we assume that the bulk and shear moduli of the grain material, and the dependence of the compliance on porosity, are functions of the clay content. Statistical analysis of published laboratory data shows that the moduli of the matrix grain material are best defined by low Hashin–Shtrikman bounds. The parameters of the model include the bulk and shear moduli of the sand and clay mineral components as well as coefficients which define the dependence of the bulk and shear compliance on porosity and clay content. The constants of the model are determined by a multivariate non-linear regression fit for P- and S-velocities as functions of porosity and clay content using the data acquired in the area of interest. In order to demonstrate the potential application of the proposed model to petrophysical interpretation, we design an inversion procedure, which allows us to estimate porosity, saturation and/or clay content from compressional and shear velocities. Testing of the model on laboratory data and a set of well logs from Carnarvon Basin, Australia, shows good agreement between predictions and measurements. This simple velocity-porosity-clay semi-empirical model could be used for more reliable petrophysical interpretation of compressional and shear velocities obtained from well logs or surface seismic data.  相似文献   

9.
Synthetic rock samples can offer advantages over natural rock samples when used for laboratory rock physical properties studies, provided their success as natural analogues is well understood. The ability of synthetic rocks to mimic the natural stress dependency of elastic wave, electrical and fluid transport properties is of primary interest. Hence, we compare a consistent set of laboratory multi-physics measurements obtained on four quartz sandstone samples (porosity range 20–25%) comprising two synthetic and two natural (Berea and Corvio) samples, the latter used extensively as standards in rock physics research. We measured simultaneously ultrasonic (P- and S-wave) velocity and attenuation, electrical resistivity, permeability and axial and radial strains over a wide range of differential pressure (confining stress 15–50 MPa; pore pressure 5–10 MPa) on the four brine saturated samples. Despite some obvious physical discrepancies caused by the synthetic manufacturing process, such as silica cementation and anisotropy, the results show only small differences in stress dependency between the synthetic and natural sandstones for all measured parameters. Stress dependency analysis of the dry samples using an isotropic effective medium model of spheroidal pores and penny-shaped cracks, together with a granular cohesion model, provide evidence of crack closure mechanisms in the natural sandstones, seen to a much lesser extent in the synthetic sandstones. The smaller grain size, greater cement content, and cementation under oedometric conditions particularly affect the fluid transport properties of the synthetic sandstones, resulting in lower permeability and higher electrical resistivity for a similar porosity. The effective stress coefficients, determined for each parameter, are in agreement with data reported in the literature. Our results for the particular synthetic materials that were tested suggest that synthetic sandstones can serve as good proxies for natural sandstones for studies of elastic and mechanical properties, but should be used with care for transport properties studies.  相似文献   

10.
This study devises a new analytical relationship to determine the porosity of water-saturated soils at shallow depth using seismic compressional and shear wave velocities. Seismic refraction surveys together with soil sample collection were performed in selected areas containing water-saturated clay–silt, sand and gravely soils. Classification of clay–silt, sand and gravel dense soils provided the coefficient of experimental equation between the data sets, namely, Poisson's ratio, shear modulus and porosity values. This study presents a new analytical relationship between Poisson's ratio and shear modulus values, which are obtained from seismic velocities and porosity values of water-saturated material computed from water content and grain densities, which are determined by laboratory analysis of disturbed samples. The analytical relationship between data sets indicates that when the shear modulus of water-saturated loose soil increases, porosity decreases logarithmically. If shear modulus increases in dense or solid saturated soils, porosity decreases linearly.  相似文献   

11.
—The feasibility of modeling elastic properties of a fluid-saturated sand-clay mixture rock is analyzed by assuming that the rock is composed of macroscopic regions of sand and clay. The elastic properties of such a composite rock are computed using two alternative schemes.¶The first scheme, which we call the composite Gassmann (CG) scheme, uses Gassmann equations to compute elastic moduli of the saturated sand and clay from their respective dry moduli. The effective elastic moduli of the fluid-saturated composite rock are then computed by applying one of the mixing laws commonly used to estimate elastic properties of composite materials.¶In the second scheme which we call the Berryman-Milton scheme, the elastic moduli of the dry composite rock matrix are computed from the moduli of dry sand and clay matrices using the same composite mixing law used in the first scheme. Next, the saturated composite rock moduli are computed using the equations of Brown and Korringa, which, together with the expressions for the coefficients derived by Berryman and Milton, provide an extension of Gassmann equations to rocks with a heterogeneous solid matrix.¶For both schemes, the moduli of the dry homogeneous sand and clay matrices are assumed to obey the Krief’s velocity-porosity relationship. As a mixing law we use the self-consistent coherent potential approximation proposed by Berryman.¶The calculated dependence of compressional and shear velocities on porosity and clay content for a given set of parameters using the two schemes depends on the distribution of total porosity between the sand and clay regions. If the distribution of total porosity between sand and clay is relatively uniform, the predictions of the two schemes in the porosity range up to 0.3 are very similar to each other. For higher porosities and medium-to-large clay content the elastic moduli predicted by CG scheme are significantly higher than those predicted by the BM scheme.¶This difference is explained by the fact that the BM model predicts the fully relaxed moduli, wherein the fluid can move freely between sand and clay regions. In contrast, the CG scheme predicts the no-flow or unrelaxed moduli. Our analysis reveals that due to the extremely low permeability of clays, at seismic and higher frequencies the fluid has no time to move between sand and clay regions. Thus, the CG scheme is more appropriate for clay-rich rocks.  相似文献   

12.
含流体砂岩地震波频散实验研究   总被引:1,自引:0,他引:1       下载免费PDF全文
为了研究孔隙流体对不同渗透率岩石地震波速度的影响,在实验室利用跨频带岩石弹性参数测试系统得到了应变幅值10-6的2~2000Hz频段下的地震波速度和1 MHz频率下的超声波速度,利用差分共振声谱法得到了频率600Hz岩石干燥和完全饱水情况下岩石声学参数.实验表明,在低饱和度下,致密砂岩在地震和超声频段下没有明显的频散;在高饱和度下纵波速度的频散变得明显.从干燥到完全水饱和条件,不同频率测量的致密砂岩的体积模量随岩石孔隙度增高而降低,且体积模量的变化量受岩石微观孔隙结构的影响较大.高孔、高渗砂岩无论在低含水度下还是在高含水饱和度下频散微弱,并且在地震频段下围压对于岩石纵横波速度的影响要大于频率的影响.高孔、高渗砂岩和致密砂岩不同含水饱和度下的频散差异可应用于储层预测,油气检测等方面,同时该研究可以更好地帮助理解岩石的黏弹性行为,促进岩石物理频散理论的发展,提高地震解释的精度.  相似文献   

13.
This study presents the results of experimental compaction while measuring ultrasonic velocities of sands with different grain size, shape, sorting and mineralogy. Uniaxial mechanical compaction tests up to a maximum of 50 MPa effective stress were performed on 29 dry sand aggregates derived from eight different sands to measure the rock properties. A good agreement was found between the Gassmann saturated bulk moduli of dry and brine saturated tests of selected sands. Sand samples with poor sorting showed low initial porosity while sands with high grain angularity had high initial porosity. The sand compaction tests showed that at a given stress well‐sorted, coarse‐grained sands were more compressible and had higher velocities (Vp and Vs) than fine‐grained sands when the mineralogy was similar. This can be attributed to grain crushing, where coarser grains lead to high compressibility and large grain‐to‐grain contact areas result in high velocities. At medium to high stresses the angular coarse to medium grained sands (both sorted sands and un‐sorted whole sands) showed high compaction and velocities (Vp and Vs). The small grain‐to‐grain contact areas promote higher deformation at grain contacts, more crushing and increased porosity loss resulting in high velocities. Compaction and velocities (Vp and Vs) increased with decreasing sorting in sands. However, at the same porosity, the velocities in whole sands were slightly lower than in the well‐sorted sands indicating the presence of loose smaller grains in‐between the framework grains. Quartz‐poor sands (containing less than 55% quartz) showed higher velocities (Vp and Vs) compared to that of quartz‐rich sands. This could be the result of sintering and enlargement of grain contacts of ductile mineral grains in the quartz‐poor sands increasing the effective bulk and shear stiffness. Tests both from wet measurements and Gassmann brine substitution showed a decreasing Vp/Vs ratio with increasing effective stress. The quartz‐rich sands separated out towards the higher side of the Vp/Vs range. The Gassmann brine substituted Vp and Vs plotted against effective stress provide a measure of the expected velocity range to be found in these and similar sands during mechanical compaction. Deviations of actual well log data from experimental data may indicate uplift, the presence of hydrocarbon, overpressure and/or cementation. Data from this study may help to model velocity‐depth trends and to improve the characterization of reservoir sands from well log data in a low temperature (<80–100o C) zone where compaction of sands is mostly mechanical.  相似文献   

14.
We conducted a laboratory study of the joint elastic‐electrical properties of sixty‐three brine‐saturated sandstone samples to assess the likely impact of differential pressure (confining minus pore fluid pressures) in the range 8–60 MPa on the joint interpretation of marine seismic and controlled‐source electromagnetic survey data. The samples showed a wide range of petrophysical properties representative of most sandstone reservoirs. We found that a regression equation comprising both a constant and an exponential part gave a good fit to the pressure dependence of all five measured geophysical parameters (ultrasonic P‐ and S‐wave velocity, attenuation and electrical resistivity). Electrical resistivity was more pressure‐sensitive in clay‐rich sandstones with higher concentrations of low aspect ratio pores and micropores than in clean sandstones. Attenuation was more pressure‐sensitive in clean sandstones with large open pores (macropores) than in clay‐rich sandstones. Pore shape did not show any influence on the pressure sensitivity of elastic velocity. As differential pressure increases, the effect of the low aspect ratio pores and micropores on electrical resistivity becomes stronger than the effect of the macropores on attenuation. Further analysis of correlations among the five parameters as a function of pressure revealed potentially diagnostic relationships for geopressure prediction in reservoir sandstones.  相似文献   

15.
Cement stabilization is often used to improve the bearing capacity and compressibility of soft clays. The present paper aims to investigate the shear modulus degradation of cement treated clay during cyclic loading. A series of cyclic triaxial test was conducted on artificially cement treated marine clay to study the factors affecting the shear modulus degradation. The parameters considered for the study are cement content (2.5–7.5%), curing days (7–28), cyclic shear strain amplitude (0.3–1%), number of loading cycles (1–100) and loading frequency (0.1–0.5 Hz). As in the case of natural clays, cement treated clays exhibit stiffness degradation which depends on mix ratio, curing days and loading conditions. The results show that the shear modulus degradation decreases with increase in the shear strain amplitude, cement content and curing days. It is also noted that irrespective of the mix ratio and curing conditions, the degradation decreases with increase in loading frequency. An empirical relationship is proposed to predict the shear modulus degradation based on Idriss׳s degradation model. The performance of the proposed empirical model is validated with the present experimental results.  相似文献   

16.
In impure chalk, the elastic moduli are not only controlled by porosity but also by contact‐cementation, resulting in relatively large moduli for a given porosity, and by admixtures of clay and fine silica, which results in relatively small moduli for a given porosity. Based on a concept of solids suspended in pore fluids as well as composing the rock frame, we model P‐wave and S‐wave moduli of dry and wet plug samples by an effective‐medium Hashin–Shtrikman model, using chemical, mineralogical and textural input. For a given porosity, the elastic moduli correspond to a part of the solid (the iso‐frame value) forming the frame of an Upper Hashin–Shtrikman bound, whereas the remaining solid is modelled as suspended in the pore fluid. The iso‐frame model is thus a measure of the pore‐stiffness or degree of cementation of the chalk. The textural and mineralogical data may be assessed from logging data on spectral gamma radiation, density, sonic velocity and water saturation in a hydrocarbon zone, whereas the iso‐frame value of a chalk may be assessed from the density and acoustic P‐wave logs alone. The iso‐frame concept may thus be directly used in conventional log‐analysis and is a way of incorporating sonic‐logging data. The Rigs‐1 and Rigs‐2 wells in the South Arne field penetrate the chalk at the same depth but differ in porosity and in water saturation although almost the entire chalk interval has irreducible water saturation. Our model, combined with petrographic data, indicates that the difference in porosity is caused by a higher degree of pore‐filling cementation in Rigs‐1. Petrographic data indicate that the difference in water saturation is caused by a higher content of smectite in the pores of Rigs‐1. In both wells, we find submicron‐size diagenetic quartz.  相似文献   

17.
The attenuation of stress waves in fluid saturated porous rock   总被引:5,自引:0,他引:5  
TheatenuationofstreswavesinfluidsaturatedporousrockDAOYINGXI(席道瑛)JINGYICHENG(程经毅)LIANGKUNYI(易良坤)BINZHANG(张斌)Departmentof...  相似文献   

18.
本文采用从法国引进的Metravib热机械分析仪用正弦波加载方式,首次对四种不同孔隙度的饱和砂岩的衰减进行了实验研究,在5~400 Hz的频率,-50 ℃~100 ℃的温度范围获得衰减的热弛豫规律,由此求得它们的激活能和原子振动频率,其激活能和弛豫时间是处在原子和电子的激活能和弛豫时间之间.可见,在饱和岩石的晶粒间界缺陷处参与扩散的是原子、电子.并得出随孔隙度增大,衰减强度和激活能增大,原子的振动速率加快,弛豫时间缩短.在交变应力作用下,由多种矿物晶体胶结而成的饱和砂岩是一种多晶、多相的固体,由于内部结构复杂,损伤、缺陷广布,弛豫衰减是普遍存在的.饱和砂岩中存在的晶界、相界等许多缺陷,以及缺陷间的相互作用,比如饱和岩石中的饱和液体与岩石骨架之间的作用等等都可以产生弛豫衰减峰,弛豫过程还受晶界上原子扩散所控制.由于饱和岩石中的种种缺陷、相界等等导致上述矿物颗粒或晶界之间的多重弛豫,才使弛豫衰减峰变宽,分布宽度增大.用饱和砂岩中特有的饱和液体及砂岩内部结构的复杂性解释了饱和砂岩的衰减机理,很自然地将其宏观衰减特征与微细观结构紧紧联在一起.衰减及其机理的研究既具有科学意义,对地球物理勘探又具有实用价值.  相似文献   

19.
A rapid reduction in sediment porosity from 60 to 70 % at seafloor to less than 10 % at several kilometers depth can play an important role in deformation and seismicity in the shallow portion of subduction zones. We conducted deformation experiments on rocks from an ancient accretionary complex, the Shimanto Belt, across the Nobeoka Thrust to understand the deformation behaviors of rocks along plate boundary faults at seismogenic depth. Our experimental results for phyllites in the hanging wall and shale‐tuff mélanges in the footwall of the Nobeoka Thrust indicate that the Shimanto Belt rocks fail brittlely accompanied by a stress drop at effective pressures < 80 MPa, whereas they exhibit strain hardening at higher effective pressures. The transition from brittle to ductile behavior in the shale–tuff mélanges lies on the same trend in effective stress–porosity space as that for clay‐rich and tuffaceous sediments subducting into the modern Nankai subduction zone. Both the absolute yield strength and the effective pressure at the brittle–ductile transition for the phyllosilicate‐rich materials are much lower than for sandstones. These results suggest that as the clay‐rich or tuffaceous sediments subduct and their porosities are reduced, their deformation behavior gradually transitions from ductile to brittle and their yield strength increases. Our results also suggest that samples of the ancient Shimanto accretionary prism can serve as an analog for underthrust rocks at seismogenic depth in the modern Nankai Trough.  相似文献   

20.
An accurate prediction of the thermal conductivity of reservoir rocks in the subsurface is extremely important for a quantitative analysis of basin thermal history and hydrocarbon maturation. A model for calculating the thermal conductivity of reservoir rocks as a function of mineral composition, porosity, fluid type, and temperature has been developed based on fabric theory and experimental data. The study indicates that thermal conductivities of reservoir rocks are dependent on the volume fraction of components (minerals, porosity, and fluids), the temperature, and the fraction of series elements (FSE) which represents the way that the mineral components aggregate. The sensitivity test of the fabric model shows that quartz is the most sensitive mineral for the thermal conductivity of clastic rocks. The study results indicate that the FSE value is very critical. Different lithologies have different optimum FSE values because of different textures and sedimentary structures. The optimum FSE values are defined as those which result in the least error in the model computation of the thermal conductivity of the rocks. These values are 0.444 for water-saturated clay rocks, 0.498 for water-saturated sandstones, and 0.337 for water-saturated carbonates. Compared with the geometric mean model, the fabric model yields better results for the thermal conductivity, largely because the model parameters can be adjusted to satisfy different lithologies and to minimize the mean errors. The fabric model provides a good approach for estimating paleothermal conductivity in complex rock systems based on the mineral composition and pore fluid saturation of the rocks.  相似文献   

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