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Providing an accurate estimate of the magnetic field on the Earth's surface at a location distant from an observatory has useful scientific and commercial applications, such as in repeat station data reduction, space weather nowcasting or aeromagnetic surveying. While the correlation of measurements between nearby magnetic observatories at low and mid‐latitudes is good, at high geomagnetic latitudes () the external field differences between observatories increase rapidly with distance, even during relatively low magnetic activity. Thus, it is of interest to describe how the differences (or errors) in external magnetic field extrapolation from a single observatory grow with distance from its location. These differences are modulated by local time, seasonal and solar cycle variations, as well as geomagnetic activity, giving a complex temporal and spatial relationship. A straightforward way to describe the differences are via confidence intervals for the extrapolated values with respect to distance. To compute the confidence intervals associated with extrapolation of the external field at varying distances from an observatory, we used 695 station‐years of overlapping minute‐mean data from 37 observatories and variometers at high latitudes from which we removed the main and crustal fields to isolate unmodelled signals. From this data set, the pairwise differences were analysed to quantify the variation during a range of time epochs and separation distances. We estimate the 68.3%, 95.4% and 99.7% confidence levels (equivalent to the 1σ, 2σ and 3σ Gaussian error bounds) from these differences for all components. We find that there is always a small non‐zero bias that we ascribe to instrumentation and local crustal field induction effects. The computed confidence intervals are typically twice as large in the north–south direction compared to the east‐west direction and smaller during the solstice months compared to the equinoxes.  相似文献   
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建立了Cu2+和阿特拉津(AT)复合污染体系中沉积物各活性组分及其交互作用对AT吸附量影响的BP神经网络模型,模型预测值和实验值的相关系数达到0.97,各集合的平均偏差均小于10%。模型显示,AT在沉积物上的主要吸附位是铁氧化物。沉积物吸附AT时铁氧化物、锰氧化物、有机质之间存在显著的交互作用,铁氧化物、锰氧化物交互作用贡献率为-130%~80%,铁氧化物、有机质交互作用贡献率为5%~28%,锰氧化物、有机质交互作用贡献率为-200%~-70%。各活性组分吸附AT的能力及其交互作用受Cu2+的影响较大,其中:Cu2+对AT在铁氧化物上的吸附表现为拮抗作用,对AT在锰氧化物上的吸附表现为协同作用,而对AT在有机质上的吸附影响不显著,同时Cu2+减弱了铁氧化物-锰氧化物和锰氧化物-有机质的交互作用影响,增强了铁氧化物-有机质的交互作用影响。  相似文献   
4.
The responses of coastal upwelling to different magnitudes of wind stress over a narrow and a wide shelf are studied using a 3-D primitive equation numerical model. The results show that the position of the upwelling front depends on both the strength and the duration of the wind forcing. The comparison between different shelf widths shows that wide shelf will limit the cold water intrusion, so that the corresponding decrease in sea surface temperature is less compared to narrow shelves. Besides, the difference between hydrostatic and nonhydrostatic model results shows that nonhydrostatic effects will enhance the growth of surface meandering, and can be more pronounced near steep fronts. Although difference does exist, our results show that the nonhydrostatic effects are very small at least in this idealized study case.  相似文献   
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We present a comprehensive characterisation of the physical, mineralogical, geomechanical, geophysical, and hydrodynamic properties of Corvio sandstone. This information, together with a detailed assessment of anisotropy, is needed to establish Corvio sandstone as a useful laboratory rock‐testing standard for well‐constrained studies of thermo–hydro–mechanical–chemical coupled phenomena associated with CO2 storage practices and for geological reservoir studies in general. More than 200 core plugs of Corvio sandstone (38.1 and 50 mm diameters, 2:1 length‐to‐diameter ratio) were used in this characterisation study, with a rock porosity of 21.7 ± 1.2%, dry density 2036 ± 32 kg m?3, and unconfined compressive and tensile strengths of 41 ± 3.28 and 2.3 ± 0.14 MPa, respectively. Geomechanical tests show that the rock behaves elastically between ~10 and ~18 MPa under unconfined conditions with associated Young's modulus and Poisson's ratio of 11.8 ± 2.8 GPa and 0.34 ± 0.01 GPa, respectively. Permeability abruptly decreases with confining pressure up to ~10 MPa and then stabilises at ~1 mD. Ultrasonic P‐ and S‐wave velocities vary from about 2.8–3.8 km s?1 and 1.5–2.4 km s?1, respectively, over confining and differential pressures between 0.1 and 35 MPa, allowing derivation of associated dynamic elastic moduli. Anisotropy was investigated using oriented core plugs for electrical resistivity, elastic wave velocity and attenuation, permeability, and tracer injection tests. Corvio sandstone shows weak transverse isotropy (symmetry axis normal to bedding) of <10% for velocity and <20% for attenuation.  相似文献   
7.
Quantifying the proportion of the river hydrograph derived from the different hydrological pathways is essential for understanding the behaviour of a catchment. This paper describes a new approach using the output from master recession curve analysis to inform a new algorithm based on the Lyne and Hollick ‘one‐parameter’ signal analysis filtering algorithm. This approach was applied to six catchments (including two subcatchments of these) in Ireland. The conceptual model for each catchment consists of four main flow pathways: overland flow, interflow, shallow groundwater and deep groundwater. The results were compared with those of the master recession curve analysis, a recharge coefficient approach developed in Ireland and the semi‐distributed, lumped and deterministic hydrological model Nedbør‐Afstrømings‐Model. The new algorithm removes the ‘free variable’ aspect that is typically associated with filtering algorithms and provides a means of estimating the contribution of each pathway that is consistent with the results of hydrograph separation in catchments that are dominated by quick response pathways. These types of catchments are underlain by poorly productive aquifers that are not capable of providing large baseflows in the river. Such aquifers underlie over 73% of Ireland, ensuring that this new algorithm is applicable in the majority of catchments in Ireland and potentially in those catchments internationally that are strongly influenced by the quick‐responding hydrological pathways. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
8.
Transient aragonite seas occurred in the early Cambrian but several models suggest the late Cambrian was a time of calcite seas. Here, evidence is presented from the Andam Group, Huqf High, Oman (Gondwana) that suggests a transient Furongian (late Cambrian) aragonite sea, characterized by the precipitation of aragonite and high‐Mg calcite ooids and aragonite isopachous, fibrous, cements. Stable carbon isotope data suggest that precipitation occurred just before and during the SPICE (Steptoean Positive Carbonate Isotope Excursion). Aragonite and high‐Mg calcite precipitation can be accounted for if mMg:Ca ratios were around 1.2 given the very high atmospheric CO2 at that time and if precipitation occurred in warm waters associated with the SPICE. This, together with reported occurrences of early Furongian aragonite ooids from various locations in North America (Laurentia), suggests that aragonite and high‐Mg calcite precipitation from seawater may have been more than just a local phenomenon.  相似文献   
9.
Meteoritical Bulletin 100 contains 1943 meteorites including 8 falls (Boumdeid [2011], Huaxi, Ko?ice, Silistra, So?tmany, Sutter's Mill, Thika, Tissint), with 1575 ordinary chondrites, 139 carbonaceous chondrites, 96 HED achondrites, 25 ureilites, 18 primitive achondrites, 17 iron meteorites, 15 enstatite chondrites, 11 lunar meteorites, 10 mesosiderites, 10 ungrouped achondrites, 8 pallasites, 8 Martian meteorites, 6 Rumuruti chondrites, 3 enstatite achondrites, and 2 angrites, and with 937 from Antarctica, 592 from Africa, 230 from Asia, 95 from South America, 44 from North America, 36 from Oceania, 6 from Europe, and 1 from an unknown location. This will be the last Bulletin published in the current format. Information about approved meteorites can be obtained from the Meteoritical Bulletin Database (MBD) available online at http://www.lpi.usra.edu/meteor/  相似文献   
10.
Dicarboxylic acids were searched for in three Sutter's Mill (SM) fragments (SM2 collected prerain, SM12, and SM41) and found to occur almost exclusively as linear species of 3‐ to 14‐carbon long. Between these, concentrations were low, with measured quantities typically less than 10 nmole g?1 of meteorite and a maximum of 6.8 nmole g?1 of meteorite for suberic acid in SM12. The SM acids' molecular distribution is consistent with a nonbiological origin and differs from those of CMs, such as Murchison or Murray, and of some stones of the C2‐ungrouped Tagish Lake meteorite, where they are abundant and varied. Powder X‐ray diffraction of SM12 and SM41 show them to be dominated by clays/amorphous material, with lesser amounts of Fe‐sulfides, magnetite, and calcite. Thermal gravimetric (TG) analysis shows mass losses up to 1000 °C of 11.4% (SM12) and 9.4% (SM41). These losses are low compared with other clay‐rich carbonaceous chondrites, such as Murchison (14.5%) and Orgueil (21.1%). The TG data are indicative of partially dehydrated clays, in accordance with published work on SM2, for which mineralogical studies suggest asteroidal heating to around 500 °C. In view of these compositional traits and mineralogical features, it is suggested that the dicarboxylic acids observed in the SM fragments we analyzed likely represent a combination of molecular species original to the meteorite as well as secondary products formed during parent‐body alteration processes, such as asteroidal heating.  相似文献   
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