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1.
采用水热法制备磁性铁酸铋(Bi_2Fe_4O_9)光催化剂,利用X线衍射仪、扫描电子显微镜、紫外—可见漫反射等仪器对Bi_2Fe_4O_9的晶相、形貌、光吸收特性进行表征。结果表明:在紫外光或可见光下,Bi_2Fe_4O_9可有效降解亚甲基蓝(MB),且在紫外光下降解效果尤为显著,其表观速率常数可达2.422×10~(-2) min~(-1)。通过加入不同种类的捕获剂推断Bi_2Fe_4O_9的光催化机理,以及光催化过程中的活性物种,h~+与·OH为光催化降解过程中的主要活性物种。  相似文献   

2.
以半导体TiO2和自制复合型半导体Fe2O3/TiO2为催化剂对光催化降解乐果废水进行了研究.研究表明复合型光催化剂在可见光照下以及紫外光照下的活性都较好;而半导体TiO2只在紫外光照下才能降解乐果.控制催化剂TiO2的用量能提高对乐果的降解率.  相似文献   

3.
采用溶剂热法经乙二醇水解,制备Ce-Cu(x)-O纳米晶体簇,电镜照片显示Ce-Cu(x)-O纳米晶体簇具有类似球形结构并且分散均匀.通过改变铜含量制备一系列样品,对样品进行BET、XRD、H2-TPR等表征.结果表明:XRD结果显示当n(Cu)/n(Ce)低于0.1时,只检测到立方相CeO2的晶相衍射峰;当n(Cu)...  相似文献   

4.
以二乙醇胺(DEA)、二氯亚砜(DCSO)为原料,在DCSO中加入N,N-二甲基甲酰胺(DMF)形成Vilsmeier 试剂,Vilsmeier试剂为氯化剂,DMF为催化剂兼溶剂,采用吡啶催化的乙酰化法测定DEA转化率,经亲核取代反应合成双(2- 氯乙基)胺.考查DMF和DEA质量比、DCSO和DEA物质的量比、反应温...  相似文献   

5.
为了考察SiO_2对W-Ni催化剂加氢脱硫活性的影响,将SiO_2以硅溶胶形式引入AlPO_4—5/Al_2O_3复合载体,制备W-Ni催化剂,对改性的复合载体及催化剂进行BET、NH3-TPD、DRS及LRS方法表征,采用二苯并噻吩的模型化合物对催化剂脱硫活性进行微反评价。结果表明:将SiO_2引入AlPO_4—5/Al_2O_3复合载体,可改善活性金属与载体间的相互作用,提高催化剂的酸强度,促进金属组分的易还原性;SiO_2质量分数为12.0%时,催化剂的加氢活性最高,说明适当加入SiO_2有利于提高催化剂加氢脱硫活性。质量分数为12.0%的SiO_2改性复合载体制备的催化剂Cat-NiW/Si12AP对大庆催化柴油加氢评价结果表明,该催化剂具有良好的加氢脱硫、脱氮及芳烃饱和性能。  相似文献   

6.
Heavy metal pollution has become a worldwide problem in aquaculture. We studied copper (Cu2+ ) accumulation and physiological responses of two red algae Gracilaria lemaneiformis and Gracilaria lichenoides from China under Cu2+ exposure of 0-500 μg/L in concentration. Compared with G. lemaneiformis, G. lichenoides was more capable in accumulating Cu2+ , specifically, more Cu2+ on extracellular side (cell wall) than on intracellular side (cytoplasm) and in cell organelles (especially chloroplast, cell nucleus, mitochondria, and ribosome). In addition, G. lichenoides contained more insoluble polysaccharide in cell wall, which might promote the extracellular Cu2+ -binding as an efficient barrier against metal toxicity. Conversely, G. lemaneiformis was more vulnerable than G. lichenoides to Cu 2+ toxin for decreases in growth, pigment (chlorophyll a, chlorophyll b, phycobiliprotein, and β-carotene) content, and photosynthetic activity. Moreover, more serious oxidative damages in G. lemaneiformis than in G. lichenoides, in accumulation of reactive oxidative species and malondialdehyde, and in electrolyte leakage, because of lower antioxidant enzyme (superoxide dismutase and glutathione reductase) activities. Therefore, G. lichenoides was less susceptible to Cu2+ stress than G. lemaneiformis.  相似文献   

7.
Calcium (Ca), phosphorus (P), and chitin are the main components of the exoskeleton of krill. Defluoridation of a solution of sodium fluoride (NaF) using calcium phosphate (Ca3(PO4)2) and chitin as defluoridation agents was studied. Orthogonal experiments were designed to find the optimum reaction conditions for defluoridation, to obtain the maximum defluoridation efficiency and fluoride removal capacity of calcium phosphate and chitin. At the same time, a comparison of the capacity of the two defluoridation agents was made. The results suggest that calcium phosphate has a far greater capability than chitin for the removal of fluoride (F) from water under similar reaction conditions. It is also suggested that Antarctic krill is likely to adsorb fluoride via compounds such as calcium phosphate, hydroxyapatite, and other compounds of Ca and P with the general form (Ca, X)x(PO4, HPO4, Y)y(OH, Z)z, in addition to chitin.  相似文献   

8.
Caulerpa lentillifera is a green algae that distributes worldwide and is cultivated for food. We assessed vegetative propagation of C. lentillifera by measuring the specific growth rate(SGR) and chlorophyll fluorescence of the green algae cultured at different salinities and nutrient levels. The results indicated that C. lentillifera can survive in salinities ranging from 20 to 50,and can develop at salinities of 30 to 40. The maximum SGR for C. lentillifera occurred at a salinity of 35. Both chlorophyll content and the ratio of variable to maximum fluorescence( Fv / Fm) were also at a maximum at a salinity of 35. Photosynthesis was inhibited in salinities greater than 45 and less than 25. Both the maximum SGR and maximum chlorophyll content were found in algae treated with a concentration of 0.5 mmol/L of NO3-N and 0.1 mmol/L of PO 4-P. The photosynthetic capacity of photosystem II(PSII) was inhibited in cultures of C. lentillifera at high nutrient levels. This occurred when NO3-N concentrations were greater than 1.0 mmol/L and when PO4- P concentrations were at 0.4 mmol/L. As there is strong need for large-scale cultivation of C. lentillifera,these data contribute important information to ensure optimal results.  相似文献   

9.
基于丽江台OSG超导重力仪在2021年漾濞M_(S)6.4和玛多M_(S)7.4地震前后的连续观测数据,使用调和分析提取重力残差时间序列与同震重力变化信号,利用球形地球地震位错理论计算2次地震在丽江台引起的同震重力变化。结果表明,漾濞和玛多地震同震重力变化观测值与理论值存在差异,观测值分别约为-4.37 nm/s^(2)和28.57 nm/s^(2),对应的理论值分别为-0.19 nm/s^(2)和0.24 nm/s^(2)。探讨地下水对重力变化的影响,发现其重力效应与地震的理论同震重力变化处于同一量级。对比丽江地区同时段GPS观测的30 s采样数据与超导重力观测数据,发现2次地震前后的同震位移突变幅度远小于重力变化幅度,表明超导重力仪受到地震脉冲信号的影响,导致其重力变化观测值在2个地震发生期间显著增强。  相似文献   

10.
为明确大民屯凹陷安福屯地区沈352井沙四下亚段细粒沉积岩的沉积环境及演化特征,利用地球化学方法,根据岩石中w(V)/w(V+Ni)判断氧化还原环境的变化,根据w(Sr)/w(Ba)、w(V/)w(Ni)、w(Mg)/w(Ca)判断沉积环境中盐度的变化,根据w(Zr)/w(Al)及w(Al2O3)、w(K2O)、w(TiO2)、w(P2O5)、w(V)判断水体深度的变化,根据w(Sr)/w(Cu)、c(为几种元素的比值)判断沉积环境的古气候变化,分析研究区沉积环境特征及变化规律。结果表明:处于陆相沉积环境的沈352井沙四下亚段由深到浅分为三部分,即在3 280~3 352m处为还原—弱还原环境,盐度为半咸水—咸水,水体较深,属于半潮湿—半干燥气候;在3 248~3 280m处为弱还原环境,盐度为咸水,水体较浅,属于干热气候;在3 169~3 248m处为还原环境,盐度为咸水—半咸水,水体较深,属于温湿气候;其中粒屑发育段(3 328~3 333m)较为特殊,为氧化环境,盐度为微咸水,水体较浅,属于干热气候。该研究对分析研究区细粒沉积岩形成时的沉积环境及勘探潜力具有一定参考意义。  相似文献   

11.
Jin  Zuquan  Zhao  Xia  Zhao  Tiejun  Hou  Baorong  Liu  Ying 《中国海洋湖沼学报》2017,35(3):681-692
The corrosion of rebar in reinforced concrete in marine environments causes significant damage to structures built in ocean environments. Studies on the process and mechanism of corrosion of rebar in the presence of multiple ions may help to control damage and predict the service life of reinforced concrete structures in such environments. The effect of interactions between sulfate and chloride ions and calcium hydroxide on the electrochemical behavior of rebar are also important for evaluation of structure durability. In this work, electrochemical impedance spectroscopy(EIS) plots of rebar in Ca(OH)_2 solution and cement grout, including NaCl and Na_2SO_4 as aggressive salts, were measured for different immersion times. The results show that corrosion of rebar was controlled by the rate of charge transfer as the rebar was exposed to chloride solution. In the presence of high concentrations of sulfate ions in the electrolyte, generation and dissolution of the passive film proceeded simultaneously and corrosion was mainly controlled by the diffusion rate. When Na_2SO_4 and NaCl were added to Ca(OH)_2 solution, the instantaneous corrosion rate decreased by a factor of 10 to 20 as a result of the higher p H of the corroding solution.  相似文献   

12.
平果岩溶堆积型铝土矿系一水硬铝石铝土矿床 ,原矿中含有大量的准胶结物———红土。研究资料证实 ,红土中的三水铝石含量甚高 ,不少地段已达到工业利用的要求。其他矿物质来源于原生沉积铝土矿床 ,并与堆积矿同产于一个层位。  相似文献   

13.
Proteins of the DYRK(dual-specificity tyrosine-phosphorylation-regulated kinase) family are characterized by the presence of a conserved kinase domain and N-terminal DH box.DYRK2 is involved in regulating key developmental and cellular processes,such as neurogenesis,cell proliferation,cytokinesis,and cellular differentiation.Herein,we report that the ortholog of DYRK2 found in zebrafish shares about 70% identity with that of human,mouse,and chick.RT-PCR showed that DYRK2 is expressed maternally and zygotica...  相似文献   

14.
Proteins of the DYRK (dual-specificity tyrosine-phosphorylation-regulated kinase) family are characterized by the presence of a conserved kinase domain and N-terminal DH box. DYRK2 is involved in regulating key developmental and cellular processes, such as neurogenesis, cell proliferation, cytokinesis, and cellular differentiation. Herein, we report that the ortholog of DYRK2 found in zebrafish shares about 70% identity with that of human, mouse, and chick. RT-PCR showed that DYRK2 is expressed maternally and zygotically. In-situ hybridization results show that DYRK2 is expressed in somite cells that will develop into muscles. Our results provide preliminary evidence for investigating the in-vivo function of DYRK2 in zebrafish muscle development.  相似文献   

15.
16.
提出了实现高阶时域有限差分法FDTD(2M,2N)的一种方法,把对时间的高阶差分转化为对空间的差分,相对于FDTD(2,2N),并不增加存储量。数值实验证明了这一方法的有效性。  相似文献   

17.
用极大交换子群阶的集合得到关于群的一些性质。证明了单群L2(q),q≡3,5(mod)在同构的意义下,能被它的极大交换子群阶的集合唯一确定。  相似文献   

18.
PANI copolymer micro/nanostructures with different surface wettability were obtained from the chemical oxidation copolymerization of aniline(Ani) with 2-ethyl aniline(EA) at diverse [EA]/[Ani+EA] molar ratios, by employing ammonium persulfate as an oxidant. The results revealed that the poly(aniline-co-2-ethyl aniline)(PANI-EA) copolymer micro/nanostructures exhibited satisfactory anticorrosion performance for carbon steel, and the corrosion protection efficiency increased with the increase of water repellent property. Poly(2-ethyl aniline)(PEA) showed the largest contact angle(CA=145°) and show the best corrosion protection for the carbon steel(h = 87.29%). It is found that the superior anticorrosion property of PEA is attributed to its high hydrophobicity, low conductivity and low porosity.  相似文献   

19.
1 Introduction6Alkaline- earth sulfides have been found to beexcellent hosts.. for versatile phosphors such as thecathodo-, photo -, thermo - and electro - luminescent materials (N. Ruelle, M. Pham Thi and C.FOuassier, 1992; S. H. Pawar, 1974). HOwever,no…  相似文献   

20.
【目的】研究马氏珠母贝(Pinctada martensii)β2肾上腺素能受体(Pmβ2AR)的生物学功能。【方法】利用cDNA末端快速扩增技术(RACE)克隆获得Pmβ2AR基因的cDNA的全长序列并对其序列特征进行分析,实时荧光定量技术(q RT-PCR)检测马氏珠母贝不同组织中β2AR基因m RNA的表达水平。【结果与结论】Pmβ2AR的cDNA全长2 426 bp,包括开放阅读框(ORF)2 091 bp,编码696个氨基酸,5′UTR长144 bp,3′UTR长191bp,预测分子质量79.0 ku,理论等电点9.18,多重序列比对结果发现β2AR在不同物种间的保守性较高。软件分析结果显示Pmβ2AR的氨基酸序列具有7个典型的跨膜结构域。q RT-PCR结果表明,Pmβ2AR基因在各组织中均有表达,在鳃中表达量最高,在肝胰腺和性腺中表达量也较高。  相似文献   

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