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文章记述并分析了20世纪90年代后期重庆巫山龙骨坡遗址出土于第7水平层的16件石制品,包括若干各具特色的工具类型,如原型手镐、原型薄刃斧、大型尖刃器、直刃砍砸器、凸刃砍砸器、长刃石刀、短刃石刀、刮削器、凿刃器等,反映出石器制作者明确的工作目标和为了达到目标所经历的一个又一个中间过程;说明了当时的人类对工具制作的具体需求和适当利用自然环境的事实。研究证据还体现了大约200万年前华南早期人类工具类型的多样性与特殊性,标志着中国早期人类在当时阶段所达到的技术发展水平。龙骨坡遗址很可能是东亚早期人类文化的一个发祥地。 相似文献
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以老挝石和寿山石的岩相学为基础,对其矿物学上的差异性进行了对比分析研究.重点用电子探针（EMPA）分析了老挝石和寿山石组成的化学元素种类及含量.用X射线粉晶衍射（XRD）分析了老挝石和寿山石的矿物组成.研究结果表明,老挝石和寿山石两者在矿物学上的差异主要体现在颜色、成分等方面,老挝石的颜色主要为红、白、粉,较少出现黄色,寿山石颜色丰富多彩,有红、白、粉、紫、黄、绿等,不同品种颜色差异较大.造成老挝石和寿山石颜色差异的主要原因为Fe元素含量的变化,Fe含量越高,颜色越深.老挝石和寿山石的主要矿物组成大致相同,主要由地开石、高岭石和珍珠陶石等组成,但两者在矿物组成含量及种类上略有差异.寿山石品种不同,矿物组成略有差异,如寿山虎口石中出现黄铁矿和叶蜡石,这在老挝石的研究中没有发现. 相似文献
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For the deep biosphere,the present is not always the key to the past: what we can learn from the geological record 
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下载免费PDF全文 Patrick Meister 《地学学报》2015,27(6):400-408
Microbial life below the Earth's surface (the deep biosphere) has probably varied significantly since the Archaean. Reconstructing changes in deep biosphere activity over geological timescales is necessary to understand its role in biogeochemical cycling. Even for the last few million years, such changes are often not captured by studying the distribution of present activity. However, several studies using samples from scientific drilling have revealed mineralogical, geochemical, isotopic and fossil organic molecule imprints in the sedimentary record that document rather different past deep biosphere conditions. Changing deep biosphere conditions can also be simulated using geochemical models. While some processes occurring in the past can be understood by comparing them with the present deep biosphere, others lack any modern analogue – they are defined as non‐actualistic. A non‐actualistic consideration of the deep biosphere is therefore essential for a better understanding of how Earth and life co‐evolved through time. 相似文献
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Native copper, both finished artifacts and worked pieces, are relatively common in pre‐Contact sites of northeastern Minnesota. Fifteen artifact samples and seven sources of native copper were submitted for trace‐element analysis as a test of the procedures developed by G. Rapp, Jr. and colleagues (2000). Although the specific sources chosen had high typicality probabilities, very low posterior probabilities preclude confidence that the artifacts were accurately sourced. Potential problems include incomplete characterization of several sources, as well as the limited number of sources in the database. Of more interest than identification of specific sources is the selection of apparent source pairs. Michipicoten (eastern Lake Superior) and Isle Royale (western Lake Superior) are often chosen together; Weyerhauser Mine (Wisconsin) and the Champion Mine (Keewenaw Peninsula) may form another pair. Future research should concentrate on identifying patterns of sources in the region rather than focusing on specific mines. © 2007 Wiley Periodicals, Inc. 相似文献
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虢国墓地位于河南省三门峡市区上村岭,于1956年被发现,经历过20世纪50年代和90年代两次大规模发掘,共发掘墓葬250多座,出土了33000余件（套）珍贵文物。本研究对象是出自M2011太子墓的380余件精美玉（石）器。采用宝玉石学和岩石学的研究思路和无损鉴定方法对M2011（太子墓）出土玉（石）器的玉质进行了详细的研究,结果表明肉眼观察颜色和不同程度受沁的26件出土玉（石）器中23件为软玉,3件为细砂岩。严重受沁会影响出土玉（石）器的材质鉴别,用强透射光观察受沁玉器玉质,部分能够看到沁色的深度,反映出本来的颜色和质地。大型仪器测试可以很好的反映出土玉器的材质与结构特征及成分的变化,弥补了肉眼观察的局限。本研究丰富了三门峡虢国博物馆出土文物的研究内容,提高了出土玉器研究的科技含量,有助于出土玉器的分类命名以及文物等级的确定。 相似文献
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草酸钙生物矿化膜的形成机理和化学仿制－－一种新型石质文物表面防护材料的开发研究 总被引：4，自引：0，他引：4
已经发现一些年代久远的含钙岩石表面有一层天然生成的矿化膜，矿化膜保护下的石刻文字可以历经上千年的风雨而保持完好。本工作探讨了这种膜的组成和来源。膜的样品用FTIR、PLM、EDAX、SEM和TEM进行了分析。检测发现天然矿化膜的主要成分为草酸钙，许多证据表明这是一种生物矿化膜。本文讨论了膜的形成机理。为了开发新型石质文物表面防护材料，我们在实验室中用化学仿制的方法在含钙岩石上生成了这种保护膜，同时研究了膜的生成条件与保护效果之间的关系。 相似文献
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Zhengfu Guo Tianlong Jiao Barry V. Rolett Jiaqi Liu Xuechun Fan Gongwu Lin 《Geoarchaeology》2005,20(8):765-776
The authors conducted a sourcing study of stone adzes recently excavated from the Damaoshan site on Dongshan Island, Fujian province, China. They used XRF, ICP‐MS, and petrographic thin‐section techniques for geochemical and petrographic analysis of six stone adzes from the site and three geological samples from Dongshan Island. The chemical data of these samples compared with other lavas in Fujian, Zhejiang, Penghu, and Taiwan suggest that the Damaoshan people imported stone raw materials either from the Penghu Archipelago in the Taiwan Strait or from the Niutoushan area on the Fujian coast. This indicates that exchange networks along the southeast coast of China, and possibly spanning the Taiwan Strait, had developed as early as 4300–5000 yr B. P. © 2005 Wiley Periodicals, Inc. 相似文献
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广西合浦清水江高岭土矿的矿物学研究 总被引：1，自引：0，他引：1
广西合浦清水江高岭土矿床属花岗岩蚀变型.在区域地质背景概况调查及矿区地质特征、矿石自然品级分布研究的基础上,在矿区内7个不同地点采集样品并分离提纯.样品的X射线粉晶衍射分析表明黏土矿物主要由高岭石和伊利石组成;热分析显示了矿物的相变过程;扫描电镜观察显示高岭石为片状;其化学成分以比较低的铁、钛含量为特征;漂白作用对黄色和红色黏土的白度改善非常明显,小于2μm的颗粒分布占80%左右.这些特征表明广西合浦清水江高岭土的品质优良,具有广阔的开发利用前景. 相似文献
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Mineralogical and spectroscopic characterization,and potential environmental use of limestone from the Abiod formation,Tunisia 总被引：1，自引：0，他引：1
Ali Sdiri Teruo Higashi Tamao Hatta Fakher Jamoussi Norio Tase 《Environmental Earth Sciences》2010,61(6):1275-1287
Limestone beds of the Late Cretaceous Abiod formation (Campanian-Maastrichtian system) are fundamentally important for the
economic growth of the raw material sector in Tunisia. However, little attention has been paid to the detailed physical and
chemical properties of the Abiod limestone. Nine limestone samples collected from the Abiod formation outcropping in the areas
of Bizerte, Gafsa and Gabes, Tunisia, as well as their separated clay fractions, were characterized using different techniques,
such as XRF, XRD, FTIR and TG/DTA. XRF showed the chemical composition of the limestone in which calcium carbonate was the
main constituent, and silica, iron and magnesium were the impurities. XRD also confirmed the presence of small amounts of
clay minerals and quartz along with sharp peaks of calcite. FTIR spectra indicated that the limestone was mainly composed
of CaCO3 in the form of calcite, as identified by its main characteristic absorption bands. These data were in agreement with XRD
and XRF analysis data. The TG/DTA curves of the limestone samples, showing a close similarity to that of pure calcium carbonate,
exhibited an endothermic peak between 600 and 760°C, with the maximum near 750°C. Moreover, FTIR spectra of clay fraction
samples indicated high silica content in some samples. Especially the samples SD1 and SD2 collected in the northern area showed
higher amounts of silica compared with those of AS1, AS2, CHB, ZNC, SND, MKM and GBS collected from southern districts. However,
among the latter seven samples, one could recognize two groups based on the clay mineral investigations: (1) limestone with
minor amounts of smectite and mixed layer minerals of smectite/illite (AS1 and 2, CHB, ZNC, SND and GBS) and (2) limestone
with smectite, kaolinite and apatite (SND and MKM). Differences in these mineralogical and chemical characteristics should
be considered when limestone from the Abiod formation is utilized as a medium for heavy metal removal from wastewater. 相似文献
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The application of mineralogical characterization to mine waste has the potential to improve risk assessment, guide appropriate mine planning for planned and active mines and optimize remediation design at closed or abandoned mines. Characterization of minerals, especially sulphide and carbonate phases, is particularly important for predicting the potential for acidic drainage and metal(loid) leaching. Another valuable outcome from mineralogical studies of mine waste is an understanding of the stability of reactive and metal(loid)-bearing minerals under various redox conditions. This paper reviews analytical methods that have been used to study mine waste mineralogy, including conventional methods such as X-ray diffraction and scanning electron microscopy, and advanced methods such as synchrotron-based microanalysis and automated mineralogy. We recommend direct collaboration between researchers and mining companies to choose the optimal mineralogical techniques to solve complex problems, to co-publish the results, and to ensure that mineralogical knowledge is used to inform mine waste management at all stages of the mining life cycle. A case study of arsenic-bearing gold mine tailings from Nova Scotia is presented to demonstrate the application of mineralogical techniques to improve human health risk assessment and the long-term management of historical mine wastes. 相似文献
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应用X射线衍射-激光拉曼光谱-电子探针等分析测试技术研究旬阳朱砂玉的矿物学特征 总被引：2，自引：2，他引：0
近年来外观形似鸡血石的红色朱砂玉备受关注,其中吉林、贵州、青海等地这种红色岩石已有矿物成分、岩性等相关方面的研究。本文利用常规宝石常数测定手段、偏光显微镜、X射线粉晶衍射仪、激光拉曼光谱仪、电子探针等分析测试技术,对陕西旬阳朱砂玉的矿物学和宝石学特征进行了研究。结果表明,该产地朱砂玉的矿物成分以石英、辰砂为主,含有少量的方解石、白云石、重晶石、黄铁矿;其中主要矿物成分辰砂的颜色随铁含量的增加而逐渐加深;矿物结构以碎屑结构、粒状变晶结构、穿插交代结构为主。根据矿物成分以及矿床成因的研究分析,初步认为陕西旬阳朱砂玉属于沉积-热液-强烈改造型矿床。该地区的朱砂玉与鸡血石的相似之处在于矿物的主要成分都含有辰砂,致使外观品质上具有一定的相似性,但具体矿床成因以及矿物成分有着明显的差别:旬阳朱砂玉产于沉积-热液-强烈改造型矿床中,其“地”主要矿物成分为石英岩,“血”为辰砂;而浙江昌化和内蒙古巴林鸡血石均产于中生代交代蚀变酸性火山岩的次级断裂小构造中,其“地”主要为地开石、高岭石、叶腊石,“血”为辰砂。此次研究采用多种分析测试手段为旬阳朱砂玉与鸡血石的鉴别提供了可靠的依据。 相似文献
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It is often necessary to locate the original quarry which supplied the stone for a particular historical building. This stones could be used for future restoration work and for testing in the laboratory (artificial aging tests, physical properties determination, control of the efficacy of conservation treatments, etc.). Generally, reviewing historical documentation gives information about the geographical setting of quarries and location of the stones in the monument, but this information needs to be proved by field and laboratory studies. The comparative study of stone from quarries and monuments should basically include the following: (1) mineralogical and petrographical studies; (2) the chemical analysis of major, minor and trace elements; (3)stable isotopes determinations; (4) physical properties of quarry materials and unweathered building stone (water absorption, ultrasound transmission velocity, porosity and porous system, density, bulk density, compressive strength, etc.). This methodology was applied to Málaga Cathedral stones represented in the main façade, towers, and the western zone of the terrace, which, according to historical literature, came from Almayate (Miocene–Pliocene limestones) and Cerro Coronado (Permotriassic sandstone) in Málaga. The conclusion of the comparative study carried out on quarries and building stones was consistent with the information available from the historical documentation. 相似文献
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Visible near infrared and shortwave infrared (VNIR-SWIR, 350 to 2500 nm) reflectance spectra obtained from an analytical spectral device (ASD) have been used to define alteration zones adjacent to porphyry copper deposits (PCDs), in the central part of Kerman magmatic arc, SE Iran. The spectral analysis identified sericite, illite, halloysite, montmorillonite, dickite, kaolinite, pyrophyllite, biotite, chlorite, epidote, calcite, jarosite, and iron oxyhydroxides (e.g. hematite, goethite) of hydrothermal and supergene origin. Identified alteration zones are classified into six principal types namely phyllic, phyllic/propylitic, propylitic, potassic, argillic and advanced argillic. The iron oxide minerals in the oxidized zone were also identified using spectral analysis. Results of spectral analyses of samples are consistent with mineralogical data obtained from X-ray diffraction (XRD) and petrographic studies. Spectroscopic studies by ASD demonstrate that this tool is very useful for semi-quantitative and cost effective identification of different types of alteration mineral assemblages. Furthermore, it can provide a valuable tool for evaluating aerial distribution of alteration minerals while coupled with remote sensing data analysis. 相似文献
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M. Dolores Petit-Dominguez M. Isabel Rucandio Almudena Galan-Saulnier Rosario Garcia-Gimenez 《Journal of Geochemical Exploration》2008
Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies. 相似文献
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Hans‐Eike Gäbler Frank Melcher Torsten Graupner Andreas Bahr Maria A. Sitnikova Friedhelm Henjes‐Kunst Thomas Oberthür Helene Brätz Axel Gerdes 《Geostandards and Geoanalytical Research》2011,35(4):431-448
Coltan (the African trade name for columbite‐tantalite, a tantalum ore) is one of several raw materials that finance the civil wars in the eastern provinces of the Democratic Republic of the Congo. To improve the transparency along the tantalum trade chain, a ‘certificate of origin’ for so‐called ‘conflict minerals’ has been recommended by the United Nations. Accordingly, the German Federal Institute for Geosciences and Natural Resources (BGR) has developed an analytical fingerprint procedure for coltan. Mineral formation age, modal mineralogy and chemical composition are important fingerprint parameters. The original workflow to obtain these parameters was streamlined and is now based on mineral liberation analysis and LA‐ICP‐MS. The use of an ICP‐MS instrument with a detector system covering an extended linear dynamic range and the application of an internal standard‐independent calibration strategy allowed data for major and trace element determination and mineral formation age estimates to be obtained simultaneously. The analytical results of this new approach were compared with analytical techniques of the original workflow and showed excellent agreement in terms of mineralogical and chemical characterisation and mineral formation age of coltan samples. Within a test, samples of different origin were allocated correctly and simple, binary mixtures were also identified successfully. 相似文献
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The Nkout deposit is part of an emerging iron ore province in West and Central Africa. The deposit is an oxide facies iron formation comprising fresh magnetite banded iron formation (BIF) at depth, which weathers and oxidises towards the surface forming caps of high grade hematite/martite–goethite ores. The mineral species, compositions, mineral associations, and liberation have been studied using automated mineralogy (QEMSCAN®) combined with whole rock geochemistry, mineral chemistry and mineralogical techniques. Drill cores (saprolitic, lateritic, BIF), grab and outcrop samples were studied and divided into 4 main groups based on whole rock Fe content and a weathering index. The groups are; enriched material (EM), weathered magnetite itabirite (WMI), transitional magnetite itabirite (TMI) and magnetite itabirite (MI). The main iron minerals are the iron oxides (magnetite, hematite, and goethite) and chamosite. The iron oxides are closely associated in the high grade cap and liberation of them individually is poor. Liberation increases when they are grouped together as iron oxides. Chamosite significantly lowers the liberation of the iron oxides. Automated mineralogy by QEMSCAN® (or other similar techniques) can distinguish between Fe oxides if set up and calibrated carefully using the backscattered electron signal. Electron beam techniques have the advantage over other quantitative mineralogy techniques of being able to determine mineral chemical variants of ore and gangue minerals, although reflected light optical microscopy remains the most sensitive method of distinguishing closely related iron oxide minerals. Both optical and electron beam automated mineralogical methods have distinct advantages over quantitative XRD in that they can determine mineral associations, liberation, amorphous phases and trace phases. 相似文献
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福建寿山高山石与坑头石的矿物学特征 总被引：2，自引：0，他引：2
运用显微硬度测试仪、静水称重法、X射线粉晶衍射仪、傅立叶红外光谱仪、原子吸收分光光度计、环境扫描电镜等测试手段,对福建寿山高山石和坑头石的矿物学特征进行了研究。结果表明,高山石含有多种高岭石族矿物,其中以地开石为主要矿物;坑头石中除含有地开石外,还存在相当数量的珍珠陶石以及地开石-高岭石、地开石-珍珠陶石的过渡矿物。认为寿山石的透明度与矿物颗粒的粒度、结晶程度有关。另外,发现铁离子为黑色寿山石的主要致色离子,寿山石中的裂解主要由矿物颗粒间定向排列造成。 相似文献
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The influence of hydrodynamics on the chemical composition of sediments is based on the uneven distribution of element abundances in different size fractions. In this study, 72 size‐fractional sediments from the Huanghe (Yellow River) and Changjiang (Yangtze River) riverbeds were measured with XRD, SEM, ICP‐AES and ICP‐MS. The analysis results show that the mineral and chemical characteristics change with grain size in the Huanghe and Changjiang sediments. According to the principal components analysis, three independent geochemical factors were found. The first factor elements, Zr, Hf, Th, U, Y, La and TiO2 are influenced by the existence of heavy minerals. The second factor elements, Al2O3, alkalis, alkaline earth (excluding Ca and Sr) and most of the transitional metals are dominated by clay minerals. The third factor group includes Ca and Sr, which were controlled by calcium‐bearing mineral contents and chemical weathering intensities. The various grain size distributions greatly affect the mineralogical and chemical compositions of bulk sediments. Compared to other size fractions, the 5–6PHI size fractions of the Huanghe and Changjiang sediments have special mineralogical and chemical compositions, and intermediate volume percentages. Weight or volume percentage of each size fraction may be more suitable than mean grain‐size of the bulk sediment to elucidate the grain size effects. Chemical Index of Alteration (CIA) values increase steeply with decreasing grain size, while Weathering Index of Parker (WIP) values are relatively stable. Because of the big influence of the abundance of clay minerals on CIA values, it is questionable to use CIA as a proxy of weathering intensity. Considering the clay mineral effects, stability in values and heterogeneous material properties, WIP has the potential to indicate the chemical weathering intensity of sediments. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献