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1.
Virginie Renson Ariane Jacobs Jan Coenaerts Nadine Mattielli Karin Nys Philippe Claeys 《Geoarchaeology》2013,28(6):517-530
This paper presents the lead isotopic composition of potential clay sources for pottery production, collected in the four major geological zones of Cyprus (Troodos Ophiolite, Circum Troodos Sedimentary Succession, Mamonia Terrane, Kyrenia Terrane) and evaluates its usefulness in Cypriote pottery provenance studies. The clay isotopic signatures from the four zones are compared to each other and to the isotopic composition of various utilitarian pottery wares from three Late Bronze Age sites, respectively located in southern Cyprus (Alassa‐Pano Mandilaris), east Cyprus (Enkomi), and southeast Cyprus (Hala Sultan Tekke). It also explores the potential of this method to better discriminate between potential raw materials used for the production of Base‐ring ware, one of the most characteristic fine pottery of Late Bronze Age Cyprus, which was widely spread in the Eastern Mediterranean (Courtois, 1981; Vaughan, 1991, 1994). Results show that three main lead isotopic fields can be distinguished among the Cypriote clay sources and the comparison of Plain sherds with the clay sources allows discrimination between local products and imports. They also clearly indicate that all the Base‐ring sherds analyzed in this study were made of the clays from the Kathikas Formation that crops out in only limited parts of southwest Cyprus. 相似文献
2.
Lead isotope analyses were carried out on fragments of White Slip II ware, a Late Bronze Age Cypriote pottery ware, and on raw materials possibly used for their production. Sherds originate from three Late Bronze Age sites (Hala Sultan Tekke and Sanidha in Cyprus and Minet el-Beida in Syria) and clays come from the surroundings of Sanidha, a production site for White Slip ware. X-ray fluorescence (XRF) and a Principal Component Analysis (PCA) are combined with Pb isotope analyses to further investigate the effectiveness of the latter method within a multiproxy approach for pottery provenance study. The pottery sherds from the three sites are compared between themselves and with potential raw material. Additional X-ray diffraction (XRD) and analyses using a scanning electron microscope (SEM) equipped with an energy dispersive X-ray detection (EDX) facility were performed on selected sherds and clays. This work confirms that the clay source used for pottery production in Sanidha derives from local weathered gabbro. It also shows that different origins can be proposed for White Slip II ware sherds from Hala Sultan Tekke and Minet el-Beida and that clays were prepared prior to White Slip II ware production. It finally confirms the effectiveness of Pb isotopes in tracing pottery provenance not only by comparing sherd assemblages but also by comparing sherds to potential raw materials. 相似文献
3.
In an effort to further characterize the Middle and Late Helladic pottery industry on Aegina, we have analyzed amphibole in 23 sherds imported to the coastal settlement of Asine. The sherds derive from vessels of different classes and shapes and range in age from MH I‐II to LH IIIB‐IIIC Early. All sherds come from vessels that carry manufacturing marks, and their amphiboles have compositions that are incompatible with those of Methana, Poros, and Melos. Twenty of the sherds have amphiboles that are identical in composition and overlap a narrow range of amphibole compositions found in specific lava flows on the northern portion of Aegina. Given that the dacites across Aegina contain amphiboles with a wide range in compositions, we suggest that the narrow range of amphibole compositions in the sherds indicates that they were derived from either a specific clay source on the island, located in a stream system southeast of the prehistoric settlement at Kolonna, or that the potters used a specific temper source along the same stream system. Multiple clay or temper sources would have produced sherds with a broader range of amphibole compositions reflecting the diversity of amphibole compositions found on Aegina. One sherd has amphibole compositions indicative of an additional Aeginetan component that is not found in the other sherds. Two sherds have amphiboles with compositions that do not match any known reference amphiboles for Aegina, Methana, Poros, or Melos. These may have been derived from still unsampled dacites on Aegina or have been manufactured from materials located outside the Saronic Gulf. © 2004 Wiley Periodicals, Inc. 相似文献
4.
晓店陶瓷矿床位于郯庐断裂带内，并分为瓷石，陶土和陶瓷土三大类型，其中瓷石矿产于下白垩统青山组火山岩中，陶土矿产于上白垩统王氏组中，瓷土矿产于上新统宿迁组中。测试结果表明，该陶瓷矿是较理想的建筑陶瓷原料，并可望成为江苏新的陶瓷原料基地。 相似文献
5.
Nastja Rogan Šmuc Matej Dolenec Judita Lux Sabina Kramar 《Environmental Earth Sciences》2014,71(11):4821-4833
This study is a geochemical analytical approach to the characterization of pottery samples from an archaeological site near Mo?nje (Slovenia). Inductively coupled plasma–mass spectrometry and statistical analyses were used to determine detailed geochemical properties of the pottery sherds and to identify potentially individual groups among the samples studied. The geochemical results indicated the existence of four major groups of the pottery sherds: the first and second groups are assembled from eight samples, all generally characterized by their high CaO and TOT/C content; the third group comprised the samples with the highest SiO2 concentrations; and the fourth group is represented by the samples K3, K5 and K13. The principal component analysis and cluster analysis validated the existing groups and revealed a high degree of chemical similarity between these groups. The geochemical and statistical data confirmed the archaeologists’ hypothesis and interpretation of a similar origin/alteration of source material/probable local ceramic production for the majority of the pottery sherds; the imported origin of samples K3 and K13 was recognized, while sample K5 had been intentionally imported as a sample for comparative purposes. 相似文献
6.
Normally, the use of clays as reference materials in chemical provenance studies of ancient ceramics is complicated due to the original clay paste processing. The primary mixing and/or refining of raw materials during pottery production makes a straightforward comparison of archaeological ceramics with extant geological materials difficult if not impossible in many cases. However, in the case of Pliocene clays from Aegina (Greece), which were examined chemically and mineralogically and compared with Bronze Age pottery produced on the island, a successful exception can be presented. The chemical composition of a large group of Aeginetan pottery resembles the chemical composition of clays from a deposit in close vicinity to the main Bronze Age settlement of the island. Clays from specific outcrops exhibit considerable chemical and mineralogical homogeneity, and the suitability of those clays for pottery production apparently made substantial clay paste processing unnecessary. © 2004 Wiley Periodicals, Inc. 相似文献
7.
J. Victor Owen Joanna L. Casey John D. Greenough Dorothy Godfrey‐Smith 《Geoarchaeology》2013,28(4):394-411
The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeOt = 100 × FeOt/[FeOt + Al2O3 + SiO2] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeOt < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc. 相似文献
8.
The central part of the Murrumbidgee River meanders across an alluvial plain which is 1.5 km to 5 km wide, and confined between low hills composed of granite and folded lower Palaeozoic rocks. Deposition commenced under humid and reducing conditions during the Miocene, and continued during Pliocene time. Oligomict quartz‐sand and gravel beds are dominant in the sequence, and are interlayered with grey to black clay and silty clay, which contain a prolific pollen fauna. During Pleistocene time, a marked reduction in rainfall and consequent change in vegetation resulted in the deposition of a widespread coarse polymict poorly‐sorted gravel associated with yellow and brown clay and silt. The quartz‐sand and gravel beds within the Pliocene deposits constitute a major aquifer system and contain low salinity water suitable for irrigation and town water‐supply purposes. Since 1968, increasing demand has been made on this aquifer system, and wells sunk for various State and Local Government bodies have a total installed capacity of approximately 1000 litres/sec. The most concentrated exploration and development has been effected east of Wagga Wagga, where a well field was constructed to provide water for a regional water supply scheme. Following a refraction seismic survey, test drilling, and mathematical simulation, four production wells were constructed. Mathematical simulation models developed on a mini‐computer were designed primarily to study the behaviour of the aquifer system in response to pumping from the Pliocene aquifers. An analytical model was used to assist in the location of production wells, and a numerical model was used, after construction of the wells, to determine what additional losses from the Murrumbidgee River would be induced by pumping them. These losses were found to correspond to approximately 90% of the pumping rate during long term pumping. 相似文献
9.
Amphorae sherds from the Laecanius workshop of Roman Istria (10–5 B.C. and 78 A.D.), Croatia, were studied by integrating archaeological and geological techniques including fabric analysis, thin‐section petrography, X‐ray diffractometry (XRD), and heavy mineral analysis. The fabric of the sherds showed distinctive characteristics, permitting their classification and allocation into nine fabric groupss. Petrography revealed that quartz is the dominant clastic component, whereas carbonate is common as temper; XRD provided information on firing temperatures that ranged between 750 and 900°C. The sherds contain diverse heavy mineral suites with generally high epidote and garnet proportions; zircon is occasionally important. Garnet/epidote ratios and the presence of diagnostic species (pyroxene, hornblende) showed systematic variations that coincided with similar variations in fabric characteristics. Heavy mineral signatures of amphorae produced in other workshops proved essential in differentiating them from Laecanius sherds. A comparative heavy mineral analysis of terra rossa samples from the vicinity of the workshop indicated that terra rossa was the major source for the paste. Differences observed in the heavy mineral composition of the sherds and terra rossa were interpreted by the spatial heterogeneity of the latter and the mixing of the paste with sandy temper. Fresh Adriatic sponge spicules in the majority of Laecanius sherds and the temper‐derived, generally immature heavy mineral assemblages suggest that sandy deposits from the Adriatic were used for the clastic temper. © 2006 Wiley Periodicals, Inc. 相似文献
10.
Scott M. Fitzpatrick Hiroto Takamiya Hector Neff William R. Dickinson 《Geoarchaeology》2006,21(8):803-822
In Okinawa, locally produced pottery dates back to the Initial Jomon period (˜6500 14C yr B.P.). Later in time, especially during the Early Yayoi‐Heian period (˜300 B.C.–A.D. 300), ceramic assemblages appear to contain mainland (Japan) Yayoi pottery. A greater number of these sherds present in Okinawa over time coincide with an increasing amount of interaction with mainland Japan, as evidenced by other exchange items. In this preliminary study, the authors analyzed sherds from several Early Yayoi‐Heian period deposits from sites in Okinawa using thin‐section petrography and laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS). The objective was to examine the applicability of these techniques for Okinawan ceramic provenance studies, assess intra‐ and intersite variation in mineralogical and chemical composition, and determine whether some sites exhibited a higher frequency of pottery from one locale versus another that might suggest the importation of pottery from mainland Japan. Results are equivocal, suggesting that the region's geological complexity may inhibit successful provenance study of ceramics using these and possibly other compositional techniques. © 2006 Wiley Periodicals, Inc. 相似文献
11.
The geothermal setting of the archaeological site at Aghia Kyriaki, Southeast Melos (or Milos) was investigated in order to help clarify the possible role of the site in mineral exploitation on Melos in Roman times. There are active sulfurous fumaroles in the area and these were also potential sources of sulfur and alum‐group minerals in Roman times. However, geothermal activity has been ongoing in Southeast Melos for hundreds of thousands of years, and extensive hydrothermal alteration of basement rocks to the northeast of the site has produced “white rocks” containing additional potential industrial minerals such as kaolin and alunite. The archaeological remains occur within, but mainly near the surface, of a deeply gullied sequence of late Quaternary alluvial sediments, which consist mainly of metamorphic detritus but are rich in sulfates; the remains contain pottery sherds through the entire sequence of about 40 m. They were deposited on an earlier gullied topography of felsic tuffs overlying the metamorphic basement. Pervasive and veinlike intense reddish alteration of these sediments is probably mainly due to superheated fluid escaping from depth. Field observations demonstrate that this took place after the main phase of building but was likely to be ongoing during occupation of the site. While industrial minerals and geothermal energy would therefore have been available in the Roman period, any relationship of the site to mineral exploitation will have to be determined by archaeological excavation. © 2003 Wiley Periodicals, Inc. 相似文献
12.
The paper presents a comparative micromorphological analysis of the range of soil materials used to make the pottery of the hilly Galilee during the Roman period, and the ceramic products made from these materials. The four soil units that served as raw material for most of the pottery made in this period and region are examined along with pottery derived from each of them. For each soil unit, the soil characteristics and processes are described, followed by a presentation of the micromorphological characteristics of the soil material and those of the pottery made from that material. The contribution of the aeolian dust component to the soil materials is discussed as well as the identification of the tempering materials (nonplastics or other soil materials) added to the pottery paste. The study demonstrates the close correlation in microfabric between the pottery and original soil materials, sheds light on the raw material selection and modification practices of the potters of Roman Galilee, and has significant implications for provenance studies, using chemical analysis, on the pottery of this period and region. © 2002 Wiley Periodicals, Inc. 相似文献
13.
Ahmed Mohamed Youssef 《Geotechnical and Geological Engineering》2008,26(5):579-591
In the current study, Thematic Mapper image was compiled along with field and laboratory investigation results to map the
Pliocene clay deposits. These deposits have high swelling potential; consequently they will have a negative impact on the
urbanization expansion surrounding the flood plain zone (Low desert zone) in Egypt. Principle Component and Minimum Noise
Fraction techniques with the help of supervised classification were successful in the mapping of these deposits. The interpretation
shows that the Pliocene clay deposits occupy most of the wadis terraces and part of the wadis floors, and sometimes they covered
by Quaternary deposits (1–5 m of sand and gravel). The physio-chemical characteristics of these deposits indicate that the
Pliocene clay ranges from silty clay to clay with small amounts of sand. Laboratory analysis (Atterberg limits, saturation
degree, and cation exchange capacity) indicate the swelling characteristics of the Pliocene clay. Different classification
systems were applied and all reveal the expansive nature of this soil, which should be taken into account for future development
in the area. 相似文献
14.
Anatolia has long been a major pottery production center of the ancient world, dating back 7000 cal yr B.P. The Early Iron Age Urartu Kingdom (800–600 B.C.) of eastern Anatolia is known for the production of high‐quality pottery, but little is known regarding firing technology and manufacture of these ceramics. Here we present a preliminary study of Urartu ceramic micromorphology and chemistry and suggest that the Urartus had good knowledge of local geology and intentionally used chemical fluxes (Pb, Rb, and Li) to attain desired firing temperatures. The sophisticated production of Urartu ceramics is comparable to later high‐quality Roman pottery (terra sigillata) procured from the same area. © 2010 Wiley Periodicals, Inc. 相似文献
15.
Three chalcolithic pottery sherds, paint removed from the surface of each sherd, and an unheated red pigment (Tell-Halaf culture, Turkey) were analysed within the frame of archaeometric studies using mineralogical methods, 57Fe Mössbauer spectroscopy, magnetization and rotational hysteresis data. From mineralogical results, the individual minerals forming the cores of the sherds were determined. It was found that the sherds are lime-rich. High temperature X-ray analysis on comparable Ca-rich material showed that the established composition is consistent with a firing temperature of 750-950°C. Apart from the pigment, each Mössbauer spectrum of Fe-bearing components consists of dominating paramagnetic doublets, arising mostly from silicate phases, and of a six-line pattern with reduced intensity, due to ferri- and/or antiferromagnetic Fe-oxide phases. For three samples, an Fe3+ silicate component of the spectra is clearly dominating, which points to oxidizing conditions during firing. For the others Fe2+ and Fe3+ components occur in about equal intensities. For the pigment, the magnetic sextet is of similar intensity to the Fe3+ silicate component. From magnetic analysis of ferrimagnetic phases it follows that a low percentage of particles of solid solutions -Fe2O3 – Fe3O4 exist, probably in part 0.1 m in diameter. The ferrimagnetic particles of at least one paint are probably covered by a thin layer of hematite as found from rotational hysteresis data. An attempt is made to draw conclusions from the experimental results, regarding the firing conditions of the sherds and paints. 相似文献
16.
《International Geology Review》2012,54(1):28-54
Pliocene intrusions in Eocene, Oligocene, and Pliocene volcanic-sedimentary rocks of the eastern Nakhichevan A. S. S.R. are of three principal types: 1) a single central cutting massif; 2) central massif with conformable apophyses; 3) conformable apophyses almost camouflaging a broken up central massif. All three are explained by differences in the morphology and tectonics of the enclosing rocks. Similarities and differences between minor intrusions and salt, gypsum, and clay diapir phenomena are discussed. ‐ ‐ Auth. 相似文献
17.
18.
Paleophytochemical Constituents from the Pliocene Fossil Wood of Pinus Armandii from Longling,Yunnan
Specimens of fossil wood preserved lignified in Pliocene brown coal and identified as Pinus armandii Francher come from an opencast coalmine at Longling in western Yunnan Province, China. Phytochemical investigation of the fossil wood isolated using liquid column chromatography seven compounds （1-7） including a new fluorene derivative named 11,11-dimethyl-11H-benzo[b]fluorene. A further 28 volatiles were detected by gas chromatography-mass spectrometry （GC-MS）. Spectroscopic investigation methods, including MS and 1D and 2D-NMR techniques elucidated the structure of the seven compounds. Two types of natural products, isopimara and stilbene commonly occuring in extant and Pliocene fossil P. armandii indicate phytochemical fidelity during burial under certain circumstances in sediments. Discovery of stilbenes that can inhibit the activities of wood-destroying fungi in the Pliocene P. armandii prompts the assumption that the chemical preservation of this Pliocene fossil wood of P. armandii in brown coal might contribute to the presence of inner natural inhibitors against wood-destroying fungi. 相似文献
19.
A combination of different scientific techniques has been utilized to estimate the initial firing temperature and kiln atmosphere of a collection of Islamic painted sherds excavated from an archaeological site in northern Jordan. Scanning electron microscope investigation of samples refired at different temperatures proves that the pottery was fired at around 750°C in an oxidizing atmosphere. Similar results were obtained by the thermal analysis study using thermogravometric, differential thermogravemetric and differential thermal analysis and by the temperature-minerological scale analysis. The obtained results shed light on the manufacturing techniques adopted by the Islamic potter of the period. © 1999 John Wiley & Sons, Inc. 相似文献
20.
Northwest China is known for its Majiayao-style Neolithic painted pottery which has received much praise for its high level of craftsmanship, yet its chain of production, in particular the step of raw material selection, is still poorly understood. To fill this lacuna, the present study explores the raw materials used in producing these wares from a geological and technological perspective. At its core stands the first geoarchaeological survey conducted around the eponymous site of Majiayao which collected 47 samples of raw materials suitable for ceramic production including clay, loess and rocks, which were all analysed macroscopically. A selection was analysed using thin-section petrography, and a subset of the clay and loess samples were subjected to firing experiments. Additionally, three clay samples were analysed by scanning electron microscope with energy-dispersive X-ray spectrometer to understand their composition and behaviour in ceramic production. These were then compared to archaeological ceramics, thus providing insights into raw-material availability and selection that will be of importance not only for research on Majiayao-style pottery but also for later-period ceramics produced in the area. This research shows how an archaeologically informed geological survey can contribute insights into human–environment interaction in early pottery production, especially the interplay between raw-material availability, technological know-how and potters' choices. 相似文献