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1.
北山造山带东段芨芨泉岩体岩性为辉长岩和辉绿岩,LA-ICP-MS锆石U-Pb测年获得(274.1±5.3)Ma的锆石结晶年龄,表明该岩体形成于早二叠世。岩体地球化学数据显示:岩石具有较低SiO_2、较高的Al_2O_3和CaO及较高的Mg~#,稀土元素总量较低,轻重稀土分异不明显,弱正Eu异常,岩石富集大离子亲石元素(Rb、Ba、K),亏损高场强元素(Nb、Ta、P、Zr)。岩石地球化学特征表明,岩浆起源于亏损地幔的部分熔融、上升过程中受到地壳物质的混染,结合区域地质背景,认为芨芨泉岩体形成于板内伸展构造背景。 相似文献
2.
研究区位于武夷—云开陆内造山带上.侧塘岩体岩性主要是片麻状中细粒斑状黑云母二长花岗岩.LA-ICP-MS锆石U-Pb锆石加权平均年龄为(441.5±13)Ma,表明片麻状花岗岩侵位时代为早志留世.岩体K2O/Na2O大于1.1(K2O/Na2O=1.10～3.52,个别为22.38),铝饱和指数(A/CNK)为1.26～3.49,属高钾钙碱性强过铝花岗岩.岩石总体上富集Rb、Th、U、K、Pb、Nd等,亏损Ba、Nb、Ta、Sr、Ti等,明显富集轻稀土元素[(La/Yb)N=5.18～10.62],具有较强的负Eu异常(δEu=0.52～0.60),具似大陆弧特征.锆石Hf同位素研究结果表明,εHf(t)=–1.3～ –12.5,其平均值为–5.82.两阶段模式年龄(TDM2)主要为1502～2228 Ma(n=10),平均值为1794.8 Ma.这些地球化学特征指示片麻状花岗岩为S型花岗岩.武夷—云开陆内造山早期挤压造山造成强烈褶皱和逆冲推覆,导致地壳加厚,并诱发下地壳古—中元古代砂泥质麻粒岩相源岩发生部分熔融而形成侧塘岩体. 相似文献
3.
出露于新疆塔里木南缘铁克里克地区西段的都维吐卫花岗岩体,侵入赫罗斯坦岩群(Pt1H)黑云二长片麻岩中,与库浪那古岩群(Pt2K)和大同西岩体呈断层接触,东部多被博查特塔格组(Jxbc)不整合覆盖。通过地球化学分析,显示岩体具高Si、高Al、高K,贫Na、低Ga、低P、低Ti和贫Mg的特征,铝饱和指数(A/CNK)为1.38~1.43,CIPW标准刚玉分子大于1%,属高钾钙碱性过铝质花岗岩。在稀土元素方面显示,轻稀土元素(LREE)富集、重稀土元素(HREE)亏损,轻重稀土元素分馏明显,Eu出现中等负异常(δEu=0.59~0.82);在微量元素方面,明显富集大离子亲石元素Rb、Ba、Th和K,亏损高场强元素Nb、Ta、Ti。岩体LA-ICP-MS锆石U-Pb同位素定年获得年龄为(1 909±47)Ma,属于古元古代花岗岩。综合分析认为该岩体是造山晚期-同碰撞环境下形成的,与加厚地壳引起的地壳重熔有关,推断西昆仑造山带强烈的陆内造山活动应在古元古代已经开始了;结合赫罗斯坦岩群(Pt1H)中角闪斜长片麻岩中锆石年龄记录,推断2 000~1 800Ma塔里木陆块存在Columbia超大陆聚合事件。 相似文献
4.
辽东王家堡子地区出露大量古元古代花岗质岩石,前人将其统称为花岗质混杂岩。通过详细的野外地质调查和室内综合研究,将该套花岗质混杂岩解体为条痕状黑云母二长花岗岩和片麻状黑云母二长花岗岩两类。岩石地球化学分析结果显示二者具有一致的地球化学特征。均显示高SiO_2、富K_2O、贫Al_2O_3的特征,K_2O/Na_2O=0.64～2.14,TiO_2含量为0.16%～0.3%,MnO、MgO、CaO和P_2O_5的含量较低,铝指数A/CNK集中分布在1.06～1.1之间,A/NK在1.50～1.62之间,均属于过铝质高钾钙碱性系列;微量元素显示强烈亏损Nb、Ti、Ta等高场强元素,富集Rb、U、K等大离子亲石元素,具有明显的负Eu异常,具有A型花岗岩的特征。条痕状黑云母二长花岗岩大部分锆石为具有清晰振荡环带的岩浆锆石,LA-ICP-MS锆石U-Pb年龄为2188±13Ma,代表该岩石的岩浆结晶年龄。片麻状黑云母二长花岗岩大部分锆石具有明显的变质增生边,部分核部锆石具有清晰的振荡环带,LA-ICP-MS锆石U-Pb测年获得核部年龄为2214±16Ma,代表该岩石的岩浆结晶年龄;增生边年龄为1905±13Ma,应代表该岩石的变质年龄。条痕状黑云母二长花岗岩和片麻状黑云母二长花岗岩的Hf同位素模式年龄分别为2387～2584Ma和2474～2641Ma,平均地壳模式年龄分别为2495～2808Ma和2633～2868Ma,大于岩石形成年龄,暗示研究区古元古代花岗岩源区主要为太古宙基底,混有少量古元古代新生地壳。结合前人报道的埃达克质花岗闪长岩的形成环境,认为胶-辽-吉古元古代造山/活动带早期经历了2.2～2.15Ga的拉伸裂解过程和2.0Ga左右俯冲挤压的构造演化过程。 相似文献
5.
《地球科学进展》2016,(3)
测定了闽西南地区5件基性岩脉的全岩主微量元素,锆石U-Pb年龄和Hf,O同位素。5件岩脉主要为辉绿岩,其全岩SiO_2含量为45%~53%,稀土元素显示轻稀土富集的右倾配分模式。基性岩脉中大部分锆石具明显振荡环带和扇状环带,为典型岩浆结晶锆石特征。锆石U-Pb年龄(96~2 400 Ma)分布较为分散。除少量锆石年龄(96~142 Ma)可能指示岩脉形成年龄外,其余均为捕获锆石。捕获锆石年龄主要分布在4个范围:早元古代(2 467~1 796 Ma),中晚元古代—震旦纪(1 343~647 Ma),志留纪—晚三叠世(427~225 Ma),晚侏罗世(159~140 Ma)。Hf-O同位素显示早元古代锆石来源于接近球粒陨石均一储库的地幔。中晚元古代以后年龄的锆石其Hf-O同位素均具有亏损地幔岩浆与地壳组分混合的特征;志留纪—晚侏罗世锆石主要来源于S型壳源花岗岩的重熔;早白垩世晚期的锆石ε_(Hf)(t)值与δ~(18)O值清晰地显示出亏损地幔与地壳岩浆混合的趋势。闽西南基性岩脉中锆石的二阶段Hf亏损地幔模式年龄(TDM2)峰值主要分布在1.6~1.9 Ga,说明早元古代晚期幔源岩浆作用形成的基性岩地壳可能是形成后期花岗岩的主要源区。 相似文献
6.
崇山杂岩带为滇西三江造山系西侧边缘的一条重要边界构造,属青藏高原造山带的南东缘.带内岩浆活动强烈,前人认为其主要由晚元古代、中生代的花岗岩组成;而据地质调查发现,带内新生代的岩浆作用十分发育.本文对带内新发现的灰白色黑云二花岗岩进行研究,获得了锆石U-Pb LA-ICP-MS年龄为34.88 Ma和35.25 Ma,表明其侵位于古近纪始新世.岩石地球化学表明,黑云二花岗岩为钾玄质-高钾钙碱性系列的过铝质花岗岩类,稀土元素配分曲线为右倾,其中LREE明显富集,HREE为不同程度亏损,具明显的负Eu异常;富集Rb、Th、Ce、Sm和亏损K、Ba、Ta、Hf、Y等元素,且为淡色花岗岩特征;据锆石Hf同位素测试分析,εHf(t)值为–2.35～+2.33和TDM2为962～1259 Ma,表明了花岗岩岩浆源区为壳幔混合的产物,以及源岩主要源自中元古代—新元古代陆壳基底物质的部分熔融.综合研究认为,始新世黑云二长花岗岩形成于喜马拉雅期碰撞造山向造山晚期转换阶段,是一套典型的"超厚地壳"部分熔融和壳幔相互作用的淡色花岗岩;以及其侵位时间代表了漕涧地区喜马拉雅碰撞造山阶段的完成和造山晚期阶段的开始,且转换时间约为35 Ma. 相似文献
7.
对西大别造山带夏店岩体进行了系统的锆石LA-ICP-MSU-Pb定年、岩石地球化学研究,发现该岩体化学成分具富硅、碱,贫钙、镁、铝等特点;岩石轻稀土元素富集,重稀土元素亏损,轻重稀土元素分馏明显,Eu亏损明显;Rb、K、Th等大离子亲石元素和Pb元素富集,Ta、Nb、Ti等高场强元素亏损和Sr、Ba元素亏损;岩石成因类型上属于A型花岗岩。LA-ICP-MS锆石U-Pb定年结果显示夏店岩体~(206)Pb/~(238)U加权平均年龄为130.0±1.8 Ma,代表岩体的结晶年龄,显示该岩体为早白垩世岩浆活动的产物。夏店岩体A型花岗岩形成于造山期后环境,预示着桐柏-大别造山带板内演化阶段的到来。 相似文献
8.
湘东北三墩铜铅锌矿区花岗岩的岩石成因——锆石U-Pb测年、岩石地球化学和Hf同位素约束 总被引：1，自引：1，他引：0
对湘东北三墩铜铅锌矿区花岗岩进行了系统的锆石U-Pb年代学、岩石地球化学和Hf同位素分析。LA-ICP-MS锆石U-Pb定年表明,三墩铜铅锌矿区花岗岩成岩年龄为131.9±1.1Ma。三墩铜铅锌矿区花岗岩为一套强过铝质钙碱性系列花岗岩,富集U、Ta、Pb,亏损Ba、Nb、Sr、Zr、Ti等元素,稀土元素配分模式为右倾配分模式,具有弱负Eu异常。Hf同位素分析表明,三墩铜铅锌矿区花岗岩燕山晚期锆石ε_(Hf)(t)值为-5.9~-2.4,Hf同位素二阶段模式年龄为1558~1338Ma,表明其物质来源于中元古代古老地壳岩石部分熔融。749.5Ma继承锆石核的ε_(Hf)(t)值为+4.8,Hf同位素二阶段模式年龄为1355Ma,暗示其物质来源有幔源物质加入。三墩铜铅锌矿区花岗岩可能是由于中下地壳的熔融岩浆形成后,混入少量幔源物质上侵形成的。 相似文献
9.
甘肃马衔山花岗岩杂岩体LA-ICPMS锆石U-Pb测年及其构造意义 总被引：5，自引：0，他引：5
甘肃马衔山侵入杂岩体位于祁连造山带的东部,侵入于新太古代—古元古代变质基底岩系(马衔山岩群)中,主体岩石类型为片麻状二长花岗岩,其次为侵入于片麻状二长花岗岩中的钾长花岗岩。利用LA-ICPMS(激光剥蚀等离子体质谱)测年设备,对片麻状二长花岗岩进行单颗粒锆石微区U-Pb同位素测定,获得1192±38Ma的年龄,为中元古代晚期;岩石地球化学特征显示二长花岗岩侵入体具有火山弧-同碰撞花岗岩特征。马衔山变形侵入体所代表的热—构造事件与格林威尔造山运动时代(1190～980Ma)相当,可能与Rodinia超大陆形成有一定的成因联系。这一新的资料,对研究祁连造山带元古宙大地构造格局、构造演化及中国大陆动力学具有重要意义。 相似文献
10.
《地质科技情报》2016,(2)
对松潘-甘孜北部岗龙地区的花岗岩岩株进行了详细的岩石地球化学、锆石U-Pb年代学和锆石Hf同位素的研究,探讨了其成因。结果表明,锆石LA-ICP-MS测年年龄分别为(207.5±2),(209±2.4)Ma,形成时期为晚三叠世。SiO_2质量分数较高,高K低Na。Al_2O_3质量分数高,为强过铝质。轻稀土元素富集,具明显的Eu负异常,亏损Ba、Nb、Ta、Sr、Ti,富集Rb、Th、Pb、Hf等,具有S型花岗岩特征,锆石εHf(t)值在-18.6~4.7之间,推测为三叠纪浊流沉积经部分熔融结晶而成,并受到地幔物质的混染,通过锆石饱和温度,推测幔源岩浆为岩体的形成提供了热源。结合松潘-甘孜造山带区域地质背景及岩浆演化规律分析表明,松潘-甘孜造山带印支期花岗岩形成于地壳拆沉作用,岗龙地区S型花岗岩是中地壳重融作用形成。 相似文献
11.
吉林省永吉县头道沟地区出露许多与头道沟岩组相伴产出的镁铁—超镁铁质岩,鉴于其处于长春-延吉构造带附近而受到业内关注,但由于缺少高精度年代学资料,制约了对区域大地构造的深入研究。本文采用锆石U-Pb(LA-ICP-MS)方法,对镁铁—超镁铁质岩进行了年代学研究。变质辉绿岩年龄为270±5 Ma,变质橄榄岩中捕获锆石最小年龄为297 Ma,考虑岩石组合及二者紧密相伴产出,认为二者均形成于中二叠世。镁铁—超镁铁质岩中捕获的锆石记录了华北克拉通及其北缘多次重要的构造热事件。其中,变辉绿岩中获得446±6 Ma的年龄与变质橄榄岩中获得的不一致线下交点434±240 Ma年龄共同对应了华北克拉通北缘早古生代的重要构造岩浆热事件;大量的1.8~2.4Ga年龄对应古元古代辽吉造山带热事件;1377 Ma、1542 Ma与蓟县系建造时代对应;869~997 Ma与青白口系建造时代对应;在变质辉绿岩中还存在众多3.0~3.2Ga锆石年龄。分析上述年龄结构及龙岗陆块北缘古生代地质体分布特征,推测研究区深部可能存在古老的变质基底,同时也表明研究区出露的镁铁—超镁铁质岩形成于陆内构造环境,而非蛇绿岩的组成成分,这对深化区域大地构造研究具有重要意义。 相似文献
12.
The Mesoproterozoic Telemark supracrustals in southern Norway comprise two major assemblages of bimodal volcanic and clastic metasedimentary rocks. The older Vestfjorddalen supergroup evolved from A-type, ca. 1500 Ma continental felsic volcanism, via within-plate type basaltic volcanism, into open sea siliciclastic sedimentation, and produced an at least 5 km thick, quartzite-dominated sequence, the Vindeggen group. It overlies a basement formed by just slightly older, 1550–1500 Ma mature arc rocks. The younger, 1170–1140 Ma Sveconorwegian supergroup was characterized by bimodal volcanism, associated with plutonism, and with several intervening periods of clastic sedimentation. The metadiabase dated in this study cuts the Vindeggen group at the top of the older supergroup and is itself delimited by an unconformity at the bottom of the younger supergroup. The 1347 ± 4 Ma age, obtained by ID-TIMS analysis of zircon, defines a mimimum age for deposition of the Vindeggen group. The age is unique in the regional context but in general terms it fits a pattern of episodic and locally intense magmatism that characterized the Mesoproterozoic development of the margins of Proto-Baltica and -Laurentia and has been related to the evolution of a long-lived convergent margin. The similarities between some of these terranes and distinctiveness from others, in both orogens, may indicate outboard evolution of the Telemarkia and Frontenac terranes before their aggregation within the Sveconorwegian–Grenvillian orogen. 相似文献
13.
早古生代加里东期造山运动(广西运动)的性质是华南大地构造演化长期争议的重大地质问题.桂东南岑溪糯垌一带奥陶纪浅变质地层中出露一套变形变质基性岩系构造岩片,主要由变枕状玄武岩、辉绿岩墙以及少量块状辉长岩和辉石岩组成.变玄武岩、变辉绿岩的SiO2含量为49.20%~52.30%,MgO含量为6.78%~9.11%,Mg#为55~63,TiO2含量为1.02%~1.34%,属低钾拉斑玄武系列基性岩.稀土元素配分平坦,轻稀土亏损,(La/Sm)N为0.72~1.05,(La/Yb)N为0.7~1.0,无明显Eu异常,大离子亲石元素Rb、Ba、Th、U、K、Pb相对富集,高场强元素Nb、Ta、Zr、Hf、Ti平坦-略亏损,Ti/V为21.30~25.12,Nb/Th为2.1~4.2,表现出俯冲带之上(SSZ)蛇绿岩的地球化学特征.变辉绿岩LA-ICP-MS锆石U-Pb成岩年龄为437±5 Ma,表明其形成于早志留世.综合研究表明,糯垌变基性岩系应属早古生代形成于俯冲之上(SSZ)弧前构造环境的肢解蛇绿岩残片,这一发现为华南扬子克拉通与华夏地块之间存在早古生代洋盆和俯冲-增生碰撞造山提供了关键证据. 相似文献
14.
Zircon textures, chemistry and microstructures have been characterized in situ within Carboniferous sandstones from the Midland Valley of Scotland using back‐scattered electron and cathodoluminescence images, electron backscatter diffraction techniques and chemical analyses. The study of polished thin sections reveals a variety of zircon types including unmodified detrital zircon, zircon outgrowths and different forms of modified zircon that formed in low‐temperature conditions within the sedimentary rocks. These rocks have only experienced temperatures of <100 °C during burial; however, altered zircon is abundant and characterized by a low mean atomic number, with relatively high contents of non‐formula elements and a nano‐crystalline or microcrystalline structure. It forms by replacement of detrital zircon that subsequently became metamict. Two types of replacement mechanisms are effective in sedimentary environments and involve either dissolution–reprecipitation or solid‐state reaction, but both require fluid access to the radiation‐damaged areas. The former process appears to become the dominant replacement mechanism as temperature increases and produces highly porous, inclusion‐rich zircon. Metamict zircon is extremely reactive in near‐surface conditions and the production of low‐temperature zircon is sensitive to both parent zircon characteristics and environmental conditions. As such, the alteration of zircon has the potential to yield unique information on the diagenetic history of sedimentary rocks. Low‐temperature zircon would be unlikely to survive sedimentary transport or the rock crushing procedures that characterize many investigations of detrital zircon populations and consequently may generate severe biases in studies of this type. 相似文献
15.
G. TOPUZ A. I. OKAY R. ALTHERR M. SATIR W. H. SCHWARZ 《Journal of Metamorphic Geology》2008,26(9):895-913
A blueschist facies tectonic sliver, 9 km long and 1 km wide, crops out within the Miocene clastic rocks bounded by the strands of the North Anatolian Fault zone in southern Thrace, NW Turkey. Two types of blueschist facies rock assemblages occur in the sliver: (i) A serpentinite body with numerous dykes of incipient blueschist facies metadiabase (ii) a well‐foliated and thoroughly recrystallized rock assemblage consisting of blueschist, marble and metachert. Both are partially enveloped by an Upper Eocene wildflysch, which includes olistoliths of serpentinite–metadiabase, Upper Cretaceous and Palaeogene pelagic limestone, Upper Eocene reefal limestone, radiolarian chert, quartzite and minor greenschist. Field relations in combination with the bore core data suggest that the tectonic sliver forms a positive flower structure within the Miocene clastic rocks in a transpressional strike–slip setting, and represents an uplifted part of the pre‐Eocene basement. The blueschists are represented by lawsonite–glaucophane‐bearing assemblages equilibrated at 270–310 °C and ～0.8 GPa. The metadiabase dykes in the serpentinite, on the other hand, are represented by pumpellyite–glaucophane–lawsonite‐assemblages that most probably equilibrated below 290 °C and at 0.75 GPa. One metadiabase olistolith in the Upper Eocene flysch sequence contains the mineral assemblage epidote + pumpellyite + glaucophane, recording P–T conditions of 290–350 °C and 0.65–0.78 GPa, indicative of slightly lower depths and different thermal setting. Timing of the blueschist facies metamorphism is constrained to c. 86 Ma (Coniacian/Santonian) by Rb–Sr phengite–whole rock and incremental 40Ar–39Ar phengite dating on blueschists. The activity of the strike–slip fault post‐dates the blueschist facies metamorphism and exhumation, and is only responsible for the present outcrop pattern and post‐Miocene exhumation (～2 km). The high‐P/T metamorphic rocks of southern Thrace and the Biga Peninsula are located to the southeast of the Circum Rhodope Belt and indicate Late Cretaceous subduction and accretion under the northern continent, i.e. the Rhodope Massif, enveloped by the Circum Rhodope Belt. The Late Cretaceous is therefore a time of continued accretionary growth of this continental domain. 相似文献
16.
James R. Rustad 《Contributions to Mineralogy and Petrology》2015,169(5):50
The interfacial contact region between a rhyolite melt and the accessory minerals monazite, xenotime, and zircon is investigated using molecular dynamics simulations. On all surfaces, major structural rearrangement extends about 1 nm into the melt from the interface. As evidenced by the structural perturbations in the ion distribution profiles, the affinity of the melt for the surface increases in going from monazite to xenotime to zircon. Alkali ions are enriched in the melt in contact with an inert wall, as well as at the mineral surfaces. Melt in contact with zircon has a particularly strong level of aluminum enrichment. In xenotime, the enrichment of aluminum is less than that in zircon, but still notable. In monazite, the aluminum enrichment in the contact layer is much less. It is expected that the relative surface energies of these accessory minerals will be a strong function of the aluminum content of the melt and that nucleation of zircon, in particular, would be easier for melts with higher aluminum concentration. The crystal growth rate for zircon is expected to be slower at a higher aluminum concentration because of the effectiveness of aluminum in solvating the zircon surface. The variable interfacial concentration profiles across the series of accessory minerals will likely affect the kinetics of trace element incorporation, as the trace elements must compete with the major elements for surface sites on the growing accessory minerals. 相似文献
17.
大别山变质岩锆石微区稀土元素和Th,U特征 总被引：6，自引：0，他引：6
对进行过微区U-Pb定年和阴极发光成像研究的大别山辛店榴辉岩、双河榴辉岩、黄镇榴辉岩和双河硬玉石英岩中锆石,进行了微区核部与边部稀土元素测定.结合U-Pb年龄和CL图象,探讨了超高压变质过程中稀土元素从原岩锆石到变质锆石的变化.结果表明,原岩锆石和变质锆石有很不相同的稀土元素含量,它取决于变质锆石是由变质重结晶还是变质增生作用形成及形成时间.一般说来,边部变质锆石比原岩锆石亏损稀土元素,特别是重稀土,并且有更低的Th/U比.变质锆石的稀土元素和Th/U比可以为变质锆石形成时的物理化学环境和变质锆石成因提供重要信息. 相似文献
18.
Mihoko Hoshino Yasushi Watanabe Hiroyasu Murakami Yoshiaki Kon Maiko Tsunematsu 《Resource Geology》2013,63(1):1-26
The two drill holes, which penetrated sub‐horizontal rare earth element (REE) ore units at the Nechalacho REE in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify the enrichment mechanism of the high‐field‐strength elements (HFSE: Zr, Nb and REE). The REE ore units occur in the albitized and potassic altered miaskitic syenite. Zircon is the most common REE mineral in the REE ore units, and is divided into five types as follows: Type‐1 zircon occurs as discrete grains in phlogopite, and has a chemical character similar to igneous zircon. Type‐2 zircon consists of a porous HREE‐rich core and LREE–Nb–F‐rich rim. Enrichment of F in the rim of type‐2 zircon suggests that F was related to the enrichment of HFSE. The core of type‐2 zircon is regarded to be magmatic and the rim to be hydrothermal in origin. Type‐3 zircon is characterized by euhedral to anhedral crystals, which occur in a complex intergrowth with REE fluorocarbonates. Type‐3 zircon has high REE, Nb and F contents. Type‐4 zircon consists of porous‐core and ‐rim, but their chemical compositions are similar to each other. This zircon is a subhedral crystal rimmed by fergusonite. Type‐5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircon grains are filled by fergusonite. Type‐4 and type‐5 zircon grains have low REE, Nb and F contents. Type‐1 zircon is only included in one unit, which is less hydrothermally altered and mineralized. Type‐2 and type‐3 zircon grains mainly occur in the shallow units, while those of type‐4 and type‐5 are found in the deep units. The deep units have high HFSE contents and strongly altered mineral textures (type‐4 and type‐5) compared to the shallow units. Occurrences of these five types of zircon are different according to the depth and degree of the hydrothermal alteration by solutions rich in F and CO3, which permit a model for the evolution of the zircon crystallization in the Nechalacho REE deposit as follows: (i) type‐1 (discrete magmatic zircon) is formed in miaskitic syenite. (ii) LREE–Nb–F‐rich hydrothermal zircon formed around HREE‐rich magmatic zircon (type‐2). (iii) type‐3 zircon crystallized through the F and CO3‐rich hydrothermal alteration of type‐2 zircon which formed the complex intergrowth with REE fluorocarbonates; (iv) the CO3‐rich hydrothermal fluid corroded type‐3, forming REE–Nb‐poor zircon (type‐4). Niobium and REE were no longer stable in the zircon structure and crystallized as fergusonite around the REE–Nb‐leached zircon (type‐4); (v) type‐5 zircon is formed by the more CO3‐rich hydrothermal alteration of type‐4 zircon, suggested by the fact that type‐4 and type‐5 zircon grains are often included in ankerite. Type‐3 to type‐5 zircon grains at the Nechalacho REE deposit were continuously formed by leaching and/or dissolution of type‐2 zircon in the presence of F‐ and/or CO3‐rich hydrothermal fluid. These mineral associations indicate that three representative hydrothermal stages were present and related to HFSE enrichment in the Nechalacho REE deposit: (i) F‐rich hydrothermal stage caused the crystallization of REE–Nb‐rich zircon (type‐2 rim and type‐3), with abundant formation of phlogopite and fluorite; (ii) F‐ and CO3‐rich hydrothermal stage led to the replacement of a part of REE–Nb–F‐rich zircon by REE fluorocarbonate; and (iii) CO3‐rich hydrothermal stage resulted in crystallization of the REE–Nb–F‐poor zircon and fergusonite, with ankerite. REE and Nb in hydrothermal fluid at the Nechalacho REE deposit were finally concentrated into fergusonite by way of REE–Nb–F‐rich zircon in the hydrothermally altered units. 相似文献
19.
Absolute ages of migmatization in the polymetamorphic, parautochthonous basement of the Sveconorwegian Province, Sweden, have been determined using U–Pb ion probe analysis of zircon domains that formed in leucosome of migmatitic orthogneisses. Migmatite zircon was formed by recrystallization whereas dissolution–reprecipitation and neocrystallization were subordinate. The recrystallized migmatite zircon was identified by comparison of zircon in mesosomes and leucosomes. It is backscatter electron‐bright, U‐rich (800–4400 ppm) with low Th/U‐ratios (generally 0.01–0.1), unzoned or ‘oscillatory ghost zoned’, and occurs as up to 100 μm‐thick rims with transitional contacts to cores of protolith zircon. Protolith ages of 1686 ± 12 and 1668 ± 11 Ma were obtained from moderately resorbed, igneous zircon crystals (generally Th/U = 0.5–1.5, U < 300 ppm) in mesosomes; protolith zircon is also present as resorbed cores in the leucosomes. Linkage of folding, synchronous migmatization and formation of recrystallized zircon rims allowed direct dating of south‐vergent folding at 976 ± 7 Ma. At a second locality, similar recrystallized zircon rims in leucosome date pre‐Sveconorwegian migmatization at 1425 ± 7 Ma; an upper age bracket of 1394 ± 12 Ma for two overprinting phases of deformation (upright folding along gently SSW‐plunging axes and stretching in ESE) was set by zircon in a folded metagranitic dyke. Lower age brackets for these events were set at 952 ± 7 and 946 ± 8 Ma by zircon in two crosscutting and undeformed granite–pegmatite dykes. Together with previously published data the present results demonstrate: (i) Tectonometamorphic reworking during the Hallandian orogenesis at 1.44–1.42 Ga, resulting in migmatization and formation of a coarse gneissic layering. (ii) Sveconorwegian continent–continent collision at 0.98–0.96 Ga, involving (a) emplacement of an eclogite unit, (b) regional high‐pressure granulite facies metamorphism, (c) southvergent folding, subhorizontal, east–west stretching and migmatization, all of which caused overprint or transposition of older Mesoproterozoic and Sveconorwegian structures. The Sveconorwegian migmatization and folding took place during or shortly after the emplacement of Sveconorwegian eclogite and is interpreted as a result of north–south shortening, synchronous with east–west extension and unroofing during late stages of the continent–continent collision. 相似文献
20.
INTRODUCTION The Olongbuluke microcontinent , which wasdisintegratedfromthe northern margin of the Qaidamblock (Lu,2002) ,is composed of a two-fold base-ment with cover strata . The lower basement is themedium- to high-grade Delingha complex and theDakendaban Group, and the upper is the low-gradeWandonggou Group. The Wandonggou Group of theupper basement experienced a Late Mesoproterozoicmetamorphic event (see Yu et al .,1994) ,consistentwith the early isotopic geochronological respo… 相似文献