共查询到20条相似文献，搜索用时 734 毫秒
1.
Two main routes of methods for the preparation of photocatalytic active titanium dioxide films on glass substrates were investigated: (1) the use of titanium dioxide powder and (2) the in situ generation of the catalyst via hydrolysis of titanium tetraisopropoxide (TTIP) or TiCl4. The activities of the catalyst films were evaluated by measuring the degradation of dichloroacetic acid (DCA), clofibric acid, and terbuthylazine used as model organic compounds. The concentration decrease of DCA and the concentration increase of chloride ions as the decomposition product allowed to distinguish between photocatalytic degradation of DCA and adsorption onto the TiO2 films. Furthermore, TiO2 films of the commercially available materials P25 (Degussa) and Hombikat UV100 (Sachtleben Chemie) were used to investigate whether there was a difference in the degradation pathways of terbuthylazine as a model compound. For the experiments mini flow‐through reactors were constructed. The investigated immobilization techniques were easy to handle without need of any expensive equipment. All TiO2 coatings showed good photocatalytic activities and mechanical stabilities with efficient long‐term stabilities. The best immobilization reproducibility was achieved by the spray coating technique and by the in situ method with the dipping sol‐gel process starting by TTIP. During the continuous use of the TiO2 films no TiO2 particles were found in the irradiated solutions. 相似文献
2.
Solar photocatalytic decolorization and detoxification of batik dye wastewater using titanium dioxide (TiO2) immobilized on poly‐3‐hydroxybutyrate (P(3HB)) film was studied. The effects of initial dye concentration, catalyst concentration, P(3HB) film thickness, and fabrication methods of the nanocomposite films were evaluated against methylene blue, a standard organic dye. It was observed that 0.4 g of P(3HB)‐40 wt% TiO2 removed 96% of the color under solar irradiation. P(3HB) and TiO2, mixed concurrently in chloroform followed by stirring for 24 h showed a more even distribution of the photocatalyst on the polymer surface and yielded almost 100% color removal. The photocatalytic films were able to completely decolorize real industrial batik dye wastewater in 3 h and induced a chemical oxygen demand (COD) reduction of 80%. Reusability of the 0.4 g P(3HB)‐40 wt% TiO2 film in decolorizing the batik dye wastewater was also possible as it gave a high consistent value of decolorization percentage (>80%) even after the sixth repeated usage. Recovery step of the photocatalysts was also not required in this simple treatment system. The decolorized batik dye wastewater had less/no toxic effects on mosquito larvae, Aedes aegypti, and microalgae, Scenedesmus quadricauda indicating simultaneous detoxification process along with the decolorization process. 相似文献
3.
Kaolin, cordierite, and calcite are investigated as supports for TiO2. The prepared TiO2/support samples are examined for the removal of organic dyes from wastewater. The samples are preliminarily investigated to identify the optimal loaded system using synthetic wastewater containing methylene blue (MB). Data indicate that the investigated support significantly affects the photocatalytic activity of the supported TiO2. Low photocatalytic activity toward MB degradation is observed upon using TiO2/calcite when compared to the unsupported TiO2. Interaction between calcite and titania species probably occurrs to produce the less photoactive CaTiO3 amorphous species. Anatase TiO2 is obtained upon using kaolin and cordierite as supports. The low photocatalytic performance of the TiO2/kaolin sample is also observed. A high concentration of MB on TiO2/kaolin surfaces blocks the photoactive sites. TiO2/cordierite shows the highest photocatalytic activity compared to the unsupported TiO2 as well as the other TiO2/support samples. Rigid cordierite particles suppress the agglomeration of TiO2 particles during the preparation, leading to a high exposed surface of TiO2 towards light illumination. TiO2/cordierite is investigated for the removal of organic dye from real wastewater collected from a textile dyeing factory. Color removal of up to 46% is achieved upon UV irradiation. 相似文献
4.
Feasibility of photocatalytic dechlorination of PCB‐138 and Aroclor‐1254 using platinum loaded TiO2 (P25) in an alkaline 2‐propanol medium has been investigated. Experiments were conducted in batch mode using a Rayonet photo‐reactor under aerated and deaerated conditions with black lamps emitting around 350 nm as light source. Two forms of platinum deposition were investigated: Photochemically loaded P25 as well as addition of potassium hexachloroplatinate into the reaction medium. Partial dechlorination of PCBs was observed after 7 h of irradiation with pure TiO2 as catalyst when the reaction vessel was kept open to air. Complete dechlorination was observed after 5 h of irradiation in a deaerated environment. Enhanced photocatalytic efficiency was observed when platinum deposited P25 was used as catalyst, with the best result being obtained when aqueous potassium hexachloroplatinate was added into the reaction medium. Lower potassium hexachloroplatinate concentration (0.1 mM) yielded better performance. 相似文献
5.
The photocatalytic decolorization and mineralization of Reactive Black 5 (RB5) dye in presence of TiO2 Degussa P25 has been studied using artificial light radiation in a shallow pond slurry reactor. The equilibrium adsorption of dye, influence of pH (3–11), catalyst load (0.5–3.0 g/L), and dye concentration (20–100 mg/L) on decolorization kinetics were studied. The effect of area to volume ratio of photoreactor on decolorization kinetics has been also studied. Mineralization studies were performed at optimized conditions of pH (3) and catalyst load (1.5 g/L). The maximum adsorption (26.5 mg/g) of dye was found to occur at pH 3. The apparent pseudo first order decolorization rate constant (kapp) value followed the order pH 3 > pH 11 > pH 9 > pH 7. As compared to available literature reduction in total organic carbon (TOC) was minimal by the time there was complete decolorization. Initial reduction in TOC was followed by subsequent increasing trend till complete decolorization. Final decreasing trend in TOC was observed only after complete decolorization. Twelve hours of treatment under experimental conditions reduced TOC content by 70% only. Discussion of results suggest that photocatalytic treatment of colored effluent under low UV intensity, and low A/V ratio may result in completely decolorized effluent but still having high COD. 相似文献
6.
The photocatalytic activity of combustion synthesized nanocrystalline CeAlO3 was determined for the degradation of four anionic and four cationic dyes. The perovskite oxide showed high‐photocatalytic activity and a complete degradation of all the dyes was possible within 2 h. The photocatalytic activity of the compound was comparable with the activity of the commercial Degussa P‐25 TiO2 catalyst. The degradation of dyes was found to follow first order kinetics and the first order degradation rate constants were determined. 相似文献
7.
Degradations of reactive brilliant red X‐3B solution by both conventional UV irradiation and microwave electrodeless UV irradiation were investigated. Degradation processes were studied by UV–VIS spectrophotometry, total organic carbon (TOC), high performance capillary electrophoresis (HPCE), conductivity, pH value, and ion chromatography. The results of color removal (%) and TOC removal (%) showed that the degradation by microwave electrodeless UV irradiation was more effective than by conventional UV irradiation. The results of UV–VIS absorption spectra and HPCE analyses indicated that the degradation of reactive brilliant red X‐3B was occurred at the conjugation system first, the benzene ring and the naphthalene ring later. The reactive brilliant red X‐3B was cleaved into some new small compounds and eventually most of the organic substances were mineralized to CO2 and H2O. The results of the conductivity analysis suggested that the degradation has mainly occurred in the first 40 min of reaction. The pH value of reactive brilliant red X‐3B solution was decreased first and then was increased. The results of inorganic anions analysis hinted that many of the N, Cl, and S elements from reactive brilliant red X‐3B were still attached in organic molecules. 相似文献
8.
Ag‐modified TiO2 nanotube arrays (Ag/TiO2 NAs) were prepared and employed as a photocatalyst for degradation of 17α‐ethinylestradiol (EE2) and inactivation of Escherichia coli. The as‐synthesized Ag/TiO2 NAs were characterized by field‐emission scanning electron microscope (FESEM), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). It was found that metallic Ag nanoparticles were firmly deposited on the TiO2 NAs with the pore diameter of 100 nm and the length of 550 nm. Photocatalytic degradation of EE2 and inactivation of E. coli were enhanced effectively in an analogical trend using Ag/TiO2 NAs. In particular, Ag/TiO2 NAs exhibited the antimicrobial activity even in the absence of light. The Ag acted as a disinfection agent as well as the dopant of the modified TiO2 NAs photocatalysis by forming a Schottky barrier on the surface of TiO2 NAs. Inorganic ions suppressed the rates of photocatalytic degradation of EE2, with HCO having a more pronounced effect than NO or SO. Humic acid (HA) was found to increase the rate of EE2 degradation. 相似文献
9.
This study investigated the degradation kinetics, formation of disinfection by‐products (DBPs), and degradation pathways during monochloramination of oxytetracycline (OTC). The degradation kinetics can be well described by a second‐order kinetic model, first‐order in monochloramine (NH2Cl), and first‐order in OTC. Reaction of OTC with NH2Cl shows a high reactivity, with the apparent rate constant of 17.64/M/s at pH 7. The apparent rate constant declined as pH increased from 5 to 10. Six DBPs were detected during monochloramination of OTC, including chloroform (CF), 1,1‐dichloro‐2‐propanone (1,1‐DCP), 1,1,1‐trichloro‐2‐propanone (1,1,1‐TCP), dichloroacetonitrile (DCAN), trichloronitromethane (TCNM), and N‐nitrosodimethlyamine (NDMA). CF, DCAN and NDMA had the maximum yields at neutral pH, while 1,1‐DCP and 1,1,1‐TCP had the maximum yields at pH 4. However, TCNM concentration increased as pH increased. Degradation pathways of OTC monochloramination were then proposed. Hydroxylation and Cl‐substitution are found to be the dominant mechanisms in monochloramination of OTC. 相似文献
10.
Design of Fenton and photo‐Fenton reactions was partially automated by using sequential injection analysis (SIA) and response surface methodology for the treatment of a wastewater sample from a coatings industry. The extension of both Fenton and photo‐Fenton reactions was evaluated by the percentage of total organic carbon (TOC) remaining in solution after 15 min of reaction. Use of small volumes of sample and reagents, as well as easy solution handling, were the remarkable features of the proposed system. The highest percentage of TOC removal (79%) was obtained by the photo‐Fenton reaction at the following initial mass‐based concentration ratios: H2O2/TOC = 10, H2O2/FeSO4 = 50, and pH 2.5. The best result for Fenton reaction indicated a TOC removal of only 45%, obtained at H2O2/initial TOC = 20, H2O2/FeSO4 = 30, and pH 2.5. The SIA system was designed to dispense reagents to the sample flasks and to drive the sample intended to photo‐Fenton reaction through a homemade photo‐reactor. Modifications in chemical parameters of the reactions were achieved via the software commanding the SI system, without the need for physical reconfiguration of reagents around the selection valve. 相似文献
11.
Fikret Inal 《洁净——土壤、空气、水》2010,38(10):897-908
Tropospheric (ground‐level) ozone has adverse effects on human health and environment. In this study, next day's maximum 1‐h average ozone concentrations in Istanbul were predicted using multi‐layer perceptron (MLP) type artificial neural networks (ANNs). Nine meteorological parameters and nine air pollutant concentrations were utilized as inputs. The total 578 datasets were divided into three groups: training, cross‐validation, and testing. When all the 18 inputs were used, the best performance was obtained with a network containing one hidden layer with 24 neurons. The transfer function was hyperbolic tangent. The correlation coefficient (R), mean absolute error (MAE), root mean squared error (RMSE), and index of agreement or Willmott's Index (d2) for the testing data were 0.90, 8.78 µg/m3, 11.15 µg/m3, and 0.95, respectively. Sensitivity analysis has indicated that the persistence information (current day's maximum and average ozone concentrations), NO concentration, average temperature, PM10, maximum temperature, sunshine time, wind direction, and solar radiation were the most important input parameters. The values of R, MAE, RMSE, and d2 did not change considerably for the MLP model using only these nine inputs. The performances of the MLP models were compared with those of regression models (i.e., multiple linear regression and multiple non‐linear regression). It has been found that there was no significant difference between the ANN and regression modeling techniques for the forecasting of ozone concentrations in Istanbul. 相似文献
12.
Darka Marković Bojan Jokić Zoran Šaponjić Branislav Potkonjak Petar Jovančić Maja Radetić 《洁净——土壤、空气、水》2013,41(10):1002-1009
This paper discusses the possibility of immobilization of TiO2 nanoparticles onto recycled wool‐based nonwoven material, which can be utilized for removal of dyes from wastewater. The photocatalytic activity of TiO2 nanoparticles deposited on the nonwoven material was evaluated in the aqueous solution of direct dye C.I. Direct Blue 78 under the UV illumination. Nonwoven material modified with TiO2 nanoparticles provides complete removal of dye from the solution already after 4–6 h of UV illumination. However, photodegradation of the dye adsorbed on the nonwoven material was obtained within 24 h of UV illumination. The rate of dye adsorption and photodegradation depends on the amount of deposited TiO2 nanoparticles. The increase of initial dye concentration induced decrease in photocatalytic efficiency of immobilized TiO2 nanoparticles. The highest photodegradation rate was achieved in acidic conditions. Elevated temperatures positively affected the removal of dye from solution. Photocatalytic activity of TiO2 nanoparticles deposited on nonwoven material was preserved after three photodegradation cycles. 相似文献
13.
Response surface methodology (RSM) was employed to investigate the effects of different operational parameters on the biological decolorization of a dye solution containing malachite green (MG) in the presence of macroalgae Chara sp. The investigated variables were the initial pH, initial dye concentration, algae amount, and reaction time. Central composite design (CCD) was used for the optimization of biological decolorization process. Predicted values were found to be in good agreement with experimental values (R2 = 0.982 and Adj‐R2 = 0.966), which indicated suitability of the employed model and the success of RSM. The results of optimization predicted by the model showed that maximum decolorization efficiency was achieved at the optimum condition of the initial pH 6.8, initial dye concentration 9.7 mg/L, algae amount 3.9 g, and reaction time 75 min. UV–VIS spectra and FT‐IR analysis showed degradation of MG. 相似文献
14.
Evapotranspiration (ET) is one of the basic components of the hydrologic cycle and is essential for estimating irrigation water requirements. In this study, an artificial neural network (ANN) model for reference evapotranspiration (ET0) calculation was investigated. ANNs were trained and tested for arid (west), semi‐arid (middle) and sub‐humid (east) areas of the Inner Mongolia district of China. Three or four climate factors, i.e. air temperature (T), relative humidity (RH), wind speed (U) and duration of sunshine (N) from 135 meteorological stations distributed throughout the study area, were used as the inputs of the ANNs. A comparison was conducted between the estimates provided by the ANNs and by multilinear regression (MLR). The results showed that ANNs using the climatic data successfully estimated ET0 and the ANNs simulated ET0 better than the MLRs. The ANNs with four inputs were more accurate than those with three inputs. The errors of the ANNs with four inputs were lower (with RMSE of 0·130 mm d?1, RE of 2·7% and R2 of 0·986) in the semi‐arid area than in the other two areas, but the errors of the ANNs with three inputs were lower in the sub‐humid area (with RMSE of 0·21 mm d?1, RE of 5·2% and R2 of 0·961. For the different seasons, the results indicated that the highest errors occurred in September and the lowest in April for the ANNs with four inputs. Similarly, the errors were higher in September for the ANNs with three inputs. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
15.
Ying-Ya Hsu Tung-Li Hsiung H. Paul Wang Yasuhiro Fukushima Yu-Ling Wei Juu-En Chang 《Marine pollution bulletin》2008,57(6-12):873
The nitrogen-doped TiO2 nanotube (N-TNT) thin films were synthesized using ZnO nanorods as the template and doped with urea at 623 K. Under ultraviolet (UV) and visible light irradiation, the efficiencies for photocatalytic degradation of methylene blue is as high as 30%. About 10% of toluene (representing aromatics in the spill oils) in sea water can be photocatalytically degraded under visible light radiation for 120 min. The aliphatic model compound (1-hexadecene) has, on the contrary, a less efficiency (8%) on the N-TNT photocatalyst. On the average, under visible light radiation, the effectnesses of the N-TNT for photocatalytic degradation of model compounds in the spill oils in sea water are 0.38 mg toluene/gN-TNT h and 0.25 mg 1-hexadecene/gN-TNT h. It is expected that spill oils in the harbors or seashores can be adsorbed and photocatalytically degraded on the N-TNT thin films that are coated onto levee at the sea water surface level. 相似文献
16.
Zeynep Eren 《洁净——土壤、空气、水》2012,40(11):1284-1289
This study illustrates the degradation of an azo dye, Reactive Yellow 81 (RY81), by the combined irradiation of UV‐C and ultrasound in the presence of homogeneous (Fe2+) and heterogeneous (TiO2, ZnO) catalysts. The efficiency of homogeneous and heterogeneous oxidation systems was evaluated in regard of the decolorization and mineralization of RY81. Decolorization followed pseudo‐first‐order kinetics with homogeneous and heterogeneous catalysts. Complete color removal was accomplished by homogeneous sonocatalytic and sonophotocatalytic oxidation processes with apparent rate constants of 0.96 × 10?3 and 46.77 × 10?3 s?1, respectively, in the presence of Fe2+. However, partial color removal was obtained by heterogeneous sonocatalytic, photocatalytic, and sonophotocatalytic oxidation processes with apparent rate constants of 2.32 × 10?3, 3.60 × 10?3, and 3.67 × 10?3 s?1, respectively, in the presence of ZnO. TiO2 had the worst catalytic effect of all of the oxidation processes. The addition of hydrogen peroxide increased the rate constants of the heterogeneous oxidation processes and decreased the rate constants of the homogeneous oxidation processes. RY81 mineralization was 62.8% for the US/UV/Fe2+ homogeneous oxidation process, which was the best oxidation process, whereas it was 43.5% for the US/UV/ZnO/H2O2 heterogeneous oxidation process within 2 h reaction time. 相似文献
17.
In this study, the decolorization, dearomatization, and mineralization efficiencies of different advanced oxidation processes (AOPs; namely O3, O3/Fe(II), O3/Fe(II)/UVA, and O3/TiO2/UVA) were investigated for the azo dye C.I. Reactive Red 194 (RR194). The effects of pH (3–11), amount of TiO2 (0.05–1 g/L), and concentration of Fe(II) (0.1–1.6 mM) were investigated for the applied methods. The decolorization and mineralization efficiencies of the photocatalytic ozonation system (O3/TiO2/UVA) were increased by decreasing the pH of the dye solution in contrast to the ozonation system (O3). Decolorization of RR194 was increased in the photocatalytic ozonation system with an increasing amount of catalyst however, a decreasing was occurred for the homogeneous catalytic system (O3/Fe(II)) when increasing the concentration of catalyst. The decolorization efficiency of the homogeneous catalytic system (O3/Fe(II)) was enhanced when combined with UVA light. In our study, the most efficient method for dearomatization and mineralization was the O3/TiO2/UVA among the applied AOPs. 相似文献
18.
Modelling suspended sediment concentration using artificial neural networks for Gangotri glacier 
下载免费PDF全文
下载免费PDF全文 The dynamics of suspended sediment involves inherent non‐linearity and complexity because of existence of both spatial variability of the basin characteristics and temporal climatic patterns. This complexity, therefore, leads to inaccurate prediction by the conventional sediment rating curve (SRC) and other empirical methods. Over past few decades, artificial neural networks (ANNs) have emerged as one of the advanced modelling techniques capable of addressing inherent non‐linearity in the hydrological processes. In the present study, feed‐forward back propagation (FFBP) algorithm of ANNs is used to model stage–discharge–suspended sediment relationship for ablation season (May–September) for melt runoff released from Gangotri glacier, one of the largest glaciers in Himalaya. The simulations have been carried out on primary data of suspended sediment concentration (SSC) discharge and stage for ablation season of 11‐year period (1999–2009). Combinations of different input vectors (viz. stage, discharge and SSC) for present and previous days are considered for development of the ANN models and examining the effects of input vectors. Further, based on model performance indices for training and testing phase, a suitable modelling approach with appropriate model input structure is suggested. The conventional SRC method is also used for modelling discharge–sediment relationship and performance of developed models is evaluated by statistical indices, namely; root mean square error (RMSE), mean absolute error (MAE) and coefficient of determination (R2). Statistically, the performance of ANN‐based models is found to be superior as compared to SRC method in terms of the selected performance indices in simulating the daily SSC. The study reveals suitability of ANN approach for simulation and estimation of daily SSC in glacier melt runoff and, therefore, opens new avenues of research for application of hybrid soft computing models in glacier hydrology. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
19.
Haikun Zhang Peng Hu Liang Cao Armin Tampubolon Asui Liu Xiang Cheng Mingguo Zhan Luozhong Pan Yu Dai Beihong Pan 《Island Arc》2020,29(1)
Late Triassic A‐type granites are identified in this study in Sarudik, SW Sumatra. We present new data on zircon U–Pb geochronology, whole‐rock major and trace elements and Sr‐Nd‐Hf isotope geochemistry, aiming to study their petrogenesis and tectonic implications. LA‐ICP‐MS U–Pb dating of zircon separated from one biotite monzogranite sample yields a concordia age of 222.6 ±1.0 Ma, indicating a Late Triassic magmatic event. The studied granites are classified as weakly peralumious, high‐K calc‐alkaline granites. They exhibit high SiO2, K2O + Na2O, FeO/(FeO + MgO) and Ga/Al ratios and low Al2O3, CaO, MgO, P2O5 and TiO2 contents, with enrichment of Rb, Th and U and depletion of Ba, Sr, P and Eu, showing the features of A‐type granites. The granites have zircon εHf(t) values from ?4.6 to ?0.4 and whole‐rock εNd(t) values from ?5.51 to ?4.98, with Mesoproterozoic TDM2 ages (1278–1544 Ma) for both Hf and Nd isotopes. Geochemical and isotopic data suggest that the source of these A‐type granites is the Mesoproterozoic continental crust, without significant incorporation of mantle‐derived component, and their formation is controlled by subsequent fractional crystallization. The Sarudik A‐type granites are further assigned to A2‐type formed in post‐collisional environment. Combined with previous knowledge on the western SE Asia tectonic evolution, we conclude that the formation of the Late Triassic A‐type granites is related to the post‐collisional extension induced by the crustal thickening, gravitational collapse, and asthenosphere upwelling following the collision between the Sibumasu and the East Malaya Block. 相似文献
20.
Experiments on the degradation of acid orange 7 (AO7) using micron‐sized zero‐valent copper (ZVC) are conducted in acidic aqueous solution under ultrasonic (US) irradiation. The US/ZVC/peroxymonosulfate (PMS) process for AO7 degradation is significantly better than that of an independent system. Based on the characterization of ZVC, it is observed that the corrosion speed of ZVC increases after ultrasound, owing to which a greater amount of Cu+ (0–3.03 mg L?1) and Cu2+ are produced. Exposure to US irradiation increases the available surface area of the catalysts to generate many new reactive sites for the degradation process. The AO7 degradation rate after the addition of a new copper reagent—neocuproine hemihydrate—from 6.33% to 100% proved that Cu+ is the main activator of PMS. Results indicated that free radicals (OH? and SO4??) act as activators of PMS in the process. And higher ultrasound power, lower solution pH, and a larger ZVC dose are favorable for AO7 removal. 相似文献