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1.
A geographically extensive investigation was carried out to analyze the concentrations of heavy metals, PCBs and OCPs in the sediments and marine organisms collected from the Liaohe Estuary. In order to determine the spatial distribution and potential ecological risk of heavy metals, the surface sediments were collected from 44 sites in the Liaohe Estuary. The results showed that the heavy metal contents in the sediments were observed in the following order: Cr (11.2–84.8 mg/kg) > Cu (1.7–47.9 mg/kg) > Pb (4.3–28.3 mg/kg) > As (1.61–12.77 mg/kg) > Cd (0.06–0.47 mg/kg) > Hg (0.005–0.113 mg/kg). In comparison with the concentrations of heavy metals and POPs in other regions, the concentrations of As, Pb and DDTs in the Liaohe Estuary were generally low, and other pollutant concentrations were inconsistent with those reported in other regions. The contamination factor (CF), the pollution load index (PLI), the geoaccumulation index and the potential ecological risk index were used to analyze the pollution situation, which showed that the heavy metal pollution in Liaohe Estuary is mainly dominated by Cd and Hg. The concentrations of the four heavy metals varied significantly in the three kinds of tested organisms (fish, mollusk and crustacean), indicating the different accumulative abilities of the species. The results obtained in this study provide useful information background information for further ecology investigation and management in this region.  相似文献   

2.
《Marine pollution bulletin》2012,64(5-12):119-123
Ballast water is essential in maintaining the balance and structural integrity of ships during voyage. However, it has created biological invasion threats to the ocean environment. An innovative electrochemical technology was developed in this study. The microorganisms regulated by the International Maritime Organization (D2) were used as the target organisms. It was found that the required energy to meet the D2 was below 0.006 kWh/m3. The size of disinfector (m3) was about 0.5% of treatment flow rate (m3/h). The complete disappearance of chlorine in seawater was achieved after three days. The ballast tank corrosion was not worsened due to the application of technology. The ecotoxicity studies showed no toxic effect on fish, invertebrate, and algae. Finally, the environmental risk assessment showed the treated water did not pose threats to the environment. It can therefore be concluded that the technology provides a cost-effective and environmental friendly solution to ballast water management.  相似文献   

3.
Microplastics in the Southern Ocean   总被引：4，自引：0，他引：4  
A field survey to collect microplastics with sizes < 5 mm was conducted in the Southern Ocean in 2016. We performed five net-tows and collected 44 pieces of plastic. Total particle counts of the entire water column, which is free of vertical mixing, were computed using the surface concentration (particle count per unit seawater volume) of microplastics, wind speed, and significant wave height during the observation period. Total particle counts at two stations near Antarctica were estimated to be in the order of 100,000 pieces km? 2.  相似文献   

4.
Metal pollutants in water poses great threats to living beings and hence requires to be monitored regularly to avoid loss of lives. Various analytical methods are available to monitor these pollutants in water and can be improved with time. Modelling of metal pollutants in any water system helps chemists, engineers and environmentalists to greatly understand the various chemical processes in such systems. Water samples were collected from waste water treatment plant and river from highlands close to its source all the way to the ocean as it passing through areas with high anthropogenic activities. Pre-concentration of pollutants in the samples was done through acid digestion and metal pollutants were analysed using inductively coupled plasma-optical emission spectra (ICP-OES) to determine the concentration levels. Metal concentrations ranged between 0.1356–0.4658 mg/L for Al; 0.0031–0.0050 mg/L for Co, 0.0019–0.0956 mg/L for Cr; 0.0028–0.3484 mg/L for Cu; 0.0489–0.3474 mg/L for Fe; 0.0033–0.0285 mg/L for Mn; 0.0056–0.0222 mg/L for Ni; 0.0265–0.4753 mg/L for Pb and 0.0052–0.5594 mg/L for Zn. Modelling work was performed using PHREEQC couple with Geochemist’s workbench (GWB) to determine speciation dynamics and bioavailability of these pollutants. Modelling thus adds value to analytical methods and hence a better complementary tool to laboratory-based experimental studies.  相似文献   

5.
The feasibility of a potential bioindicator based on functional groups of microzooplankton tintinnids for bioassessments of water quality status was studied during southwest monsoon (June to September) along the coastal waters of Kalpakkam, India during 2012–2015. The work highlights the following features (1) tintinnid community composed of 28 species belonging to 11 genera and 9 families, revealed significant differences among the four study sites (2) maximum numerical abundance (2224 ± 90 ind. l? 1) and species diversity (H′ = 2.66) of tintinnid were recorded towards Bay of Bengal whereas minimum abundance (720 ± 35 ind. l? 1) and diversity (H′ = 1.74) were encountered in the backwater sites, (3) multivariate analyses [RELATE, Biota-environment (BIOENV) and canonical analysis of principal coordinates (CAP)] reveal that chl a, nitrate and phosphate were the potential causative factors for tintinnid distribution. Based on the results, we suggest that tintinnids may be used as a potential bioindicator of water quality status in marine ecosystem.  相似文献   

6.
This study aimed to evaluate the spatial and temporal distribution of heavy metals (Cd, Cr, Cu, Co, Fe, Pb, Ni, V, and Zn) in the sediments of Bayan Lepas Free Industrial Zone of Penang, Malaysia. Ten sampling stations were selected and sediment samples were collected during low tide (2012 ? 2013). Metals were analyzed and the spatial distribution of metals were evaluated based on GIS mapping. According to interim sediment quality guidelines (ISQG), metal contents ranged from below low level to above high level at different stations. Based on the geoaccumulation index (Igeo) of sediment, sampling stations were categorized from unpolluted to strongly polluted. The enrichment factor (EF) of metals in the sediment varied between no enrichment to extremely high enrichment. The potential ecological risk index (RI) indicated Bayan Lepas FIZ was at low risk.  相似文献   

7.
Real-time measurements of Suspended Sediment mass Concentration(SSC) and Particle Size Distribution(PSD) are of prime importance for the investigation and management of fine-sediment related processes in surface water systems and hydraulic schemes. In a field study at the waterway of the hydropower plant(HPP) Fieschertal in the Swiss Alps, the real-time measurement performance of the following techniques and instruments were assessed based on measurements in the sediment seasons of the years 2013 and 2014:(1) turbidimetry,(2) single-frequency acoustic attenuation using a standard acoustic discharge measurement(ADM) installation,(3) laser diffraction(Laser In-Situ Scattering and Transmissometry, LISST), and(4) vibrating tube densimetry using a Coriolis Flow and Density Meter(CFDM).Reference SSCs were obtained from gravimetric analysis of 219 automatically pumped water samples.LISST additionally supplied PSD every minute. The median particle diameter, d_(50), was usually 15μm and increased occasionally to 100μm. The turbidimeter and the ADM underestimated the SSC when the transported particles were coarser than usual. Such temporary biases resulted from the poor correlation between d_(50) and SSC at this study site. The SSCs from CFDM and LISST were not or less biased by PSD variations. Mainly due to angular and flaky particle shapes, SSC from LISST needed a correction by 79% on average. With the usually prevailing silt particles, an optical path length of 5 mm and no dilution, the SSC measurement range of LISST was limited to about 1.5 g/l. The CFDM allowed measuring higher SSC than the other investigated instruments(e.g. up to 13.5 g/l). With a periodic offset correction, its relative SSC measurement uncertainty was 20% for SSC≥ 1.5 g/I. To reliably measure a wide range of SSC with temporarily variable PSD, a combination of instruments is recommended: e.g. a standard LISST, a CFDM,and an automatic water sampler for gravimetric reference measurements.  相似文献   

8.
Temporal mass variations in the continental hydrosphere and in the atmosphere lead to changes in the gravitational potential field that are associated with load-induced deformation of the Earth’s crust. Therefore, models that compute continental water storage and atmospheric pressure can be validated by measured load deformation time series. In this study, water mass variations as computed by the WaterGAP Global Hydrology Model (WGHM) and surface pressure as provided by the reanalysis product of the National Centers for Environmental Prediction describe the hydrological and atmospheric pressure loading, respectively. GPS observations from 14 years at 208 stations world-wide were reprocessed to estimate admittance factors for the associated load deformation time series in order to determine how well the model-based deformation fits to real data. We found that such site-specific scaling factors can be identified separately for water mass and air pressure loading. Regarding water storage variation as computed by WGHM, weighted global mean admittances are 0.74 ± 0.09, 0.66 ± 0.10, 0.90 ± 0.06 for the north, east and vertical component, respectively. For the dominant vertical component, there is a rather good fit to the observed displacements, and, averaged over all sites, WGHM is found to slightly overestimate temporal variations of water storage. For Europe and North America, with a dense GPS network, site-specific admittances show a good spatial coherence. Regarding regional over- or underestimation of WGHM water storage variations, they agree well with GRACE gravity field data. Globally averaged admittance estimates of pre-computed atmospheric loading displacements provided by the Goddard Geodetic VLBI Group were determined to be 0.88 ± 0.04, 0.97 ± 0.08, 1.13 ± 0.01 for the north, east and vertical, respectively. Here, a relatively large discrepancy for the dominant vertical component indicates an underestimation of corresponding loading predictions.  相似文献   

9.
Recent studies have shown that polychlorinated biphenyl (PCB) levels are high in coastal sites. Various types of deposition events, including dry deposition, air–water exchange and wet deposition, were analyzed as part of the study to illustrate the pollution level. The atmospheric levels and deposition mechanisms of 82 PCBs were investigated in Mudanya, a coastal city in Turkey. A total of 175 samples and 112 blanks were collected. Air–water exchange and particle phase dry deposition fluxes were 120 ± 90 ng/m2-d and 125 ± 160 ng/m2-d, respectively. The wet-dry deposition sampler (WDDS) consisted of two reservoirs, wet and dry. Collected with the WDDS, the dry deposition flux was 21 ± 20 ng/m2-d, and the wet deposition fluxes (during the rainy period) were 145 ± 130 ng/m2-d and 195 ± 270 ng/m2-d for the dissolved and particulate phases, respectively. Mass transfer coefficients (MTCs), dry deposition velocities and washout ratios were calculated and compared with the literature values.  相似文献   

10.
With anthropogenic changes, the structure and quantity of nitrogen nutrients have changed in coastal ocean, which has dramatically influenced the water quality. Water quality modeling can contribute to the necessary scientific grounding of coastal management. In this paper, some of the dynamic functions and parameters of nitrogen were calibrated based on coastal field experiments covering the dynamic nitrogen processes in Jiaozhou Bay (JZB), including phytoplankton growth, respiration, and mortality; particulate nitrogen degradation; and dissolved organic nitrogen remineralization. The results of the field experiments and box model simulations showed good agreement (RSD = 20% ± 2% and SI = 0.77 ± 0.04). A three-dimensional water quality model of nitrogen (3DWQMN) in JZB was improved and the dynamic parameters were updated according to field experiments. The 3DWQMN was validated based on observed data from 2012 to 2013, with good agreement (RSD = 27 ± 4%, SI = 0.68 ± 0.06, and K = 0.48 ± 0.04), which testifies to the model's credibility.  相似文献   

11.
Sixteen years (1997–2013) of physicochemical, nutrient and phytoplankton biomass (Chlorophyll-a (Chl-a)) data and a decade (2003-2013) of phytoplankton composition and abundance data were analyzed to assess how the algal community in a temperate southeastern Australian estuary has responded to decreased chronic point source nitrogen loading following effluent treatment upgrade works in 2003. Nitrogen concentrations were significantly lower (P < 0.05) following enhanced effluent treatment and Chl-a levels decreased (P < 0.05) during the warmer months. Temperature and nutrient concentrations significantly influenced temporal changes of Chl-a (explaining 55% of variability), while salinity, temperature, pH and nutrient concentrations influenced phytoplankton abundance and composition (25% explained). Harmful Algal Bloom (HAB) dynamics differed between sites likely influenced by physical attributes of the estuary. This study demonstrates that enhanced effluent treatment can significantly decrease chronic point source nitrogen loading and that Chl-a concentrations can be lowered during the warmer months when the risk of blooms and HABs is greatest.  相似文献   

12.
Spatial distribution, source apportionment, and potential ecological risks of sixteen polycyclic aromatic hydrocarbons (PAHs) and seven endocrine disrupting compounds (EDCs) in the intertidal sediment at the Shuangtaizi Estuary, Bohai Sea of China were analyzed. Results showed that the total PAH concentrations ranged from 28.79 ng g? 1 dw to 281.97 ng g? 1 dw (mean: 115.92 ng g? 1 dw) and the total EDC concentrations from 0.52 ng g? 1 dw to 126.73 ng g? 1 dw (mean: 37.49 ng g? 1 dw). The distribution pattern for the PAHs was generally different from that of the EDCs possibly due to their distinct sources and n-octanol-/water partition coefficients (KOW). Qualitative and quantitative analytical results showed that PAH sources were mainly from a mixture of pyrogenic and petrogenic contributions. The higher levels at the southeast of Geligang indicated that the EDC pollutants may have mainly originated from the plastic industry and other chemical plants located along the Liao River. Ecological risk assessment revealed that PAHs exhibited low ecotoxicological effects, whereas EDCs, especially 4-tert-octylphenol and bisphenol A, had high ecological hazard to the estuarine biota.  相似文献   

13.
In this study, remediation results of trace metals in natural water and treated water using three functionalized nanofiber mats of cellulose and chitosan are reported. The nanofiber materials, packed in mini-columns, were employed for the remediation of five toxic trace metals (Cd, Pb, Cu, Cr and Ni) from natural water samples. Trace metals in real water samples were undetectable as the concentrations were lower than the instrument’s detection limits of 0.27 × 10−3 (Cd) and 4.2 × 10−2 (Pb) μg mL−1, respectively. However, after percolation through the functionalised biosorbents in cartridges, detectability of the metal ions was enhanced. The starting volume of the natural water sample was 100 mL, which was passed through a column containing the nanofibers sorbent and the retained metals eluted with 5 mL of 2.0 M nitric acid. The eluate was analyzed for metals concentrations. An enrichment factor of 20 for the metals was realized as a result of the pre-concentration procedure applied to handle the determination of the metals at trace levels. The order of remediation of the studied metals using the nanofibers was as follows: chitosan/PAM-g-furan-2,5-dione < cellulose-g-furan-2,5-dione < cellulose-g-oxolane-2,5-dione. The modified biopolymer nanofibers were able to adsorb trace metals from the river water and treated water, thereby confirming their capability of water purification. These materials are proposed as useful tools and innovative approach for improving the quality of drinking for those consumers in small scale households.  相似文献   

14.
《Marine pollution bulletin》2012,65(12):2742-2748
Ballast water has been identified as one of the key pathways for the movement of species between different ecosystems. The purpose of this study is to evaluate the biological efficacy and the potential toxicological impact of a proposed ballast water treatment using hydroxyl radicals as the main active substances. Living biomass of organisms kept in treated water for 2 days met the requirement stated in the International Maritime Organization (IMO) Ballast Water Convention (Regulation D-2), and no re-growth was observed over a period of 5 days. Aquatic toxicity tests of three trophic levels for the treated ballast water were performed. The results indicated that the toxicological risk of the discharge water to the receiving environment was not significant.  相似文献   

15.
Increasing evidence from fission track studies in Sweden indicate that large parts of the Fennoscandian Shield have been affected by a large-scale thermotectonic event in the Palaeozoic. In this study the results of 17 apatite fission track analyses from central Sweden are presented collected along three NW–SE transects trending from the Bothnian Sea to the Caledonides. On the Bothnian coast samples have been collected directly from the Sub-Cambrian Peneplain. The sedimentary cover protecting this surface until recently is responsible for the thermal increase detected through apatite fission track (FT) thermochronology.The apatite FT ages range between 516 ± 46 Ma (±1σ) on the Bothnian coast around sea level to 191 ± 11 Ma in the Caledonides (～500–1500 m.a.s.l.). The mean track lengths vary from 11.3 ± 2.2 μm (±1σ) in the east to 14.2 ± 2.8 μm in the west, indicating a longer stay in the PAZ in the east, versus a continuous cooling pattern in the west. This pattern in combination with other geological constraints indicates that the crystalline basement rocks near the Caledonian deformation front in the west experienced higher temperatures after the formation of the Sub-Cambrian Peneplain followed by denudation, compared with the basement rocks in the east near the Bothnian coast.The apatite FT data near the Caledonian deformation front indicates prevailing temperatures of more than 110 ± 10 °C prior to the Mid Palaeozoic, causing a resetting of the apatite fission track clock. The temperatures were progressively lower away from the deformation front. Apatite fission track analysis of samples collected from the Sub-Cambrian Peneplain along the Bothnian coast indicate maximum temperatures of 90 ± 15 °C during Late Silurian–Early Devonian time. This heating event is argued to be the result of burial beneath a developing foreland basin in front of the Caledonian orogeny. Assuming a geothermal gradient of 20 °C/km, this temperature increase can be converted to a total burial of the samples. The resulting geometry of this basin can be described as an asymmetrical basin at least 3.5 km deep in the vicinity of the Caledonian deformation front decreasing to about 2.5 km on the Bothnian coast, continuing further onto Finland. The width of this basin was in thus in the order of 600 km. Whether this was formed completely synorogenic or partly synorogenic, broadening after cessation of the orogeny, could not be revealed.The Late Palaeozoic and Mesozoic thermal evolution of this area is related to the extensional tectonics in the North Atlantic Domain.  相似文献   

16.
This work shows a study of in situ and ex situ phytoextraction as a polishing step in the treatment of an industrial urban soil polluted with nickel, arsenic and copper. The soil was previously washed, and phytoextraction was performed by application of a mixture of grass (Festuca rubra, Cynodon dactylon, Lolium multiforum, Pennisetum). The soil had initial heavy metals concentrations of 131 ppm for Ni, 717 for As and 2734 for Cu (mg of metal/kg of dry soil). After seeding and emerging of grass, vegetal and soil samples were taken monthly during 4 months. Biomass generation, and concentration of Ni, As and Cu in vegetal tissue and soil were determined for every sample. Plants biomass growth in ex situ process was inhibited by 37% when compared with blank soil. Grass showed remarkable phytoextraction capability in situ, it produced 38 g of biomass every 15 days (wet weight) during a period of 3 months, but then declined in the fourth month. Concentrations of metals in grass biomass were up to 83 mg Ni/kg, 649 mg As/kg and 305 mg Cu/kg dry weight. Metal reduction of 49% for Ni, and 35% for Cu and As was observed at rhizospheric soil.  相似文献   

17.
Shipping noise is a threat to marine wildlife. Grey seals are benthic foragers, and thus experience acoustic noise throughout the water column, which makes them a good model species for a case study of the potential impacts of shipping noise. We used ship track data from the Celtic Sea, seal track data and a coupled ocean-acoustic modelling system to assess the noise exposure of grey seals along their tracks. It was found that the animals experience step changes in sound levels up to ~ 20 dB at a frequency of 125 Hz, and ~ 10 dB on average over 10–1000 Hz when they dive through the thermocline, particularly during summer. Our results showed large seasonal differences in the noise level experienced by the seals. These results reveal the actual noise exposure by the animals and could help in marine spatial planning.  相似文献   

18.
During the past two-three decades the water chemistry in southern Norway has recovered considerably from acidification. The biological response, however, has been more variable. Thus, it has become increasingly apparent that decades of acidification may have masked other restrictors to fish populations in this area. The current study compiles data on young brown trout (Salmo trutta) density and water chemistry from 16 sites in River Sira in southwestern Norway during 2003–2014. The water chemistry during late snowmelt period was highly dilute, having a median conductivity and Ca of 10.5 μS/cm and 0.42 mg/l, respectively (n = 208). The corresponding minimum values were 5.0 μS/cm and 0.15 mg/l. With a pH median value of 5.89, the water was only slightly acidic. No effect of pH on the density of young brown trout was found, suggesting that acidification is no longer a limiting factor. However, both conductivity in year n-1 and Ca in year n correlated significantly with the density of 1+ brown trout. Al in year n, and surprisingly Ca in year n-1, correlated negatively on their densities. We conclude that very dilute water chemistry during late snowmelt is a limiting factor for the recruitment of brown trout in the study river. This effect has probably existed in the past as well, but has been less apparent due to decades of severe acidification.  相似文献   

19.
《Marine pollution bulletin》2013,77(1-2):427-434
Concentrations of heavy metals were measured in sediment and water from Málaga Bay (South Spain). In the later twentieth century, cities such as Málaga, have suffered the impact of mass summer tourism. The ancient industrial activities, and the actual urbanization and coastal development, recreation and tourism, wastewaters treatment facilities, have been sources of marine pollution. In sediments, Ni was the most disturbing metal because Ni concentrations exceeded the effects range low (ERL), concentration at which toxicity could start to be observed in 85% of the samples analyzed. The metal bioavailability decreased in the order: Cd > Ni > Pb > Cu > Cr. In the sea water samples, Cd and Pb were the most disturbing metals because they exceeded the continuous criteria concentration (CCC) of US EPA in a 22.5% and 10.0% of the samples, respectively. Statistical analyses (ANOVA, PCA, CA) were performed.  相似文献   

20.
We report a survey of natural mass-dependent cadmium isotope fractionation measured by thermal ionization mass spectrometry using a double-spike technique (DS-TIMS). Over sixty samples of natural terrestrial Cd from diverse environments, including MORB, OIB, continental loess, hydrogenic and hydrothermal ferromanganese deposits, and sphalerites (both oceanic and from major continental ore deposits) were analysed. Our results are expressed in terms of ε112/110Cd, which are deviations in 112Cd/110Cd from our in-house JMC Cd standard in parts per 104. The total ε112/110Cd variation is relatively small, with a range of only 5 ε-units, and is one-to-two orders of magnitude smaller than that previously found in meteorites.The MORB, OIB and loess ε112/110Cd values are similar and provide a good estimate for the bulk silicate Earth (BSE) value which is ? 0.95 ± 0.12 relative to our Cd standard (ε112/110Cd = + 0.16 relative to Münster JMC Cd). Taken together, these data suggest little Cd isotope fractionation takes place during crust–mantle segregation. Cd isotopic compositions of continental sphalerite (ZnS) deposits worldwide and high-temperature oceanic hydrothermal sulphides show remarkably similar ε112/110Cd values, consistent with our estimate for the BSE. In contrast, mid-temperature oceanic sulphides from a single extinct hydrothermal chimney display over 4 ε-units variation — along with the most negative values. These variations are most probably caused by precipitation/redissolution of sulphide phases en route within the hydrothermal system.The ε112/110Cd variability found in worldwide marine Fe–Mn deposits reflects the seawater Cd isotope signal upon precipitation from ambient seawater. A decrease in ε112/110Cd is observed in passing from shallow-water Fe–Mn deposits to those from deeper waters (> 2000 m depth). This shift is explained by biological fractionation related to the uptake of dissolved seawater Cd by phytoplankton in the upper water column. The relatively uniform ε112/110Cd values close to zero at great depths are consistent with regeneration and remineralization of Cd at depth. Our data suggest that Cd isotopes – much like the Cd/Ca ratio in foraminifera – could potentially serve as a proxy for past changes in biological productivity. The temporal Cd isotope record in a Fe–Mn crust archive at 2000 m depth from the NE Atlantic suggests no gross long-term changes in Cd cycling took place over the past 8 Ma.  相似文献   

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