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1.
Two procedures for the calibration of an electron capture detector (ECD) for peroxyacetyl nitrate (PAN) are discussed. One is based on the first-order decay rate of the the PAN mixing ratio in conditioned glass storage vessels. The other method makes use of the photochemical generation of PAN in mixtures of acetone and NO2 in air. For this purpose a Penray Hg lamp was inserted into a glass vessel filled with 1 atmosphere of air containing 10 ppm NO2 and 1% acetone. After 3 min of irradiation, the average PAN mixing ratio formed was 8.87±0.25 ppmv as determined in six separate runs. 相似文献
2.
The accurate measurement of concentration is the basis for
determining emission sources and sinks of nitrous oxide (N2O). The
detection of N2O showed that the presence of carbon dioxide (CO2 biased the
N2O response when pure nitrogen (N2) was used as a carrier gas for gas chromatography (GC) equipped with an electron capture detector (GC-ECD). In this study, laboratory experiments were carried out to explore how the presence of CO2 interferes with the accurate determination of N2O. The aims were to address the extent of the influence to try and explain the underlying mechanism, and to uncover technical options for solving the problem. Three GC carrier gases are discussed: pure nitrogen (DN); a mixture of argon and methane (AM); and a high concentration CO2, which was introduced into the ECD cell with a low flow rate based on DN (DN-CO2). The results show that when DN was used, the existence of CO2 in the ECD cell greatly enhanced the response of N2O, which increased with CO2 content and remained constant when the content reached a limit. Comparisons between the three methods show that the DN method is defective for the accurate determination of N2O. The bias is caused by ifferent electron capture mechanisms of CO2 and N2O and depends heavily on the detector
temperature. New GC carrier gas types with make-up gases that can remove the
CO2-induced influence, such as the DN-CO2 and DN-CH4 methods reported in this paper, are recommended for the accurate measurement of N2O. 相似文献
3.
The solubilities and hydrolysis rates of PAN (peroxyacetyl nitrate) and its homologues PPN (peroxypropionyl nitrate), PnBN (peroxy-n-butyl nitrate), PiBN (peroxy-isobutyl nitrate) and MPAN (peroxymethacryloyl nitrate) in liquid water have been studied at 20 °C. Temperature dependencies were measured for PAN and PPN. The solubilities of peroxyacyl nitrates decrease smoothly with increasing carbon-chain length fromH (293 K)=4.1 M atm–1 (PAN) toH (293 K)=1.0 M atm–1 (PiBN). Hydrolysis-rate constants, which cover the range fromk
h
(293 K)=(2.4–7.4)×10–4 s–1, do not show a systematic chain-length dependency. Solubilities of PAN and PPN in solutions which mimic the composition and ionic strength of sea water are 15% and 20% lower than in pure water. The hydrolysis rate constants are not affected. 相似文献
4.
W. Schrimpf K. P. Müller F. J. Johnen K. Lienaerts J. Rudolph 《Journal of Atmospheric Chemistry》1995,22(3):303-317
In this paper we describe a gas-chromatographic method for PAN measurements in the background atmosphere, which has been adapted to the special requirements of aircraft based campaigns. The instrument is installed in a 1.21 m high, 19 inch rack which has a total weight of 70 kg and a power consumption of 750 VA. The gas chromatograph is equipped with a commercial liquid injector and a valve system for injection of gaseous samples. The gas-inlet system allows automatic injection of samples with defined and constant mass, independent from ambient pressure variations. Two different methods are used for calibration: Liquid PAN calibration samples and a diffusion source for gas-phase calibrations. Both methods have reproducibilities better than 90% and agree with each other to better than 85%. An optimum selectivity of the gas-chromatographic separation is obtained by a combination of two short megabore capillary columns of different polarity. The flow rates are 15 cm3/min, the column temperature is 26°C. For detection an electron-capture detector, operated at 30°C, is used. To allow a reliable control of these relatively low temperatures the instrument is equipped with peltier cooling. To avoid baseline or signal drifts caused by pressure variations in the aircraft cabin an electronic control of the system pressure is integrated into the instrument. The lower limit of detection is better than 15 ppt (3 ), the time needed for one measurement is less than 4 min. Preliminary results from a flight campaign conducted in June 1994 demonstrate the suitability of the instrument for airborne PAN measurements. 相似文献
5.
Takanori Shimizu 《Boundary-Layer Meteorology》2007,122(2):417-438
The theoretical correction of CO2 fluxes for high frequency attenuation in closed-path systems was re-summarized and its applicability examined using both
measurements obtained at an Asiaflux forest site and empirical transfer functions used in previous studies. For our measurement
system, the theoretical transfer function was applicable to high frequency correction, even when condensation occurred in
the sampling line. Further, in respect to some measurement systems described in previous studies, it was found that the theoretical
function was potentially applicable along with the empirical functions used. Meanwhile, in some systems significant errors
could not be resolved by re-estimation of the theories. In these systems, because of undefined buffering effects, the actual
response lag time decided by the maximum covariance method or by measurement of the system response time using tracer gas
was significantly different from the lag time calculated from the tube dimensions and the measured flow rate. If the average
flow rate calculated by the actual lag time was used to determine the theoretical function, the theoretical function became
closer to, and sometimes agreed with, the empirical function. Any remaining deviation from each function might be associated
with pressure fluctuations, but this problem was unable to be examined here. The results suggested that an empirical formulation
for each site is considered applicable rather than a theoretical approach, although the theories are being developed to practical
application. 相似文献
6.
从系统测量原理、组成结构、计算过程及测量效果等方面介绍了一种自行研制的透射式能见度测量系统。该系统使用白色LED光源,实现发散角为1mrad的平行光路;利用积分球进行分光监控以补偿光能量变化;使用非球面镜实现全光斑接收。系统与积分浊度计在2～10km量程内能见度测试误差小于10%。从透射式能见度测量原理与计算过程,分析了影响系统测量性能的因素。结果显示定标准确性、测量线性度与系统稳定性是影响系统测量性能的主要因素,同时给出了该系统的定标准确性、测量线性度与系统稳定性的评估方法及评估数据,验证了该系统的测量性能。 相似文献
7.
8.
利用一个三维的冰雹云模式与化学组分输送模块耦合，得到云输送引起大气光化学组分的再分布，然后用一个包含详细气相化学反应机制的箱模式研究了云输送引起的气相体积分数的变化及其对大气化学系统产生的影响。结果表明，云输送后O3体积分数大于无云个例，但其后两天内两者的变化趋势相差不大；HNO3、NO2、NO3、PAN等的体积分数均明显高于无云个例，分别增长了87％、70％、62％和49％，其中NO2体积分数的增加主要由于云输送造成，而NO3、HNO3、PAN主要是输送对化学扰动的结果。两天内OH和HO2自由基体积分数比无云个例平均增长了13％和11％。 相似文献
9.
On-line Measurement of Water-Soluble Ions in Ambient Particles 总被引：8，自引：0，他引：8
Combining the system of rapid collection of ambient particles and ion chromatography, the system of rapid collection of fine particles and ion chromatography (RCFP-IC) was established to automatically analyze on-line the concentrations of water-soluble ions in ambient particles. Here, the general scheme of RCFP-IC is described and its basic performance is tested. The detection limit of RCFP-IC for SO2? 4 , NO?3 , NO?2 , Cl? and F? is below 0.3 μg m?3. The collection efficiency of RCFP-IC increases rapidly with increasing sized particles. For particles larger than 300 nm, the collection efficiency approaches 100%. The precision of RCFP-IC is more than 90% over 28 repetitions. The response of RCFP-IC is very sensitive and no obvious cross-pollution is found during measurement. A comparison of RCFP-IC with an integrated filter measurement indicates that the measurement of RCFP-IC is comparable in both laboratory experiments and field observations. The results of the field experiment prove that RCFP-IC is an effective on-line monitoring system and is helpful in source apportionment and pollution episode monitoring. 相似文献
10.
A REGIONAL MODEL STUDY OF THE VARIATIONS AND DISTRIBUTIONS OF OZONE AND ITS PRECURSORS ON EASTERN ASIA AND WEST PACIFIC OCEAN REGIONS* 
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下载免费PDF全文 A simulated study of mechanism for variations and distributions of ozone and its precursors was made by using the three-dimensional regional Eulerian model.The results showed that the ozone production was controlled by NOx,but there is a complicated nonlinear relation between them.The photochemical reactions controlled by solar radiation are the determinative factors affecting the variations of the surface ozone and its precursors.The relations of ozone and CO,PAN were studied.We compared the simulated and observed results during the PEM-WEST A in order to better understand the photochemical processes of ozone and its precursors. 相似文献
11.
A REGIONAL MODEL STUDY OF THE VARIATIONS AND DISTRIBUTIONS OF OZONE AND ITS PRECURSORS ON EASTERN ASIA AND WEST PACIFIC OCEAN REGIONS 下载免费PDF全文
下载免费PDF全文 A simulated study of mechanism for variations and distributions of ozone and its precursors was made by using thethree-dimensional regional Eulerian model.The results showed that the ozone production was controlled by NO,butthere is a complicated nonlinear relation between them.The photochemical reactions controlled by solar radiation arethe determinative factors affecting the variations of the surface ozone and its precursors.The relations of ozone and CO,PAN were studied.We compared the simulated and observed results during the PEM-WEST A in order to better under-stand the photochemical processes of ozone and its precursors. 相似文献
12.
S. E. Hobbs 《Boundary-Layer Meteorology》1994,68(3):259-273
The results of calibrations of the airspeed measurement, distance constant and cosine response for a sensitive propellor (vane) anemometer are described. A triad of these anemometers may be used to measure wind velocity, and the estimated uncertainty in this measurement is evaluated for a typical triad and a range of wind directions.The propellor anemometers tested provide sensitivity similar to that of sonic anemometers for research, but at much lower cost (although for a narrower range of wind conditions). Large arrays of the anemometers allow the spatial and temporal structure of wind turbulence to be measured directly. The anemometers have been used for several years, and are robust enough for micrometeorological research. 相似文献
13.
过氧乙酰硝酸酯（PAN）是由VOCs和NOx的光化学反应生成的一种典型二次污染物,比O3更适合作为光化学污染的指示剂.2019年6—10月对浙江中部盆地金华市大气中PAN进行了在线监测,并对影响其体积分数变化的因素进行了分析,同时还分析了一次典型的光化学污染过程.结果表明,观测期间PAN的平均体积分数为0.656×10-9,最高体积分数为4.348×10-9,日均体积分数水平在0.130×10-9~2.203×10-9之间.PAN日变化特征显著,9月为明显的双峰变化,其他月份均为单峰.受气象条件的影响,夏季的污染程度显著低于秋季.9月27—30日典型污染时段内,PAN的小时均值是整个观测期均值的2.8倍,污染以本地积累为主.前体物浓度水平差异与去除机制的不同是影响PAN和O3相关性的重要因素,此外NO/NO2的比值是影响PAN生成速率的重要因素,PAN的峰值基本出现在NO/NO2比值较低的时段.在生成PAN的VOCs物种中,丙烷、乙烷和间/对二甲苯所占比例较大. 相似文献
14.
Quick measurement of CH<Subscript>4</Subscript>, CO<Subscript>2</Subscript> and N<Subscript>2</Subscript>O emissions from a short-plant ecosystem 总被引：43，自引：0，他引：43
Combining improved injector, gas line and valve-driving models, a gas chromatograph (GC) equipped with Hydrogen Flame Ionization Detector (FID) and Electron Capture Detector (ECD), can measure CH4, CO2, and N2O simultaneously in an air sample in four minutes. Test results show that the system has high sensitivity, resolution, and precision; the linear response range of the system meets the requirement of flux measurements in situ. The system is suitable for monitoring fluxes of the main greenhouse gases in a short-plant field since it is easy to use, efficacious, and constant and reliable in collecting data. 相似文献
15.
随着我国新一代天气雷达（CINRAD）的广泛布网,雷达的维修维护工作显得日益繁重。利用虚拟仪器测试系统对雷达重要参数指标测试是一种便捷有效的方式。本文从发射机射频脉冲包络以及其测量方法的介绍出发,搭建一套基于PXI(PCI eXtensions for Instrumentation)模块化仪器的虚拟仪器系统,采用LabVIEW(Laboratory Virtual Instrument Engineering Workbench)软件编程实现参数测试测量功能,通过实验完成了对脉冲包络的重要参数测试。虚拟仪器测试系统与传统仪器对比测量结果,验证了该测试系统的可靠性。 相似文献
16.
臭氧探空仪作为获取地面至上平流层区域内大气臭氧垂直结构的有效手段之一,施放之前需要进行地基检测,评估其探测性能,保证其施放之后可以获取高质量观测数据。首次介绍了国内自主研制的测试臭氧探空仪电化学反应池探测性能的地基检测系统,系统包括检测仪、数据采集模块和处理软件,主要用于检测电化学反应池的背景电流和响应时间两个指标参数。检测仪可以控制输出测试电化学反应池所需的具有不同臭氧含量的空气,测试结果通过数据采集模块传送至计算机,处理软件实现数据自动存储和处理,并提取出响应时间和背景电流。应用结果表明,该套系统检测精度高,性能稳定,可用于未来国内臭氧探空业务化的地基检测工作。 相似文献
17.
Whilst the measurement of radiation emissions from a surface is relativelystraightforward, correct interpretation and proper utilization of the informationrequires that the surface area `seen' be known accurately. This becomes non-trivialwhen the target is an urban surface, due to its complex three-dimensional form andthe different thermal, radiative and moisture properties of its myriad surface facets.The geometric structure creates shade patterns in combination with the solar beamand obscures portions of the surface from the sensor, depending on where it is pointing and its field-of-view (FOV). A model to calculate these surface-sensor-sun relations (SUM) is described. SUM is tested against field and scale model observations, and theoretical calculations, and found to perform well. It can predict the surface area`seen' by a sensor of known FOV pointing in any direction when placed at any pointin space above a specified urban surface structure. Moreover, SUM can predict theview factors of the roof, wall and ground facets `seen' and whether they are sunlit orshaded at any location and time of day. SUM can be used to determine the optimalplacement and orientation of remote sensors to study urban radiation emissions; ifthe facet temperatures are known or modelled it can calculate the average temperatureof the system, and it can determine the directional variation of temperature (anisotropy) due to any particular surface-sensor-sun geometric combination. Thepresent surface geometry used in SUM is relatively simple, but there is scope to makeit increasingly realistic. 相似文献
18.
19.
During spring the atmospheric concentration of Peroxyacetyl Nitrate, PAN, in the UK varies over three orders of magnitude due to long range transport and local photochemical production. An experiment at Great Dun Fell was used to determine which of these sources of PAN controlled spring time concentrations and to quantify the contribution of PAN to oxidised nitrogen in cloud water. The gas phase mixing ratio of a wide range of trace gas pollutants, including PAN, along with cloud water chemical composition and aerosol/cloud droplet distributions were measured. A chemical model was developed to determine the contribution of PAN hydrolysis to cloud water nitrification and to quantify the sink strengths of PAN. Chemical reaction following thermal decomposition was found to be the dominant sink mechanism in the model but transport was the most important factor controlling PAN concentration. During cloud episodes PAN concentrations varied from 100 ppt to over 1 ppb but the calculated inorganic oxidised nitrogen loading in the cloud due to PAN dissolution and hydrolysis was an insignificant fraction of the observed total oxidised nitrogen loading of the cloud. Extrapolation of the model to persistent cloud in marine conditions showed that PAN has a negligible effect on cloud nitrification. It was concluded that PAN concentrations were heavily influenced by regional concentrations and that the hydrolysis of PAN in cloud water was an insignificant source of oxidised nitrogen in cloud water. 相似文献
20.
应用大气光化学模式研究了日间影响NOx光化学转化率的主要物理化学因子.探讨了在不同NMHC/NOx比值时,NOx光化学特征及其转化产物的变化规律.结果表明,影响NOx转化率的主要因子是阳光辐射强度和NMHC/NOx比值.但在NMHC/NOx比值很低时,光强的增加并不能显著提高NOx转化率.温度和初始臭氧浓度对NOx转化率的影响次之.相对湿度对NOx转化率的影响较小.在不同NMHC/NOx比值下,NOx转化特征和产物有很大区别.NMHC/NOx比值高时,产物中PAN＞HNO3.NMHC/NOx比值中(低)时,产物主要是HNO3,PAN等有机氮不到10%(1%).最后初步比较了模拟和观测的NOy组成. 相似文献