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1.
Coastal nucleation events and behavior of cluster ions were characterized through the measurements of air ion mobility distributions at the Mace Head research station on the west coast of Ireland in 2006. We measured concentrations of cluster ions and charged aerosol particles in the size range of 0.34–40 nm. These measurements allow us to characterize freshly nucleated charged particles with diameters smaller than 3 nm. The analysis shows that bursts of intermediate ions (1.6–7 nm) are a frequent phenomenon in the marine coastal environment. Intermediate ion concentrations were generally close to zero, but during some nucleation episodes the concentrations increased to several hundreds per cm3. Nucleation events occurred during most of the measurement days. We classified all days into one of seven classes according to the occurrence and type of new particle formation. Nucleation events were observed during 207 days in 2006, most prominently in the spring and summer months. Rain-induced events, in turn, were observed during 132 days. Particle formation and growth events mostly coincided with the presence of low tide. Also small cluster ions (0.34–1.6 nm) were characterized. Average concentrations of small ions were 440 cm− 3 for the negative ions and 423 cm− 3 for the positive ions. Average mean mobilities of small ions were 1.86 cm2V− 1s− 1 and 1.49 cm2V− 1s− 1 for the negative and positive polarities, respectively. Concentrations of small ions were observed to be strongly dependent on the variations of meteorological parameters including wind speed and direction.  相似文献   

2.
The South China Sea (SCS) interocean circulation and its associated heat and freshwater budgets are examined using the results of a variable-grid global ocean model. The ocean model has a 1/6° resolution in the SCS and its adjacent oceans. The model results from 1982 to 2003 show that the western Pacific waters enter the SCS through the Luzon Strait with an annual mean volume transport of 4.80 Sv, of which 1.71 Sv returns to the western Pacific through the Taiwan Strait and East China Sea and 3.09 Sv flows toward the Indian Ocean. The heat in the western Pacific is transported to the SCS with a rate of 0.373 PW (relative to a reference temperature 3.72 °C), while the total heat transport through the outflow straits is 0.432 PW. The net heat transport out of the SCS is thus 0.059 PW, which is balanced by a mean net downward heat flux of 17 W/m2 across the SCS air–sea interface. Therefore, the interocean circulation acts as an “air conditioner”, cooling the SCS and its overlaying atmosphere. The SCS contributes a heat transport of 0.279 PW to the Indian Ocean, of which 0.240 PW is from the Pacific Ocean through the Luzon Strait and 0.039 PW is from the SCS interior gained from the air–sea exchange. The Luzon Strait salt transport is greater than the total salt transport leaving the SCS by 3.97 Gg/s, implying a mean freshwater flux of 0.112 Sv (or 3.54 × 1012 m3/year) from the land discharge and P − E (precipitation minus evaporation). The total annual land discharge to the SCS is estimated to be 1.60 × 1012 m3/year, the total annual P − E over the SCS is thus 1.94 × 1012 m3/year, equivalent to a mean P − E of 0.55 m/year. The SCS freshwater contribution to the Indian Ocean is 0.096 Sv. The pattern of the SCS interocean circulation in winter differs greatly from that in summer. The SCS branch of the Pacific-to-Indian Ocean throughflow exists in winter, but not in summer. In winter this branching flow starts at the Luzon Strait and extends to the Karimata Strait. In summer the interocean circulation is featured by a north-northeastward current starting at the Karimata Strait and extending to the Taiwan and Luzon Straits, and a subsurface inflow from the Luzon Strait that upwells into the surface layer in the SCS interior to supply the outward transports.  相似文献   

3.
We present results of direct aerosol radiative forcing over a French Mediterranean coastal zone based on one year of continuous observations of aerosol optical properties during 2005–2006. Monthly-mean aerosol optical depth at 440 nm ranged between 0.1 and 0.34, with high Angstrom coefficient (α > 1.2). The single scattering albedo (at 525 nm) estimated at the surface ranged between 0.7 and 0.8, indicating significant absorption. The presence of aerosols over the Mediterranean zone during summer decreases the shortwave radiation reaching the surface by as much as 26 ± 3.9 W m− 2, and increases the top of the atmosphere reflected radiation by as much as 5.2 ± 1.0 W m− 2. The shortwave atmospheric absorption translates to an atmospheric heating of 2.5 to 4.6 K day− 1. Concerted efforts are needed for investigating the possible impact of the increase in heating rate on the maintenance of heat-waves frequently occurring over this coastal region during summer time.  相似文献   

4.
The study of fog dynamics in the island of Tenerife began in 1993 at six sites. The analysis of the relationship between fog and several meteorological parameters was conducted at the site located at Anaga. Anaga is located at the summit of a mountain range, at an altitude of 842 m and 3.5 km away from the north-western coastline of the island. The study uses hourly data of the three summer months (June, July and August) that were collected over a period of nine years — from 1996 to 2005. The mean summer (June–August) rainfall was found to be 21.2 mm whilst the total volume of fog water collected was 879.9 l m− 2; the daily average fog water collection was 9.5 l m− 2 day− 1, and the hourly average about 0.4 l m− 2 h− 1. Although these amounts were recorded with wind speeds of between 8 and 12 m s− 1, the correlation between water collected and wind speed is not statistically significant. In spite of this, the volume of fog water collected and wind speed showed a very distinct daily behavioural pattern, their frequency and speed reaching their minimum at 12 a.m. and their maximum from 7 p.m. to 8 a.m. GMT. The importance of this research is that it shows that the fog in the Canary Islands occurs more frequently and makes a more significant contribution to the growth of vegetation in the summer (the dry season) than in the winter, when fog accompanies rainfall.  相似文献   

5.
Analyses of cloud condensation nuclei (CCN) number concentrations (cm− 3) measured at the Mace Head Atmospheric Research Station, near Carna, County Galway, Ireland, using a DH Associates Model M1 static thermal diffusion cloud chamber over the period from March 1994 to September 2002 are presented in this work. Air masses are defined as being ‘marine’ if they originate from a wind direction of 180–300° and ‘continental’ air masses are defined as originating from a wind direction of 45–135°. Air masses without such filtering were classified as ‘undefined’ air masses. Air masses were found to be dominated by marine sector air, re-affirming Mace Head as a baseline atmospheric research station. CCN levels for specific air masses at Mace Head were found to be comparable with earlier studies both at Mace Head and elsewhere. Monthly averaged clean marine (wind direction of 180–300° and black carbon absorption coefficient < 1.425 Mm− 1) CCN and marine CCN varied between 15–247 cm− 3 and 54–670 cm− 3, respectively. As expected, significant increases in number concentration were found in continentally sourced CCN over that of marine CCN and were found to follow a log-normal distribution significantly tighter than that of clean marine air masses. No significant trend was found for CCN over the 9-year period. While polluted continental air masses showed a slight increase in CCN concentrations over the winter months, most likely due to increased fuel usage and a lower mixed boundary layer, the dominance of marine sector air arriving at Mace Head, which generally consists of background CCN concentrations, reduced seasonal differences for polluted air. Marine air showed a distinct seasonal pattern, with elevated values occurring over the spring and summer seasons. This is thought to be due to enhanced biogenic aerosol production as a result of phytoplankton bloom activity in the North Atlantic.  相似文献   

6.
In the present study, the wet and dry depositions of particulate NO3−, SO42−, Cl− and NH4+ were measured using a wet/dry sampler as a surrogate surface. Gas phase compounds of nitrogen, sulfur and chloride (HNO3, NH3, SO2 and HCl) were measured by an annular denuder system (ADS) equipped with a back up filter for the collection of particles with diameter ≤ 5 μm. Ambient concentrations of NO, NO2 and SO2 were also taken into consideration. Sampling was conducted at an urban site in the center of the city of Thessaloniki, northern Greece. The presence of the aerosol species was examined by cold/warm period and the possible compounds in dry deposits were also considered. Dry deposition fluxes were found to be well correlated with ambient particle concentrations in order to be used for the calculation of particle deposition velocity. Average particulate deposition velocities calculated were 0.36, 0.20, 0.20 and 0.10 cm s− 1 for Cl−, NO3−, SO42− and NH4+, respectively. Total dry deposition fluxes (gas and particles) were estimated at 3.24 kg ha− 1 year− 1 for chloride (HCl + p-Cl), 9.97 kg ha− 1 year− 1 for nitrogen oxidized (NO + NO2 + HNO3 + p-NO3), 5.32 kg ha− 1 year− 1 for nitrogen reduced (NH3 + p-NH4) and 15.77 kg ha− 1 year− 1 for sulfur (SO2 + p-SO4). 70–90% total dry deposition was due to gaseous species deposition. The contribution of dry deposition to the total (wet + dry) was at the level of 60–70% for sulfur and nitrogen (oxidized and reduced), whereas dry chloride deposition contributed 35% to the total. The dry-to-wet deposition ratio of all the studied species was found to be significantly associated with the precipitation amount, with nitrogen species being better and higher correlated. Wet, dry and total depositions measured in Thessaloniki, were compared with other countries of Europe, US and Asia.  相似文献   

7.
A total of 48 precipitation samples have been collected from individual precipitation events at the Nam Co Monitoring and Research Station for Multisphere Interactions (Nam Co Station, 30°47′N, 90°58′E; 4730 m a.s.l) located in the central Tibetan Plateau from August 2005 to August 2006. All samples were analyzed for major cations (NH4+, Na+, K+, Ca2+ and Mg2+) and anions (Cl−, NO3− and SO42−), conductivity and pH. Precipitation pH values ranged from 6.03 to 7.38 with an average value of 6.59. The high pH is due to large inputs of crustal aerosols in the atmosphere, which contain a large fraction of carbonate. Ca2+ is the dominant cation in precipitation with an average value of 65.58 μeq L− 1 (4.91–301.41 μeq L− 1), accounting for 54% of the total cations in precipitation. HCO3− is the predominant anion, accounting for 62% of the total anions. When compared with data from a snow pit in the Zhadang Glacier 50 km away (5800 m a.s.l), major ion concentration in precipitation at the Nam Co Station is much higher due to local aerosol inputs. Correlation and empirical orthogonal function (EOF) analysis indicate that regional crustal aerosols and species from combustion emissions of residents are the major sources for these ions, lake salt aerosols from the Nam Co nearby and regional mineral aerosols from dry lake sediments are secondary sources, and sea salt contribution is the least due to the long distance transport.  相似文献   

8.
A high-volume cascade impactor, equipped with a PM10 inlet, was used to collect size-segregated aerosol samples during the summer of 2004 at two Portuguese locations: a coastal-rural area (Moitinhos) and an urban area (Oporto). Concentrations of airborne particulate matter (PM), total carbon (TC), organic carbon (OC), elemental carbon (EC), and water-soluble organic carbon (WSOC) were determined for the following particle size ranges: < 0.49, 0.49–0.95, 0.95–3.0, and 3.0–10 µm. The total PM mass concentrations at the urban and coastal-rural sites ranged from 22.8 to 79.6 μg m− 3 and 19.9 to 28.2 μg m− 3, respectively, and more than 56% of the total aerosol mass was found in the fractions below 3.0 μm. At both locations the highest concentrations of OC and EC were found in the submicrometer size range. The regional variability for the OC and EC concentrations, with the highest concentrations being found in the urban area, was related to the contribution of local primary sources (mostly traffic emissions). It was also verified an enrichment of the small size particles in WSOC, representing on average 37.3(± 12.4)% and 59.7(± 18.0)% of OC in the very fine aerosol at the coastal-rural and urban areas, respectively. The amount of secondary OC calculated by the minimum OC/EC ratio method indicates that secondary organic aerosol formation was important throughout the study at both sites. The obtained results suggest that long-range transport and favourable summer conditions for photochemical oxidation are key factors determining secondary OC formation in the coastal-rural and urban areas. The ultraviolet absorption properties of the chromophoric constituents of the WSOC fractions were also different among the different particle size ranges and also between the two sampling locations, thus suggesting the strong impact of the diverse emission sources into the composition of the size-segregated organic aerosol.  相似文献   

9.
Low-molecular-weight carbonyl compounds, generated by photochemical reactions in the atmosphere and found in the exhaust of motor vehicles, have recently come to the attention of researchers because some of them are suspected carcinogens or mutagens. Six bifunctional carbonyl compounds were detected and measured in a suburban site 30 km northwest of the Tokyo metropolitan area. Samples were taken on five sunny days between 2 August and 11 August 2003 with a low-volume denuder and three-filter tandem system using O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) as a sorbent. Bifunctional carbonyls were measured by gas chromatography–mass spectrometry after two derivatization processes with PFBHA and N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA). The average total (gas plus particle) concentrations were 162.8 ng m− 3 for pyruvic acid, 113.7 ng m− 3 for methylglyoxal, 36.0 ng m− 3 for glycolaldehyde and 58.6 ng m− 3 for glyoxal.  相似文献   

10.
To further investigate the influence of cloud base temperature, updraft velocity and precipitation particle constitution on cloud electrification, five thunderstorms in various regions of China were simulated by using the three-dimensional compressible hailstorm numerical model including inductive and non-inductive charging mechanisms. The results indicate that changes of cloud base temperature have an influence on the initial electrification. Comparison of the above cases shows that in the case of warm cloud base and moderate updraft velocity (< 20 m s−  1), active electrification occurred below the − 10 °C level before moving upward to the − 20 °C level. In contrast, when cloud base is cold and updraft velocity is intensive, the main charging region is at the − 20 °C or even higher level. In that case, the vertical extent of the main negative charge region becomes larger with the increase of cloud base temperature. Apart from the main dipolar or tripolar charge structure, some smaller charge regions with relatively high values of charge density may also appear. Frozen drops, originating mainly from supercooled raindrops, mainly get electrified through charging interactions with snow at or below the − 20 °C level. They are responsible for the negative charge region near the melting level at the initial stage of precipitation if there is a large supercooled raindrop content. Non-inductive charging during hail-snow collisions is rather weak, resulting in the charge density on hail of no more than − 0.01 nC m− 3.  相似文献   

11.
The potential resources on the ion-stimulated syntheses effects of aerosol particles of lower troposphere in test sites in the arctic, mountain, arid and forest areas as the function of irradiation time and gas-precursor concentration were experimentally and theoretically evaluated. The dust-free outdoor air was irradiated with an ionization current of 10− 6 A by α-rays from isotope 239Pu. The total output of radiolytic aerosols (RA) with a diameter of 3–1000 nm was found to be 0.05–0.1 molecules per 1 eV of absorbed radiation, while the physical upper limit is 0.25–0.4 molecules/eV. In an interval of exposition time from 6 to 800 s (adsorbed energy is 3 · 1012–1014 eV/cm3) the RA mass concentration at different sites was increased from 1–10 to 50–500 μg/m3. According to the liquid chromatography data the major RA material is the H2O/HNO3 solution with acid concentration  25%. The used physical model presents new aerosols as a product from small and intermediate ion association through formation of neutral clusters and describes adequately some of the peculiarities in field experiment data. Introducing SO2, NH3, and also hydrochloric, nitric and sulphuric acid vapours with concentration 0.1–1 mg/m3 in the irradiated air stimulated an increase of mass aerosol concentration by a factor of 8–30. The mean size also decreased by a factor of 3–5. These facts allowed us to expect that the chemical composition of radiolytic aerosols generated in outdoor air would noticeably differ after addition of the gas-precursors.  相似文献   

12.
The main objective of this study is to investigate the chemical characteristics of biomass burning aerosol and its impact on regional air quality during an agricultural waste burning period in early summer in the rural areas of Korea. A 12-h integrated intensive sampling of biomass burning aerosol in the fine and coarse modes was conducted on 2–20 June 2003 in Gwangju, Korea. The collected samples were analyzed for concentrations of mass, ionic, elemental, and carbonaceous species. Average concentrations of fine and coarse mass were measured to be 67.9 and 18.7 μg m− 3 during the biomass burning period, 41.9 and 18.8 μg m− 3 during the haze period, and 35.6 and 13.3 μg m− 3 during the normal period, respectively. An exceptionally high PM2.5 concentration of 110.3 μg m− 3 with a PM2.5/PM10 ratio of 0.79 was observed on 6 June 2003 during the biomass burning period. The potassium ratio method was used to identify biomass burning samples. The average ratio of potassium in the fine mode to the coarse mode (FK/CK) was 23.8 during the biomass burning period, 6.0 during the haze period, and 4.7 during the normal period, respectively. A FK/CK ratio above 9.2 was considered a criterion for biomass burning event in this study. Particulate matter from the open field burning of agricultural waste has an adverse impact on visibility, human health, and regional air quality.  相似文献   

13.
Deposition of atmospheric particulate PCBs in suburban site of Turkey   总被引：2，自引：1，他引：2  
Dry deposition and air concentration samples were collected from July 2004 to May 2005 at a suburban site in Turkey. A water surface sampler (WSS) was used to measure directly the dry deposition flux of particulate polychlorinated biphenyls (PCBs) while a high volume air sampler (HVAS) was employed to collect air samples. Particulate PCB concentrations accounted for 15% of total PCBs (gas + particle phase) at the site. The overall particulate phase PCB flux ranged from 2 to 160 ng m− 2 d− 1 with an average of 46.3 ± 40.6 ng m− 2 d− 1. Forty one PCB congeners were targeted in the samples while twenty one congeners were found to be higher than detection limits in deposition samples. Fluxes for homolog groups ranged between 0.9 (7-CBs) and 21.0 (3-CBs) ng m− 2 d− 1. Measured dry deposition fluxes were lower than the ones usually reported for urban sites. Average PCB dry deposition velocity, calculated using flux values and concurrently measured atmospheric concentrations, was 1.26 ± 1.86 cm s− 1 depended on size distribution of particles, atmospheric PCB concentrations and meteorological conditions.  相似文献   

14.
Terry Deshler   《Atmospheric Research》2008,90(2-4):223-ICNAA07
Stratospheric aerosol, noted after large volcanic eruptions since at least the late 1800s, were first measured in the late 1950s, with the modern continuous record beginning in the 1970s. Stratospheric aerosol, both volcanic and non-volcanic are sulfuric acid droplets with radii (concentrations) on the order of 0.1–0.5 µm (0.5–0.005 cm− 3), increasing by factors of 2–4 (10–103) after large volcanic eruptions. The source of the sulfur for the aerosol is either through direct injection from sulfur-rich volcanic eruptions, or from tropical injection of tropospheric air containing OCS, SO2, and sulfate particles. The life cycle of non-volcanic stratospheric aerosol, consisting of photo-dissociation and oxidation of sulfur source gases, nucleation/condensation in the tropics, transport pole-ward and downward in the global planetary wave driven tropical pump, leads to a quasi steady state relative maximum in particle number concentration at around 20 km in the mid latitudes. Stratospheric aerosol have significant impacts on the Earth's radiation balance for several years following volcanic eruptions. Away from large eruptions, the direct radiation impact is small and well characterized; however, these particles also may play a role in the nucleation of near tropopause cirrus, and thus indirectly affect radiation. Stratospheric aerosol play a larger role in the chemical, particularly ozone, balance of the stratosphere. In the mid latitudes they interact with both nitrous oxides and chlorine reservoirs, thus indirectly affecting ozone. In the polar regions they provide condensation sites for polar stratospheric clouds which then provide the surfaces necessary to convert inactive to active chlorine leading to polar ozone loss. Until the mid 1990s the modern record has been dominated by three large sulfur-rich eruptions: Fuego (1974), El Chichón (1982) and Pinatubo (1991), thus definitive conclusions concerning the trend of non-volcanic stratospheric aerosol could only recently be made. Although anthropogenic emissions of SO2 have changed somewhat over the past 30 years, the measurements during volcanically quiescent periods indicate no long term trend in non-volcanic stratospheric aerosol.  相似文献   

15.
Measuring of charged nanometer particles in atmospheric air is a routine task in research on atmospheric electricity, where these particles are called the atmospheric ions. An aspiration condenser is the most popular instrument for measuring atmospheric ions. Continuous scanning of a mobility distribution is possible when the aspiration condenser is connected as an arm of a balanced bridge. Transfer function of an aspiration condenser is calculated according to the measurements of geometric dimensions, air flow rate, driving voltage, and electric current. The most complicated phase of the calibration is the estimation of the inlet loss of ions due to the Brownian deposition. The available models of ion deposition on the protective inlet screen and the inlet control electrofilter have the uncertainty of about 20%. To keep the uncertainty of measurements low the adsorption should not exceed a few tens of percent. The online conversion of the mobility distribution to the size distribution and a correct reduction of inlet losses are possible when air temperature and pressure are measured simultaneously with the mobility distribution. Two instruments called the Balanced Scanning Mobility Analyzers (BSMA) were manufactured and tested in routine atmospheric measurements. The concentration of atmospheric ions of the size of about a few nanometers is very low and a high air flow rate is required to collect enough of ion current. The air flow of 52 l/s exceeds the air flow in usual aerosol instruments by 2–3 orders of magnitude. The high flow rate reduces the time of ion passage to 60 ms and the heating of air in an analyzer to 0.2 K, which suppresses a possible transformation of ions inside the instrument. The mobility range of the BSMA of 0.032–3.2 cm2 V− 1 s− 1 is logarithmically uniformly divided into 16 fractions. The size distribution is presented by 12 fractions in the diameter range of 0.4–7.5 nm. The measurement noise of a fraction concentration is typically about 5 cm− 3 and the time resolution is about 10 min when measuring simultaneously both positive and negative ions in atmospheric air.  相似文献   

16.
The performance of two different optical concentration-measuring techniques was investigated over a concentration range starting with about 102 cm−3 and extending over more than four decades. Both instruments are capable of real-time counting, however due to their particular design-single particle counter and ensemble particle-measuring system—they operate in overlapping, but different concentration ranges. The upper, coincidence-free counting limit for the single particle counter used in this study was established to be in the order of 104 cm−3. The ensemble technique was found to be functional and stable for concentrations of about 103 cm−3 and limited by the onset of multiple scattering at concentrations nearby 2×106 cm−3. Within the determined boundaries, both techniques proved to provide reliable aerosol concentration data.  相似文献   

17.
The concentrations of submicron aerosols in the size range 10−7 to 10−5 cm, also called Aitken nuclei (AN) were measured over the Indian Ocean enroute India-Antarctica-India within the 10°E–70°E longitude zone from about 10°N to 70°S latitude on board MV Thuleland during the period from November 26, 1986 to March 18, 1987 as part of the scientific activities on the Sixth Indian Antarctic Expedition. Our analyses showed that only in about 25% of the cases, AN count fell below 1000 cm−3. Throughout the tropical trade wind region, the concentrations of AN were relatively stable with an average of about 3000 cm−3 (medians of 2600 and 1700 cm−3 in Northern and Southern Hemispheres, respectively). Large AN concentrations were found to be associated with higher sea surface temperatures and stronger surface winds in this region. In contrast, the scatter of single observations was found to be remarkable over South Indian Ocean and in Antarctic waters. The average AN concentration over the Indian Ocean to the south of 30°S was of the order of 1500 cm−3. No definite correlation could be established between large AN concentration and sea surface temperature, wind speed or wave height. Period with very low concentrations were, however, associated with clear sky conditions and calm winds or light breeze. Many events of sudden short-lived but large increase in AN concentrations were observed over the south Indian Ocean and in Antarctic waters and these were always associated with the approach of frontal systems. It is likely that particle production by bursting bubbles and sea spray as well as photochemical reactions and gas-to-particle conversions play important role in the observed high concentration of AN over South Indian Ocean.  相似文献   

18.
Esmaiel Malek   《Atmospheric Research》2008,88(3-4):367-380
An automated-ventilated radiation station has been set up in a mountainous valley at the Logan Airport in northern Utah, USA, since mid-1995, to evaluate the daily and annual radiation budget components, and develop an algorithm to study cloudiness and its contribution to the daily and annual radiation. This radiation station (composed of pyranometers, pyrgeometers and a net radiometer) provides continuous measurements of downward and upward shortwave, longwave and net radiation throughout the year. The surface temperature and pressure, the 2-m air temperature and humidity, precipitation, and wind at this station were also measured. A heated rain gauge provided precipitation information. Using air temperature and moisture and measured downward longwave (atmospheric) radiation, appropriate formula (among four approaches) was chosen for computation of cloudless-skies atmospheric emissivity. Considering the additional longwave radiation during the cloudy skies coming from the cloud in the waveband which the gaseous emission lacks (from 8–13 μm), an algorithm was developed which provides continuous 20-min cloud information (cloud base height, cloud base temperature, percent of skies covered by cloud, and cloud contribution to the radiation budget) over the area during day and night. On the partly-cloudy day of 3 February, 2003, for instance, cloud contributed 1.34 MJ m− 2 d− 1 out of 26.92 MJ m− 2 d− 1 to the daily atmospheric radiation. On the overcast day of 18 December, 2003, this contribution was 5.77 MJ m− 2 d− 1 out of 29.38 MJ m− 2 d− 1. The same contribution for the year 2003 amounted to 402.85 MJ m− 2 y− 1 out of 9976.08 MJ m− 2 y− 1. Observations (fog which yielded a zero cloud base height and satellite cloud imaging data) throughout the year confirmed the validity of the computed data. The nearby Bowen ratio station provided the downward radiation and net radiation data. If necessary, these data could be substituted for the missing data at the radiation station. While the automated surface observing systems (ASOS) ceilometer at the Logan airport provides only the overhead cloud information, the proposed algorithm provides this information over the valley. The proposed algorithm is a promising approach for evaluation of the cloud base temperature, cloud base height, percent of skies covered by cloud, and cloud contribution to the daily and annual radiation budget at local and regional scales.  相似文献   

19.
The changing chemical composition of cloud water and precipitation in the Western Sudety Mountains are discussed against the background of air-pollution changes in the Black Triangle since the 1980s until September 2004. A marked reduction of sulphur dioxide emissions between the early 1990's and the present (from almost 2 million tons to around 0.2 million tons) has been observed, with a substantial decline of sulphate and hydrogen concentration in cloud water (SO42− from more than 200 to around 70 μmol l− 1; H+ from 150 to 50 μmol l− 1) and precipitation (SO42− from around 80 to 20–30 μmol l− 1; H+ from around 60 to 10–15 μmol l− 1) samples. At some sites, where fog/cloud becomes the major source of pollutants, deposition hot spots are still observed where, for example, nitrogen deposition can exceed 20 times the relevant critical load. The results show that monitoring of cloud water chemistry can be a sensitive indicator of pollutant emissions.  相似文献   

20.
This paper presents the development of a simple and precise analytical method for the determination of nitrogen dioxide in ambient air. In this method nitrogen dioxide is determined in the form of nitrite. The determination of nitrogen dioxide needs no reagents except for a solution of sodium hydroxide mixed with sodium arsenite (NaOH–Na2As2O3) which is used as an absorbing reagent for trapping the nitrogen dioxide from the atmosphere in the form of nitrite, i.e., a prior analysis step. The determination of submicrogram levels of nitrogen dioxide is based on the selection of a strong and sharp quantitative analytical peak at 1380 cm− 1 using diffuse reflectance infrared spectroscopy (DRS-FTIR). The limit of detection (LOD) and the limit of quantification of the method are found to be 0.008 μg g− 1 NO2− and 0.05 μg g− 1 NO2−, respectively. The precision in terms of standard deviation and relative standard deviation value at a level of 2 μg NO2− / 0.1 g KBr for n = 10 is found to be 0.036 μg NO2− and 1.8%, respectively. The relative standard deviation (n = 10) for the determination of nitrogen dioxide in ambient air was observed to be in the range 2.6–3.8%. The method proposed is time-saving and eliminates the slow and cumbersome steps of pH maintenance of the reaction mixture and color formation of the EPA recommended spectrophotometric and other methods for quantitative determination of nitrogen dioxide.  相似文献   

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