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1.
Two large oil fields (QHD32-6 and QHD33-1), located in the middle part of the Shijiutuo Uplift, have generally suffered mild biodegradation. Based on multivariate statistical analysis of the biomarker parameters, this study discussed the origin and charging directions for these two oil fields.In contrast to Ed3-derived oil, all available oil samples from these two large oil fields displayed low C19/C23, C24/C26 and high G/H and 4-MSI, which are attributed to the mixtures of oils derived from the Shahejie (Es1 and Es3) source rocks. Oils in QHD32-6, which contain relatively more Es3-derived oil, are called Group I oils, and most oils in QHD33-1, which share relatively more Es1-derived oil, are called Group II oils. Our mixed oil experiments reveal the predominant Es3- and Es1-derived oil contribution for Group I and Group II oil groups, respectively; however, the selection of end member oils warrants further research.Based on comparisons of biomarker parameters, the QHD32-6 oil field was mainly charged in the north by oil generated from Shahejie formation source rocks in the Bozhong depression. However, oils from the north of QHD32-6 field display a remarkable difference to the oils in the south of this field, which may indicate that a charging pathway exists from the QHD33-1 field. Considering the variations in biomarker compositions in the west to -east and northwest to -southeast sections across the QHD33-1 and QHD32-6 oil fields, it can be deduced that Es3-sourced oil migrated westward to the QHD32-6 traps, and then charging by Es1 oil from the Bozhong Sag resulted in the QHD33-1 oil field being characterized by the mixture of Es3- and Es1-sourced oil. Moreover, migration of Es1-derived oil from the Qinnan Sag was not identified, implying that the QHD33-1 oil field is mainly charged from the northeast of the Bozhong Sag.  相似文献   

2.
网毯式油气成藏体系仓储层运移机理研究   总被引:2,自引:0,他引:2  
研究网毯式油气成藏体系仓储层运移油的机理,揭示断层幕式排烃期仓储层运移油的机理,以油气二次运移理论为指导,开展了油沿断裂纵向运移及油在仓储层内横向运移的定量研究.首先根据地质模型,建立断层内油压力衰减梯度的数学模型,根据能量守恒原理,推导出油沿断层纵向运移的压力梯度公式,计算出油沿断裂进入仓储层的初始压力,再根据仓储层的地质模型,建立油在仓储层内横向运移的压力衰减模型及上网层开启时的泄压模型,推导出油沿仓储层横向运移的压力梯度公式及泄压公式,最终得出仓储层运移油的合力公式.并指出当运移动力大于运移阻力,即运移合力为正时,仓储层以运移油为主,当运移动力等于或小于运移阻力,即运移合力为负时,仓储层以临时仓储(成毯)、成藏为主.通过对运移合力的计算,可以判断油在仓储层内运移、成毯和成藏的状态,预测仓储层运移、成毯或成藏的范围,从而指导该体系隐蔽油气藏的勘探.  相似文献   

3.
The origin of the fourteen major oil fields in the Bozhong sub-basin, Bohai Bay basin was studied based on the results of Rock-Eval pyrolysis on more than 700 samples and biomarker analysis on 61 source rock samples and 87 oil samples. The three possible source rock intervals have different biomarker assemblages and were deposited in different environments. The third member of the Oligocene Dongying Formation (E3d3, 32.8–30.3 Ma in age) is characterized mainly by high C19/C23 tricyclic terpane (>0.75), high C24 tetracyclic terpane/C26 tricyclic terpane (>2.5), low gammacerane/αβ C30 hopane (<0.15) and low 4-methyl steranes/ΣC29 steranes (<0.15) ratios, and was deposited in sub-oxic to anoxic environments with significant terrigenous organic matter input. The first (E2s1, 35.8–32.8 Ma) and third (E2s3, 43.0–38.0 Ma) members of the Eocene Shahejie Formation have low C19/C23 tricyclic terpane and low C24 tetracyclic terpane/C26 tricyclic terpane ratios and were deposited in anoxic environments with minor terrestrial organic matter input, but have different abundances of 4-methyl steranes and gammacerane. The hydrocarbon-generating potential and biomarker associations of these three source rock intervals were controlled by tectonic evolution of the sub-basin and climate changes. Three oil families derived from E2s3, E2s1 and E3d, respectively, and three types of mixed oils have been identified. All large oil fields in the Bozhong sub-basin display considerable heterogeneities in biomarker compositions and originated from more than one source rock interval, which suggests that mixing of oils derived from multiple source rock intervals or multiple generative kitchens, and/or focusing of oils originated from a large area of a generative kitchen, is essential for the formation of large oil fields in the Bozhong sub-basin. E2s3- and E2s1-derived oils experienced relatively long-distance lateral migration and accumulated in traps away from the generative kitchen. E3d3-derived oils had migrated short distances and accumulated in traps closer to the generative kitchen. Such a petroleum distribution pattern has important implications for future exploration. There is considerable exploration potential for Dongying-derived oils in the Bozhong sub-basin, and traps close to or within the generative kitchens have better chance to contain oils generated from the Dongying Formation.  相似文献   

4.
The Niudong Buried Hill Field, which lies in the Baxian Depression of the Bohai Bay Basin, is the deepest oil/gas accumulation in eastern China. Its Precambrian dolomite reservoir occurs at burial depths of 5860 m–6027 m. This paper attempts to document the hydrocarbon charging and accumulation history in this field, which could greatly enhance the understanding of the mechanisms for the formation of deep hydrocarbon accumulations. Our previous study of oil trapped in fluid inclusions has demonstrated that the ratio parameters of the fluorescence spectral intensities at 425 nm and 433 nm (Q425/433 ratio), and at 419 nm and 429 nm (Q419/429 ratio) can be more effective for revealing hydrocarbon charging history than the previously-used fluorescence parameters such as Lambda max and red/green quotient as well as fluorescence colors. The hydrocarbon charging and accumulation history in the Niudong Buried Hill Field was studied with an integrated approach involving the application of these two spectral parameters of petroleum inclusion fluorescence as well as utilization of other data including homogenization temperatures of aqueous inclusions coeval with petroleum inclusions, and cross-cutting relationships of cements and “oil veins” in pores and fractures. The results indicate that the dolomite reservoir in the Niudong Buried Hill Field experienced three episodes of hydrocarbon charging. In the first two episodes (between 38.5Ma and 25Ma), the low mature and mature oils, which were derived from source rocks in the Sha-4 Member of the Eocene Shahejie Formation, migrated into the reservoir, but part of them leaked out due to normal faulting at the updip margin of the buried hill. These early-charged oils were preserved mainly in small pores in micritic dolomites by oil-wettability and capillary pressure. In the Neogene, the basin subsided as a whole and local faults at the updip margin became inactive and played a sealing role. By approximately 13Ma, the source rocks became highly mature and the generated hydrocarbons then migrated into the reservoir and accumulated. Therefore, the last charging is the most important for hydrocarbon accumulation in the Niudong Buried Hill Field.  相似文献   

5.
The Pearl River Mouth Basin in the South China Sea has accumulated >2 km of Eocene sediments in its deep basin, and has become the exploration focus due to the recent discoveries of the HZ25-7 oil field in the Eocene Wenchang (E2w) Formation. In this study, the geochemical characteristics of potential source rocks and petroleum in the HZ25-7 oil field are investigated and the possible origins and accumulation models developed. The analytical results reveal two sets of potential source rocks, E2w and Enping (E2e) formations developed in the study area. The semi-deep-to-deep lacustrine E2w source rocks are characterized by relatively low C29 steranes, low C19/C23 tricyclic terpane (<0.6), low C24 tetracyclic terpane/C30 hopane (<0.1), low trans-trans-trans-bicadinane (T)/C30 hopane (most <2.0), and high C30 4-methyl sterane/ΣC29 sterane (>0.2) ratios. In contrast, the shallow lacustrine and deltaic swamp-plain E2e source rocks are characterized by relatively high C29 steranes, high C19/C23 tricyclic terpane (>0.6), high C24 tetracyclic terpane/C30 hopane (>0.1), variable yet overall high T/C30 hopane, and low C30 4-methyl sterane/ΣC29 sterane (<0.2) ratios. The relatively low C19/C23 tricyclic terpane ratios (mean value: 0.39), low C24 tetracyclic terpane/C30 hopane ratios (mean value: 0.07), high C30 4-methyl sterane/ΣC29 sterane ratios (mean value: 1.14), and relatively high C27 regular sterane content of petroleum in the HZ25-7 oil field indicate that the petroleum most likely originated from the E2w Formation mudstone in the Huizhou Depression. One stage of continuous charging is identified in the HZ25-7 oil field; oil injection is from 16 Ma to present and peak filling occurs after 12 Ma. Thin sandstone beds with relatively good connectivity and physical properties (porosity and permeability) in the E2w Formation are favorable conduits for the lateral migration of petroleum. This petroleum accumulation pattern implies that the E2w Formation on the western and southern margins of the Huizhou Depression are favorable for petroleum accumulation because they are located in a migration pathway. Thus exploration should focus in these areas in the future.  相似文献   

6.
断层面形态对中浅层石油运移影响的模拟实验研究   总被引:2,自引:1,他引:2  
为认识中浅层油气成藏特征,在东营凹陷中浅层油气成藏地质研究基础上,利用二维模型模拟了不同断面形态的情况下,断层对中浅层石油运移和聚集的影响。研究结果表明:(1)在幕式(非稳态)充注条件下,断层面的形态对中浅层石油的运移路径和方式构成重要的影响,S形断层面最有利于断层上、下盘砂层油的充注,这时油在砂层中的运移速率较大,而凹形断层面则有利于断层下盘砂层油的充注,凸形断层面有利于断层上盘砂层油的充注;(2)越陡、弯度越少的断层面越有利于油的运移,即通常所认为的凸形断层面对油气运移起到发散作用,凹形断面起到油气运移汇集作用从模型试验中得到证实。  相似文献   

7.
The petroleum charge history of the Barrandian basin was investigated by analysing quartz and calcite and organic phases that occur in veins and fractures cutting dolerite sills within the Liteň Formation (Silurian). The geochemical characteristics of fluid inclusions trapped in vein quartz and calcite, vein bitumens and adjacent potential source rocks when combined with burial and thermal history data reflect the presence of at least three separate hydrocarbon charge episodes. Solid highly reflecting (Rmax = 0.92–1.49%) bitumen provides information on the first and oldest episode of oil migration. The precursor oil was probably derived relatively early during diagenesis from nearby organic-rich sediments and was subsequently thermally altered to form the solid bitumen.  相似文献   

8.
Faults play an intricate role in hydrocarbon migration and accumulation since they can serve either as a conduit or a seal. Quantitative evaluation of fault opening/sealing properties requires the selection of valid and optimal parameters among numerous geological factors to characterize the hydraulic behaviors of faults. The present study focuses on the Chengbei Step-Fault Area in the Qikou Depression, Bohai Bay Basin, NE China, because hydrocarbon migration and accumulation in this area occurred in a relatively short period so that accumulated hydrocarbons can be used as an indicator to deduce hydraulic connectivity of a fault zone between two sites. Various geological parameters pertinent to a fault, such as burial depth, dip angle, throw, strike, percentage of sandstone of faulted intervals, fluid pressure in faulted mudstone, stress normal to the fault plane, and shale gouge ratio, are analyzed to assess their effectiveness in characterizing fault connectivity. An index, the fault-connectivity probability (Np), is proposed to evaluate the possibility that a fault has been once serving as a migration pathway. The statistical relationship between Np and any a geological parameter may be used to indicate the effectiveness of this parameter in characterizing the connectivity of a fault during hydrocarbon migration. The correlation coefficient of a relationship is a good indicator of the effectiveness; and the results are generally in agreement with qualitative assessments. Parameters representing a single geological factor are generally ineffective, whereas those representing implicitly or explicitly two or more factors, such as shale gouge ratio, stress normal to the fault plane, and fault opening index, are more effective.  相似文献   

9.
The petroleum generation and charge history of the northern Dongying Depression, Bohai Bay Basin was investigated using an integrated fluid inclusion analysis workflow and geohistory modelling. One and two-dimensional basin modelling was performed to unravel the oil generation history of the Eocene Shahejie Formation (Es3 and Es4) source rocks based on the reconstruction of the burial, thermal and maturity history. Calibration of the model with thermal maturity and borehole temperature data using a rift basin heat flow model indicates that the upper interval of the Es4 source rocks began to generate oil at around 35 Ma, reached a maturity level of 0.7% Ro at 31–30 Ma and a peak hydrocarbon generation at 24–23 Ma. The lower interval of the Es3 source rocks began to generate oil at around 33–32 Ma and reached a maturity of 0.7% Ro at about 27–26 Ma. Oil generation from the lower Es3 and upper Es4 source rocks occurred in three phases with the first phase from approximately 30–20 Ma; the second phase from approximately 20–5 Ma; and the third phase from 5 Ma to the present day. The first and third phases were the two predominant phases of intense oil generation.Samples from the Es3 and Es4 reservoir intervals in 12 wells at depth intervals between 2677.7 m and 4323.0 m were investigated using an integrated fluid inclusion workflow including petrography, fluorescence spectroscopy and microthermometry to determine the petroleum charge history in the northern Dongying Depression. Abundant oil inclusions with a range of fluorescence colours from near yellow to near blue were observed and were interpreted to represent two episodes of hydrocarbon charge based on the fluid inclusion petrography, fluorescence spectroscopy and microthermometry data. Two episodes of oil charge were determined at 24–20 Ma and 4–3 Ma, respectively with the second episode being the predominant period for the oil accumulation in the northern Dongying Depression. The oil charge occurred during or immediately after the modelled intense oil generation and coincided with a regional uplift and a rapid subsidence, suggesting that the hydrocarbon migration from the already overpressured source rocks may have been triggered by the regional uplift and rapid subsidence. The expelled oil was then charged to the already established traps in the northern Dongying Depression. The proximal locations of the reservoirs to the generative kitchens and the short oil migration distance facilitate the intimate relationship between oil generation, migration and accumulation.  相似文献   

10.
The discovery of the giant Daqing oil field in the Songliao Basin led to the realisation of the significant petroleum potential of non-marine basins. In order to reconstruct the basin evolution and oil formation, an integrated organic geochemical-basin modelling study along a regional transect across the Songliao Basin was conducted. It provided a regional heat flow evolution model, and revealed post-orogenic or late syn-orogenic maturation in the Central Depression and pre-orogenic maturation in the Southeast Uplift Zone. Kinetic parameters of petroleum generation for the lacustrine source formations are the basis for the simulation of oil generation and migration in the Songliao Basin. Using the principle activation energy peaking at 54 kcal/mol and a pre-exponential factor of about 4.2·1027 Ma−1, the simulation obtained a relatively good match with the measured transformation ratios. The Qingshankou Formation in the West and East Central Depressions constituted the major source in the basin. Major oil generation, migration and accumulation occurred during the Early Tertiary. In the West Central Depression, the generated oils migrated upwards into the Yaojia Formation followed by the updip migration into the Daqing Anticline and towards the local structural high along the West Slope. In contrast, the oil migration in the East Central Depression was dominated by the downward movement from the lower member of the Qingshankou Formation followed by the updip migration towards the Caoyang Anticline. The simulated oil accumulations are in good agreement with discovered oil fields, implying a potential application of the model for prediction and evaluation of new exploration targets in the basin.  相似文献   

11.
The Ordovician is the most important exploration target in the Tabei Uplift of the Tarim Basin, which contains a range of petroleum types including solid bitumen, heavy oil, light oil, condensate, wet gas and dry gas. The density of the black oils ranges from 0.81 g/cm3 to 1.01 g/cm3 (20 °C) and gas oil ratio (GOR) ranges from 4 m3/m3 to 9300 m3/m3. Oil-source correlations established that most of the oils were derived from the Mid-Upper Ordovician marine shale and carbonate and that the difference in oil properties is mainly attributed to hydrocarbon alteration and multi-stage accumulation. In the Tabei Uplift, there were three main periods of hydrocarbon accumulation in the late Caledonian stage (ca. 450–430 Ma), late Hercynian stage (ca. 293–255 Ma) and the late Himalayan stage (ca. 12–2 Ma). The oil charging events mainly occurred in the late Caledonian and late Hercynian stage, while gas charging occurred in the late Hercynian stage. During the late Caledonian stage, petroleum charged the reservoirs lying east of the uplift. However, due to a crustal uplifting episode in the early Hercynian (ca. 386–372 Ma), most of the hydrocarbons were transformed by processes such as biodegradation, resulting in residual solid bitumen in the fractures of the reservoirs. During the late Hercynian Stage, a major episode of oil charging into Ordovician reservoirs took place. Subsequent crustal uplift and severe alteration by biodegradation in the west-central Basin resulted in heavy oil formation. Since the late Himalayan stage when rapid subsidence of the crust occurred, the oil residing in reservoirs was exposed to high temperature cracking conditions resulting in the production of gas and charged from the southeast further altering the pre-existing oils in the eastern reservoirs. A suite of representative samples of various crude oils including condensates, lights oils and heavy oils have been collected for detailed analysis to investigate the mechanism of formation. Based on the research it was concluded that the diversity of hydrocarbon physical and chemical properties in the Tabei Uplift was mainly attributable to the processes of biodegradation and gas washing. The understanding of the processes is very helpful to predict the spatial distribution of hydrocarbon in the Tabei Uplift and provides a reference case study for other areas.  相似文献   

12.
The secondary migration of petroleum is one of the most critical geological processes responsible for the accumulation of hydrocarbons in a sedimentary basin. Pyrrolic nitrogen compounds such as carbazoles and benzocarbazoles are thought to be practical molecular indicators for estimating relative migration distances of oil. In light oils or condensates, however, considerable analytical errors are usually caused by low concentrations of NSO-compounds. Here we show that polycyclic sulfur aromatic hydrocarbons such as dibenzothiophene, C1∼C3 alkylated dibenzothiophenes and benzo[b]naphthothiophenes, which are present in relatively higher concentrations than the pyrrolic nitrogen compounds, exhibit changes in both absolute and relative concentrations that correlate with migration distances. The polycyclic sulfur aromatic hydrocarbons related parameters — benzo[b]naphtho[2,1-d]thiophene/{benzo[b]naphtho[2,1-d]thiophene + benzo[b]naphtho[1,2-d]thiophene} (abbreviated as [2,1]BNT/([2,1]BNT+[1,2]BNT) and the concentration of total dibenzothiophenes plus benzo[b]naphthothiophenes — are proposed by this paper to trace the oil migration distances.  相似文献   

13.
海底石油管线泄漏可能导致海床内部形成高浓度石油污染。在波浪作用下,海床沉积物易发生再悬浮甚至液化失稳现象,进而导致海床内部石油类污染物通过多种途径向水体再次释放并在土体内部发生迁移,造成更大范围的石油扩散。本研究以总石油烃(Total Petroleum Hydrocarbon,TPH)设为代表性污染物,将污染泥浆以椭球状埋设在沉积物内部,采用波浪水槽试验研究不同强度波浪作用下TPH向上覆水体的释放规律及在沉积物内部的迁移规律。结果表明,在沉积物静置固结阶段前期,TPH随孔隙水由沉积物向上覆水体迁移释放,固结阶段前期TPH向上覆水体的释放量高于后期。在波浪作用未引起沉积物液化阶段,波浪促进石油类污染物向水体释放的作用较弱,由于悬浮泥沙对石油类污染物的吸附作用,水体中石油类污染物的浓度略低于静置固结阶段。在波浪作用引起沉积物液化阶段,随着悬浮泥沙浓度升高,TPH向上覆水体释放量加大;TPH在沉积物内部垂向迁移及平面扩散迁移距离加大,平面迁移距离大于垂向迁移距离,垂向扩散深度与液化深度基本一致,污染土体体积占比约为土体未液化时的3倍。  相似文献   

14.
莺歌海盆地新构造运动与超压体系喷溢油气成藏作用   总被引:7,自引:0,他引:7  
莺歌海盆地是在岩石圈伸展减薄和红河断裂带南段的右旋扭动联合作用下形成的一个以伸展为主的转换—伸展盆地。受该应力场作用,盆地新构造运动活跃,主要表现包括中新统末、上新统与第四纪之间及层系内部的不整合,盆地的沉降,沉积中心的迁移,断裂活动,底辟带的发育与分布,泥火山和地震等。新构造运动不但控制了盆地的形成演化、沉降—沉积中心的迁移和底辟构造带发育以及它们的雁行排列特征,同时还控制了盆地油气的成藏和分布。莺歌海盆地是一个强超压盆地,新构造时期断裂的多期活动及其控制的多期底辟活动不但形成超压体系(包括油气)快速垂向运移的通道,同时决定了莺歌海超压盆地油气田的快速幕式充注成藏规律。成熟的烃类以溶解状态储存在超压体系中,当超压体系孔隙流体压力大于封闭盖层破坏压力时封闭盖层就产生水压破裂,超压体系便沿着活动断裂和底辟带等通道发生喷溢活动,油气向上或侧向往过渡带和常压带运移聚集成藏,随着压力的下降,断裂重新闭合形成新的封闭层。这一喷溢过程以幕式活动形式周而复始,在超压盆地的过渡带和常压带中形成大的油气藏。  相似文献   

15.
旅大6构造是渤海海域新近发现的一个中型油田.该构造位于辽东低凸起中南段陡坡带,为层状构造油气藏,垂向上多层系含油,形成典型的“阶梯式”陡坡带复式油气藏.走滑作用对构造形成、储层发育、断层封堵、油气运移都有重要的作用.构造转折端对沉积卸载形成优质储层具有重要作用,奠定了旅大6构造是辽东低凸起中南段有利成藏区的物质基础;辽中一号断层与区域走滑断层同向,具有走滑压扭性质是控圈断层侧封的关键.南北区块以及东二下段、东三段油气丰度迥异,伸展断层的运移能力和控圈断层的封堵能力共同决定了旅大6构造南区东二下段油气的差异富集成藏.  相似文献   

16.
在对构造演化、成藏要素、油源对比、成藏期次分析的基础上,结合Trinity油气运移成藏模拟分析软件对锦州25—1油田的油气运聚模拟研究,分析了形成锦州25—1油田的成藏主控因素,建立了其成藏模式,指出了该地区有利勘探方向。模拟分析结果表明,锦州25—1构造是辽西凹陷沙三段烃源岩生成油气运聚的有利指向区,而优良成藏要素的优势时空配置则是形成锦州25—1油田的关键因素。其成藏模式为:辽西凹陷沙三段烃源岩在东下段时期进入了大量生排烃期,生成的油气为一期充注,充注时间发生在东营组末期,沿东下段时期强烈构造运动伴生的断裂系统、沙二段广泛发育的砂体、沙二段与沙三段之间大型不整合面以及古构造脊所构成的疏导体系运移至沙二段圈闭成藏,而沙三段砂体则可以近源优势成藏。辽西凹陷西斜坡、凹中隆以及古构造脊是今后较为有利的勘探区域。  相似文献   

17.
The hydrocarbon migration and accumulation of the Suqiao deep buried-hill zone, in the Jizhong Subbasin, the Bohai Bay Basin, eastern China, was investigated from the perspective of paleo-fluid evidence by using fluid inclusions, quantitative fluorescence techniques (QGF), total scanning fluorescence method (TSF) and organic geochemical analysis. Results show that the current condensate oil-gas reservoirs in the study area once were paleo-oil reservoirs. In addition, the reservoirs have experienced at least two stages of hydrocarbon charge from different sources and/or maturities. During the deposition of the Oligocene Dongying Formation (Ed), the deep Ordovician reservoirs were first charged by mature oils sourced from the lacustrine shale source rocks in the fourth member of Shahejie and Kongdian Formations (Es4+Ek), and then adjusted at the end of Ed period subsequently by virtue of the tectonic movement. Since the deposition of the Neogene Minghuazhen Formation (Nm), the reservoirs were mainly charged by the gas that consisted of moderate to high-maturity condensate and wet gas sourced from the Es4+Ek lacustrine shale source rocks and mature coal-derived gas sourced from the Carboniferous-Permian (C-P) coal-bearing source rocks. Meanwhile, the early charged oil was subjected to gas flushing and deasphalting by the late intrusion of gas. The widely distributed hydrocarbon inclusions, the higher QGF Index, and FOI (the frequency of oil inclusions) values in both gas-oil and water zone, are indicative of early oil charge. In addition, combined with the homogenization temperatures of the fluid inclusions (<160 °C) and the existence of solid-bitumen bearing inclusions, significant loss of the n-alkanes with low carbon numbers, enrichments of heavier components in crude oils, and the precipitation of asphaltene in the residual pores suggest that gas flushing may have played an important role in the reservoir formation.  相似文献   

18.
The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schöneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of different fields are only in the western part consistent with northward displacement of immature oils by subsequently generated oils. In the eastern part of the basin different migration pathways must be assumed. The trend in S/(S + R) isomerisation of ααα-C29 steranes versus the αββ (20R)/ααα (20R) C29 steranes ratio from oil samples can be explained by differences in thermal maturation without involving long-distance migration. The results argue for hydrocarbon migration through highly permeable carrier beds or open faults rather than relatively short migration distances from the source. The lateral distance of oil fields to the position of mature source rocks beneath the Alpine nappes in the south suggests minimum migration distances between less than 20 km and more than 50 km.Biomarker compositions of the oils suggest Oligocene shaly to marly successions (i.e. Schoeneck, Dynow, and Eggerding formations) as potential source rocks, taking into account their immature character. Best matches are obtained between the oils and units a/b (marly shale) and c (black shale) of the “normal” Schöneck Formation, as well as with the so-called “Oberhofen Facies”. Results from open system pyrolysis-gas chromatography of potential source rocks indicate slightly higher sulphur content of the resulting pyrolysate from unit b. The enhanced dibenzothiophene/phenanthrene ratios of oils from the western part of the basin would be consistent with a higher contribution of unit b to hydrocarbon expulsion in this area. Differences in the relative contribution of sedimentary units to oil generation are inherited from thickness variations of respective units in the overthrusted sediments. The observed trend towards lighter δ13C values of hydrocarbon fractions from oil fields in a W-E direction are consistent with lower δ13C values of organic matter in unit c.  相似文献   

19.
The Dniepr-Donets Basin (DDB) hosts a multi-source petroleum system with more than 200 oil and gas fields, mainly in Carboniferous clastic rocks. Main aim of the present study was to correlate accumulated hydrocarbons with the most important source rocks and to verify their potential to generate oil and gas. Therefore, molecular and isotopic composition as well as biomarker data obtained from 12 oil and condensate samples and 48 source rock extracts was used together with USGS data for a geological interpretation of hydrocarbon charging history.Within the central DDB, results point to a significant contribution from (Upper) Visean black shales, highly oil-prone as well as mixed oil- and gas-prone Serpukhovian rocks and minor contribution from an additional Tournaisian source. Devonian rocks, an important hydrocarbon source within the Pripyat Trough, have not been identified as a major source within the central DDB. Additional input from Bashkirian to Moscovian (?) (Shebelinka Field) as well as Tournaisian to Lower Visean rocks (e.g. Dovgal Field) with higher contents of terrestrial organic matter is indicated in the SE and NW part, respectively.Whereas oil–source correlation contradicts major hydrocarbon migration in many cases for Tournaisian to Middle Carboniferous reservoir horizons, accumulations within Upper Carboniferous to Permian reservoirs require vertical migration up to 4000 m along faults related to Devonian salt domes.1-D thermal models indicate hydrocarbon generation during Permo-Carboniferous time. However, generation in coal-bearing Middle Carboniferous horizons in the SE part of the basin may have occurred during the Mesozoic.  相似文献   

20.
Calcite veins and cements occur widely in Carboniferous and Permian reservoirs of the Hongche fault zone, northwestern Junggar Basin in northwest China. The calcites were investigated by fluid inclusion and trace-element analyses, providing an improved understanding of the petroleum migration history. It is indicated that the Hongche fault behaved as a migration pathway before the Early Cretaceous, allowing two oil charges to migrate into the hanging-wall, fault-core and footwall reservoirs across the fault. Since the Late Cretaceous, the Hongche fault has been sealed. As a consequence, meteoric water flowed down only into the hanging-wall and fault-core reservoirs. The meteoric-water incursion is likely an important cause for degradation of reservoir oils. In contrast, the footwall reservoirs received gas charge (the third hydrocarbon event) following the Late Cretaceous. This helps explain the distribution of petroleum across the fault. This study provides an example of how a fault may evolve as pathway and seal over time, and how reservoir diagenetic minerals can provide clues to complex petroleum migration histories.  相似文献   

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