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船舶的微生物腐蚀与防护技术* 总被引：2，自引：0，他引：2
海洋环境中的微生物腐蚀已被公认为是海洋工程金属构筑物的腐蚀破坏的重要形式。航行在海洋中的船舶不仅受到海水腐蚀的影响,各个部件还会受到微生物腐蚀的影响。严重的微生物腐蚀会导致管路阻塞、部件失效和腐蚀穿孔,不仅影响船舶设备正常运行,也严重威胁船舶安全。本文系统分析了船舶微生物腐蚀发生的位点和危害、不同位点的腐蚀微生物群落结构特征、船舶材料的微生物腐蚀以及不同防护技术的适用范围,并在此基础上提出对船舶微生物腐蚀研究工作的建议。 相似文献
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根据实践经验并参考近10年来的文献,从工程技术角度分析了原油处理厂处理油田采出水时遇到的腐蚀和结垢问题,从污水水质、腐蚀形态和污垢形成3个方面阐述了管道设备污损现状和原因,并分别从应用耐蚀材料、阴极保护技术、改变水质和提高工程质量4个方面提出了应对方案。 相似文献
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中国水环境腐蚀试验站网工作回顾与展望 总被引：6，自引：0，他引：6
材料在天然水环境(海洋、江河、湖泊)中的腐蚀造成了巨大的经济损失。一般来说，发达国家因材料腐蚀造成的损失占其GDP的2％-4％，而材料在水环境中的腐蚀损失大于总腐蚀损失的1／3。因此，材料在水环境的腐蚀数据积累及试验研究一直受到各国的重视。由于材料的自然水环境腐蚀十分复杂，影响因素很多，难以在实验室进行模拟，必须通过野外试验站点现场暴露试验和观测，才能获得符合实际的腐蚀数据和规律。自上世纪初开始，工业发达国家就通过建立水环境腐蚀试验暴露装置和站点， 相似文献
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金属大气腐蚀实验方法进展与研究动态 总被引：1，自引：0，他引：1
金属材料及其制品与所处的自然环境间因环境因素的作用而引起材料变质或破坏称为金属材料的大气腐蚀。金属材料的大气腐蚀机制主要是材料受大气中所含的水分、氧气和腐蚀性介质的联合作用而引起的破坏。按腐蚀反应可分为化学腐蚀和电化学腐蚀两种，在干燥无水分的大气环境中发生的腐蚀属化学腐蚀，其它情况下均属于电化学腐蚀，但它又别于全浸在电解液中的电化学腐蚀，它是在电解液薄膜下的电化学腐蚀，水膜的厚度及干湿交变频率、氧的扩散速度等因素，都影响着大气腐蚀的过程与速度。 相似文献
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本文以热浸锌处理的CM系列钢为研究对象,通过盐雾处理进行了加速腐蚀试验,利用电化学极化测试分析了材料的腐蚀机理,利用扫描电镜和三维数字显微镜观察了材料的表面形貌。盐雾加速试验表明,随着时间增长腐蚀速度降低,主要是由于腐蚀产物膜抑制了腐蚀的阳极过程和阴极过程（产生钝化平台）。厌氧环境下的试验表明,在细菌繁殖到达高峰时产生了钝化平台,主要是形成致密、溶解度极小的ZnS腐蚀产物,在电极表面形成连续完整的腐蚀产物膜。以99.99%纯锌为原料的热浸锌产品在港湾海洋环境中有高的耐蚀性,其原因是由于腐蚀产物及锌-铁合金层的保护作用。 相似文献
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海洋环境微生物腐蚀机理研究进展 总被引：5，自引：0，他引：5
微生物腐蚀(microbiologically influenced corrosion, MIC)是海洋环境中一种非常重要的腐蚀形式,其是微生物、环境、材料共同作用的结果,本文自MIC对海洋环境、菌株、材料性质的依赖性三个方面概述其机理的研究进展。在MIC对海洋环境的依赖性方面,突出溶解氧浓度和营养水平的影响规律与机制。在MIC对菌株的依赖性方面,首先介绍典型单菌株的腐蚀影响机制,然后分析混合菌株间不同菌株的腐蚀协同与拮抗作用,最后阐述复杂微生物群落的影响。在MIC对材料性质的依赖性方面,在总结基体化学成分与结构影响的基础上,介绍对MIC有抑制作用的典型表面的特性及其作用机制。 相似文献
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采用线性极化电阻法,测试了C60全珊瑚海水混凝土（coral aggregate seawater concrete,简称CASC）的线性极化曲线、自腐蚀电位（Ecorr）和极化电阻（Rp）,研究了不同暴露时间、不同种类钢筋CASC的钢筋腐蚀行为,提出了提升岛礁CASC结构耐久性的建议措施。结果表明：随着暴露时间的延长,CASC的Ecorr和Rp均逐渐降低,钢筋的耐蚀性能逐渐减弱。不同种类钢筋CASC耐蚀性能规律为：316不锈钢筋优于有机新涂层钢筋,优于普通钢筋。即使暴露0 d,CASC中普通钢筋仍会发生锈蚀,表明普通钢筋在不附加任何防腐措施的条件下不适用于岛礁CASC结构。综合分析阻锈效果和成本因素,316不锈钢筋的性价比明显低于有机新涂层钢筋,建议岛礁CASC工程优先选用有机新涂层钢筋。 相似文献
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采用放射性免疫(RIA)和组织学切片技术,系统地研究了虹鳟(Oncorhynchus mykiss)选育群体的血清性类固醇激素周年变化与性腺发育特点的关系,以及血清中性类固醇激素雌二醇(E2)和睾酮(T)在雌雄亲本中的周年变化规律和生理作用。结果表明,虹鳟性腺发育可划分为6期。雌鱼血清中E2在10月(V期性腺)达到峰值,T浓度在11月达到峰值,而进入繁殖期后(11—12月)E2开始下降。雄鱼血清T浓度在11月达到最大值,E2在6月份达到峰值,在11月之后T开始下降。在各月份,雌鱼E2浓度水平远高于雄鱼,而雄鱼T浓度个别月份低于雌鱼。这些研究揭示出,测定血清性类固醇激素浓度水平可用于准确判断鱼类的生殖状态,且可为虹鳟家系选育出早熟亲本群体提供重要技术依据。 相似文献
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During deposition in the Palaeogene, the Pearl River Mouth Basin (Enping Sag) was filled by sediments derived from northern and southern source regions. The northern sources are the fold belt Caledonian and Hercynian metamorphic rocks that are widely exposed along the South China block and stacked with Mesozoic igneous rocks, and the southern sources are Mesozoic igneous rocks from the southern Panyu lower uplift. We analysed the characteristics of the provenance and sediment-dispersal patterns of the beach and bar systems in the Palaeogene third-order sequence framework on the basis of detritus, thin section, zircon and the geophysical response test data. The source and deposition areas were distinguished based on their palaeogeomorphology. The sedimentary material composition of the deposition area was determined based on the characteristics of the detrital assemblage and cathode luminescence, and the characteristics of the age distribution were determined in detail using detrital zircon U–Pb dating. This study suggests that the provenance system in the Palaeogene mainly consisted of Palaeozoic metamorphic rocks and Mesozoic igneous rocks, with a supplement of Proterozoic metamorphic rocks. The transport capacity of three large fault troughs that delivered the northern provenances gradually increased from the Wenchang Formation (E2w) to the Enping Formation (E3e), whereas the southern provenances were transported by four or five incised valleys in E2w and then submerged in E3e. In the 3D seismic area, the features of the beach and bar sedimentary systems were described and interpreted based an analysis of the well-based sedimentary facies, seismic reflection characteristics and multiple attribute clustering. The results show that the beach and bar systems by the short-axis braided deltas mainly developed in the upper member of E2w and that the beach and bar systems on the subaqueous high in E3e developed during the Palaeogene. In addition, the bedrock-beach bar sedimentary system in the lower member (E3eL) was transferred to the braided delta–beach bar sedimentary system in the upper member (E3eU). 相似文献
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Mechanisms of petroleum accumulation in the Bozhong sub-basin, Bohai Bay Basin, China. Part 1: Origin and occurrence of crude oils 总被引：1，自引：0，他引：1
Fang Hao Xinhuai Zhou Yangming Zhu Huayao Zou Xiaohuan Bao Qingying Kong 《Marine and Petroleum Geology》2009,26(8):1528-1542
The origin of the fourteen major oil fields in the Bozhong sub-basin, Bohai Bay basin was studied based on the results of Rock-Eval pyrolysis on more than 700 samples and biomarker analysis on 61 source rock samples and 87 oil samples. The three possible source rock intervals have different biomarker assemblages and were deposited in different environments. The third member of the Oligocene Dongying Formation (E3d3, 32.8–30.3 Ma in age) is characterized mainly by high C19/C23 tricyclic terpane (>0.75), high C24 tetracyclic terpane/C26 tricyclic terpane (>2.5), low gammacerane/αβ C30 hopane (<0.15) and low 4-methyl steranes/ΣC29 steranes (<0.15) ratios, and was deposited in sub-oxic to anoxic environments with significant terrigenous organic matter input. The first (E2s1, 35.8–32.8 Ma) and third (E2s3, 43.0–38.0 Ma) members of the Eocene Shahejie Formation have low C19/C23 tricyclic terpane and low C24 tetracyclic terpane/C26 tricyclic terpane ratios and were deposited in anoxic environments with minor terrestrial organic matter input, but have different abundances of 4-methyl steranes and gammacerane. The hydrocarbon-generating potential and biomarker associations of these three source rock intervals were controlled by tectonic evolution of the sub-basin and climate changes. Three oil families derived from E2s3, E2s1 and E3d, respectively, and three types of mixed oils have been identified. All large oil fields in the Bozhong sub-basin display considerable heterogeneities in biomarker compositions and originated from more than one source rock interval, which suggests that mixing of oils derived from multiple source rock intervals or multiple generative kitchens, and/or focusing of oils originated from a large area of a generative kitchen, is essential for the formation of large oil fields in the Bozhong sub-basin. E2s3- and E2s1-derived oils experienced relatively long-distance lateral migration and accumulated in traps away from the generative kitchen. E3d3-derived oils had migrated short distances and accumulated in traps closer to the generative kitchen. Such a petroleum distribution pattern has important implications for future exploration. There is considerable exploration potential for Dongying-derived oils in the Bozhong sub-basin, and traps close to or within the generative kitchens have better chance to contain oils generated from the Dongying Formation. 相似文献
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Olga Leaos-Castaeda Glen Van Der Kraak Andrea Lister Raúl Sim-Alvarez Gerardo Gold-Bouchot 《Marine environmental research》2002,54(3-5)
In order to investigate the mechanism by which o,p′-DDT disrupts endocrine functioning of Nile tilapia in vivo, the estrogenicity of o,p′-DDT was investigated in conjunction with 17β-estradiol (E2) and tamoxifen. Mature, male tilapia were treated intraperitoneally with o,p′-DDT (60 mg/kg, one dose) or E2 (5 mg/kg, four doses) in the presence or absence of tamoxifen (5 mg/kg, six doses) for 12 days and then plasma vitellogenin (Vtg) (measured as alkaline-labile phosphorous), E2, and testosterone (T) were measured. Vtg levels were increased dramatically by E2 (1744±171 μg/ml) and moderately by o,p′-DDT (82±15 μg/ml) compared with controls (23±3.5 μg/ml). Tamoxifen alone had no effect on Vtg production, but inhibited both E2 and o,p′-DDT stimulated vitellogenesis. T levels were reduced with E2 administration (1688±383 pg/ml) and declined further with the combined treatment of E2 and tamoxifen (281±70 pg/ml), compared with controls (6558±1438 pg/ml). Tamoxifen or o,p′-DDT alone did not affect T levels, but their combined treatment did (2069±647 pg/ml). The results of this study suggest that o,p′-DDT is weakly estrogenic in male tilapia, and that this activity may be mediated through the estrogen receptor. 相似文献
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研究海水环境中Q235碳钢锈层中微生物群落的多样性。应用16SrDNA基因文库技术,分别对实海全浸一年的Q235碳钢内外锈层中的微生物进行基因文库的构建和分析。通过克隆测序构建了含有64个OTUs的细菌16SrRNA基因文库,结果表明锈层中微生物种类丰富,主要分布于13个已知的菌门,包括变形菌门;拟杆菌门;硅藻门;酸杆菌门;浮霉菌门;硝化螺旋菌门;厚壁菌门;绿弯菌门;疣微菌门;绿菌门;放线菌门;红藻门以及螺旋体门。内外锈层的优势菌均为变形细菌门,分别占文库序列的46%和53%,其中α-变形菌纲又为门中优势类群,但在内外锈层中还存在明显的系统发育学分歧。 相似文献
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The Pearl River Mouth Basin in the South China Sea has accumulated >2 km of Eocene sediments in its deep basin, and has become the exploration focus due to the recent discoveries of the HZ25-7 oil field in the Eocene Wenchang (E2w) Formation. In this study, the geochemical characteristics of potential source rocks and petroleum in the HZ25-7 oil field are investigated and the possible origins and accumulation models developed. The analytical results reveal two sets of potential source rocks, E2w and Enping (E2e) formations developed in the study area. The semi-deep-to-deep lacustrine E2w source rocks are characterized by relatively low C29 steranes, low C19/C23 tricyclic terpane (<0.6), low C24 tetracyclic terpane/C30 hopane (<0.1), low trans-trans-trans-bicadinane (T)/C30 hopane (most <2.0), and high C30 4-methyl sterane/ΣC29 sterane (>0.2) ratios. In contrast, the shallow lacustrine and deltaic swamp-plain E2e source rocks are characterized by relatively high C29 steranes, high C19/C23 tricyclic terpane (>0.6), high C24 tetracyclic terpane/C30 hopane (>0.1), variable yet overall high T/C30 hopane, and low C30 4-methyl sterane/ΣC29 sterane (<0.2) ratios. The relatively low C19/C23 tricyclic terpane ratios (mean value: 0.39), low C24 tetracyclic terpane/C30 hopane ratios (mean value: 0.07), high C30 4-methyl sterane/ΣC29 sterane ratios (mean value: 1.14), and relatively high C27 regular sterane content of petroleum in the HZ25-7 oil field indicate that the petroleum most likely originated from the E2w Formation mudstone in the Huizhou Depression. One stage of continuous charging is identified in the HZ25-7 oil field; oil injection is from 16 Ma to present and peak filling occurs after 12 Ma. Thin sandstone beds with relatively good connectivity and physical properties (porosity and permeability) in the E2w Formation are favorable conduits for the lateral migration of petroleum. This petroleum accumulation pattern implies that the E2w Formation on the western and southern margins of the Huizhou Depression are favorable for petroleum accumulation because they are located in a migration pathway. Thus exploration should focus in these areas in the future. 相似文献
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Near-surface upward irradiances within each band of the MSS (multi spectral scanner) of LANDSAT, were computed from observed spectral upward irradiances measured just beneath the sea surface. Computation of these irradiances is a useful first step in the analysis of remotely-sensed radiance because the data are not affected by the effects of the atmosphere and sea surface. The computed irradianceE in LANDSAT bands 4, 5 and 6 was normalized by forming ratios,i.e., R
45=E4/E5, R46=E4/E6, andR
56=E5/E6, and then the relationship between these ratios and chlorophylla plus phaeopigment concentration (C) observed simultaneously at 59 stations was examined by linear regression analysis. The observedC ranged over nearly three orders of magnitude, and there is a close to linear relationship between log10-R
45 and log10
C. This suggests that it may be possible to evaluateC from LANDSAT data, if an appropriate atmospheric correction is made. The relationship between suspended solids determined at 35 stations and the same ratios of upward irradiance is also presented and discussed. 相似文献