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1.
‘Offshore CO2 storage’ refers to the injection of liquefied CO2 into deep geological formations beneath the seabed (e.g. depleted oil and gas reservoirs, and saline aquifers) for the purpose of storing it there on a permanent basis. The storage in this manner of captured CO2 emissions from industrial installations and power plants has attracted considerable scientific and technical interest as a potential mitigation response to climate change. A key issue facing policymakers in several countries is how to reconcile policy commitments to develop offshore CO2 storage with other competing – and potentially conflicting – uses of the marine environment. With a view to informing policy responses to this issue, this paper presents a case study of legal and policy frameworks concerning offshore CO2 storage in United Kingdom. The paper maps key design features of the United Kingdom׳s framework for marine permitting and planning, appraising the extent to which they enable orderly development of offshore CO2 storage in a manner consistent with relevant high-level policy objectives.  相似文献   

2.
An increase in the level of atmospheric carbon dioxide (CO2) and the resultant rise in CO2 in seawater alter the inorganic carbon concentrations of seawater. This change, known as ocean acidification, ...  相似文献   

3.
The refined data obtained from the spectroscopic measurements of carbon dioxide in the column of the continental atmosphere over the Issyk Kul Monitoring Station during the period 1980–2006 and the results of their comparison with the data obtained from the measurements of carbon dioxide in air samples and with the mean zonal empirical model of the Climate Monitoring and Diagnostics Laboratory (CMDL) are given. Seasonal variations and a long-term trend of carbon dioxide concentration in the atmospheric thickness over a 25-year period of measurements are analyzed. The monthly mean concentration of CO2 is increased by ～40.5 ppm, and the linear-trend index is 1.62 ppm per year. The results of the aircraft measurements of CO2 concentration in air samples are, on the average, in agreement with the data obtained from the spectroscopic measurements of carbon dioxide concentration in the atmospheric column. The CO2 concentration in the surface air varies from day to day, and only its minimum values coincide with the CO2 concentration in the atmospheric thickness. The results of measurements of CO2 concentration in the atmospheric thickness and in the atmospheric surface layer over the KZD and KZM stations nearest to each other are, on the whole, in disagreement; moreover, the KZD and KZM data are inconsistent. The CO2 concentration in the atmospheric thickness is, on the average, 1–2% higher than that obtained with the CMDL model for 42.6° N latitude. The coefficient of correlation between the measurement results and model data is high (r= 0.95).  相似文献   

4.
Purposeful deep-sea carbon dioxide sequestration by direct injection of liquid CO2 into the deep waters of the ocean has the potential to mitigate the rapid rise in atmospheric levels of greenhouse gases. One issue of concern for this carbon sequestration option is the impact of changes in seawater chemistry caused by CO2 injection on deep-sea ecosystems. The effects of deep-sea carbon dioxide injection on infaunal deep-sea organisms were evaluated during a field experiment in 3600 m depth off California, in which liquid CO2 was released on the seafloor. Exposure to the dissolution plume emanating from the liquid CO2 resulted in high rates of mortality for flagellates, amoebae, and nematodes inhabiting sediments in close proximity to sites of CO2 release. Results from this study indicate that large changes in seawater chemistry (i.e. pH reductions of ∼0.5–1.0 pH units) near CO2 release sites will cause high mortality rates for nearby infaunal deep-sea communities. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

5.
This article presents the results of long-term studies of the dynamics of carbonate parameters and air–sea carbon dioxide fluxes on the Chukchi Sea shelf during the summer. As a result of the interaction of physical and biological factors, the surface waters on the west of Chukchi Sea were undersaturated with carbon dioxide when compared with atmospheric air; the partial pressure of CO2 varied in the range from 134 to 359 μatm. The average value of CO2 flux in the Chukchi Sea per unit area varied in the range from–2.4 to–22.0 mmol /(m2 day), which is significantly higher than the average value of CO2 flux in the World Ocean. It has been estimated that the minimal mass of C absorbed by the surface of Chukchi Sea from the atmosphere during ice-free season is 13 × 1012 g; a great part of this carbon is transported to the deeper layers of sea and isolated from the atmosphere for a long period of time. The studies of the carbonate system of the Chukchi Sea, especially of its western part, will provide some new data on the fluxes of carbon dioxide in the Arctic Ocean and their changes. Our analysis can be used for an interpretation of the satellite assessment of CO2 fluxes and dissolved CO2 distribution in the upper layers of the ocean.  相似文献   

6.
Low carbon shipping research focuses on energy efficiency and mitigation measures related to operations and technology. However, reducing energy use and greenhouse gas emissions associated with a vessel’s material production receives limited attention. Material efficiency is defined as “providing material services with less material production and processing”. The current business model for ship building and breaking does not embrace fully material efficiency principles. Exploring a case study of a vessel's steel hull, this study applies a Life Cycle Assessment approach to determine the effectiveness of material efficiency to reduce CO2 emissions. When compared to Business as Usual, designing and manufacturing for 100% hull reuse provides an emissions reduction of 29% from 221,978 t CO2 to 158,285 t CO2; 50% reuse provides a 10% reduction (199,816 t CO2). From a technical and safety perspective there remain key barriers that need addressing: a vessel’s hull would require to be designed for dismantling to improve reuse; the operation and maintenance schedule must ensure the value of the steel is retained and; data must flow between key stakeholders on the quality of the steel. Despite these challenges, progressing material efficiency would require different business models that reach out and integrate the whole supply chain. There is a need for public and privately funded demonstration projects at a range of scales and markets, to provide investors the confidence that there is retained value in the steel hull when it reaches its end-of-life.  相似文献   

7.
The effects of marine photosynthesis and calcification on the partial pressure of carbon dioxide in seawater (P CO 2) are examined in the light of recent studies and using original model calculations. The ratio of organic carbon to inorganic carbon production (R OI) determines whether an ecosystem is a net sink or source for atmospheric CO2. TheP CO 2 maintains its initial value when the photosynthetic rate is approximately 0.6 times the calcification rate under normal sea surface condition. In case of higherR OI, theP CO 2 decreases and seawater can absorb atmospheric CO2. The ratio of organic carbon to inorganic carbon production can be used as a potential indicator of sink-source behavior in aquatic photo-calcifying systems.  相似文献   

8.
Photochemical mineralization of dissolved organic matter (DOM) plays an important role in the cycling of carbon in estuarine systems. A key to modeling this process is knowledge of apparent quantum yields (AQYs) for the photochemical products. Here we determined spectral AQYs for carbon dioxide (CO2) and carbon monoxide (CO), the main products of DOM photomineralization, along the main axis of the Delaware Estuary. Apparent quantum yields for CO2 photoproduction were determined shipboard using a multi-spectral irradiation system. Carbon monoxide AQYs were determined in stored samples by employing a narrow band spectral irradiation system. A single AQY spectrum described carbon dioxide photochemical production within the estuary whereas CO AQY spectra varied with salinity, suggesting different precursors and mechanisms for the production of these two species. CO2 AQYs were used along with shipboard measurements of DOM absorbance and solar irradiance to calculate photoproduction rates. Calculated CO2 photoproduction rates agreed with directly measured rates (2 to 4 μM CO2 d? 1) within experimental error, supporting the further development and use of AQYs to calculate regional-scale photochemical fluxes.  相似文献   

9.
An overview into the development of a carbon dioxide (CO2) removal plant for submarines to meet the Navy's CO2 requirements is presented.The monoethanolamine (MEA)-CO2 removal process and parametric studies to reduce atmospheric CO2-levels in submarines to 0.5% and possibly 0.2% are discussed.  相似文献   

10.
Observations of the equilibrium partial pressure of carbon dioxide in the surface waters of the North Pacific Ocean and Bering Sea indicate conditions of local upwelling or vertical mixing near the Aleutian Island passes, seasonal depletion of CO2 in the sea surface by photosynthesis, and conditions of CO2 supersaturation in the surface waters off the mouths of large rivers. Horizontal mixing has a large effect on the PCO2 distribution. The area distribution of carbon dioxide in the surface waters of the Pacific Ocean from 19°N to 55°N latitude and in the Bering Sea is presented.  相似文献   

11.
Carbon capture and storage (CCS) is one method to reduce CO2 emissions to the atmosphere. As CCS has the greatest potential for greenhouse gas (GHG) emission reduction, it gains a wide currency in the developed countries. However, the technology for CCS does not spread at the international level especially to the developing countries like South China Sea states. As the CO2 storage period is quite long and potential environmental risks involved, fully deployed CCS projects need not only the technological support but the appropriate legal and regulatory regime to safeguard CCS operations. This article offers a survey of CCS projects in the South China Sea region and discusses the legal challenges associated with CCS activities in state practice.  相似文献   

12.
The integrity of the caprock of a storage formation is the most crucial parameter for the long-term performance of a geological CO2 storage site. The Sleipner area in the Southern Viking Graben hosts the first and longest operating industrial scale CO2 storage project, where CO2 is injected in a saline aquifer of the Utsira Formation. Time-lapse seismic monitoring shows neither that CO2 has left the Utsira Formation nor indications for fracturing of the caprock by the CO2 injection activity, which is in agreement with previous numerical simulations. However, large chimney structures as close as 7 km from the injection point indicate that the caprock has been breached in the geological past, which may raise questions about the integrity of the caprock above the Sleipner CO2 storage site. Here, we present seismically constrained numerical fluid flow simulations that evaluate the influence of chimney structures on the long-term performance of the CO2 storage operation at Sleipner. The simulation could reproduce the spreading of the Sleipner CO2 plume, which is controlled by the anisotropic permeability field of the Utsira Formation and the regional dip of the formation top. We have performed long-term plume evolution simulations, which show that the injected CO2 will not reach the existing chimney structures assuming a realistic injection duration of 30 years. Our simulations indicate that an unrealistically long injection period between 92 and 140 years would be required for the CO2 to reach the existing chimney structures. In this case, a comparably low chimney permeability of 10 mD may be sufficient to facilitate CO2 migration from the storage formation to the seafloor, once the CO2 has reached a chimney structure. However, the simulations indicate that it is very unlikely that the CO2 may migrate along existing chimney structures at Sleipner. Our results highlight that the reconstruction of palaeo fluid flow systems and the identification of focused fluid conduits should be considered in the assessment of CO2 storage sites.  相似文献   

13.
ABSTRACT

Having a reliable ocean carbon flux (f(CO2)) retrieval model is essential to monitoring the global carbon cycle and to evaluating the climate change. Remote sensing techniques provide alternatives for f(CO2) retrieval with its advantages of wide area surveys and real-time monitoring. In the present study, a semianalytical f(CO2) estimation model was developed based on remote sensing data and in situ measurements in the Chinese Bohai Sea. The used model performed well (R2?=?0.84) in deriving f(CO2) based on the collected remotely sensed dataset, including sea surface temperature, estimated sea surface salinity, wind speed, Chl-a concentration. The results showed that the distribution of partial pressure of carbon dioxide (p(CO2)) and f(CO2) varied spatially and temporally during the 12 months in 2009. The spatial fluctuations of p(CO2) and f(CO2) in Bohai Sea in summer and autumn were more obvious than that in Spring and Winter. The highest values of p(CO2) and f(CO2) generally appeared in coastal regions. Moreover, the average f(CO2) value of the 12 months showed that the Bohai Sea performed as a weak carbon source in 2009. The results provided technical and data support for carbon management and climate negotiation in the Bohai Sea.  相似文献   

14.
On the basis of the experimental data accumulated in 1998–2005, we analyzed the space and time variations of the carbonate system of waters and the content of organic carbon in bottom sediments of the Sevastopol Bay. The intensity of gas exchange through the water-atmosphere interface was quantitatively estimated. It was shown that the partial pressure of carbon dioxide pCO2 in waters of the bay became much higher for the period of observations. The maximum changes were observed in summer. They were especially pronounced for the bottom layer of waters. For the entire period of observations, the invasion of carbon dioxide CO2 was predominant in the major part of the bay, and the content of organic carbon in the bottom sediments increased. The ability of waters in the bay to absorb CO2 is explained by the synthesis of organic substances, which becomes possible due to the presence of the equivalent load of nutrients. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 2, pp. 57–67, March–April, 2008.  相似文献   

15.
The annual cycle of dissolved nutrients and the fugacity of CO2 (fCO2), calculated from the concentration of dissolved inorganic carbon (DIC) and pH, was studied over a 14-month long period (December 1993 to February 1995) at a site in Prydz Bay near Davis Station, Vestfold Hills, East Antarctica. Significant spring decreases in fCO2 began under the sea-ice in mid-October, when both water column and sea-ice algal activity resulted in the removal of nutrients and DIC and increased pH. Minimum fCO2 (<100 μatm) and lowest nutrient and DIC concentrations occurred in December and January. The low summer fCO2 values were clearly the result of biological activity. The seasonal depletion of dissolved nitrate reached 85% in mid-summer when chlorophyll-a concentrations exceeded 15 mg m−3. Oceanic uptake of carbon dioxide from the atmosphere, calculated from the fugacity difference and daily wind speeds, averaged more than 30 mmol m−2 day−1 during the summer ice-free period. This exchange replaced approximately half of the DIC consumed by biological activity. Apparent nutrient utilisation ratios (C/N/P) were close to Redfield values. In autumn fCO2 began to rise, continuing slowly well into winter, and reaching a maximum close to modern atmospheric values between July and September. This increase can be attributed to a combination of local remineralisation of organic carbon in the water column and the steady increase in the mixing depth of the water column. At first glance, this suggests that air–sea equilibration occurred in winter despite the sea-ice cover, perhaps by horizontal circulation from regions outside the pack ice, or through openings in the ice. However, the persistent 15 to 20% undersaturation of dissolved oxygen throughout the winter suggests an alternate explanation. The late winter fCO2 level may represent a characteristic established by global circulation, so that as a result of increasing atmospheric CO2 concentrations, these Antarctic waters are in transition from being a winter-time source of CO2 to the atmosphere to becoming a sink. Our fCO2 observations emphasize the need to address seasonal variations in assessing Antarctic contributions to the oceanic control of atmospheric CO2.  相似文献   

16.
The interannual variations of CO2 sources and sinks in the surface waters of the Antarctic Ocean (south of 50°S) were studied between 1986 and 1994. An existing, slightly modified one-dimensional model describing the mixed-layer carbon cycle was used for this study and forced by available satellite-derived and climatological data. Between 1986 and 1994, the mean Antarctic Ocean CO2 uptake was 0.53 Pg C year−1 with an interannual variability of 0.15 Pg C year−1.Interannual variation of the Antarctic Ocean CO2 uptake is related to the Antarctic Circumpolar Wave (ACW), which affects sea surface temperature (SST), wind-speed and sea-ice extent. The CO2 uptake in the Antarctic Ocean has increased from 1986 to 1994 by 0.32 Pg C. It was found that over the 9 years, the surface ocean carbon dioxide fugacity (fCO2) increase was half that of the atmospheric CO2 increase inducing an increase of the air–sea fCO2 gradient. This effect is responsible for 60% of the Antarctic Ocean CO2 uptake increase between 1986 and 1994, as the ACW effect cancels out over the 9 years investigated.  相似文献   

17.
The climate model of intermediate complexity developed at the Oboukhov Institute of Atmospheric Physics, Russian Academy of Sciences (IAP RAS CM), has been supplemented by a zero-dimensional carbon cycle model. With the carbon dioxide emissions prescribed for the second half of the 19th century and for the 20th century, the model satisfactorily reproduces characteristics of the carbon cycle over this period. However, with continued anthropogenic CO2 emissions (SRES scenarios A1B, A2, B1, and B2), the climate-carbon cycle feedback in the model leads to an additional atmospheric CO2 increase (in comparison with the case where the influence of climate changes on the carbon exchange between the atmosphere and the underlying surface is disregarded). This additional increase is varied in the range 67–90 ppmv depending on the scenario and is mainly due to the dynamics of soil carbon storage. The climate-carbon cycle feedback parameter varies nonmonotonically with time. Positions of its extremes separate characteristic periods of the change in the intensity of anthropogenic emissions and of climate variations. By the end of the 21st century, depending on the emission scenario, the carbon dioxide concentration is expected to increase to 615–875 ppmv and the global temperature will rise by 2.4–3.4 K relative to the preindustrial value. In the 20th–21st centuries, a general growth of the buildup of carbon dioxide in the atmosphere and ocean and its reduction in terrestrial ecosystems can be expected. In general, by the end of the 21st century, the more aggressive emission scenarios are characterized by a smaller climate-carbon cycle feedback parameter, a lower sensitivity of climate to a single increase in the atmospheric concentration of carbon dioxide, a larger fraction of anthropogenic emissions stored in the atmosphere and the ocean, and a smaller fraction of emissions in terrestrial ecosystems.  相似文献   

18.
An experimental method for the continuous determination of the partial pressure of carbon dioxide was attempted during a cruise in the Mediterranean Sea. The method, which uses infrared analysis of air continuously equilibrated with pumped seawater, is described. Calculations to obtain pCO2 in seawater from measured pCO2 are given with an example of the results.  相似文献   

19.
The ocean captures a large part of the anthropogenic carbon dioxide emitted to the atmosphere. As a result of the increase in CO2 partial pressure the ocean pH is lowered as compared to pre-industrial times and a further decline is expected. Ocean acidification has been proposed to pose a major threat for marine organisms, particularly shell-forming and calcifying organisms. Here we show, on the basis of meta-analysis of available experimental assessments, differences in organism responses to elevated pCO2 and propose that marine biota may be more resistant to ocean acidification than expected. Calcification is most sensitive to ocean acidification while it is questionable if marine functional diversity is impacted significantly along the ranges of acidification predicted for the 21st century. Active biological processes and small-scale temporal and spatial variability in ocean pH may render marine biota far more resistant to ocean acidification than hitherto believed.  相似文献   

20.
A global survey of the distribution of dissolved CO2 taking advantage of sampling opportunities provided by the World Ocean Circulation Experiment: World Hydrographic Program (WOCE-WHP) is being carried out through 1995. Goals include the measurement of oceanic inorganic carbon transport and the development of a data base from which future fossil-fuel CO2 build-up can be monitored. The analytical method selected for total carbon dioxide (CT) is gas extraction of acidified seawater with coulometric titration of the acid formed by the resultant carbon dioxide and monoethanolamine. To combine high accuracy and precision (± 1.5 μmol/kg for CT ≥ 2000 μmol/kg) with a high rate of analysis, we have modified an automated single-parameter system. Following prototype development between 1987 and 1990, an instrument emerged with the acronym Somma standing for single-operator multiparameter metabolic analyzer. Improved functional and operating procedures have integrated electronic calibration, CO2 gas calibration, and sample analysis with automated pressure, temperature, and conductivity (salinity) sensing into a single convenient transportable package.  相似文献   

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