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1.
Money C Braungardt CB Jha AN Worsfold PJ Achterberg EP 《Marine environmental research》2011,72(1-2):3-12
As part of the PREDICT Tamar Workshop, the toxicity of estuarine waters in the Tamar Estuary (southwest England) was assessed by integration of metal speciation determination with bioassays. High temporal resolution metal speciation analysis was undertaken in situ by deployment of a Voltammetric In situ Profiling (VIP) system. The VIP detects Cd (cadmium), Pb (lead) and Cu (copper) species smaller than 4?nm in size and this fraction is termed 'dynamic' and considered biologically available. Cadmium was mainly present in the dynamic form and constituted between 56% and 100% of the total dissolved concentration, which was determined subsequently in the laboratory in filtered discrete samples. In contrast, the dynamic Pb and Cu fractions were less important, with a much larger proportion of these metals associated with organic ligands and/or colloids (45-90% Pb and 46-85% Cu), which probably reduced the toxicological impact of these elements in this system. Static toxicity tests, based on the response of Crassostrea gigas larva exposed to discrete water samples showed a high level of toxicity (up to 100% abnormal development) at two stations in the Tamar, particularly during periods of the tidal cycle when the influence of more pristine coastal water was at its lowest. Competitive ligand-exchange Cu titrations showed that natural organic ligands reduced the free cupric ion concentration to levels that were unlikely to have been the sole cause of the observed toxicity. Nonetheless, it is probable that the combined effect of the metals determined in this work contributed significantly to the bioassay response. 相似文献
2.
This paper explores the accumulations ana distributions of Cd, Pb and Cu in clam Area granosa through determining their contents in Dlood and soft parts. The results show an order of concentration factors for these metals therein as: Cd>Cu>Pb; the values of concentration factors and the patterns of distribution are similar for Cu and Pb but different from Cd. Concentration factors in blood can reflect the enrichement abilities of soft parts. Exposure experiments have indicated that the Pb level in blood is controlled by Pb concentrations in surrouding seawater, changing with time, that the Pb cocentration causing poisoning in the seawater is 1-100 μg/l, and that the Pb content in blood and soft parts of Area granosa increases with that of Pb increasing in seawater. There exist relationships of double logatithmic concentrations for Pb among the three mediums. 相似文献
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A study was performed in the Tyrrhenian Sea in front of S. Rossore Park (Pisa) to ascertain the degree of Cu, Pb, Cd and Cr pollution and to investigate whether the rivers flowing into the sea may be considered potential sources of seawater contamination. Owing to the variability of such a system, the research, covering a one-year period, involved five surveys on 13 selected sampling stations and two surveys following the floats along the river Arno and its plume. The results refer to the total concentration of the above metals in the water phase after filtration. The content of Cu, Pb and Cd was always found to be higher than in the reference station (about 8 km offshore), generally reaching maximum values around the mouths of the rivers. Concentrations exceeding the minimal risk concentration were observed in the case of Cd. As for Cr, its concentration was always below the detection limit of the analytical method used. Rivers thus appear to be the main sources of coastal metal pollution.By the samplings carried out along the river Arno and its plume (involving 3–5 km from the mouth), it was found that the dilution model represents the concentration pattern for Cu and Pb fairly well over a large range of salinity. 相似文献
5.
The historical trend of pollution sources of Pb in Tokyo Bay, Japan was investigated on the basis of Pb isotope ratios in a sediment core. The isotope ratios of anthropogenic Pb decreased gradually with increasing Pb concentration in the 1900s–1970s, suggesting a combination of Pb sources with various isotope ratios. In contrast, the isotope ratios of anthropogenic Pb in the 1980s–2000s showed no significant trend, and corresponded to the Pb isotope ratios in the three principal rivers flowing into the bay. It is probable that river bottom sediments contaminated with Pb are principal sources of anthropogenic Pb in Tokyo Bay. 相似文献
6.
采用室内暴露试验方法,以单细胞凝胶电泳技术(SCGE)检测,研究了Cu、Pb不同浓度梯度与不同暴露时间联合染毒对泥鳅卵细胞DNA的损伤.结果表明,各Cu、Pb浓度组DNA平均迁移长度增加,与阴性对照组比较差异有显著性(P＜0.05).此外,随着Cu、Pb染毒剂量的增加,各试验组DNA的平均迁移长度逐渐增加,在试验浓度梯度范围内(Cu 0.01mg/L+Pb 0.05mg/L、Cu 0.10mg/L+Pb 0.50mg/L、Cu 0.25mg/L+Pb 0.75mg/L),存在较为显著的剂量-效应关系(P＜0.05),但未见明显的时间-效应关系(P＞0.05).Cu、Pb可引起泥鳅卵细胞凋亡和DNA损伤,卵细胞的不同损伤水平可望作为较为理想的水环境基因毒性指标. 相似文献
7.
T.O. Richter H.C. de Stigter W. Boer C.C. Jesus T.C.E. van Weering 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(2):267-282
Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (206Pb/207Pb vs. 208Pb/206Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (206Pb/207Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher 206Pb/207Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls. 相似文献
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采用2009～2011年珠江口海域获取的代表春、夏、秋、冬4个季节的240个气溶胶样品,分析重金属（Cu、Pb、Zn、ca）质量浓度和大气干沉降通量的年、季变化特征．结果表明：气溶胶中zn的质量浓度最高,其次是Pb和Cu,Cd的质量浓度最低,年平均质量浓度依次为69,2、31．2、12．6和0．58ng／m3．Cu、Pb和Zn的年平均质量浓度和入海通量表现为2009年〉2011年〉2010年．Cd的年平均质量浓度和入海通量呈现逐年递减的变化趋势．各金属质量浓度及大气干沉降通量均为秋季最高,冬春季次之,夏季最低,这种季节性差异主要与季风和雨水冲刷作用有关．气溶胶中Cu、Ph、Cd和Zn平均质量浓度的较低值出现在2010年夏季．Pb在4个季节的平均质量浓度低值均出现在2010年,平均质量浓度依次为18．9、3．8、56．7、20．2ng／m3,表明加强人为污染物排放的控制,可有效地降低气溶胶中重金属的含量,提高环境空气质量．通过评估金属元素分别从大气和河流进入珠江口海域的输入量,该海域金属物质输送入海仍以河流输入为主,但大气中Pb对该海域的输入具有重要作用． 相似文献
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E. García-Luque T. A. DelValls C. Casado-Martínez J. M. Forja A. Gmez-Parra 《Marine environmental research》2004,58(2-5):671
We describe the effect of heavy metals Zn, Cd, Pb and Cu on the induction of methallothioneins on the clam Scrobicularia plana along a salinity gradient simulated under laboratory conditions. The clams were exposed to constant heavy metal concentrations in a dynamic estuary simulator during a 15-day assay to investigate possible induction of metal-binding proteins in them. The concentration of heavy metals in water was analysed. Clams were analysed for methallothionein concentrations. The speciation of Zn, Cd, Pb and Cu along the salinity gradient was modelled. Zn showed the highest concentrations and its prevalent species was the free ion. Intersite differences have been observed in methallothionein concentration and related to the salinity gradient. It seems that synthesis of methallothioneins is the result of physiological forces acting in concert with the changes in the chemical speciation of metals, owing to the trace metals uptake is controlled by means of an interaction of physiology and physicochemistry. 相似文献
10.
García-Luque E DelValls TA Casado-Martínez C Forja JM Gómez-Parra A 《Marine environmental research》2004,58(2-5):671-674
We describe the effect of heavy metals Zn, Cd, Pb and Cu on the induction of methallothioneins on the clam Scrobicularia plana along a salinity gradient simulated under laboratory conditions. The clams were exposed to constant heavy metal concentrations in a dynamic estuary simulator during a 15-day assay to investigate possible induction of metal-binding proteins in them. The concentration of heavy metals in water was analysed. Clams were analysed for methallothionein concentrations. The speciation of Zn, Cd, Pb and Cu along the salinity gradient was modelled. Zn showed the highest concentrations and its prevalent species was the free ion. Intersite differences have been observed in methallothionein concentration and related to the salinity gradient. It seems that synthesis of methallothioneins is the result of physiological forces acting in concert with the changes in the chemical speciation of metals, owing to the trace metals uptake is controlled by means of an interaction of physiology and physicochemistry. 相似文献
11.
The adsorption of Pb, Cu and Cd on synthetic hydrous ferric oxide (HFO) has been performed under simulated environmental conditions of the Changjiang Estuary. An improved M2 - H exchange-adsorption model is proposed to explain the adsorption processes. The adsorption of these elements falls in the order: Pb ≥ Cu > Cd and has a good coincidence with the field results obtaimed from the Estuary. It has been concluded that the adsorption processes of Pb and Cu on HFO are mainly chemical actions, whereas static-electrical action dominates in the case of Cd. 相似文献
12.
本研究通过识别海洋气团特征及沿海城市大气受到海洋气团的影响方式与程度,为评价沿海城市空气环境质量提供科学依据。以青岛市为例,收集大气气溶胶样品中放射性核素~(210)Pb、40K数据及采集时段当地大气颗粒物数据;分析~(210)Pb活度浓度与气溶胶颗粒物浓度变化;对当地当时大气气团进行溯源分析。研究表明:(1)研究期间青岛沿岸地区2015年4月至2016年6月与2016年6月至2017年6月大气污染特征显著不同,前者~(210)Pb活度浓度与污染颗粒物浓度显著相关,而后者~(210)Pb活度浓度与污染颗粒物无相关关系;(2)穿越海洋的陆地气团呈现出高活度浓度、低颗粒物浓度的特征;来自海洋气团的气溶胶呈现出低活度浓度、低颗粒物浓度的特征;(3)海洋气团气溶胶中~(210)Pb活度浓度较低。临近大陆的海洋(黄海、东海)上层大气受到大陆气团的影响,其海洋气团的特征有所减弱。~(210)Pb活度浓度、颗粒物浓度(PM2.5)可作为判断海洋气团的指标,识别"来自海洋的气团"与"经过海洋的气团"。 相似文献
13.
Bioaccumulation and toxicity of four dissolved metals in Paracentrotus lividus sea-urchin embryo 总被引：1，自引：0，他引：1
The bioaccumulation of four metals (Cd, Cu, Pb, Zn) dissolved in water was assessed measuring the concentrations recorded within sea-urchin larvae (Paracentrotus lividus, Lmk.) after a 48-h exposure period. Concurrently, the frequencies of abnormalities were evaluated at the 48-h pluteus stage to check the actual toxicity of such contaminants with regards to larval development. Maximum metal concentrations in the larvae reached 43.8 +/- 6.7 micrograms Cd g-1 dry weight (d.w.), 1269 +/- 392 micrograms Cu g-1 d.w., 3106 +/- 679 micrograms Pb g-1 d.w., 534 +/- 62 micrograms Zn g-1 d.w. Bioconcentration factors (BCFs) reached very high values for Pb (maximum value: 16,282 +/- 973) and indicated that the concentrations of Pb and Cd were directly related to the water concentration at least in the range of concentrations tested. Zn appeared to be partially regulated above a certain threshold concentration (between 5 and 25 micrograms l-1). Cu was accumulated with an active uptake at least below lethal threshold level (100 micrograms l-1). Nevertheless, above these thresholds, high mortality of embryos prevent any interpretation of Zn and Cu bioconcentration factors. Concurrent studies carried out on embryotoxicity confirmed the high toxicity of Cu towards sea-urchin pluteus larvae and highlighted the different behaviour of Cd. The internal Cd concentrations were directly related to the external ones, comparable to other non-essential metals, but Cd had little toxic effect on the initial larval development. 相似文献
14.
A Mu?oz-Barbosa E A Gutiérrez-Galindo G Flores-Mu?oz 《Marine environmental research》2000,49(2):123-144
Samples of Mytilus californianus were analyzed to determine the spatial and temporal distribution of Ag, Al, Cd, Cr, Cu, Mn, Pb and Zn concentrations on the northwest coast of Baja California and to compare the results with levels reported for California, USA. The samples were collected at eight sites from the US-Mexican border to San Quintín, BC (300 km south of the border) in February and July 1982 and 1994. During both years, north-south gradients in the concentration of Ag and Pb were observed, with the highest values close to the US-Mexican border (Ag = 0.60-1.54 and Pb = 0.21-2.89 micrograms g-1) and the lowest in the southern part of the study area (Ag = 0.05-0.10 and Pb = not detectable-0.03 microgram g-1). The Ag and Pb gradients suggest that their distributions are affected by anthropogenic activities close to the US-Mexican border. South-north gradients in the concentration of Cd (minimum = 0.59-2.16 and maximum = 2.61-12.93 micrograms g-1), for both 1982 and 1994, were observed. The geographic annual means of Pb for California (average of six stations along the entire state) were significantly higher than those of this study (average of the eight sampling sites) in 1982 and 1994. Cu in California was significantly greater than that of this study only in 1994. Cluster analyses on all metals indicate three similar geographic zones in 1982 and 1994, suggesting a relative consistency in the processes that determine the spatial variability of the concentration of some metals in M. californianus on the northwest coast of Baja California. 相似文献
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铅(Pb)在海水中易产生沉淀,这将影响毒性实验中效应值的计算。本研究通过海水中不同重金属对中国广泛分布的底栖无脊椎动物双齿围沙蚕(Perinereis aibuhitensis)以及毒理学研究常用的海水模式生物卤虫(Artemiasalina)的急性毒性实验,对比分析了海水中Pb的生物毒性特点以及暴露溶液中Pb的析出对毒性实验结果的影响。用人工海水与天然海水配制Pb溶液时,理论浓度为18.7～1 200mg/L的Pb溶液中均出现大量白色沉淀。通过扫描电子显微镜能谱(SEM-EDS)对析出物进行检测,根据元素组成推测析出物主要为氯化铅与碳酸铅。对溶液浓度进行检测发现,Pb的实测浓度仅为理论浓度的1/15～1/2,根据实测浓度计算的Pb对双齿围沙蚕和卤虫的96h/48h半数致死浓度(LC50)值低于根据理论浓度计算值的1/10。对比Pb、Cu、Cd对双齿围沙蚕与卤虫的LC50值发现, Pb对水生生物的毒性低于Cu和Cd,且对不同生物的毒性效应存在差异。对比研究报道中Pb对海洋生物的急性毒性效应发现,Pb对幼体生物的毒性效应较显著,而在海水有效溶解... 相似文献
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To investigate the factors controlling lead (Pb) concentration and identify the sources of Pb in Yellow Sea sediments along the Korean coast, the concentration of Pb and Pb isotopes in 87 surface and 6 core sediment samples were analyzed. The 1 M HCl leached Pb concentrations had a similar geographic distribution to those of fine-grained sediments, while the distribution of residual Pb concentrations resembled that of coarse-grained sediments. Leached Pb was presumed to be associated with manganese (Mn) oxide and iron (Fe) oxy/hydroxide, while residual Pb was associated with potassium (K)-feldspar, based on good linear relationships between the leached Pb and the Fe/Mn concentrations, and the residual Pb and K concentrations. Based on a ratio–ratio plot with three isotopes (207Pb/206Pb and 208Pb/206Pb) and the geographic location of each sediment, sediments were categorized into two groups of samples as group1 and group2. Group 1 sediments, which were distributed in Gyeonggi Bay and offshore (north of 36.5°N), were determined to be a mixture of anthropogenic and natural Pb originating from the Han River, based on a 208Pb/206Pb against a Cs/Pbleached mixing plot of core and surface sediments. Group 2 sediments, which were distributed in the south of 36.5°N, also showed a two endmembers mixing relationship between materials from the Geum River and offshore materials, which had very different Pb concentrations and isotope ratios. Based on the isotopes and their concentrations in core and surface sediments, this mixing relationship was interpreted as materials from two geographically different origins being mixed, rather than anthropogenic or natural mixing of materials with the same origin. Therefore, the relative percentage of materials supplied from the Geum River was calculated using a two endmembers mixing model and estimated to be as much as about 50% at 35°N. The spatial distribution of materials derived from the Geum River represented that of fine-grained sediments originating from the Geum River. It was concluded that Pb isotopes in sediments could be used as a tracer in studies of the origin of fine-grained sediments along the Korean Yellow Sea coast. 相似文献
17.
The resuspension of 65 marine sediments was simulated in the laboratory with elutriates from 30 different sites from the north coast of Spain. The partitioning of Cu, Pb and Zn between sediment and elutriate was studied as a function of different physicochemical characteristics of the sediment: organic matter (OM), fine fraction (FF), redox potential and acid volatile sulfides (AVS). Mean remobilization factors (RF) -calculated as metal concentration in the elutriate (μg/L) divided by metal concentration in the sediment (μg/g dry weight)- were 0.072 for Cu, 0.012 for Pb and 0.071 for Zn. Remobilization of Pb was significantly lower than that of Cu and Zn. Although AVS, OM and FF presented a strong intercorrelation, OM explained great part of the variability on Cu and Pb remobilization while AVS did it for Zn. A multiple regression model considering both OM and AVS explained slightly better the remobilization of Pb and Cu, but not that of Zn. 相似文献
18.
海州湾南部近岸柱状样沉积物重金属污染 总被引：7，自引：0，他引：7
按照《海洋监测规范》,As采用原子荧光法分析,Hg采用冷原子吸收分光光度法分析,Pb、Cd、Cu采用阳极溶出伏安法分析,对海州湾南部近岸3个柱状样主要重金属在不同深度浓度的变化和重金属潜在生态危害指数随深度的变化进行了分析,结合210Pb测年,探讨了重金属的污染历史。结果表明,海州湾南部近岸柱状样重金属浓度随深度基本呈锯齿状变化;同有机质的相关性分析表明As、Cu、Pb与人为污染有关;重金属污染水平总体轻微,其中主要污染元素是Hg,已达极强生态危害。 相似文献
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In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang(Yangtze) Estuary,the contents of heavy metals(Zn,Pb,Cd,Co and Ni) have been analyzed.During a tidal cycle,the average contents of heavy metals are in the order of ZnNiPbCo àCd.The average contents in ebb tide are generally higher than that in flood tide.However,at the inshore Sta.11,influenced by the contamination from the nearby waste treatment plant,the average contents of Zn and Ni in flood tide are higher than those in ebb tide and at the offshore Sta.10,the content of Cd in flood tide higher than that in ebb tide due to marine-derived materials.The five heavy metals,mainly terrigenous,are transported towards east-northeast,and settle down with suspended matters in the area between Sta.11 and Sta.10.Influenced by marine-derived materials,the flux value of Cd does not alter significantly with obviously changing in flux direction towards northwest.The source of heavy metals,the salinity of water and the concentration of suspended matters are the main factors controlling the content distributions of heavy metals during a tidal cycle.There is a positive correlation between the contents of heavy metals(Zn,Pb,Co and Ni) and the salinity of water,while the opposite correlation between the contents and the concentrations of suspended matters.Because of marine-derived materials,the content of Cd is not correlated with the concentration of suspended matters and the salinity of water. 相似文献