共查询到18条相似文献，搜索用时 62 毫秒
1.
HA-5型微机海水营养盐自动分析仪是适用于海水中NO_3~-、NO_2~-、NH_4~+、PO_4~(3-)、SiO_3~(2-),含量测定,是微机化的自动高速分析仪。该仪器也可以用于养殖、环保,水质现场对上述离子的测定。 相似文献
2.
3.
磷酸盐现场自动分析仪化学工艺优化研究 总被引：3，自引：0，他引：3
本文结合营养盐现场自动分析仪的研制,研究了磷酸盐分析所南各种试剂的用量及其作用,重点研究了低浓度磷酸盐的浓度与吸光值之间的关系以及温度对完全反应时间的影响,给出了０．００６～０．１２０ｍｇ／Ｌ范围内ＰＯ４－Ｐ浓度与吸光值的线性函数关系和较合适的完全反应温度,并且提出了现场自动分析仪的两点定标方法。 相似文献
4.
对《海洋调查规范》中测定海水 NO2 - N的常规方法进行了优化 ,达到简化操作过程 ,缩短分析时间以适应水下现场自动分析的目标。此外还对亚硝酸盐测定所使用的试剂及标准贮备液的稳定性进行了一系列的研究 ,改进试剂保存方法 ,延长试剂使用寿命 ,以满足长期现场测定的要求。 相似文献
5.
6.
7.
以营养盐自动分析仪为研究对象,研究海水氨氮测量过程中海水盐度效应的特点,并在此基础上研究降低盐度效应的方法。采用营养盐自动分析仪测量不同盐度标准溶液,标准曲线线性度都能达到0.999 0以上,说明海水盐度对分析仪标准曲线线性度基本没有影响;随海水盐度增加,标准曲线斜率呈增加趋势。通过对比15条不同盐度标准曲线测量准确性,确定在海水盐度已知情况下选取与被测海水盐度最为相近的人工海水定标能够最大程度降低盐度效应;在海水盐度未知或海水盐度变化较大情况下,以盐度15的人工海水定标,能够最大程度降低盐度效应对氨氮测量结果的影响。 相似文献
8.
根据《海洋监测规范》规定的总有机碳分析方法，利用HW－5610非色散红外CO2气体分析仪，设计制造成功总有机碳分析装置，对《海洋监测规范》的方法进行了根本的改进，方法成熟可靠，用该仪器和方法测定TOC，检出限低于0．01mg/L，性优于1％，达到了与进口TOC分析仪相近的分析精度及再现性，而该TOC分析仪的制造成本仅相当于进口仪器价格的1／10－1／5，值得海洋，河流、湖泊等有关监测和研究部门借鉴。 相似文献
9.
10.
海水中的颗粒有机碳(POC)是联系海洋生命与非生命过程最重要的参数之一,其在全球碳循环的作用异常重要,准确获取海水中颗粒有机碳的含量是揭示其重要作用的前提。目前,元素分析仪测定POC是其准确测定最常用的方法,但元素分析仪分析海水中颗粒有机碳过滤的膜样时,存在包样困难、滤膜对反应管损坏严重、灰分难以清理等问题,严重影响仪器的正常使用。本文采用总有机碳分析仪固体进样装置建立了海水中颗粒有机碳的分析方法,优化了样品前处理过程,对玻璃纤维膜进行了空白校正,考察了酸化方式和时间对测定结果的影响,方法检出限为CL(C)=0.019%。对青岛近海三个不同采样站位海水样品POC的测定结果相对标准偏差(RSD)为0.95%~2.66%(n=12),结果重复性好,精密度高,经国家标准样品水系沉积物GDS-9验证,结果与标准值符合,表明方法准确可靠,能满足海水中的颗粒有机碳(POC)的准确测定要求。所建立的方法完全克服了常规元素分析仪测定POC的弊端,同时降低了仪器的维护成本。 相似文献
11.
A high sensitivity manifold for the determination of trace quantities (nanomolar concentrations) of nitrate+nitrite and nitrite alone is described. The method uses a classical Technicon AutoAnalyzer II usually employed for shipboard analysis. A reproducibility of ± 1 nmol dm−3 for nitrate plus nitrite and nitrite alone was obtained, with an analytical rate of 40 samples h−1. 相似文献
12.
A chemiluminescent technique for the determination of nanomolar concentrations of nitrate and nitrite in seawater 总被引：1，自引：0，他引：1
C. Garside 《Marine Chemistry》1982,11(2):159-167
A chemiluminescent analysis technique for the determination of nanomolar quantities of nitrate, nitrate plus nitrite or nitrite alone in seawater is described. The method depends on the selective reduction of these species to nitric oxide which is then determined by its chemiluminescent reaction with ozone, using a commercial nitrogen oxides analyzer. The necessary equipment is compact and sufficiently sturdy to allow shipboard use. A precision of ±2 nM is claimed with analytical rates of 10–12 samples h?1, and modifications are discussed to allow doubling the analytical rate. 相似文献
13.
During 1985～1987,the concentration of nitrate nitrogen was higher in the Laizhou Bay and the Bohai Bay while that of nitrite nitrogen was higher in the Liaodong Bay and the Bohai Bay,The concentration of nitrate nitrogen was highest in winter and lowest in summer while that of nitrite nitrogen was highest in autumn and lowest in spring .the seasonal variation of the concentration of nitrate nitrogen was maximum in the Laizhou Bay and the Bohai Bay while that of the concentration of nitrite nitrogen was maximum in the Liaodong Bay.There was a great difference in the concentration of nitrate nitrogen between the surface and the bottom in autumn and in the concentration of nitrite nitrogen between the surface and the bottom in summer.The main reason for the seasonal variations of the concentration of nitrate nitrogen and nitrite nitrogen was the marine biochemical process.The nitrate nitrogen and nitrite nitrogen in the Bohai Sea basically maintained a quasi-equilibrium state seasonal cycle,The quesi-equilibrium state seasonal cycle of nitrate nitrogen and nitrite nitrogen at the bottom was stable while that at the surface was liable to variations caused by other factors. 相似文献
14.
Nitrite is chemically stable but photochemically unstable in seawater. The net disappearance rate in abiotic low-nitrate seawater exposed to sunlight is ～ 10% per day. The primary products are the free radicals NO and OH. Quantitative aspects of the kinetics and secondary product formation are discussed in terms of a fourteen-step reaction scheme. Possible pathways explaining the results are suggested but not unequivocally identified.The rate of reaction in various marine environments is estimated from cruise data and extrapolations to vary between 0.2–60·10?3 moles m?2yr?1, with a suggested global average for comparison purposes of 1–10·103 moles m?2yr?1.These results confirm and quantify our previous suggestion that nitrite photolysis represents a source of OH radical in seawater. The reaction rate is large enough that significant impacts on the geochemical cycles of dissolved organic carbon and nitrogen and heavy metals may plausibly result. Effects on marine biota and atmospheric trace gas composition are also possible. However, specific reactions coupling the nitrite system to other processes have not yet been identified or demonstrated empirically. 相似文献
15.
2008年春季对莱州湾小清河口的走航调查发现,调查区域大部分水体的DOC,CODMn,NH4+-N,PO43--P高于4类海水的限定值,处于严重污染状态。水体CHla的浓度范围在1.02~37.92μg/L之间,但DO饱和度却在23%~96%之间,盐度小于15水体的DO饱和度低于50%,水体缺氧严重。河口存在NO2--N含量偏高现象。由河口向外,NO2--N浓度逐渐增加,至盐度24.4的水体达到0.27 mg/L的高值,NO2--N增加主要是NH4+-N的硝化反应产生的。NH4+-N生成NO2--N主要受DO和NH4+-N比例与浓度的影响,DO饱和度在30%~70%,NH4+-N大于3.33 mg/L的水体中NO2--N生成速率最快。 相似文献
16.
17.
This paper describes the characteristics of a prototype of a modular multiparametric analyzer (MicroMAC FAST MP3) for automatic monitoring of seawater and analytical methods for nutrients.The MicroMAC FAST reactor is an evolution of the basic LFA (Loop Flow Analysis) reactor. It has been conceived to assay ammonium, nitrate–nitrite and orthophosphate at low concentration in seawater samples. A sample analysis is 3–4 times faster than that obtainable with a standard LFA reactor. With respect to the previous analyzer a temperature control (30–52 °C) on the measurement cell has been added (only for modules NH4 and PO4), while the colorimeter and the related links for transporting the sample have been moved beyond the Loop and form a hydraulic-optical set almost completely independent from the main LFA. All the steps of a wet-chemical colorimetric analysis method are carried out in an analysis cycle sequentially. The hermetic closed Loop provides full protection against background interference, which is a basic requirement for stable trace analysis. At the start of a cycle the loop is washed and filled with sample. The sample color is measured for compensation. Small amounts of concentrated reagents are added and mixed with high intensity. This new technique allows the preparation of two products of reaction which can be introduced at intervals of 150 s in the measurement cell. The intensity of the color of the reaction product is measured on the colorimeter using a monochromatic light beam of specific wavelength. The statistical test shows that the results of automated and manual analyses agree for all the examined parameters. Precision of all three analyses is ≤ 4% RSD.Multiparametric online analyzer: it is possible to connect the analytical modules to a data logger with analogue and digital signals, in order to have online simultaneous analysis of the sample. A typical application is used during research at sea which vessel does not require an operator. 相似文献
18.
Sequential injection spectrophotometric determination of nanomolar nitrite in seawater by on-line preconcentration with HLB cartridge 总被引：1，自引：0，他引：1
The unstable state of nitrite results in its very low concentration in seawater,which is below the limit of detection(LOD) of conventional techniques of analysis. Some sensitivity-enhanced methods have been proposed for the determination of nitrite at nanomolar level to illustrate the role of nitrite in the marine nitrogen cycle. However,most of previous reports are not widely accepted,because of their complexity and cost equipment or intensive labor requirement. In this study,a simple automatic system for the determination of nanomolar level nitrite using on-line preconcentration with spectrophotometric detection was described. An Oasis HLB cartridge was adopted to quantitatively enrich the pink-colored azo compound,formed from nitrite via Griess reaction. The cartridge was rinsed with water and ethanol(volume fraction is 55%,the same below) ,in turn,then eluted by an eluent containing 50% ethanol and 0.25 M(mol/dm 3 ) H 2 SO 4,and determined at 543 nm with a 2 cm path-length flow cell. Under the optimized experimental conditions,the calibration curve showed a good linearity in the range of 1.4-85.7 nM,and the LOD(3σ) was estimated to be 0.5 nM. The relative standard deviations of 7 measurements were 4.0% and 1.0% for the samples spiked at 7.1 and 28.6 nM,respectively. The recoveries for the different natural water samples were between 92.2%-108.4%. Each HLB cartridge could be reused for at least 50 times. As compared with other SPE methods,the advantages of this method included the free of interference from salinity variation and less sample consuming. The results of the application of the proposed method to natural water showed good agreement with liquid waveguide capillary cell detection method. 相似文献