where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   

7.
The Biology of Upogebia pusilla (PETAGNA) (Decapoda, Thalassinidea)     
Peter C.  Dworschak 《Marine Ecology》1988,9(1):51-77
Abstract. Populations of the thalassinidean shrimp Upogebia pusilla were studied on tidal flats in the Northern Adriatic Sea. Biometric analysis showed a sexual dimorphism, especially in propodus size. Size frequency distributions revealed the presence of large animals during all seasons; recruitment by juveniles occurred in autumn. Moult intervals and moult increments were determined in the laboratory and used to generate growth curves which were compared with those calculated from size frequency distributions. The life span of U, pusilla is over 5 years. Ovigerous females occurred between March and September. Egg numbers were high in spring, lower in summer and increased with body size. The incubation time of embryos was 35 days; a female produces an estimated number of three egg batches during the breeding season. A total annual production of 994 kJ was estimated for a theoretical population of 100 animals; 13.5 % is spent for somatic growth, 31 % for egg production of females, and 55.2% is lost as exuviae. The population structures, growth and breeding patterns, as well as embryonic and larval development within the Upogebiidae and Callianassidae are discussed.  相似文献   

8.
9.
多棘海盘车对太平洋牡蛎、紫贻贝、菲律宾蛤仔摄食选择性的研究   总被引:3,自引:0,他引:3  
刘佳  张秀梅 《中国海洋大学学报(自然科学版)》2012,(Z2):98-105
以多棘海盘车(Asterias amurensis)为试验对象,研究了多棘海盘车对3种双壳贝类的摄食选择性、摄食过程中用于搜寻和处理饵料生物的时间分配以及摄食机制等。试验以选择指数、捕食速率、日平均摄食率对多棘海盘车的摄食行为及搜寻和处理时间比进行了描述和统计。结果表明:各处理组多棘海盘车对菲律宾蛤仔的选择指数均为最高,占3种饵料生物的70%以上,显著高于太平洋牡蛎和紫贻贝(P<0.05),而各处理组对太平洋牡蛎的选择性均最低。多棘海盘车对菲律宾蛤仔的捕食速率和日平均摄食率显著高于太平洋牡蛎和紫贻贝。研究发现,在各处理组中多棘海盘车用于搜寻饵料生物的时间无显著差异,但随饵料密度的增加,用于处理饵料的时间逐渐减少。  相似文献   

10.
The Biology of Upogebia pusilla (PETAGNA) (Decapoda, Thalassinidea)     
Peter C.  Dworschak 《Marine Ecology》1987,8(4):337-358
Abstract. The distribution of the thalassinidean shrimp Upogebia pusilla was studied at four sites in the North Adriatic Sea: 1) a tidal flat in the lagoon of Grado, 2) a tidal flat at Lido di Staranzano near the mouth of the Isonzo, 3) a mud flat seawards of a salt marsh in a protected bay north of Rovinj, and 4) a sublittoral station in 6m depth near Aurisina. Information on grain size distribution, organic content, amount of debris, redox profiles and pH of sediment as well as temperature and salinity is given. Density, as determined by hole counts and a hole: burrow relationship derived from resin casting, generally increased with increasing water depth in the intertidal. The upper limits ranged between +10cm (Rovinj) and -20cm (Grado); densities between mean water and low water level varied strongly due to microtopography and macrophyte cover. Maximum densities in the intertidal ranged from 189 (Grado) to 2420 (Rovinj, juveniles) animals m2. Shrimp density at the sublittoral station ranged between 80 and 230 m"2. The zonation of the Upogebiidae and Callianassidae with respect to environmental parameters is discussed.  相似文献   

11.
12.
Juvenile form of the New Zealand turbot Colistium nudipinnis (Waite) (Pisces: Heterosomata: Rhombosoleinae) (note)     
J. A. Colman 《新西兰海洋与淡水研究杂志》2013,47(4):575-579
A juvenile (26 mm) specimen of the New Zealand turbot Colistium nudipinnis (Waite) is figured and described. Differences between the juvenile and adult forms, and characters distinguishing juvenile C. nudipinnis from the young of other New Zealand species of flatfish, are noted.  相似文献   

13.
14.
Leathery turtle (reptilia: Chelonia) in Foveaux Strait (note)     
D. Eggleston 《新西兰海洋与淡水研究杂志》2013,47(3-4):522-523
Further records of the leathery turtle, Dermochelys coriacea (Linnaeus), augment earlier records and perhaps indicate that this species may be a regular visitor.  相似文献   

15.
16.
开链冠醚2,6-二(8''''-喹啉氧甲基)-4-甲基-苯甲醚及其Ag( Ⅰ )、Cu( Ⅱ )、Ni( Ⅱ )配合物的合成与性质研究     
张前前  季振平  萧文锦  吴成泰 《中国海洋大学学报(自然科学版)》2001,31(3):420-424
设计合成一种尚未见文献报道的酚醚型双臂开链冠醚化合物L(L=2,6-二(8’-喹啉氧甲基)-4-甲基-苯甲醚),经元素分析、IR、1HNMR、MS等方法确定了其组成和结构。其Ag(Ⅰ)、Cu(Ⅱ)、Ni(Ⅱ)固体配合物的元素分析结果表明金属离子不同,则其配合物的配位比(M∶L)不同,Ag(Ⅰ)配合物为1∶1,Cu(Ⅱ)、Ni(Ⅱ)配合物为2∶3。并运用热重-差热分析对其热稳定性进行初步研究。  相似文献   

17.
Sexual size dimorphism in calanoid copepods (Centropagidae) from Patagonia (Argentina)     
RD Garcia  M Reissig 《新西兰海洋与淡水研究杂志》2013,47(4):504-514
Calanoid copepods of the genus Boeckella and Parabroteas (P. sarsi) are dominant in zooplankton communities of Patagonian lakes and ponds. This study addresses the occurrence of sexual size dimorphism in calanoid copepods of the genus Boeckella and in the monospecific genus Parabroteas occurring in 12 lakes and ponds of Patagonia (Argentina). The morphometric analysis performed showed that in all the species studied the female is larger than the male, although the difference in size among sexes was found to be variable between species. Interestingly, all species showed significant intraspecific stability in their sexual size dimorphism despite potential differences in their environments regarding predation pressure, environmental stability (permanent or temporary waters) and altitude distribution of populations. Finally, we discuss the potential implications of sexual dimorphism in terms of resource use and vulnerability to predation among other environmental forces which may play a role in promoting larger female to male size.  相似文献   

18.
19.
Arnoglossus boops (hector): A synonym of a. scapha (schneider) (pisces: Heterosomata: Bothidae)     
J. A. Colman 《新西兰海洋与淡水研究杂志》2013,47(4):693-697
The unique holotype of Arnoglossus boops Hector is compared with specimens of Arnoglossus scapha (Schneider). It is concluded that the two species are identical, and that A. boops is therefore a junior synonym of A. scapha.  相似文献   

20.
The barnacles Chirona (Striatobalanus) amaryllis (Darwin 1854) and Megabalanus coccopoma (Darwin 1854) (Crustacea,Cirripedia): two invasive species new to tropical West African waters     
《African Journal of Marine Science》2013,35(2):265-268
The collection of the barnacle Chirona (Striatobalanus) amaryllis (Darwin 1954) (Crustacea, Cirripedia) from the hull of a ship that had been operating for five months in the Gulf of Guinea and off Sierra Leone triggered a closer investigation of the cirriped fauna of the West African coast. Both C. amaryllis and Megabalanus coccopoma can now be added to the list of successful invasions in tropical West African waters. This discovery, as well as the circumstances of the findings, necessitates an update of the invertebrate faunal inventory of tropical West African marine waters.  相似文献   

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1.
在实验生态条件下研究了重金属离子(Cu2 、Pb2 、Hg2 、Cd2 )对日本鳃丝和肝胰脏显微结构(15d)的影响。观察结果表明:在2 mg/L Cu2 处理组,日本鳃叶不规则增厚,鳃腔相对扩大,其中血细胞明显增多;上皮层出现破坏:角质膜(CU)呈波状拱起,部分上皮细胞脱离角质膜形成大的空泡(VA);上皮细胞排列不规则,并与数目众多的血细胞充挤于血腔;肝胰脏中构成肝管的细胞发生严重崩解,只残留包被在外周的一层结缔组织的被膜。10mg/L Pb2 处理组鳃丝角质膜明显呈波状突起;肝管结构紊乱,开始出现大量空泡(VA)。0.1 mg/L Hg2 暴露下,鳃丝上皮层偶有溶解现象;肝胰脏肝细胞空泡化(VA)现象更为严重,细胞间界限不明显,肝细胞溶解,有些细胞核固缩;被膜中的结缔组织充血,出现血细胞浸润现象。1 mg/L Cd2 暴露下,鳃丝上皮层严重解体,只剩一层角质层,鳃腔相对扩大,部分区域有充血现象;肝胰脏出现细胞质溶解,细胞间界限不明显,血细胞浸润等现象。  相似文献   

2.
3.
The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log αM(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 1020 M− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log αM(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

4.
Alterations to nomenclature for two common intertidal New Zealand ‘top shells’ necessitated by re‐examination of type material have been confused by ambiguities in the way the alterations were first presented. We draw attention to recent misinterpretations and clarify the nomenclature. Condensed synonymies that indicate names used for each species during the interregnum are given, allowing papers dealing with these trochids to be read without uncertainty as to which species were really meant by the authors.  相似文献   

5.
A fossil seal jaw from the Early Pleistocene (Wanganui Series; Hautawan Stage) of Napier, New Zealand, is identified as that of an Ommatophoca rossi juvenile of less than 1.8 m body length.  相似文献   

6.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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