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皖北新元古代刘老碑组页岩的地球化学特征及其地质意义 总被引：16，自引：0，他引：16
从安徽北部新元古代刘老碑组页(泥)岩中采集了11个样品。地球化学分析表明,研究区南部的淮南和凤阳页岩样品SiO2、TiO2、Al2O3、K2O、TFeO和CaO含量分别为55.28%、0.87%、15.60%、2.99%、4.01%和5.83%,接近页岩平均值,只是CaO含量稍高。北部宿县地区页岩样品SiO2、TiO2、Al2O3、K2O、TFeO和CaO含量分别为57.01%、1.82%、20.97%、4.85%、3.31%和0.57%,与南部地区相比,TiO2和K2O含量显著偏高,是其2.1倍和1.6倍。刘老碑组页岩REE总量平均为219×10-6,LREE富集,La/Yb为14.2(9.8～18.6),Eu负异常,Eu/Eu*为0.60(0.54～0.63),但是北部页岩有更高的REE总量(295.8×10-6)和La/Yb比值(17.8)。微量元素分析表明,北部页岩中Sc、V、Zr、Nb和Th较高,南部Co和Pb较高。但是南部和北部却有比较一致的La/Sc(2.29±0.15)、Th/Sc(0.69±0.06)和La/Th(3.29±0.20)比值。La-Th-Sc和Th-Sc-Zr/10判别图清楚地表明,刘老碑组页岩形成于大陆岛弧构造环境,岛弧可能位于研究区的南部边缘。北部页岩明显偏高的TiO2和Al2O3含量以及化学风化指数(CIW)表明北部沉积物的源区经历了更强烈的风化作用。 相似文献
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淮南地区中—新元古代地层保存有大量精美的宏体碳质压膜化石和有机质壁微体化石,是新元古代大冰期之前生命演化的重要实证材料.然而,淮南地区中—新元古代地层的沉积时间仍未得到较好的约束,碎屑锆石年龄随地层层序的变化特征也未明确.为此本文对碎屑锆石数据较少的淮南寿县地区中—新元古代地层开展了系统的碎屑锆石U-Pb同位素测年.结果显示,八公山组碎屑锆石以古元古代锆石为主体,无小于1600 Ma的锆石;刘老碑组和寿县组碎屑锆石以中元古代锆石为主体,中元古代之前的锆石较少.综合已知的碎屑锆石年龄以及与邻区地层的对比,约束寿县组沉积时间为～950-～945 Ma,刘老碑组沉积时间为～1110-～945 Ma.淮南与鲁西地区中—新元古代地层的碎屑锆石年龄谱、沉积序列、沉积环境和化石产出相似,两地地层可相互对比.淮南地区中元古代早期及之前的碎屑锆石源区可能在华北克拉通东部,而中元古代晚期的碎屑锆石的源区则可能不在华北克拉通. 相似文献
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冰川底部富铁溶液氧化沉淀:塔里木北缘新元古界库鲁克赛铁矿床的成因 总被引：1，自引：1，他引：0
新元古代沉积变质铁矿床是继大氧化事件(GOE)后,沉积间断10亿年(~1800 Ma至~750 Ma)之后,再次大规模出现的一种沉积铁建造类型。这类铁建造与新元古代冰碛岩密切伴生,是新元古代雪球地球事件的重要证据。文章选择与新元古代雪球地球事件有关的沉积变质赤铁矿床—库鲁克赛铁矿进行研究,通过锆石U-Pb定年和区域地层对比工作限定其形成时代为新元古代青白口纪末期—南华纪早期。锆石年龄谱值对比和岩相学研究表明,铁矿床中的碎屑物质主要来自于青白口系下部独断山组石英砂岩地层。主、微量元素研究表明,库鲁克赛铁矿形成于相对富氧或者从贫氧向富氧变化的环境,其成矿元素应主要与陆源物质风化有关,可能有少量成矿元素来自于低温海底热液或海水。笔者认为,库鲁克赛铁矿的形成与成冰纪冰水沉积作用有关,来自冰下水体、从冰下通道中流出的富铁缺氧水溶液与富氧的表层海水混合时,成矿元素快速氧化沉淀,胶结冰水中的近源砾石,进而形成了此种富铁砾岩型铁矿。 相似文献
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赣东北婺源-德兴地区新元古代浅变质火山岩的地球化学和锆石U-Pb年龄 总被引：3，自引：1，他引：2
赣东北婺源-德兴地区新元古代地层中浅变质火山岩主要由变质玄武岩、英安岩和流纹岩组成.全岩地球化学分析表明浅变质玄武岩具有拉斑玄武岩的地球化学特征,起源于尖晶石辉橄岩低度部分熔融,英安岩岩浆起源于壳源杂砂岩部分熔融,流纹岩可能为英安质岩浆结晶分异的产物.LA-ICP-MS锆石U-Pb同位素定年揭示婺源浅变质英安岩形成于861±8Ma,德兴张村西浅变质流纹岩形成于860±3Ma,铜厂铜矿矿区凝灰质板岩形成于860±6Ma,均为早新元古代Tonian期.同时这些定年样品中保存了2.8 ～2.5Ga、2.0～1.7Ga和～1.0Ga的继承或捕获锆石记录.结合浅变质玄武岩和英安质火山岩的地球化学特征和成因,这套岩石最有可能形成于新元古代早期安第斯型活动大陆边缘弧后盆地构造背景. 相似文献
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下江群沉积地质特征及其对华南
新元古代构造演化的约束 总被引：3，自引：1，他引：2
华南西部新元古代裂陷纪大地构造属性和原型盆地性质是一个涉及到扬子古陆在全球构造中的定位、且争议较大的基础地质问题。新元古代下江群发育于强变形变质的盐边群和弱变形变质的板溪群之间, 处于以滨浅海沉积为主的板溪群向深海沉积转化的过渡带内。下江群以浊流沉积的杂砂岩为主, 沉积物扩散方向指向西。下江群清水江组砂岩骨架颗粒统计分析表明, 物源来自再旋回造山带。常量元素地球化学特征显示, 下江群碎屑岩系形成于活动陆缘区的弧后盆地靠大陆一侧。结合盐边群、苏雄组大地构造属性及其与下江群的空间关系, 推测当时的华南西部处于汇聚型板块边缘内, 总体属弧后伸展型盆地。 相似文献
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为探讨江南造山带东段新元古代构造演化机制,对江南造山带东段登山群砂岩及火山岩进行锆石U-Pb年代学及地球化学研究.SHRIMP锆石U-Pb定年显示登山群高山组凝灰岩年龄为855.5±8.2 Ma,叶家组流纹岩年龄为798.1±7.8 Ma.地球化学数据显示高山组砂岩物源区为大陆岛弧,形成于弧后盆地;叶家组火山岩为双峰式火山岩,流纹岩轻稀土富集,重稀土亏损;高FeOt/（FeOt+MgO）和Ga/Al值、低CaO、MgO,εHf（t）值为7.9~10.9,富集Ba、Th、U等大离子亲石元素和高场强元素,强烈亏损Sr、P、Ti的特征显示其为典型的A型花岗岩,来自初生地壳的部分熔融;玄武岩属拉斑玄武岩系列,具有OIB特征,富集轻稀土及大离子亲石元素,来自软流圈地幔的部分熔融.双峰式火山岩形成于板内伸展背景.年代学及地球化学结果表明新元古代江南造山带东段扬子与华夏板块拼贴时限为855~800 Ma之间.造山结束之后地幔物质上涌,华南板块进入裂谷期. 相似文献
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风化壳的元素地球化学组成可以反映风化壳的发育类型及其气候特征,地史时期形成的古风化壳的元素地球化学组成可以揭示古风化壳的类型及其古气候特征.华北地区新元古代晚期（景儿峪组）至寒武纪（府君山组）期间的地层记录缺乏连续性,广泛发育一套典型的古风化壳,该古风化壳的发育过程可能记录了晚新元古代至早寒武纪期间的古气候特点.针对华北房山地区景儿峪组顶部保存的古风化壳中常量元素的组成、元素迁移富集特征和风化系数等分布规律开展了较系统分析,结果表明:（1）SiO2、Al2O3、TFe2O3、CaO是景儿峪组顶部古风化壳的主要组分,Al2O3、TFe2O3、TiO2、K2O在风化壳的中上部相对富集,SiO2则轻微亏损,CaO、Na2O、MgO、P2O5被迁移淋失;（2）硅铝系数、硅铝铁系数、化学蚀变指数（CIA）、残积系数、风化淋溶系数（BA）等地球化学指标的垂向变化特征指示该古风化壳形成于温暖湿润条件下中等强度的化学风化作用,其风化过程可能经历了由较弱至较强再逐渐减弱的演变过程;（3）与现代发育于湖南、贵州、云南等地碳酸盐岩类基岩之上的风化壳元素地球化学特征对比,发现景儿峪组顶部古风化壳的Si淋失度和Fe、Al富集度均较低.综合研究区古风化壳的常量元素地球化学特征,同时结合新元古代晚期至寒武纪的华北板块古纬度迁移特征,认为房山地区景儿峪组顶部发育的古风化壳形成于温暖湿润的亚热带-热带气候,为脱硅富铝化程度较低的硅铝粘土型风化壳. 相似文献
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新元古代冰期事件记录了“雪球地球”事件重要的地质信息。塔里木盆地周缘新元古代冰碛岩地层露头发育,是研究新元古代冰期事件的理想基地。由于发育多套新元古代火山岩,盆地东北缘库鲁克塔格地区新元古代冰碛岩地层时代已获得较多年代学数据约束;但盆地周缘其他地区新元古代冰碛岩地层公开报道年代学数据较少,不能准确限定其沉积时代,导致冰期事件对比存在争论。为此,本文选择塔里木盆地研究程度较低的西南缘叶城地区新元古代冰碛岩地层,开展岩石学、同位素年代学、岩石地球化学等研究,明确其冰期沉积特征,约束其沉积时代,开展冰期事件对比,讨论古气候风化条件等。南华系波龙组和雨塘组冰碛岩地层具有较低的化学蚀变指数(CIA),分别代表新元古代2次寒冷的冰川气候记录。冰川沉积及其相邻层位的碎屑锆石U-Pb年代学数据显示,波龙冰期的起始年龄晚于(710±13) Ma,与全球Sturtian冰期对应;雨塘冰期的起始年龄不会早于(656±18) Ma,其结束年龄可被南华系顶界年龄635 Ma或上覆震旦系库尔卡克组碎屑锆石年龄(634±9) Ma限定,与全球Marinoan冰期对应。 相似文献
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华南新元古代沉积盆地演化与Rodinia超大陆裂解存在紧密联系,但仍缺乏精细刻画.对扬子西缘澄江组开展了系统的碎屑锆石年代学和沉积学研究.澄江组砂岩的碎屑锆石U-Pb年龄主要为新元古代（870~780 Ma）,少数为前新元古代（2 850~1 010 Ma）,最显著的峰值为820 Ma,最年轻一组碎屑锆石206Pb/238U年龄加权平均值为804.5±5.4 Ma.结合已发表年龄数据,将澄江组沉积时限进一步限定为800~720 Ma.物源分析揭示澄江组的新元古代碎屑锆石剥蚀自邻近的新元古代岩浆岩,而前新元古代锆石可能来自于邻近新元古代岩体的剥蚀或地层的沉积再循环.扬子西缘新元古代中期沉积盆地具有由冲积扇相逐渐过渡为前扇三角洲相的沉积演化序列,最终形成了具有裂谷充填特征的“楔状地层”.这种沉积超覆演化过程在整个华南新元古代裂谷系普遍存在,指示在800 Ma左右华南全面进入裂谷盆地成熟阶段. 相似文献
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Sandstones from the Neoproterozoic Jinshanzhai Formation in northern Anhui Province, China, were analyzed for major oxides and trace elements to infer their provenance, the intensity of paleo-weathering of their source rocks and the depositional tectonic setting. Diagrams of (SiO2/20)-(Na2O+K2O)-(MgO+TiO2+FeO*), TiO2-Ni, Th-Hf-Co, Hf-La/Th and some ratios of elements indicate that felsic rocks constitute the source rocks in the provenance. The values of Chemical Index of Alteration (CIA) are low, which are considered to be affected by K-metasomatism. Whereas the high CIW (Chemical Index of Weathering) values indicate intensive weathering of the source material. Plots of sandstones on bivariate and triangle discriminant diagrams, as well as ICV (Index of Compositional Variation) values revealed that they were deposited on a passive continental margin or in an intra-plate basin. Our recent study, in combination with previous studies and the research progress of the Rodinia super continent, demonstrated that the convergence and extension of the Rodinia super continent were preserved by twice extension as expressed by petrological variation of the southeastern margin of the North China Craton (NCC) during the Neoproterozoic. 相似文献
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Akhtar R. Mir V. Balaram Javid A. Ganai Shamim A. Dar A. Keshav Krishna 《中国地球化学学报》2016,35(4):428-436
The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si2O versus K2O/Na2O tectonic setting diagram. 相似文献
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东昆仑地区发育一套显生宙碎屑岩地层,包括下寒武统沙松乌拉组、中—上奥陶统纳赤台群、上石炭统—下二叠统浩特洛哇组、下三叠统洪水川组、中三叠统希里科特组以及上三叠统八宝山组。研究区砂岩的CIA值反映沙松乌拉组砂岩源区化学风化程度较高,其余各组砂岩源区化学风化程度较低。主量和微量元素研究结果表明各组砂岩源区以长英质岩石为主,包含少量中性成分。La、Ce、Th、U、∑REE含量和La/Sc、Th/Sc、Sc/Cr、La/Y比值指示沙松乌拉组和纳赤台群砂岩沉积环境为大陆岛弧或活动大陆边缘,浩特洛哇组砂岩形成于被动大陆边缘环境,洪水川组砂岩沉积环境为活动大陆边缘,希里科特组砂岩的微量元素含量及其比值接近于活动大陆边缘和被动大陆边缘,八宝山组砂岩沉积环境为活动大陆边缘。综合分析认为沙松乌拉组和纳赤台群砂岩形成于原特提斯洋俯冲阶段,浩特洛哇组砂岩形成于古特提斯洋持续扩张阶段,洪水川组砂岩形成于古特提斯洋俯冲阶段,希里科特组砂岩形成于陆(弧)陆初始碰撞阶段,八宝山组砂岩形成于陆陆全面碰撞—碰撞后阶段。 相似文献
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The characteristics of source rocks and weathering of Palaeoproterozoic phyllitic rock of Mahakoshal Group and Mesoproterozoic shales and siliciclastics of Vindhyan Supergroup exposed in Son Valley, Central India have been investigated by analyzing their chemical compositions. The investigations pertaining to the relationship between major-elements were carried out along Parshoi, Chitrangi, and Markundi areas of Son valley, Central, India. The studied rock strata have been classified into three categories namely phyllitic rocks, shales and sandstone.The A-CN-K ternary diagram, CIW, CIA, MIA, and ICV values indicate about the similar provenance or source rocks subjected to severe chemical weathering, under dry and hot-humid climates in a basic and acidic environment with changing lower to higher PCO2 of continental flora. Various geochemical discriminantts diagrams, elemental ratios suggest that rocks are derived from post-Archaean-Proterozoic igneous source. The igneous source was mainly granite with a minor contribution of granodioritic rock, in a passive margin setting. The sediments responsible for formation of shale and sandstones were most likely deposited in the interglacial period in between the Mesoproterozoic and Neoproterozoic glacial times. Compositionally the sandstones is distinctive of cratonic environments with their passive continental margin setting. However, the phyllities of Mahakoshal Group suggests their formation under lower weathering conditions in dry climatic conditions which were operating on more intermediate to basic igneous rocks with abundance of mafic minerals. 相似文献
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M. Khanehbad R. Moussavi-Harami A. Mahboubi M. Nadjafi 《Geochemistry International》2012,50(9):777-790
The Sardar Formation (Carboniferous) has a lithological variation that is characterized by sandstone, shale and limestone members. Shales of the Sardar Formation from the east central Iran have been analyzed for major elements and a number of trace elements. The shales of Sardar Formation are rich in quartz minerals and clay minerals of the bulk minerals. Clay minerals of shales are composed of illite, kaolinite and slightly montmorillonite. SiO2 versus K2O/Na2O diagram shows these shales plotted in the passive continental margin or cratonic field. Geochemical data suggest high acidic source rocks similar to granite and intermediate igneous rocks. CIA and ICV suggest semi-humid climatic conditions during depositions and indicate high chemical weathering in the source area. The geochemical parameters such as V/Cr, Ni/Co and Cu/Zn ratios indicate that these shales were deposited in oxic environment. 相似文献
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Mohammad KHANEHBAD Reza MOUSSAVI-HARAMI Asadollah MAHBOUBI Mehdi NADJAFI Mohammad Hosein MAHMUDY GHARAIE 《《地质学报》英文版》2012,86(5):1200-1210
Geochemical analysis of sandstones from the Sardar Formation (from two stratigraphic successions) in east-central Iran were used for identification of geochemical characterization of sandstones, provenance and tectonic setting. Sandstones in the two lithostratigraphic successions have similar chemical compositions suggesting a common provenance. Bulk-rock geochemistry analysis of Carboniferous sandstones from Sardar Formation indicates that they are mainly quartz dominated and are classified as quartzarenites, sublitharenites and subarkoses, derived from acid igneous to intermediate igneous rocks. Discrimination function analysis indicates that the sandstones of Sardar Formation were derived from quartzose sedimentary provenance in a recycled orogenic setting. Also, major and trace elements in sandstones of Sardar Formation (e.g., K2O/Na2O vs. SiO2) indicate deposition in a stable passive continental margin (PM). Chemical index of alteration (CIA) for these rocks (> 65%) suggests a moderate to relatively high degree of weathering in the source area. 相似文献
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《Chemie der Erde / Geochemistry》2019,79(1):94-112
To constrain the tectonic evolution of the eastern segment of the Paleo-Asian Ocean, we conducted zircon U–Pb-Hf dating and whole-rock geochemical analyses for metasedimentary rocks from the Dongnancha Formation in the Huadian area in central Jilin Province, Northeastern (NE) China. Most detrital zircons from the metasedimentary rocks display clear oscillatory zoning and striped absorption in cathodoluminescence (CL) images and have Th/U ratios of 0.1–1.8, thus indicating a magmatic origin. U–Pb isotopic dating using LA-ICP-MS method for zircon samples from the metasedimentary rocks reveals that the depositional age can be constrained to the period between 250 and 222 Ma. Geochemical data reveal low to intermediate degrees of weathering of the source material and compositionally low to intermediate maturity. Detailed analyses of detrital zircon U–Pb-Hf geochronology and geochemistry show that these metasedimentary rocks are derived from a bidirectional provenance. The predominant derivation is from Permian–Early Triassic felsic-intermediate igneous rocks of central Jilin Province and adjacent regions in the northern margin of the North China Craton, although felsic-intermediate igneous rocks and continental material in the eastern segment of the Central Asian Orogenic Belt from the Cambrian–Carboniferous represent additional sources and minor amounts of Paleoproterozoic–Neoproterozoic material have been input from the North China Craton. A number of geochemical indicators and tectonic discrimination diagrams collectively indicate a continental island arc-active continental margin setting for the deposition of the protoliths of the metasedimentary rocks. The results of geochemical and geochronological analyses of the provenance and tectonic setting of the metasedimentary rocks indicate that the Dongnancha Formation was likely deposited in an intermountain basin in a post-orogenic fast uplift setting, suggesting that the final closure of the eastern segment of the Paleo-Asian Ocean in the Huadian area of central Jinlin Province likely occurred between the Early Triassic and Middle Triassic. 相似文献
19.
关于塔里木北缘南华-震旦纪的构造演化存在争议,本文研究了其东北缘库鲁克塔格地区南华系阿勒通沟组的沉积环境、地球化学特征等方面,揭示其源区风化、物源类型和构造背景等信息,以期为塔北同期构造演化及古地理环境恢复提供更多证据。阿勒通沟组由底部的冰碛砾岩和之上发育细密纹层的细砂-粉砂-泥岩组成,砂岩中发育丘状交错层理、渠模等典型风暴沉积构造,可识别出3种风暴沉积序列,为风暴浪控浅海陆棚沉积,是阿勒通沟组冰期和特瑞艾肯组冰期分属两个冰期的有力证据。该组宽广陆棚相的沉积环境,砂岩较高的结构成熟度及V-Cr-Ni-Sc负异常、Ti-Hf-Zr-Y正异常等地球化学特征皆显示其处于被动大陆边缘。物源判别图解、过渡族元素含量和稀土配分特征显示该组砂岩主要碎屑物质为来自南部塔里木克拉通的长英质岩类,另有古老沉积岩的加入。砂岩样品CIA值、A-CN-K图解和Th／U比值等显示其源区经历了微弱-中等的化学风化,碎屑物质具沉积分选、沉积物再旋回特征,且在成岩过程中钾交代明显,这些特征也与被动大陆边缘一致。在此基础上,结合前人研究成果认为库鲁克塔格自贝义西组裂解至阿勒通沟组演化为被动大陆边缘,且至少持续到震旦系扎摩克提组。 相似文献