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1.
西藏冈底斯带中段以东得明顶地区晚白垩世花岗岩类锆石U-Pb年代学和地球化学证据 总被引：2，自引：0，他引：2
得明顶地区花岗岩位于西藏冈底斯火山岩浆弧中段以东,主要岩石类型有:石英闪长岩、石英二长闪长岩、英云闪长岩、黑云花岗闪长岩、斑状黑云二长花岗岩,岩石具钙碱性特征,w(SiO2)在57.19%～71.78%之间,K2O/Na2O=0.39～0.98,相对富钠,A/CNK=0.80～1.02,Al2O3变化于13.64%～18.74%之间,为准铝质岩石,花岗岩体稀土元素总量ΣREE变化于94.69×10-6～227.28×10-6之间;轻稀土元素富集,负Eu异常由不明显到明显,富K,Rb,Ba,Th等大离子亲石元素和亏损Nb,Y,Yb等高场强元素为特征。岩石学和岩石地球化学研究表明,该时期的花岗岩有由中性向酸性演化的规律,为同源岩浆,具俯冲I型花岗岩的特点,形成于板块俯冲下的岛弧环境。冈底斯岩带中东段雪拉岩体花岗闪长岩锆石的SHRIMPU-Pb年龄为70.4Ma±2.2Ma,表明冈底斯岩浆弧带在白垩世从早到晚岩浆均在剧烈地活动,是新特提斯洋向北俯冲作用的产物。 相似文献
2.
青海祁漫塔格中晚三叠世花岗岩:年代学、地球化学及成矿意义 总被引：39，自引：12，他引：27
地处柴达木盆地西南缘的青海祁漫塔格地区不仅是一个特征显著的构造-岩浆岩带,而且也是重要的多金属成矿带。本文对该区中晚三叠世花岗岩开展了详细的年代学、岩石地球化学及Sr-Nd-Pb同位素组成研究,并探讨了成矿意义。结果表明,本区中晚三叠世花岗岩均系准铝质到弱过铝质高钾钙碱性花岗岩类,晚三叠世花岗岩具有更高的K2O/Na2O比值,富集大离子亲石元素(LILE)和轻稀土元素(LREE),明显亏损高场强元素(HFSE),中等初始锶比值和偏负的εNd(t)值表明它们主要源于古老地壳物质的深熔或重熔,并可能有幔源物质的加入;发育闪长质暗色微粒包体的中三叠世花岗岩锆石U-Pb年龄为230～237Ma,大多具斑状或似斑状结构的晚三叠世高分异富钾花岗岩形成于204～228Ma,表明大约240Ma祁漫塔格主造山已由挤压转入伸展并伴有幔源岩浆活动,晚三叠世后演化到后碰撞阶段;中晚三叠世花岗岩与本区密集产出的矽卡岩型和斑岩型多金属矿床的时空与成因关系密切,具有重要找矿指示意义。 相似文献
3.
滇西南澜沧江带官房地区三叠纪火山岩地质地球化学特征及其构造环境 总被引：3，自引：1，他引：3
官房地区火山岩属三江构造带南澜沧江构造岩浆带北段,中晚三叠世喷发了一套由中三叠统忙怀组酸性火山岩和上三叠统小定西组基性火山岩组成的火山岩系。忙怀组酸性火山岩以高硅、富钾、低钛为特征,SiO2含量平均为75·49%,K2O含量平均为3·88%,TiO2含量平均为0·136%,A/CNK>1·1(平均为1·53),属高钾钙碱性流纹质火山岩类;∑REE平均为276·85×10-6,富集轻稀土元素,具强Eu负异常,微量元素在蛛网图上显示出K、Rb、Ba、Th强烈富集,而Ti、P则明显亏损。小定西组也以富钾为特征(K2O含量平均为2·68%),里特曼指数σ在2·23~9·24之间(平均为6·27),为高钾钙碱性玄武岩钾玄岩系列,∑REE平均为171·83×10-6,轻度富集轻稀土元素,稀土元素配分型式为缓右倾斜平坦型,无Eu或弱的负Eu异常;微量元素配分模式以K、Rb、Ba、Th强烈富集,Ti、Y、Yb、Cr则明显亏损为特征。南澜沧江带三叠纪火山岩系的地质、岩石组合和地球化学特征表明其为活动大陆边缘弧的产物。 相似文献
4.
西藏冈底斯岩浆岩带除了大范围分布的晚白垩世以来的花岗岩类以外,还发育少量晚三叠世—侏罗纪花岗岩,目前关于其岩石成因还存在很多争议。为了进一步认识冈底斯早侏罗世花岗岩的岩浆起源,本文选择代表性的加查县香木村英云闪长岩开展了岩相学、岩石地球化学、锆石U-Pb年代学和Hf同位素研究。所研究的英云闪长岩主要由斜长石、石英、黑云母和少量的角闪石组成。LA-ICP-MS锆石U-Pb定年结果表明其结晶年龄为184±4Ma。锆石εHf(t)值均为正值,变化范围为7.9~10.3。在全岩地球化学组成上,英云闪长岩为中钾钙碱性、准铝质,并具有埃达克质岩石特征:高SiO2、Al2O3、Na2O/K2O(1)和Sr/Y(35.5~106),低Y(4.46×10-6~12.9×10-6)和Yb(0.51×10-6~1.39×10-6),富集Rb、Ba、K、Pb等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素。在稀土元素配分图中呈现轻稀土元素富集、中稀土亏损的右倾"凹"型的式样,无明显Eu异常。岩石地球化学和锆石Hf同位素特征表明其岩浆可能起源于下地壳基性物质的部分熔融,残留相主要为角闪石、石榴子石,无斜长石。综合前人资料,冈底斯晚三叠世—早侏罗世花岗岩的锆石Hf同位素具有由西向东、由南向北逐渐富集的规律,反映古老地壳组分的贡献逐渐增多,这暗示了南冈底斯带东部也可能存在古老的地壳基底。 相似文献
5.
西藏错龙错晚三叠世粗粒巨斑二长花岗岩锆石U-Pb年龄和地球化学特征 总被引：1，自引：1，他引：0
对出露于冈底斯中带偏西部错龙错地区原划为早白垩世的粗粒巨斑二长花岗岩进行了较系统的岩石学、LA-ICP-MS锆石U-Pb定年、地球化学研究。结果表明,该地区粗粒巨斑二长花岗岩的成岩年龄为212.6±2.7Ma,属晚三叠世。岩石为高钾钙碱性-钾玄岩系列,具高SiO_2、K_2O的特征。Al_2O_3含量为13.18%~16.26%,铝饱和指数A/CNK为0.96~1.33(平均值为1.11),为准铝质-过铝质花岗岩。稀土元素总量在182.99×10~(-6)~324.34×10~(-6)之间,轻稀土元素明显富集,重稀土元素相对亏损,δEu值变化于0.38~0.57之间,具明显的负Eu异常。微量元素富集K、Rb、Th和相对亏损Ba、Nb、Sr、P、Ti,具有类似造山后花岗岩的微量元素特征。该类岩石的地球动力学背景应为班公湖-怒江洋壳南向俯冲有关的由挤压向伸展转变的同碰撞向后碰撞的过渡阶段。 相似文献
6.
青海鄂拉山地区陆相火山岩地球化学特征及构造环境 总被引：2，自引：0，他引：2
鄂拉山岩浆岩带晚三叠世火山岩为中-中酸性火山岩组合,由玄武安山岩、安山岩、英安岩、流纹岩及少量火山碎屑岩等组成,岩石蚀变强烈,成层性差,柱状节理发育,具典型的陆相喷发特点.火山岩属铝饱和类型,里特曼指数(δ)及岩石学等显示具钙碱性特征, (FeO/MgO)、K2 O/Na2O显示可能具有陆缘岛弧环境的特性;轻稀土元素分馏程度高且富集,δEu小于1,为弱负异常,稀土元素配分模式曲线与岛弧型稀土元素配分模式图相似;微量元素Rb、Ba、Th等元素明显富集,而Ti、Y、Yb、Sc、Cr等元素较亏损.Nb/Zr、La/Nb、Th/Ta、Th×Ta/Hf2等特征反映鄂拉山组火山岩产于陆缘火山弧环境.结合区域地质背景、岩石地球化学及构造环境等特征,认为鄂拉山地区晚三叠世火山岩产于大陆碰撞与陆缘弧并存的环境. 相似文献
7.
西藏冈底斯带昂仁县措迈乡差绒—丁欧复式花岗岩岩石类型为石英闪长岩、黑云二长花岗岩和二长花岗岩,各侵入体之间为突变接触关系,闪长岩U- Pb同位素年龄为155.4±2.7Ma;黑云二长花岗岩U- Pb同位素年龄为152.0±13Ma、153.96±0.92Ma,时代均为晚侏罗世。岩石地球化学显示三者均为高钾钙碱性系列岩石,石英闪长岩为弱铝质―准铝质;黑云二长花岗岩和二长花岗岩则为准铝质—过铝质。黑云二长花岗岩和二长花岗岩相比石英闪长岩表现为富硅、富碱、贫Ca、Ti、Mg,轻稀土元素更富集,轻稀土分馏程度更高,分异更加明显的特点,微量元素二长花岗岩Ba、Sr、P、Ti亏损最为明显,黑云二长花岗岩的Rb、Th、K富集最为明显,石英闪长岩相比黑云二长花岗岩和二长花岗岩的Rb/Sr（0.18~0.46）、Rb/Ba值（0.13~0.26）最低,指示其分异演化程度较低。差绒—丁欧花岗岩应是同时代不同期次侵入的复式岩体,早期为I型的石英闪长岩和黑云二长花岗岩,晚期为S型二长花岗岩,该复式岩体并非产出于单一的俯冲环境,二长花岗岩可能为弧陆碰撞时的产物。 相似文献
8.
那陵郭勒河中游位于东昆仑西段祁漫塔格地区,分布着大量的花岗岩。对该地区晚三叠世侵入岩的研究有助于认识东昆仑造山带印支期构造-岩浆演化历史。对研究区内花岗岩进行了岩石学、年代学及岩石地球化学分析。分析结果表明,研究区花岗闪长岩和二长花岗斑岩锆石LA-ICP-MS U-Pb年龄分别为(225.7±1)Ma、(213.74±1)Ma,为晚三叠世岩浆活动产物。岩石地球化学分析结果显示,该地区晚三叠世侵入岩属高钾钙碱性系列,饱和铝指数显示为偏铝质到过铝质,富集Rb、Th、K等大离子亲石元素和轻稀土元素,明显亏损Nb、P、Ti等高场强元素。花岗岩具有I型花岗岩特征,具有板块俯冲阶段的特征。通过分析认为岩浆岩形成于板块碰撞前的火山弧环境中。 相似文献
9.
呼吉尔岩体位于索伦山-西拉木伦缝合带北侧,由中细粒黑云二长花岗岩、中细粒二长花岗岩、细粒二长花岗岩组成。岩石具高Si、高碱、低Al特征,为亚碱性系列岩石,岩石分异程度较高,属于I型花岗岩。岩石的稀土元素含量整体略低,配分曲线为低缓右倾型,重稀土元素分布较为平缓,具Eu负异常。岩石的大离子亲石元素富集、高场强元素亏损。锆石的LA-ICP-MS定年结果显示,中细粒黑云二长花岗岩、中细粒二长花岗岩、细粒二长花岗岩的U-Pb加权平均年龄值分别为(291.7±1.3)Ma、(281.6±1.6)Ma、(289.1±1.3)Ma,岩体形成于早二叠世陆缘弧环境。 相似文献
10.
额尔宾山花岗岩岩体位于南天山晚古生代侵入岩带,对该花岗岩进行锆石U-Pb定年获得296.1±1.8Ma的年龄,为早二叠世。岩石主量元素分析结果表明,该花岗岩的Si O2含量为66.96%~67.3%,富碱(Na2O+K2O=7.53%~7.97%),K2O/Na2O1(1.15~1.27),属高钾钙碱性系列岩石;Al2O3为15.56%~15.62%,Al2O3K2O+Na2O+Ca O,属于过铝型。岩石稀土元素配分模式呈现轻稀土元素(LREE)富集((La/Yb)N=27.03~30.62)、重稀土元素(HREE)亏损((LREE/HREE)=18.2~20.1)、具有中等程度的负Eu异常(δEu=0.64~0.68)。微量元素判别结果显示,其具有I-A型花岗岩过渡的特征。结合区域地质背景综合分析,初步认定该岩体可能形成于南天山同碰撞向后碰撞构造体制转换时期,据此可以推测南天山洋盆闭合时限至少应该在早二叠世以前。 相似文献
11.
Police, politics, and the right to the city 总被引：1，自引：0，他引：1
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete. 相似文献
12.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
13.
I. M. Gorokhov M. A. Semikhatov M. M. Arakelyants E. A. Fallick N. N. Mel’nikov T. L. Turchenko T. A. Ivanovskaya T. S. Zaitseva E. P. Kutyavin 《Stratigraphy and Geological Correlation》2006,14(3):260-274
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation. 相似文献
14.
Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA 总被引：1，自引：0，他引：1
Joseph L. Domagalski Steven P. Phillips E. Randall Bayless Celia Zamora Carol Kendall Richard A. WildmanJr Janet G. Hering 《Hydrogeology Journal》2008,16(4):675-690
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. 相似文献
15.
扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究 总被引：7，自引：3，他引：4
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。 相似文献
16.
Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean 总被引：2，自引：0，他引：2
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston
situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine
fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and
at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological
(i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates)
controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution
sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were
<20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf
of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is
lost to sediments. 相似文献
17.
18.
V. Yu. Prokof’ev L. D. Zorina V. A. Kovalenker N. N. Akinfiev I. A. Baksheev A. N. Krasnov G. A. Yurgenson N. V. Trubkin 《Geology of Ore Deposits》2007,49(1):31-68
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type. 相似文献
19.
山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义 总被引：10，自引：0，他引：10
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。 相似文献