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1.
对北山造山带小红山地区三叠纪花岗斑岩锆石U-Pb年龄、锆石Hf同位素和全岩地球化学组成进行了研究。LA-MC-ICP-MS锆石U-Pb测年结果显示,2个花岗斑岩样品的锆石~(206)Pb/~(238)U年龄为211.8±1.6 Ma和205.9±1.7 Ma,显示花岗斑岩的侵位时代为晚三叠世晚期。花岗斑岩具有高硅、富碱、准铝,贫钙、镁、铁的特征,属于高钾钙碱性至钾玄岩系列,分异程度较高,属高分异I型花岗岩,富集Rb、Th、U、La、Ce等大离子亲石元素,亏损Nb、P、Ti等高场强元素和Ba、Sr,表现出低Sr,高Yb和Y的特点,并具有明显的负Eu异常。ε_(Hf)(t)值较高(-1.43~9.93),Hf同位素地壳模式年龄T~C_(DM)为610~1335 Ma,指示花岗斑岩均源于具有幔源烙印的新生地壳并混有重熔的古老地壳。结合最近获得的数据及区域地质资料,提出在后造山伸展体制下,基性岩浆底侵带来的热导致新元古代—古生代新生地壳的部分熔融,并遭受了下元古界古老地壳重熔的岩浆混染,形成的岩浆经过分离结晶作用,最终在中上地壳侵位形成了晚三叠世花岗斑岩。  相似文献   

2.
杜保峰  何凯  杨长青  蔡志超  鲁培庆  耿爱宾 《地质论评》2022,68(3):2022062012-2022062012
则不吓铅锌矿床位于冈底斯成矿带西段,西藏谢通门县境内,矿区发育大量钾长花岗斑岩,其与铅锌成矿存在密切联系。通过对其开展岩石学、LA-MC-ICP-MS锆石U-Pb年代学和岩石地球化学研究,探讨区内钾长花岗斑岩岩石成因、侵入时代及其与铅锌成矿之间的关系。岩石地球化学结果显示,钾长花岗斑岩具高硅、富钾而贫镁特征,A/CNK值介于1.08~1.38之间;REE具有较明显中等负Eu异常,总体呈现右倾的轻稀土富集特征,微量元素富集Rb、K、U、Th、Pb等大离子亲石元素,而Ba、Sr和Nb、Ta、Ti、P等高场强元素相对亏损。岩石地球化学研究表明钾长花岗斑岩属分异的S型花岗岩。锆石U-Pb测年结果显示,钾长花岗斑岩侵位年龄为14.18±0.15 Ma,系中新世岩浆作用产物,与印度—亚洲大陆碰撞后伸展背景下的引张构造有关,并与冈底斯成矿带中新世大规模斑岩侵位时代和相关斑岩型铜(钼)矿化时代一致,可能具有相同的成岩成矿环境,这为在该成矿带西段寻找与斑岩有关的铅锌矿床提供了参考。  相似文献   

3.
云南镇沅地区位于哀牢山构造带中段,是古特提斯哀牢山洋关闭及碰撞造山的关键部位。本文对该地区出露的花岗斑岩进行了年代学、岩石地球化学与同位素地球化学研究。锆石U-Pb年代学给出加权平均年龄为253.3±2.0Ma,表明花岗斑岩形成于晚二叠世。3个花岗斑岩脉共5个样品分析结果表明,其SiO_2含量65.30%~70.79%,全碱含量(K_2O+Na_2O)3.53%~4.39%,Al_2O_3含量13.42%~16.40%,为高钾钙碱性亚碱性系列岩石,成分上与花岗闪长岩类似,为S型花岗岩。稀土元素含量较低,轻重稀土分异程度较高,稀土配分曲线为右倾,无明显Ce异常,具弱负Eu异常,微量元素配分曲线为右倾,大离子亲石元素相对富集,高场强元素相对亏损,与典型地壳相一致。锆石Hf同位素ε_(Hf)(t)为-1.0~4.1,显示岩浆源区为亏损地幔和古老地壳物质部分熔融。岩石大地构造环境分析表明,该花岗斑岩形成于晚二叠世同碰撞构造环境。  相似文献   

4.
甘肃公婆泉铜矿是我国西北地区一个非常重要的斑岩型铜矿床,矿体主要产在花岗闪长斑岩和英安斑岩体内。地球化学特征上,这两种斑岩的主量元素表现为低铝、高钾、高碱,微量元素以富集大离子亲石元素(LILE),如Rb、Ba、Th、Sr等元素,亏损高场强元素(HFSE),如Nb、Ta等元素为特征,具有较为明显的Eu负异常。锆石Hf同位素研究显示,本区花岗闪长斑岩的锆石εHf(t)值为4.7~8.2,单阶段Hf模式年龄(t DM1)为714~857Ma,平均为791Ma;二阶段模式年龄(t DM2)的变化范围为887~1113Ma,平均为1003Ma,显示幔源特征。利用LA-ICP-MS锆石U-Pb年代学方法,测得花岗闪长斑岩的年龄为453.2±6.5Ma,为晚奥陶世,代表了公婆泉铜矿花岗闪长斑岩的成岩结晶时代。花岗闪长斑岩的结晶时间为晚奥陶世,因此认为,公婆泉铜矿的成矿时代为晚奥陶世。  相似文献   

5.
内蒙古塔尔气地区花岗斑岩的形成时代与岩石成因   总被引:2,自引:1,他引:1  
通过对内蒙古塔尔气地区花岗斑岩的野外地质特征、LA-ICP-MS锆石U-Pb年龄及地球化学特征的研究,讨论了该地区花岗斑岩的形成时代和成因机制。锆石U-Pb年龄及地球化学结果表明,塔尔气地区花岗斑岩形成于早白垩世136.5~126.4Ma;花岗斑岩具有高硅、富碱,弱过铝质(A/CNK=1.0~1.29),分异程度高的特点,属于高钾钙碱性系列,相对富集轻稀土元素和部分大离子亲石元素(Rb、Th、U、K),亏损高场强元素(Nb、Ta、Ti、P)。锆石Hf同位素组成表明,花岗斑岩具有较高的εHf(t)值(+7.19~+7.29),二阶段模式年龄为851~569Ma,暗示其可能起源于新元古代—早古生代期间从亏损地幔增生的地壳物质的部分熔融。结合区域地质资料分析,塔尔气花岗斑岩与研究区白音高老组火山岩可能为同期岩浆活动的产物,形成于伸展的构造环境。  相似文献   

6.
在野外地质工作的基础上,本文通过显微观察、岩石化学、锆石U-Pb定年、锆石原位Hf同位素分析研究,深入探讨水口山Pb—Zn矿区花岗闪长岩的岩石化学性质、形成时代和物质来源。研究表明:花岗闪长岩以高钾、富碱,富集轻稀土元素、大离子亲石元素(Rb、Th、U、La)和Pb,亏损重稀土元素、高场强元素(Nb、Ta、Ti)和Ba、Sr等元素为特征。锆石U-Pb加权平均年龄为156.0±1.0Ma(MSWD=0.33,2σ,N=20),属于燕山早期产物。锆石原位Hf同位素初始比值εHf(t)为-10.80~-8.71,平均-9.71;Hf同位素二阶段模式年龄TCDM为1.75~1.88Ga,平均1.82Ga,指示花岗闪长岩的岩浆源区主要来自古元古界下地壳物质。燕山早期湘南地区岩石圈处于全面的拉张—减薄期,导致地幔物质上涌,岩浆底侵,引发大规模的地壳熔融,熔融形成的岩浆沿深大断裂上侵,形成水口山Pb—Zn矿区花岗闪长岩。  相似文献   

7.
拉萨地块南木林盆地北缘的林子宗群火山岩地层侵位有大量的花岗斑岩岩株和岩脉,空间分布上与南北向正断层的次级断裂相一致。本次研究对南木林盆地北缘的花岗斑岩进行了系统的元素地球化学,LA-MCICP-MS锆石U-Pb年代学和Lu-Hf同位素测试。数据结果表明:花岗斑岩具有高硅(68.31%~71.34%)、高钾(4.52%~4.96%)、高(La/Yb)N(21.59~36.81)、Sr/Y(Sr/Y=15.59~38.10)等特征,富集大离子亲石元素(LILE),亏损高场强元素(HFSE);花岗斑岩LA-MC-ICP-MS锆石U-Pb年龄为12.2±0.1Ma,ε_(Hf)(t)值为-0.6~+4.0。拉萨地块南木林盆地北缘花岗斑岩岩石学、地球化学特征显示其为新生下地壳部分熔融产物,且源区残留了石榴子石、金红石、角闪石,无斜长石残留,在岩浆上侵过程中,发生了碱性长石的分离结晶作用。花岗斑岩侵位于中新世,与区内南北向裂谷发育时代一致,成分上类似于拉萨地块南部同时期发育的高锶低钇斑岩、钾质岩,同为印度—欧亚大陆碰撞后东西向伸展背景产物。  相似文献   

8.
于明杰 《地质与勘探》2014,50(1):145-155
[摘 要]甘肃公婆泉铜矿是我国西北地区一个非常重要的斑岩型铜矿床。矿体主要产在花岗闪长斑岩和英安斑岩体内。在斑岩的地球化学特征上,这两种斑岩的主量元素表现为低铝、高钾、高碱,微量元素以富集大离子亲石元素(LILE),如Rb、Ba、Th、Sr等元素,亏损高场强元素(HFSE),如Nb、Ta等元素为特征,具有较为明显的Eu负异常。锆石Hf同位素研究显示,本区花岗闪长斑岩的锆石?Hf (t)值为4.7 ~ 8.2,单阶段Hf模式年龄(tDM1)为714 ~ 857 Ma,平均为791 Ma;二阶段模式年龄(tDM2)的变化范围为887 ~ 1113 Ma,平均为1003 Ma,显示幔源特征。利用LA-ICP-MS锆石U-Pb年代学方法,测得花岗闪长斑岩的年龄为453.2 + 6.5 Ma,为晚奥陶世,代表了公婆泉铜矿花岗闪长斑岩的成岩结晶时代。花岗闪长斑岩的结晶时间为晚奥陶世,因此认为,公婆泉铜矿的成矿时代为晚奥陶世。  相似文献   

9.
张鲲  徐德明  胡俊良  卢友月  黄皓 《地质通报》2017,36(9):1591-1600
对湘东北三墩铜铅锌矿区花岗岩进行了系统的锆石U-Pb年代学、岩石地球化学和Hf同位素分析。LA-ICP-MS锆石U-Pb定年表明,三墩铜铅锌矿区花岗岩成岩年龄为131.9±1.1Ma。三墩铜铅锌矿区花岗岩为一套强过铝质钙碱性系列花岗岩,富集U、Ta、Pb,亏损Ba、Nb、Sr、Zr、Ti等元素,稀土元素配分模式为右倾配分模式,具有弱负Eu异常。Hf同位素分析表明,三墩铜铅锌矿区花岗岩燕山晚期锆石ε_(Hf)(t)值为-5.9~-2.4,Hf同位素二阶段模式年龄为1558~1338Ma,表明其物质来源于中元古代古老地壳岩石部分熔融。749.5Ma继承锆石核的ε_(Hf)(t)值为+4.8,Hf同位素二阶段模式年龄为1355Ma,暗示其物质来源有幔源物质加入。三墩铜铅锌矿区花岗岩可能是由于中下地壳的熔融岩浆形成后,混入少量幔源物质上侵形成的。  相似文献   

10.
中冈底斯成矿带查个勒矿床含矿岩体的年代学及成因   总被引:8,自引:2,他引:6  
查个勒矿床是中冈底斯成矿带(即中部拉萨地体)目前发现的一个中-大型矽卡岩+斑岩型矿床,但是其成岩成矿时代一直缺乏年代学约束。本文报道该矿床含矿岩体的LA-ICPMS法锆石U-Pb定年、辉钼矿Re-Os定年、地球化学及Hf同位素数据。花岗斑岩锆石U-Pb年龄明显可分为两组,206Pb/238U加权平均年龄分别为72.2~70.1Ma、65.2~64.4Ma,前者记录了早期的构造岩浆事件,后者代表了岩浆的结晶年龄;而辉钼矿Re-Os等时线年龄为71.5±1.3Ma,所代表的查个勒主成矿期年龄与早期的构造岩浆事件一致;结合65~64Ma时期的岩浆侵位、林子宗群大规模火山活动以及以亚贵拉矿床为代表的成矿作用,表明在印度与欧亚大陆初始碰撞过程中都可能产生不同规模的成矿作用。查个勒含矿岩体具富硅、富钾,贫钛、磷的特征,铝饱和指数(A/CNK)为1.05~1.27,富集大离子亲石元素Rb、Th、U,亏损高场强元素Nb、Ta、Zr、Ti等,并具有不均一的锆石εHf(t)值(-7.9~-2.2)和古老地壳Hf同位素模式年龄(tDMC=1.3~1.6Ga),属于过铝质"S"型花岗岩类。本文认为中冈底斯成矿带南部晚白垩世岩浆活动和成矿作用很可能是与雅鲁藏布江洋盆闭合之后初始碰撞幔源岩浆底侵导致的拉萨微陆块古老地壳物质的部分熔融有关,岩浆在上升过程中有不同程度的分离结晶。同时本文认为冈底斯成矿带成矿元素组合的分带性与新特提斯洋壳俯冲消减-碰撞过程中岩浆产生的源区物质有关。  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.  相似文献   

14.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

15.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

16.
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.  相似文献   

17.
18.
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.  相似文献   

19.
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明:玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。  相似文献   

20.
海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.  相似文献   

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