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1.
Mesothermal vein-type Sb mineralization in the Rheinisches Schiefergebirge, Germany, is characterized by two different mineralization styles, which are (1) extensional quartz-stibnite vein systems, and (2) (Cu)-Pb-Sb sulphosalt assemblages in overprinted pre-existing Pb-Zn veins. A detailed Pb isotope study of 52 representative samples from both mineralization types indicates distinct compositional patterns. (Cu)-Pb-Sb sulphosalts (meneghinite, boulangerite, bournonite) formed by reaction/remobilization are characterized by Pb isotope compositions (206Pb/204Pb=18.179-18.223), which are identical to the precursor galena (206Pb/204Pb=18.168-18.223). The Pb isotope composition of sulphosalt minerals in these vein systems was controlled by lead inherited from pre-existing galena. Stibnite and Pb-sulphosalts (zinkenite, semseyite, plagionite) formed in quartz-stibnite vein systems display Pb isotope ratios (206Pb/204Pb=18.250-18.354), which are more radiogenic than galenas from Variscan Pb-Zn ore veins (206Pb/204Pb=18.162-18.303). Detailed small-scale investigation of thrust zones hosting Pb-Zn ores and crosscutting quartz-ankerite fissure veins (Ramsbeck deposit) indicates that the Pb isotope compositions of recrystallized (galena) and remobilized phases (boulangerite, semseyite, bournonite) are arranged along a linear trend. This is interpreted as mixing between primary galena with 206Pb/204Pb᜞.206 and overprinting hydrothermal fluids with a more radiogenic composition (206Pb/204Pb⁾.354), expressed by intermediate compositions (206Pb/204Pb=18.256-18.334) of newly-formed sulphosalts. The Pb isotope systematics of the vein-type Sb mineralization is in accordance with a model of Pb extraction from similar crustal sources (Palaeozoic sedimentary sequences) at different times.  相似文献   

2.
Mineral assemblages, chemical compositions of ore minerals, wall rock alteration and fluid inclusions of the Gatsuurt gold deposit in the North Khentei gold belt of Mongolia were investigated to characterize the gold mineralization, and to clarify the genetic processes of the ore minerals. The gold mineralization of the deposit occurs in separate Central and Main zones, and is characterized by three ore types: (i) low‐grade disseminated and stockwork ores; (ii) moderate‐grade quartz vein ores; and (iii) high‐grade silicified ores, with average Au contents of approximately 1, 3 and 5 g t?1 Au, respectively. The Au‐rich quartz vein and silicified ore mineralization is surrounded by, or is included within, the disseminated and stockwork Au‐mineralization region. The main ore minerals are pyrite (pyrite‐I and pyrite‐II) and arsenopyrite (arsenopyrite‐I and arsenopyrite‐II). Moderate amounts of galena, tetrahedrite‐tennantite, sphalerite and chalcopyrite, and minor jamesonite, bournonite, boulangerite, geocronite, scheelite, geerite, native gold and zircon are associated. Abundances and grain sizes of the ore minerals are variable in ores with different host rocks. Small grains of native gold occur as fillings or at grain boundaries of pyrite, arsenopyrite, sphalerite, galena and tetrahedrite in the disseminated and stockwork ores and silicified ores, whereas visible native gold of variable size occurs in the quartz vein ores. The ore mineralization is associated with sericitic and siliceous alteration. The disseminated and stockwork mineralization is composed of four distinct stages characterized by crystallization of (i) pyrite‐I + arsenopyrite‐I, (ii) pyrite‐II + arsenopyrite‐II, (iii) galena + tetrahedrite + sphalerite + chalcopyrite + jamesonite + bournonite + scheelite, and iv) boulangerite + native gold, respectively. In the quartz vein ores, four crystallization stages are also recognized: (i) pyrite‐I, (ii) pyrite‐II + arsenopyrite + galena + Ag‐rich tetrahedrite‐tennantite + sphalerite + chalcopyrite + bournonite, (iii) geocronite + geerite + native gold, and (iv) native gold. Two mineralization stages in the silicified ores are characterized by (i) pyrite + arsenopyrite + tetrahedrite + chalcopyrite, and (ii) galena + sphalerite + native gold. Quartz in the disseminated and stockwork ores of the Main zone contains CO2‐rich, halite‐bearing aqueous fluid inclusions with homogenization temperatures ranging from 194 to 327°C, whereas quartz in the disseminated and stockwork ores of the Central zone contains CO2‐rich and aqueous fluid inclusions with homogenization temperatures ranging from 254 to 355°C. The textures of the ores, the mineral assemblages present, the mineralization sequences and the fluid inclusion data are consistent with orogenic classification for the Gatsuurt deposit.  相似文献   

3.
Mineral assemblages and chemical compositions of ore minerals from the Boroo gold deposit in the North Khentei gold belt of Mongolia were studied to characterize the gold mineralization, and to clarify crystallization processes of the ore minerals. The gold deposit consists of low‐grade disseminated and stockwork ores in granite, metasedimentary rocks and diorite dikes. Moderate to high‐grade auriferous quartz vein ores are present in the above lithological units. The ore grades of the former range from about 1 to 3 g/t, and those of the latter from 5 to 10 g/t, or more than 10 g/t Au. The main sulfide minerals in the ores are pyrite and arsenopyrite, both of which are divisible into two different stages (pyrite‐I and pyrite‐II; arsenopyrite‐I and arsenopyrite‐II). Sphalerite, galena, chalcopyrite, and tetrahedrite are minor associated minerals, with trace amounts of bournonite, boulangerite, geerite, alloclasite, native gold, and electrum. The ore minerals in the both types of ores are variable in distribution, abundance and grain size. Four modes of gold occurrence are recognized: (i) “invisible” gold in pyrite and arsenopyrite in the disseminated and stockwork ores, and in auriferous quartz vein ores; (ii) microscopic native gold, 3 to 100 µm in diameter, that occurs as fine grains or as an interstitial phase in sulfides in the disseminated and stockwork ores, and in auriferous quartz vein ores; (iii) visible native gold, up to 1 cm in diameter, in the auriferous quartz vein ores; and (iv) electrum in the auriferous quartz vein ores. The gold mineralization of the disseminated and stockwork ores consists of four stages characterized by the mineral assemblages of: (i) pyrite‐I + arsenopyrite‐I; (ii) pyrite‐II + arsenopyrite‐II; (iii) sphalerite + galena + chalcopyrite + tetrahedrite + bournonite + boulangerite + alloclasite + native gold; and (iv) native gold. In the auriferous quartz vein ores, five mineralization stages are defined by the following mineral assemblages: (i) pyrite‐I; (ii) pyrite‐II + arsenopyrite; (iii) sphalerite + galena + chalcopyrite; (iv) Ag‐rich tetrahedrite‐tennantite + bournonite + geerite + native gold; and (v) electrum. The As–Au relations in pyrite‐II and arsenopyrite suggest that gold detected as invisible gold is mostly attributed to Au+1 in those minerals. By applying the arsenopyrite geothermometer to arsenopyrite‐II in the disseminated and stockwork ores, crystallization temperature and logfs2 are estimated to be 365 to 300 °C and –7.5 to –10.1, respectively.  相似文献   

4.
近年来,在相山铀矿田的西部牛头山地区深部发现了铅锌矿化体,其成因机制不明.为探讨牛头山铅锌矿化体物质来源,开展了硫化物原位硫同位素分析研究.根据硫化物矿物之间的充填和包裹关系判断,铅锌矿化体金属硫化物形成的先后顺序是:黄铁矿形成最早,方铅矿和闪锌矿次之,细脉状黄铜矿形成最晚.利用LA-MC-ICP-MS技术对矿化体中几种金属硫化物分别进行了系统的原位硫同位素分析.结果显示:黄铁矿、闪锌矿、方铅矿、细脉状黄铜矿的δ34S值介于-4.8‰~+5.4‰之间,各硫化物矿物之间硫同位素未达到完全平衡分馏,利用黄铁矿δ34S值得到的矿化流体δ34SΣS值（总硫同位素组成）近似为+3.7‰,与共生矿物对（闪锌矿-方铅矿）图解法得到的闪锌矿和方铅矿沉淀时矿化流体的δ34SΣS值（+3.2‰）相近,表明形成牛头山铅锌矿化体的矿化流体δ34SΣS值大约为+3.7‰,为岩浆硫.结合前人的岩浆岩年龄数据,我们判断该铅锌矿化体金属硫化物的硫可能主要来自次火山岩相花岗斑岩岩浆热液.同一薄片中闪锌矿δ34S值高于共生的方铅矿,表明两者硫同位素基本平衡,利用共生矿物对（闪锌矿-方铅矿）硫同位素温度计计算得出平衡温度为197~476℃,与前人通过脉石矿物流体包裹体得到的铅锌矿化流体温度基本一致.相山火山盆地与相邻的北武夷黄岗山、梨子坑等产铅锌矿的火山盆地具有相似的成矿条件及成矿物质来源,使相山火山盆地具有良好的铅锌多金属找矿前景.   相似文献   

5.
Several distinct assemblages of Pb-Sb, Pb-As, Cu-Pb-Sb and Cu-Fe-Zn-Sn sulphosalts are identified in sulphide samples from Bleikvassli mine, Norway. Detailed optical microscopy and electron probe microanalysis have permitted investigation of textural relationships between minerals and compositional variations between different ore types. Tetrahedrite, typically containing 10–16?wt.% Ag (rare freibergite containing 25–30?wt.% Ag has also been identified in two samples), stannite (Cu2(Fe>Zn)SnS4), and meneghinite, CuPb13Sb7S24, are widely distributed as trace constituents throughout massive pyritic and galena-rich ores. Native antimony and pyrargyrite occur in trace amounts in all ore types, as the breakdown products of earlier sulphosalts. Several distinct types of wall-rock mineralisation are present at Bleikvassli. Of considerable mineralogical interest are the coarse-grained sulphide mobilisates within the wall rock which contain a distinct?and characteristic suite of Pb-As sulphosalts:?tennantite?+?jordanite (Pb14As6S23)?+?seligmannite (CuPbAsS3) ± dufrenoysite (Pb2As2S5). Bournonite (CuPbSbS3) is the only Sb-bearing sulphosalt recognised in significant amounts within the mobilisates, meneghinite and tetrahedrite being conspicuously absent. These mobilisates display considerable Au enrichment; electrum can be confirmed, intimately associated with jordanite and tennantite. Appreciable Sb (up to 3?wt.%) is contained within galena in the mobilisates, in contrast to galena from massive ores which contains only negligible Sb. Contents of Ag and Bi in galena vary considerably in all ore types, but confirm earlier suggestions that galena is a major Ag-carrier at Bleikvassli. Boulangerite (Pb5Sb4S11), jamesonite (FePb4Sb6S14) and gudmundite (FeSbS) occur in trace amounts. Sn-sulphosalts are represented by kësterite, (Cu2(Zn> Fe)SnS4), but commonly zoned with respect to Zn/Fe ratio, in the mobilisates, rather than by stannite. A rare type of mobilisate, also in the wall rock, in which chalcocite and bornite are the main minerals, contains native Ag, stromeyerite (AgCuS), mckinstryite ((Ag,Cu)2?S), Ag-free tetrahedrite, an unnamed Cu-Ag-Fe sulphide (Cu3Ag2FeS4) and native Bi, myrmekitically intergrown with chalcocite. Although a comprehensive genetic model for the wall-rock mineralisation at Bleikvassli is largely impossible given the limitations in the present state of knowledge regarding mechanisms involved in remobilisation processes, a multi-stage model of remobilisation during regional metamorphism is considered to best explain the observations. An interplay of different solid- and liquid-state remobilisation mechanisms, in various combinations, is required to account for the macro- and microscopic observations. Remobilisation probably began during the earlier stages of metamorphism, with crystallisation and further remobilisation taking place during the entire metamorphic cycle, giving rise to the extensive chemical and mineralogical diversity observed today. Preserved mineral assemblages and their textural relationships reflect a complex sequence of replacement and decomposition reactions taking place during the latest phase of late-metamorphic crystallisation and subsequent cooling.  相似文献   

6.
The mineralogy and structure of the supergene profile in recently-exploited volcaniс hosted massive sulphide (VHMS) deposits of Cyprus, Uralian and Kuroko type in the South Urals, Russia, have been studied. Specific subzones enriched in secondary sulphides and associated minerals have been distinguished in residual pyrite and quartz–pyrite sands at the Gayskoye, Zapadno-Ozernoye, Dzhusinskoye and Alexandrinskoye deposits. Besides minerals which are common to the cementation subzones (covellite, chalcocite and acanthite), non-stoichiometric colloform and framboidal pyrite, pyrite–dzharkenite, pyrrhotite-like and jordanite-like minerals, metacinnabar, sphalerite, selenium-enriched tetrahedrite and unidentified As-, Sb sulphosalts of Pb or Hg and Ag, sulphur-bearing clausthalite, naumannite and tiemannite were also found. Secondary sulphide minerals in VHMS deposits of the South Urals region are characterized by light sulphur isotope compositions (− 8.1 to − 17.2‰). Superposition of the advanced oxidation of colloform pyrite, an enrichment in impurities (sphalerite, galena, and tennantite) from the primary ores, stagnant water conditions, an elevation of the water table during oxidation, and bacterial activity led to supergene concentrations of the base metals as sulphide, selenides or sulphosalts.  相似文献   

7.
桂西那弱银金矿床矿物组合特征及银和金的赋存状态研究   总被引：2，自引：1，他引：1  
广西天峨那弱银金矿床以银矿为主,共/伴生金及铅、锌、锑等金属,矿物组合在右江盆地内为首次发现。矿体受那弱背斜及其轴向断层控制,赋矿层位为中三叠统百逢组含钙质浊积岩系。矿石矿物以硫锑铅矿、铁闪锌矿、黄铁矿、毒砂和方铅矿为主;脉石矿物主要有石英、方解石、绢云母等。主要矿石矿物由早到晚的生成顺序为:毒砂→黄铁矿→铁闪锌矿→硫锑铅矿→方铅矿。单矿物化学分析显示硫锑铅矿含Ag最高,其次为闪锌矿;黄铁矿含Au相对较高。EPMA测试结果表明Ag于方铅矿中含量最高,其次为硫锑铅矿;主要矿石矿物中毒砂含Au相对较高,其余矿物中Au含量均偏低。因矿石中的铅矿物主要为硫锑铅矿,可以认为那弱银金矿床的Ag主要赋存于硫锑铅矿中,Au主要赋存于毒砂与黄铁矿中,二者均以显微-次显微状态赋存于载体矿物中。根据矿物组合及其相互交代、切割关系等特征,将矿床划分为2个成矿期共4个成矿阶段。其中,第一成矿期为金的成矿期,矿物组合为黄铁矿和毒砂,由于后期成矿作用的叠加,仅保留一个成矿阶段;第二成矿期为银铅锌成矿期,矿物组合为方铅矿-闪锌矿-硫锑铅矿;包含第二至第四共3个完整的成矿阶段。该矿床Ag、Au共生是不同期次成矿作用叠加的结果。  相似文献   

8.
The Mount Black Pb‐Zn deposit is a quartz‐galena‐sphalerite replacement body in the Silurian Cooleman Limestone. Fluid inclusion homogenisation temperatures range from 120° to 170°C for paragenetically early sphalerite, to 210° to 315°C for late quartz, and 245° to 320°C for calcite from contiguous recrystallised limestone. Fluid salinities increased with rising temperature, during deposition of the minerals, and the fluid composition changed from NaCl‐rich to possibly CaCl2‐NaCl (‐?MgCl2)‐rich brines.

δ34S values of sphalerite and galena range from —8.1 to —2.7 per mil, and —13,5 to —4.4 per mil respectively. Although a magmatic source for sulphur is not excluded, it is suggested that most probably the sulphur was derived by biogenic reduction of sea‐water sulphate during diagenesis. Carbon and oxygen isotope data for the Cooleman Limestone range from compositions typical of Silurian marine carbonate in samples distant from the deposit, to fluctuating, but 12C‐ and 16O‐enriched in recrystallised material adjacent to the quartz‐sulphide rocks. 12C‐enrichment probably reflects organic carbon oxidation during karst formation, continuing later during limestone recrystallisation and accompanied by 16O‐enrichment during the action of saline formation waters.

The process of formation of the Mount Black deposit may have been analogous to that of Mississippi Valley‐type deposits, but modified by and/or resulting from, an increasing geothermal gradient caused by nearby synchronous intrusions.  相似文献   

9.
The Nuevo Entredicho deposit contains the richest concentration of mercury in the Almadén district, locally grading as much as 45% Hg. This ore deposit is hosted within an alkaline, conically shaped diatreme, about 150 m in diameter, which was subsequently filled with phreatomagmatic breccias. The diatreme cuts an Ordovician to Silurian clastic sedimentary rock sequence that is intercalated with basaltic sills. Structural analysis reveals a complex tectonic history with three main phases of Hercynian deformation. Mineralisation occurs as cinnabar replacements in volcanic tuffs and breccias and as recrystallised veins in tensions cracks associated with pyrophyllite and hydrothermal pyrite, which is strongly enriched in Cu, Pb and Hg. Lead isotopes in pyrite are characterised by high 207Pb/204Pb ratios (15.70-15.75), suggesting a contribution of ancient upper continental crust remobilised by Silurian-Devonian volcanism, with no mantle involvement. Sulphur isotopes of epigenetic cinnabar and pyrite range from +10.3 to +10.8‰ and from +10.6 to +11.9‰ respectively, suggesting a uniform sulphur source or a constant mixing ratio in the ore fluids. These isotopic compositions differ from those measured in the syngenetic deposits of the Almadén district; they suggest a higher temperature of ore formation of about 300 °C, and a genesis related to a distinct hydrothermal flow path at the Nuevo Entredicho deposit. Deposition of anomalously high-grade mercury ore at Nuevo Entredicho is related to a combination of (1) an abundance of black shale that provided sulphur and increasingly reducing conditions with high sulphide/sulphate ratios, (2) explosive Silurian-Devonian mafic magmatism that provided an initial source of mercury, (3) tectonic activity that lead to structurally favourable sites for ore deposition, and (4) replacement of secondary, carbonate-rich volcanic rocks.  相似文献   

10.
本文研究的铅锌矿床在大地构造上位于华北地台燕山沉降带中部马兰峪背斜的北翼。北翼主要出露太古界和上元古界地层。  相似文献   

11.
The early Tertiary Sanerlin uranium deposit is located near the southwestern margin of the Chaling-Yongxing pull-apart basin defined by the Chaling-Yongxing and Chenxian-Linwu sinistral strike-slip faults in southern China. The uranium ores are hosted in 15 breccia-vein bodies, which are separately located in the cores of three secondary anticlines of the Upper Permian Dangchong Formation. Individual breccia-vein bodies are composed of fragments of silicified shale and sandstone from the Dangchong Formation, and quartz veinlets as cements. These fragments, together with quartz veins, form a mosaic texture. Hydrothermal pitchblende is the only commercial uranium mineral, mainly occurring as disseminated grains within quartz veins or coating fragments. Other metallic minerals include molybdenite, pyrite, chalcopyrite, galena, sphalerite, and red microcrystalline hematite. Fluid inclusions in quartz veins have homogenization temperatures ranging from 150 to 280 °C, and calculated salinity values between 5.6 and 13.4 wt% NaCl equivalent. Stable isotope analyses show that the mineralizing fluid was characterized by '18O values of -2.2 to +2.6‰ and 'DH2O values of -134 to -110‰. These analytical data demonstrate that hydrothermal fluids were mainly derived from formation waters (brines) of the Chaling-Yongxing basin. Fluid overpressuring was caused by an abnormal geothermal gradient and impermeable shales in the deposit area. The geometry, texture, and structure of the breccia-vein system, along with the fluid pressure estimates, suggest that hydraulic fracturing generated the mineralized breccia-vein system. Pitchblende and associated minerals were deposited when gaseous phases were released abruptly from the ore fluids due to the hydraulic fracturing.  相似文献   

12.
The sulphur isotopic characteristics of ore deposits in the Australian Mount Isa Eastern Succession are not well known, unlike those of the Western Succession. In this study new detailed analyses are provided for recently discovered Eastern Succession mineralisation, such as the Starra and Osborne BIF-hosted Cu-Au ores, the Dugald River sediment-hosted Pb-Zn prospect, and four vein-hosted Cloncurry-style Cu±Au deposits (Hampden, Mt Elliot/Swan, Mt Cobalt, and the Answer Mine). All of the deposits of the Eastern Succession have 34Ssulphide between –8 and +9%., regardless of their genesis. Empirically a moderate (34S range averaging close to 0%. characterises Starra-style Cu-Au and Pegmont Pb-Zn BIF ores, whereas shear and vein-style Cu mineralisation populations are tighter and do not average close to 0%. This is a particularly surprising result for Dugald River, where a larger isotopic variation more typical of stratiform sediment-hosted Pb-Zn ores in the region might have been expected. By comparison, Western Succession stratiform Pb-Zn and vein-style Cu deposits span a huge range of-15 to 51%. Large sulphur isotope ranges typify sulphate evaporite or organic sulphur-rich sedimentary successions. The lack of such variation in the Eastern Succession in turn suggests that primary evaporite sequences there were halite-dominated but sulphate-poor, and/or contained only limited volumes of organic-sulphur-rich sediment. Eastern Succession sequences were therefore less likely hosts for giant stratiform Pb-Zn deposits, because of their paucity of sulphur, although local sulphur sources permitted small deposits such as Dugald River to develop. Sedimentary conditions were more favourable for the development of sulphur-poor synsedimentary hydrothermal systems such as Starra, Osborne, and Pegmont, although sulphur isotope evidence is equivocal about the origin of these. Epigenetic deposits close to the Williams Batholith (Mt Dore, Hampden) owe their clustering around 0%. to their granitic fluid source.  相似文献   

13.
Massive stratiform zinc-lead-copper sulfide ores, in association with cordierite-anthophyllite rocks, occur in adjacent localities of Ambaji and Deri, in Western India. The metasedimentary country rocks, interlayered with amphibolites and intruded by acidic to intermediate plutonic rocks, belong to the Precambrian Delhi Supergroup. The ore minerals identified by detailed mineragraphic studies include: sphalerite, galena, chalcopyrite, pyrite, pyrrhotite (both monclinic and hexagonal phases), magnetite, ilmenite, rutile, arsenopyrite, molybdenite, cubanite, mackinawite, boulangerite, gudmundite, meneghinite, lautite, tenantite, native bismuth, native silver, chalcocite and covellite. The common sulfide-silicate schistosity in the ores, flowage of sulfide streaks and tails around rotated poikiloblasts and in their pressure shadow region developed during early folding (F1) and regional metamorphism of the rocks under green schist facies condition. These were superimposed by a pervasive hornfelsic fabric involving sulfides and silicates and including microfabrics due to annealing and grain growth in sulfides, during a subsequent phase of low pressure thermal metamorphism and related tectonism (F2). Finally certain deformation features and some uncommon fabrics like martensitic lamellae in galena and subgrains in sphalerite developed during a mild deformation episode (F3) in the waning stages of tectonism in the area. Compositional change in the ores during thermal metamorphism was minimal.  相似文献   

14.
银多金属矿床中黝铜矿族银硫盐矿物的特征及其意义   总被引：10，自引：0，他引：10  
在国内外几个不同成因类型的银多金属矿床内产出的黝铜矿族银硫盐矿物中,除朗达矿床见有砷黝铜矿和含银砷黝铜矿外,较普遍共同发育有黝铜矿、含银黝铜矿和银黝铜矿、而后两者是最主要或主要的工业银矿物之一。按国际矿物学协会新矿物及矿物命名委员会的矿物命名原则,黝铜矿族矿物所含的Ｆｅ、Ｚｎ、Ｈｇ、Ｃｄ、Ｍｎ等不可作为矿物种的命名元素。蔡家营矿床的含银黝铜矿和银黝铜矿以Ｆｅ、Ｚｎ含量近似而有别于其余矿床的富Ｆｅ贫  相似文献   

15.
The Navia gold belt is located in the West Asturian-Leonese Zone of the Iberian Variscan Orogen. The host rocks of the mineralization are quartzites, sandstones and black shales of Cambro-Ordovician age. The gold belt extends along 35 km and has five major veins: Penedela, Encarnita, Fornaza, Carmina and S. Jose. The ores belong to at least four associations having contrasting mineralogies and textures. The δ34S values for individual mineral phases reflect the polyphase metallogenic history. The older association (Stage 1) is Fe-Mn-rich and is made up of spessartine, grunerite-dannemorite and quartz, with magnetite, pyrrhotite and chalcopyrite as metallic phases. The mineralization of Stage 1 is followed by the As-rich Stage 2 with quartz, arsenopyrite and pyrite. The δ34S values for pyrite range from 14.9 to 19.9 per mil (n = 16), and for arsenopyrite from 13.2 to 17.3 per mil (n = 7). The observed isotopic homogeneity likely implies isotopic equilibrium at the scale of the gold vein. Stage 3 contains a coarse-grained base metal sulphide-rich association. The δ4S values for sphalerite range from 16.4 to 20.6 per mil (n= 16), and for galena from 17.0 to 18.7 per mil (n = 11). δ34Ssp > δ34Sgl suggests that the sulphur isotopic fractionation of the ore-forming system had reached equilibrium. The youngest crosscutting mineral association (Stage 4) consists of Pb-Sb sulphosalts, bornite, electrum and quartz. The δ34S values for sulphosalts range from 9.7 to 15.8 per mil, showing the lightest results of the Navia sulphides.The relatively tight clustering of δ34S values of the Au-related sulphides, and the results of fluid inclusions and paragenetic studies, can be interpreted to indicate that the hydrothermal fluids of the last three stages were dominated by H2S. In the H2S predominant field, sulphide minerals precipitating from solutions would exhibit δ34S values similar to the δ34SΣS value of the ore fluid. The heavy δ34SΣS of the Navia fluids is consistent with leaching of sulphur from the host rocks. The main sulphur source could be diagenetic pyrite from the siliciclastic rocks of the Cabos and Luarca Formations, which exhibit δ34S values from 8.3 to 21.2 per mil. An additional sulphur-source in Stage 3 would be the leaching of disseminated sphalerite and galena present in Cambrian carbonates.  相似文献   

16.
夏塞银多金属矿床中硫化物和硫盐系列矿物特征及其意义   总被引：4，自引：1，他引：3  
黄典豪  胡世华 《矿床地质》2000,19(4):363-375
夏塞矿主档是大型的热液脉型银多金属矿床,通过对大量矿石光（薄）片观察和电子探针分析表明,除主要（方铅矿、富铁闪锌矿）和次要（黄铁矿、毒砂、磁黄铁矿、黄铜矿等）硫化物外,硫盐毓硫物十分发育,主要有Ｃｕ－Ｓｂ－Ａｇ硫盐（黝铜矿、含银黝铜矿和银黝铜矿）、Ｓｂ－Ａｇ硫盐（深红银矿、辉锑银矿）、Ｐｂ－Ｓｂ硫盐（脆硫锑铅矿、硫锑铅矿）和Ｂｉ－Ｐｂ硫盐（斜方辉饿铅矿）。此外,尚有少（微）量黄锡矿、锡石、自然饿和银金矿等。银的硫盐硫物和硫化物（辉银矿）乃是获得银的主要工业矿物,这些硫盐毓矿物常与硫化物伴生,多沿方铅矿、富铁闪锌矿、黄铁矿等的解理、裂隙或粒间产出,这些研究结果不仅有助于了解矿化作用过程,而且为矿床评价,组分综合利用和选冶提供重要依据。  相似文献   

17.
We conducted experiments to simulate sulfide remobilisation from sulfide ore. The starting material was from the Hongtoushan massive sulfide deposit, NE China, and is composed of pyrite, pyrrhotite, chalcopyrite, sphalerite, quartz, and silicate minerals. The ore was immersed in a solution of 20 wt.% NaCl for 260 h, and then was mounted in a Changjiang 500 triaxial rock stress machine. After the experiments were performed for 13 h at temperatures of 362, 464, 556 and 682°C, with corresponding confining and axial pressures, the samples were cooled at room temperatures. Our results from all the runs indicate that sulfides can be remobilised both mechanically and chemically, and that remobilisation is enhanced at higher temperatures. Mechanical remobilisation can only take place over limited distances and results in minor differentiation between various sulfide minerals. Distant external remobilisation to form new orebodies is most likely caused by chemical remobilisation. In contrast to plastically deformed areas, space resulting from cataclastic deformation could provide conduits for fluid transport and space for metal precipitation. Remobilised iron sulfides will precipitate as pyrrhotite at high temperatures, but as pyrite when temperature decreases. Furthermore, chalcopyrite is more easily remobilised than sphalerite under the conditions of the present experiments. Remobilisation accompanying deformation and metamorphism may add epigenetic features to syngenetic deposits.  相似文献   

18.
The Tianqiao Pb-Zn ore deposit of Guizhou Province, China, is located in the mid-east of the Si-chuan-Yunnan-Guizhou Pb-Zn-Ag multi-metallic mineralization area, which is representative of the Pb-Zn ore de-posits in this area. It consists of three main orebodies, whose Pb+Zn reserves are more than 0.2 million ton. This paper analyzes the sulfur isotopic composition of these orebodies. The data show that the ore minerals (galena, sphalerite, pyrite) in these orebodies are enriched in heavy sulfur, with δ34SV-CDT values varying between 8.35‰ and 14.44‰, i.e. the δ34SV-CDT values of pyrite are between 12.81‰ and 14.44‰, the mean value is 13.40‰; the δ34SV-CDT values of sphalerite are range from 10.87‰ to 14.00‰, the mean value is 12.53‰; the δ34SV-CDT values of galena are range from 8.35‰ to 9.83‰, the mean value is 8.84‰, and they have the feature of δ34Spyrite>δ34Ssphalerite>δ34Sgalena, which indicates the sulfur isotope in ore-forming fluids has attained equilibrium. The δ34S V-CDT values of the deposit are close to those of sulfates from carbonate strata of different ages in the ore-field (15‰), which suggests that the sulfur in the ore-forming fluids should be derived from the thermo-chemical sulfate reduction of sulfates from the sedimentary strata.  相似文献   

19.
位于扬子板块西南缘的"川滇黔接壤铅锌矿集区"是我国西南大面积低温成矿域的重要组成部分,麻栗坪铅锌矿床位于该矿集区昭通-曲靖成矿带中段,是近年来滇东北地区新发现的铅锌矿床。本文以麻栗坪铅锌矿不同硫化物为研究对象,通过LA-ICPMS原位点测试和元素Mapping分析,尝试揭示该矿床中Ge、Cd和In等微量元素在不同硫化物中分布规律与赋存状态。本次研究发现,麻栗坪矿床不同硫化物中富集的微量元素明显不同,闪锌矿主要富集Mn、Cu、Sn、Cd、In和Ge,而方铅矿主要富集Ag、Sb和Se,黄铁矿则富集As、Co和Ni。闪锌矿是分散元素Ge、In和Cd的主要载体矿物,且Cd、Ge、In、Mn、As、Sb和Ag以类质同象形式赋存于闪锌矿中;而Cu则主要以类质同象形式存在,部分Cu以黄铜矿的显微包裹体形式赋存于闪锌矿中,其中以类质同象赋存于闪锌矿中Cu和Ge呈现明显的相关性,可能暗示其与Zn的置换方式为:3Zn2+Ge4++2Cu+。总体上,该矿床闪锌矿以富集Cd、Ge,贫Fe、Mn、Co、Sn为特征,这些微量元素组成与典型MVT型矿床基本一致,明显有别于喷流沉积和岩浆热液型矿床,而与中低温条件下形成的闪锌矿微量元素组成相似。结合该矿床后生成矿特征明显等地质地球化学研究成果,我们认为该矿床应属于MVT型铅锌矿床。值得注意的是,该矿床闪锌矿相对富集In,可能暗示其形成具有特殊性,这可能与其成矿流体在长距离运移过程中所流经地层有关,该类流体活化萃取了基底地层的中-酸性岩浆岩或火山碎屑岩中的In,致使矿床中闪锌矿相对富集In。  相似文献   

20.
The El Cobre deposit is located in eastern Cuba within the volcanosedimentary sequence of the Sierra Maestra Paleogene arc. The deposit is hosted by tholeiitic basalts, andesites and tuffs and comprises thick stratiform barite and anhydrite bodies, three stratabound disseminated up to massive sulphide bodies produced by silicification and sulphidation of limestones or sulphates, an anhydrite stockwork and a siliceous stockwork, grading downwards to quartz veins. Sulphides are mainly pyrite, chalcopyrite and sphalerite; gold occurs in the stratabound ores. Fluid inclusions measured in sphalerite, quartz, anhydrite and calcite show salinities between 2.3 and 5.7 wt% NaCl eq. and homogenisation temperatures between 177 and 300°C. Sulphides from the stratabound mineralisation display δ 34S values of 0‰ to +6.0‰, whilst those from the feeder zone lie between −1.4‰ and +7.3‰. Sulphides show an intra-grain sulphur isotope zonation of about 2‰; usually, δ 34S values increase towards the rims. Sulphate sulphur has δ 34S in the range of +17‰ to +21‰, except two samples with values of +5.9‰ and +7.7‰. Sulphur isotope data indicate that the thermochemical reduction of sulphate from a hydrothermal fluid of seawater origin was the main source of sulphide sulphur and that most of the sulphates precipitated by heating of seawater. The structure of the deposit, mineralogy, fluid inclusion and isotope data suggest that the deposit formed from seawater-derived fluids with probably minor supply of magmatic fluids.  相似文献   

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