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1.
《Quaternary Science Reviews》2003,22(2-4):225-244
The Thebes Section in unglaciated southwestern Illinois contains a well preserved ∼500 kyr loess–paleosol sequence with four loesses and three interglacial soils. Various magnetic, mineralogical, and elemental properties were analyzed and compared over the thickness of soil sola. These proxies for soil development intensity have the following trend: Yarmouth Geosol>Sangamon Geosol>modern soil. Quartz/plagioclase, Zr/Sr, and TiO2/Na2O ratios were most sensitive to weathering. Frequency dependent magnetic susceptibility and anhysteretic remanent magnetization, greatest in A horizons, also correspond well with soil development intensity. Neoformed mixed-layered kaolinite/expandables, suggestive of a warm/humid climate, were detected in the Sangamon and Yarmouth soil sola. Clay illuviation in soils was among the least sensitive indicators of soil development. Differences in properties among interglacial soils are interpreted to primarily reflect soil development duration, with climatic effects being secondary. Assuming logarithmic decreases in weathering rates, the observed weathering in the Sangamon Geosol is consistent with 50 kyr of interglacial weathering (Oxygen Isotope Stage 5) compared to 10 kyr for the modern soil (Oxygen Isotope Stage 1). We propose that the Yarmouth Geosol in the central Midwest formed over 180 kyr of interglacial weathering (including oxygen isotope stages 7, 9, and 11).  相似文献   

2.
《Earth》2009,95(1-4):23-38
Erosion is a major threat to soil resources in Europe, and may impair their ability to deliver a range of ecosystem goods and services. This is reflected by the European Commission's Thematic Strategy for Soil Protection, which recommends an indicator-based approach for monitoring soil erosion. Defined baseline and threshold values are essential for the evaluation of soil monitoring data. Therefore, accurate spatial data on both soil loss and soil genesis are required, especially in the light of predicted changes in climate patterns, notably frequency, seasonal distribution and intensity of precipitation. Rates of soil loss are reported that have been measured, modelled or inferred for most types of soil erosion in a variety of landscapes, by studies across the spectrum of the Earth sciences. Natural rates of soil formation can be used as a basis for setting tolerable soil erosion rates, with soil formation consisting of mineral weathering as well as dust deposition. This paper reviews the concept of tolerable soil erosion and summarises current knowledge on rates of soil formation, which are then compared to rates of soil erosion by known erosion types, for assessment of soil erosion monitoring at the European scale.A modified definition of tolerable soil erosion is proposed as ‘any actual soil erosion rate at which a deterioration or loss of one or more soil functions does not occur,’ actual soil erosion being ‘the total amount of soil lost by all recognised erosion types.’ Even when including dust deposition in soil formation rates, the upper limit of tolerable soil erosion, as equal to soil formation, is ca. 1.4 t ha− 1 yr− 1 while the lower limit is ca. 0.3 t ha− 1 yr− 1, for conditions prevalent in Europe. Scope for spatio-temporal differentiation of tolerable soil erosion rates below this upper limit is suggested by considering (components of) relevant soil functions. Reported rates of actual soil erosion vary much more than those for soil formation. Actual soil erosion rates for tilled, arable land in Europe are, on average, 3 to 40 times greater than the upper limit of tolerable soil erosion, accepting substantial spatio-temporal variation. This paper comprehensively reviews tolerable and actual soil erosion in Europe and highlights the scientific areas where more research is needed for successful implementation of an effective European soil monitoring system.  相似文献   

3.
Rapid weathering and erosion rates in mountainous tropical watersheds lead to highly variable soil and saprolite thicknesses which in turn impact nutrient fluxes and biological populations. In the Luquillo Mountains of Puerto Rico, a 5-m thick saprolite contains high microorganism densities at the surface and at depth overlying bedrock. We test the hypotheses that the organisms at depth are limited by the availability of two nutrients, P and Fe. Many tropical soils are P-limited, rather than N-limited, and dissolution of apatite is the dominant source of P. We document patterns of apatite weathering and of bioavailable Fe derived from the weathering of primary minerals hornblende and biotite in cores augered to 7.5 m on a ridgetop as compared to spheroidally weathering bedrock sampled in a nearby roadcut.Iron isotopic compositions of 0.5 N HCl extracts of soil and saprolite range from about δ56Fe = 0 to ? 0.1‰ throughout the saprolite except at the surface and at 5 m depth where δ56Fe = ? 0.26 to ? 0.64‰. The enrichment of light isotopes in HCl-extractable Fe in the soil and at the saprolite–bedrock interface is consistent with active Fe cycling and consistent with the locations of high cell densities and Fe(II)-oxidizing bacteria, identified previously. To evaluate the potential P-limitation of Fe-cycling bacteria in the profile, solid-state concentrations of P were measured as a function of depth in the soil, saprolite, and weathering bedrock. Weathering apatite crystals were examined in thin sections and an apatite dissolution rate of 6.8 × 10? 14 mol m? 2 s? 1 was calculated. While surface communities depend on recycled nutrients and atmospheric inputs, deep communities survive primarily on nutrients released by the weathering bedrock and thus are tightly coupled to processes related to saprolite formation including mineral weathering. While low available P may limit microbial activity within the middle saprolite, fluxes of P from apatite weathering should be sufficient to support robust growth of microorganisms in the deep saprolite.  相似文献   

4.
How and how fast do hillslope soils form as the landscape’s morphology changes over time? Here results are shown from an ongoing study that simultaneously examines the morphologic and geochemical evolution of soil mantled hillslopes that have been exposed to distinctively different denudation history. In Northern Sierra Nevada, California, the authors are investigating a tributary basin to the Middle Fork Feather River. A major incision signal from the river is well marked in a knickpoint within the tributary basin which stretches from its mouth to the Feather River at an elevation of ～700 m to the plateau at an elevation of ～1500 m. Hillslopes are significantly steeper below the knickpoint. The area’s total denudation rates are currently being constrained using cosmogenic radio nuclides, but a previous study suggested an order of magnitude difference in total denudation rates below and above the knickpoint. When compared with topographic attributes calculated from LIDAR data, physical erosion rates can be modeled as a linear function of ridge top curvature. Surprisingly, over the wide range of total denudation rates, soil thicknesses do not vary significantly until a threshold point where soil mantled landscapes abruptly shift to bedrock dominated landscapes. Bioturbation by tree falls appear to buffer soil thickness over the wide range of physical soil erosion rates. From three hillslopes with different physical erosion rates, the concentrations of Zr, which were considered conserved during dissolution and leaching, were determined and used as a proxy for the degree of mass losses via chemical denudation. There is a general trend that colluvial soils along the hillslopes with lower physical erosion rates are enriched in fine size fractions, Zr, and pedogenic crystalline Fe oxides. Likewise, the saprolites show greater degrees of chemical denudation at the sites above the knickpoint, presumably because of the saprolites’ longer turnover time in the slowly eroding landscapes. In the two steep hillslopes below the knickpoint, no significant or systematic topgraphic trends were found for soil geochemistry. However, soils show increasing Zr enrichment in the downslope direction in the hillslope above the knickpoint, which suggests a critical denudation rate beyond which soils’ turnover time is too short to develop a geochemical catena. As detailed CRN-based soil production rates and catchment scale denudation rates are acquired, the data will be combined with a mass balance model to calculate the rates of chemical denudation and weathering in soils and saprolites along the denudation gradient.  相似文献   

5.
Exposure dating using cosmogenic 36Cl demonstrates that the summit plateau of Scafell Pike (978 m) in the SW Lake District escaped erosion by glacier ice during the last glacial maximum (LGM; c. 26–21 kyr) and probably throughout the Devensian Glacial Stage (MIS 5d-2). Exposure ages obtained for ice-moulded bedrock on an adjacent col at 750–765 m confirm over-riding and erosion of bedrock by warm-based glacier ice during the LGM. The contrast between the two sites is interpreted in terms of preservation of tors, frost-shattered outcrops and blockfields on terrain above 840–870 m under cold-based ice. An exposure age of 17.3 ± 1.1 kyr for the col at 750–765 m suggests that substantial downwastage of the last ice sheet had occurred by c. 17 kyr, consistent with deglacial exposure ages obtained for other high-level sites in the British Isles. An exposure age of 12.5 ± 0.8 kyr obtained for a glacially transported rockfall boulder within the limits of later corrie glaciation confirms that the final episode of local glaciation in the Lake District occurred during the Loch Lomond Stade (c. 12.9–11.7 kyr). This research also demonstrated the difficulties of obtaining reliable exposure ages from rhyolite and andesite bedrock that has proved resistant to glacial abrasion.  相似文献   

6.
《Quaternary Research》2014,81(3):538-544
Measurements of 137Cs concentration in soils were made in a representative catchment to quantify erosion rates and identify the main factors involved in the erosion in the source region of the Yellow River in the Tibetan Plateau. In order to estimate erosion rates in terms of the main factors affecting soil loss, samples were collected taking into account the slope and vegetation cover along six selected transects within the Dari County catchment. The reference inventory for the area was established at a stable, well-preserved, site of small thickness (value of 2324 Bq·m− 2). All the sampling sites had been eroded and 137Cs inventories varied widely in the topsoil (14.87–25.56 Bq·kg− 1). The effective soil loss values were also highly variable (11.03–28.35 t·km− 1·yr− 1) in line with the vegetation cover change. The radiometric approach was useful in quantifying soil erosion rates and examining patterns of soil movement.  相似文献   

7.
The dynamics of granitic landscapes are modulated by bimodal weathering, which produces patchy granular soils and expanses of bare rock ranging from meter-scale boulders to mountain-scale domes. We used terrain analysis and with cosmogenic nuclide measurements of erosion rates to quantitatively explore Wahrhaftig’s decades-old hypothesis for the development of “stepped topography” by differential weathering of bare and soil-mantled granite. According to Wahrhaftig’s hypothesis, bare granite weathers slower than soil-mantled granite; thus random erosional exposure of bare rock leads to an alternating sequence of steep, slowly weathering bedrock “steps” and gently sloped, but rapidly weathering, soil-mantled “treads.” Our investigation focused on the terrain surrounding the Southern Sierra Critical Zone Observatory (CZO), which is underlain by granitic bedrock and lies outside the limits of recent glaciation, in the heart of the stepped topography described by Wahrhaftig. Our digital terrain analysis confirms that steep steps often grade into gentle treads, consistent with Wahrhaftig’s hypothesis. However, we observe a mix-and-match of soil and bare rock on treads and steps, contrary to one of the hypothesis’ major underpinnings – that bare rock should be much more common on steps than on treads. Moreover, the data show that bare rock is not as common as expected at step tops; Wahrhaftig’s hypothesis dictates that step tops should act as slowly eroding base levels for the treads above them. The data indicate that, within each landscape class (i.e., the steps and treads), bare rock erodes more slowly than surrounding soil. This suggests that the coupling between soil production and denudation in granitic landscapes harbors a tipping point wherein erosion rates decrease when soils are stripped to bedrock. Although broadly consistent with the differential weathering invoked by Wahrhaftig, the data also show that steps are eroding faster than treads, undermining Wahrhaftig’s explanation for the origins of the steps. The revised interpretation proposed here is that the landscape evolves by back-wearing of steps in addition to differential erosion due to differences in weathering of bare and soil-mantled granite.  相似文献   

8.
《Applied Geochemistry》2004,19(8):1217-1232
Laboratory experiments were conducted with volcanic ash soils from Mammoth Mountain, California to examine the dependence of soil dissolution rates on pH and CO2 (in batch experiments) and on oxalate (in flow-through experiments). In all experiments, an initial period of rapid dissolution was observed followed by steady-state dissolution. A decrease in the specific surface area of the soil samples, ranging from 50% to 80%, was observed; this decrease occurred during the period of rapid, initial dissolution. Steady-state dissolution rates, normalized to specific surface areas determined at the conclusion of the batch experiments, ranged from 0.03 μmol Si m−2 h−1 at pH 2.78 in the batch experiments to 0.009 μmol Si m−2 h−1 at pH 4 in the flow-through experiments. Over the pH range of 2.78–4.0, the dissolution rates exhibited a fractional order dependence on pH of 0.47 for rates determined from H+ consumption data and 0.27 for rates determined from Si release data. Experiments at ambient and 1 atm CO2 demonstrated that dissolution rates were independent of CO2 within experimental error at both pH 2.78 and 4.0. Dissolution at pH 4.0 was enhanced by addition of 1 mM oxalate. These observations provide insight into how the rates of soil weathering may be changing in areas on the flanks of Mammoth Mountain where concentrations of soil CO2 have been elevated over the last decade. This release of magmatic CO2 has depressed the soil pH and killed all vegetation (thus possibly changing the organic acid composition). These indirect effects of CO2 may be enhancing the weathering of these volcanic ash soils but a strong direct effect of CO2 can be excluded.  相似文献   

9.
Understanding the interactions of climate, physical erosion, chemical weathering and pedogenic processes is essential when considering the evolution of critical zone systems. Interactions among these components are particularly important to predicting how semiarid landscapes will respond to forecasted changes in precipitation and temperature under future climate change. The primary goal of this study was to understand how climate and landscape structure interact to control chemical denudation and mineral transformation across a range of semiarid ecosystems in southern Arizona. The research was conducted along the steep environmental gradient encompassed by the Santa Catalina Mountains Critical Zone Observatory (SCM-CZO). The gradient is dominated by granitic parent materials and spans significant range in both mean annual temperature (>10 °C) and precipitation (>50 cm a?1), with concomitant shift in vegetation communities from desert scrub to mixed conifer forest. Regolith profiles were sampled from divergent and convergent landscape positions in five different ecosystems to quantify how climate-landscape position interactions control regolith development. Regolith development was quantified as depth to paralithic contact and degree of chemical weathering and mineral transformation using a combination of quantitative and semi-quantitative X-ray diffraction (XRD) analyses of bulk soils and specific particle size classes. Depth to paralithic contact was found to increase systematically with elevation for divergent positions at approximately 28 cm per 1000 m elevation, but varied inconsistently for convergent positions. The relative differences in depth between convergent and divergent landscape positions was greatest at the low and high elevation sites and is hypothesized to be a product of changes in physical erosion rates across the gradient. Quartz/Plagioclase (Q/P) ratios were used as a general proxy for bulk regolith chemical denudation. Q/P was generally higher in divergent landscape positions compared to the adjacent convergent hollows. Convergent landscape positions appear to be collecting solute-rich soil–waters from divergent positions thereby inhibiting chemical denudation. Clay mineral assemblage of the low elevation sites was dominated by smectite and partially dehydrated halloysite whereas vermiculite and kaolinite were predominant in the high elevation sites. The increased depth to paralithic contact, chemical denudation and mineral transformation are likely functions of greater water availability and increased primary productivity. Landscape position within a given ecosystem exerts strong control on chemical denudation as a result of the redistribution of water and solutes across the landscape surface. The combined data from this research demonstrates a strong interactive control of climate, landscape position and erosion on the development of soil and regolith.  相似文献   

10.
《Applied Geochemistry》2004,19(11):1655-1686
Water samples from short-screen monitoring wells installed along a 90-km transect in southwestern Kansas were analyzed for major ions, trace elements, isotopes (H, B, C, N, O, S, Sr), and dissolved gases (He, Ne, N2, Ar, O2, CH4) to evaluate the geochemistry, radiocarbon ages, and paleorecharge conditions in the unconfined central High Plains aquifer. The primary reactions controlling water chemistry were dedolomitization, cation exchange, feldspar weathering, and O2 reduction and denitrification. Radiocarbon ages adjusted for C mass transfers ranged from <2.6 ka (14C) B.P. near the water table to 12.8 ± 0.9 ka (14C) B.P. at the base of the aquifer, indicating the unconfined central High Plains aquifer contained a stratified sequence of ground water spanning Holocene time. A cross-sectional model of steady-state ground-water flow, calibrated using radiocarbon ages, is consistent with recharge rates ranging from 0.8 mm/a in areas overlain by loess to 8 mm/a in areas overlain by dune sand. Paleorecharge temperatures ranged from an average of 15.2 ± 0.7 °C for the most recently recharged waters to 11.6 ± 0.4 °C for the oldest waters. The temperature difference between Early and Late Holocene recharge was estimated to be 2.4 ± 0.7 °C, after taking into account variable recharge elevations. Nitrogen isotope data indicate NO3 in paleorecharge (average concentration=193 μM) was derived from a relatively uniform source such as soil N, whereas NO3 in recent recharge (average concentration=885 μM) contained N from varying proportions of fertilizer, manure, and soil N. Deep water samples contained components of N2 derived from atmospheric, denitrification, and deep natural gas sources. Denitrification rates in the aquifer were slow (5 ± 2× 10−3 μmol N L−1 a−1), indicating this process would require >10 ka to reduce the average NO3 concentration in recent recharge to the Holocene background concentration.  相似文献   

11.
The role of ocean feedback on monsoon variations at 6 and 9.5 kyr Before Present (BP) compared to present-day is investigated by using sets of simulations computed with the IPSL–CM4 ocean–atmosphere coupled model and simulations with the atmospheric model only with the SST prescribed to the present-day simulation for the coupled model. This work is complementary to the study by Marzin and Braconnot (2009) who have analyzed in detail the response of Indian and African monsoons to changes in insolation at 6 and 9.5 kyr BP using the IPSL–CM4 coupled model. The monsoon rainfall was intensified at 6 and 9.5 kyr BP compared to 0 kyr BP as a result of the intensified seasonal cycle of insolation in the Northern Hemisphere. In this paper, the impact of the ocean feedback is analysed for the Indian, East-Asian and African monsoons. The response of the ocean to the 6 and 9.5 kyr BP insolation forcing shares similarities between the two periods, but we highlight local differences and a delay in the response of the surface ocean between 6 and 9.5 kyr BP. The ocean feedback is shown to be positive for the early stage of the African monsoon. A dipole of SST in the tropical Atlantic favouring the earlier build-up of the monsoon in the 6 and 9.5 kyr BP coupled simulations. However, it is strongly negative for the Indian and East Asian monsoons, and of stronger amplitude at 9.5 than at 6 kyr BP over India. In these Asian regions, the convection is more active over the ocean than over the continent during the late monsoon season due to the ocean feedback. The results are consistent with previous studies about 6 kyr BP climate. In addition, it is shown that the ocean feedback is not sufficient to explain the relative amplifications of the different monsoon systems within the three periods of the Holocene, but that the mechanisms such as the effect of the precession on the seasonal cycle of monsoons as discussed in Marzin and Braconnot (2009) are more plausible.  相似文献   

12.
To better understand chemical weathering and controlling processes in the Yalong River of the eastern Tibetan Plateau, this study presents major ion concentrations and stable isotopes of the dissolved loads. The isotopic compositions (δ13C-DIC, δ34S and δ18O-SO4) of the dissolved loads are very useful to quantify solute sources and define the carbon budget related with chemical weathering in riverine systems. The isotopic composition of sulphate demonstrates that most of the sulphate is derived from sulphide oxidation, particularly in the upper reach of the Yalong River. The correlations between δ13C-DIC, water chemistry and isotopes of sulphate, suggest that the carbon dynamics are mainly affected by carbonate weathering by sulphuric acid and equilibration processes. Approximately 13% of the dissolved inorganic carbon in the Yalong River originates from carbonate weathering by strong acid. The CO2 consumption rates are estimated to be 2.8 × 105 mol/km2/yr and 0.9 × 105 mol/km2/yr via carbonate and silicate weathering in the Yalong River, respectively. In this study, the influence of sulphide oxidation and metamorphic CO2 on the carbon budget is estimated for the Yalong River draining the eastern Tibetan Plateau.  相似文献   

13.
The Albany-Fraser Orogen (AFO), southeast Western Australia, is an underexplored, deeply weathered regolith-dominated terrain that has undergone complex weathering associated with various superimposed climatic events. For effective geochemical exploration in the AFO, integrating landscape evolution with mineralogical and geochemical variations of regolith and bedrock provides fundamental understanding of mechanical and hydromorphic dispersion of ore and pathfinder elements associated with the different weathering processes.In the Neale tenement, northeast of the AFO, a residual weathering profile that is 20-55 m thick was developed under warm and humid climatic conditions over undulating Proterozoic sheared granitoids, gneisses, schists and Au-bearing mafic rocks. From the base, the typical weathering profile consists of saprock, lower ferruginous saprolite, upper kaolinitic saprolite and discontinuous silcrete duricrust or its laterally coeval lateritic residuum. These types of duricrusts change laterally into areas of poorly-cemented kaolinitic grits or loose lateritic pisoliths and nodules.Lateritic residuum probably formed on remnant plateaus and was transported mechanically under arid climatic conditions over short distances, filling valleys to the southeast. Erosion of lateritic residuum exposes the underlying saprolite and, together with dilution by aeolian sands, constitutes the transported overburden (2-25 m thick). The reworked lateritic materials cover the preserved silcrete duricrusts in valleys. The lower ferruginous saprolite and lateritic residuum are well developed over mafic and sulphide-bearing bedrocks, where weathering of ferromagnesian minerals and sulphides led to enrichment of Fe, Cu, Ni, Cr, Co, V and Zn in these units. Kaolinitic saprolite and the overlying pedogenic silcrete are best developed over alkali granites and quartzofeldspathic gneisses, which are barren in Au and transition elements, and enriched in silica, alumina, rare earth and high field strength elements.A residual Au anomaly is formed in the lower ferruginous saprolite above a Au -bearing mafic intrusion at the Hercules prospect, south of the Neale tenement, without any expression in the overlying soil (< 20 cm). Conversely, a Au anomaly is recorded in the transported cover, particularly in the uppermost 3 m at the Atlantis prospect, 5 km southwest of the Hercules prospect. No anomalies have been detected in soils using five different size fractions (> 2,000 μm, 2,000-250 μm, 250-53 μm, 53-2 μm and < 2 μm). Therefore, soil cannot be efficiently applied as a reliable sampling medium to target mineralization at the Neale tenement. This is because mechanical weathering was interrupted by seasonal periods of intensive leaching under the present-day surface conditions and/or dilution by recently deposited aeolian sediments which obscure any signature of a potential Au anomaly in soils. Therefore, surface soil sampling should extend deeper than 20 cm to avoid dilution by aeolian sands and seasonal leaching processes. Regolith mapping and the distinction between the residual and transported weathering products are extremely significant to follow the distal or proximal mineralization.  相似文献   

14.
Mylonite textures in granodiorite boulders are responsible for higher rates of surface denudation of host rocks and the progressive development of unusual rock weathering features, termed weathering posts. These textures are characterized by smaller grain sizes, higher biotite content, and a higher biotite axial ratio in host rocks relative to weathering posts. Elemental concentrations do not show a significant difference between weathering posts and the host rocks in which they are found, and this reflects the absence of a weathering residue on the rock surfaces. Chemical weathering loosens the bonds between mineral grains through the expansion of biotite, and the loosened grains fall off or are blown off the boulder surface and continue their chemical alteration in the surrounding soil. The height of weathering posts on late Quaternary moraines increases at a linear rate of ~ 1.45 ± 0.45 cm (1000 yr)? 1 until post heights reach the diameter of host rocks. Such a rate of boulder denudation, if unrecognized, would generate significant errors (> 20%) in cosmogenic exposure ages for Pleistocene moraines. Given the paucity of boulders with diameters that significantly exceed 1.5 m, the maximum age of utility of weathering posts as a numeric age indicator is ~ 100 ka.  相似文献   

15.
Soils derived from black shale can accumulate high concentrations of elements of environmental concern, especially in regions with semiarid to arid climates. One such region is the Colorado River basin in the southwestern United States where contaminants pose a threat to agriculture, municipal water supplies, endangered aquatic species, and water-quality commitments to Mexico. Exposures of Cretaceous Mancos Shale (MS) in the upper basin are a major contributor of salinity and selenium in the Colorado River. Here, we examine the roles of geology, climate, and alluviation on contaminant cycling (emphasis on salinity and Se) during weathering of MS in a Colorado River tributary watershed. Stage I (incipient weathering) began perhaps as long ago as 20 ka when lowering of groundwater resulted in oxidation of pyrite and organic matter. This process formed gypsum and soluble organic matter that persist in the unsaturated, weathered shale today. Enrichment of Se observed in laterally persistent ferric oxide layers likely is due to selenite adsorption onto the oxides that formed during fluctuating redox conditions at the water table. Stage II weathering (pedogenesis) is marked by a significant decrease in bulk density and increase in porosity as shale disaggregates to soil. Rainfall dissolves calcite and thenardite (Na2SO4) at the surface, infiltrates to about 1 m, and precipitates gypsum during evaporation. Gypsum formation (estimated 390 kg m−2) enriches soil moisture in Na and residual SO4. Transpiration of this moisture to the surface or exposure of subsurface soil (slumping) produces more thenardite. Most Se remains in the soil as selenite adsorbed to ferric oxides, however, some oxidizes to selenate and, during wetter conditions is transported with soil moisture to depths below 3 m. Coupled with little rainfall, relatively insoluble gypsum, and the translocation of soluble Se downward, MS landscapes will be a significant nonpoint source of salinity and Se to the Colorado River well into the future. Other trace elements weathering from MS that are often of environmental concern include U and Mo, which mimic Se in their behavior; As, Co, Cr, Cu, Ni, and Pb, which show little redistribution; and Cd, Sb, V, and Zn, which accumulate in Stage I shale, but are lost to varying degrees from upper soil intervals. None of these trace elements have been reported previously as contaminants in the study area.  相似文献   

16.
Recent work on the weathering of high standing islands (HSI’s) of New Zealand (Goldsmith et al., 2008), Dominica (Goldsmith et al., 2010) Martinique and Guadeloupe (Rad et al., 2006) and portions of the Philippines (Schopka et al., 2011) shows weathering rates based on stream water chemistry for areas draining andesitic terrains are comparable to weathering rates determined for basaltic terrains, indicating that andesite weathering might be much more important in drawing down atmospheric CO2 than previously recognized. While an easily erodible parent material has been largely attributed to sustaining rates at these locations, little is known to known regarding its associated reaction kinetics. We conducted a series of batch dissolution experiments on andesitic material collected from ∼10,000 year old tephra deposits from Dominica to determine the dissolution rate of major and trace mineral phases to better understand geochemical processes controlling weathering flux from these areas. Dissolution experiments were conducted over a range of pH (4 and 7) on bulk samples and mineral separates.The dissolution rates based on Si release from the Dominica tephra bulk samples were similar, and ranged from 0.04 to 0.13 μmole Si/g-day in water, and ∼0.14 to 0.27 μmole Si/g-day in dilute acid (initial pH ∼4). Although the bulk of the ash is predominately composed of vesicular felsic (Na–Al–Si) volcanic glass, reaction rates and stoichiometry indicate ash dissolution is dominated by the reactivity of trace Mg or Ca-bearing silicate phases (olivine, pyroxene or amphiboles) and Ca–phosphate phases (apatite), especially under slightly acidic conditions. Analysis of reacted phases by SEM shows little evidence of alteration of glassy material, whereas surfaces of Ca–Mg inosilicates, olivine and apatite show etched features indicative of dissolution. Results of the dissolution experiments suggest that, although these phases are relatively minor components of the ash, they contribute disproportionately to the overall weathering flux, and their reactivity may be particularly important in areas where physical weathering and erosion are constantly exposing new fresh surfaces available for chemical reaction.  相似文献   

17.
This study presents the results of the palynological and diatom analyses of the sediment core recovered in Hoton-Nur Lake (48°37′18″N, 88°20′45″E, 2083 m) in 2004. Quantitative reconstruction of the Holocene vegetation and climate dynamics in the semiarid Mongolian Altai suggests that boreal woodland replaced the primarily open landscape of northwestern Mongolia at about 10 kyr BP (1 kyr = 1000 cal yr) in response to a noticeable increase in precipitation from 200–250 mm/yr to 450–550 mm/yr. A decline of the forest vegetation and a return to a predominance of open vegetation types occurred after 5 kyr BP when precipitation sums decreased to 250–300 mm/yr. Prior to 11.5 kyr BP diatom concentrations are relatively low and the lake is dominated by planktonic Cyclotella and small Fragilariaceae, suggesting the existence of a relatively deep and oligotrophic/mesotrophic lake. The great abundance of Staurosirella pinnata from the beginning of the record until 10.7 kyr BP might imply intensified erosion processes in the catchment and this is fully consistent with the presence of scarce and dry vegetation and the generally arid climate during this period. From about 10.7 kyr BP, more planktonic diatom taxa appeared and increased in abundance, indicating that the lake became more productive as diatom concentration increased. This change correlates well with the development of boreal woodland in the catchment. Decrease in precipitation and changes in the vegetation towards steppe are reflected by the rapid increase in Aulacoseira distans from about 5 kyr BP. The Holocene pollen and diatom records do not indicate soil and vegetation cover disturbances by the anthropogenic activities, implying that the main transformations of the regional vegetation occurred as a result of the natural climate change. Our reconstruction is in agreement with the paleomonsoon records from China, demonstrating an abrupt strengthening of the summer monsoon at 12 kyr BP and an associated increase in precipitation and in lake levels between 11 and 8 kyr BP, followed by the stepwise attenuation of the monsoon circulation and climate aridization towards the modern level. The records from the neighboring areas of Kazakhstan and Russia, situated west and north of Hoton-Nur, demonstrate spatially and temporally different Holocene vegetation and climate histories, indicating that the Altai Mountains as a climate boundary are of pivotal importance for the Holocene environmental and, possibly, habitation history of Central Asia.  相似文献   

18.
《Earth》2007,80(1-2):75-109
The soil's resistance to concentrated flow erosion is an important factor for predicting rill and (ephemeral) gully erosion rates. While it is often treated as a calibration parameter in process-based soil erosion models, global change studies require the estimation of erosion resistance from measurable soil properties. Several laboratory and field experiments have been conducted to determine the erosion resistance of various types of soils, but no attempts have been made hitherto to summarize all these data and to explore them for general trends. In this study, all available data on the resistance of topsoils to concentrated flow erosion in terms of channel erodibility (Kc) and critical shear stress (τcr) has been collected together with all soil and environmental properties reported in literature to affect the soil erosion resistance. Reported Kc values for cropland topsoils range between 0.002 10− 3 s m− 1 and 250 10− 3 s m− 1 (n = 470), whereas τcr values range between 0 and 15 Pa (n = 522). It is demonstrated that so far, the heterogeneity of measurement methods, the lack of standardized definitions and the shortcomings of the flow shear stress model hamper the comparability of soil erosion resistance values from different datasets. Nevertheless, combining Kc and τcr data from different datasets, a general soil erosion resistance ranking for different soil textures can be proposed. The compiled dataset also reveals that tillage practices clearly affect Kc (Kc for conventional tillage > Kc for reduced tillage > Kc for no tillage) but not τcr.It was concluded that Kc and τcr are not related to each other and that soil and macro-environmental properties affecting the foremost do not necessarily affect the latter as well and vise versa. Often Kc seems to be a more appropriate parameter than τcr to represent the differences in soil erosion resistance under various soil and environmental conditions (e.g. bulk density, moisture content, consolidation, tillage). The two parameters represent different quantities and are therefore both needed to characterize the soil's resistance to concentrated flow erosion.  相似文献   

19.
Two coeval stalagmites from Katerloch Cave show pronounced intervals of low δ18O values around 8.2, 9.1, and 10.0 kyr (all ages are reported before the year 2000 AD) and represent an inorganic U–Th dated climate archive from the southeast of the European Alps, a region where only very few well-dated climate records exist. The O isotope curves, providing near-annual resolution, allow a direct comparison to the Greenland ice core records, as temperature was the primary factor controlling the O isotopic composition of Katerloch speleothems.The 8.2 kyr climate anomaly lasted about one century, from 8196 to 8100 yr, with a maximum amplitude of 1.1‰ at 8175 yr. The event is characterized by a rapid onset and a more gradual demise and U–Th data as well as annual lamina counting support a rapid climate change towards cooler conditions within 10–20 yr. There is no strong evidence that the 8.2 kyr anomaly was superimposed on a pronounced longer-term cooling episode, nor do the new data support two separate cooling events within the 8.2 kyr event as reported by other studies. Our record also shows a distinct climate anomaly around 9.1 kyr, which lasted 70–110 yr and showed a maximum amplitude of 1.0‰, i.e. it had a similar duration and amplitude as the (central) 8.2 kyr event. Compared to the 8.2 kyr event, the 9.1 kyr anomaly shows a more symmetrical structure, but onset and demise still occurred within a few decades only. The different progression of the 8.2 (asymmetrical) and 9.1 kyr anomaly (symmetrical) suggests a fundamental difference in the trigger and/or the response of the climate system. Moreover, both stalagmites show evidence of a climate anomaly around 10.0 kyr, which was of comparable magnitude to the two subsequent events.Using a well constrained modern calibration between air temperature and δ18O of precipitation for the study area and cave monitoring data (confirming speleothem deposition in Katerloch reflecting cave air temperature), a maximum cooling by ca 3 °C can be inferred at 8.2 and 9.1 kyr, which is similar to other estimates, e.g., from Lake Ammersee north of the Alps. The O isotopic composition of meteoric precipitation, however, is a complex tracer of the hydrological cycle and these temperature estimates do not take into account additional effects such as changes in the source area or synoptic shifts. Apart from that, the relative thickness of the seasonally controlled lamina types in the Katerloch stalagmites remains rather constant across the intervals comprising the isotopic anomalies, i.e. the stalagmite petrography argues against major shifts in seasonality during the early Holocene climate excursions.  相似文献   

20.
Coral terrace surveys and U-series ages of coral yield a surface uplift rate of ∼0.5 m/ka for Kisar Island, which is an emergent island in the hinterland of the active Banda arc–continent collision. Based on this rate, Kisar first emerged from the ocean as recently as ∼450 ka. These uplifted terraces are gently warped in a pattern of east–west striking folds. These folds are strike parallel to more developed thrust-related folds of similar wavelength imaged by a seismic reflection profile just offshore. This deformation shows that the emergence of Kisar is influenced by forearc closure along the south-dipping Kisar Thrust. However, the pinnacle shape of Kisar and the protrusion of its metamorphic rocks through the forearc basin sediments also suggest a component of extrusion along shear zones or active doming.Coral encrusts the island coast in many locations over 100 m above sea level. Terrace morphology and coral ages are best explained by recognizing major surfaces as mostly growth terraces and minor terraces as mostly erosional into older terraces. All reliable and referable coral U-series ages determined by MC-ICP-MS correlate with marine isotope stage (MIS) 5e (118–128 ka). The only unaltered coral samples are found below 6 m elevation; however an unaltered Tridacna (giant clam) shell in growth position at 95 m elevation yields a U-series age of 195 ± 31 ka, which corresponds to MIS 7. This age agrees with the best-fit uplift model for the island. Loose deposits of unaltered coral fragments found at elevations between 8 and 20 m yield U-series ages of <100 years and may represent paleotsunami deposits from previously undocumented tectonic activity in the region.  相似文献   

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