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1.
矿床新类型的识别往往导致大批矿床和成矿省的发现，预测和识别矿床新类型是矿床研究的重要任务之一。造山型金矿的普遍性和重要性已被世界范围的大量研究所证明，但其他矿种的造山型矿床却很少被涉及。笔者提出了造山型矿床的概念及其变质流体成矿的实质，建立了矿床、矿田和成矿省等不同尺度的造山型矿床成矿模式及其随时间演化的3阶段模式。强调会聚造山作用的挤压伸展转变期是大规模成矿时间。同造山成矿系统的特点是成矿年龄滞后于造山作用时间。通过矿床实例研究证明了造山型银矿床、铅锌矿床、铜矿床和钼矿床的客观存在．阐明了中国巨大的造山型矿床的勘查潜力，例证了运用矿田尺度成矿模式进行成矿预测的有效性和重要意义。 相似文献
2.
准噶尔造山带碰撞体制的成矿作用及金等矿床分布规律 总被引：35，自引：0，他引：35
准噶尔造山带是乌拉尔—蒙古造山带的重要组成部分。该区的碰撞造山作用主要发生在石炭纪和二叠纪,并经历了先挤压后伸展的演化过程。区内的金等矿床主要就位于晚石炭世—二叠纪,集中分布在碰撞造山作用较强烈的地带,矿床形成于碰撞作用的挤压—伸展转变期。因此该区金等矿床的成矿时间、空间和地球动力学背景等与碰撞造山作用发生的时间、空间及动力学背景完全吻合,表明适于用碰撞造山成矿模式指导找矿和研究。而该区矿床的实际分布也确与碰撞造山成矿模式完全一致。 相似文献
3.
碰撞造山作用期后伸展体制下的成矿作用——以小秦岭金矿集中区为例 总被引：3，自引：0，他引：3
小秦岭在中生代期间经历了强烈的构造活动变迁，区域构造体制由挤压向伸展过渡，并最终在伸展体制下于晚燕山期形成小秦岭变质核杂岩，其深部过程为中国东部大陆岩石圈拆沉作用而引起软流圈物质上涌。小秦岭是中国重要的金矿集中区，主要产出3种类型的金矿床，其空间分布规律和成矿时代特征表明，本区金的成矿作用奏始于碰撞造山作用的后期，主成矿期发生在造山作用期后以伸展体制为主导的晚燕山期。碰撞造山带在造山作用期后常常发育伸展构造，伸展体制下的变形变质演化和多源流体活动使大规模成矿作用成为可能。 相似文献
4.
小秦岭在中生代期间经历了强烈的构造活动变迁,区域构造体制由挤压向伸展过渡,并最终在伸展体制下于晚燕山期形成小秦岭变质核杂岩,其深部过程为中国东部大陆岩石圈拆沉作用而引起软流圈物质上涌.小秦岭是中国重要的金矿集中区,主要产出3种类型的金矿床,其空间分布规律和成矿时代特征表明,本区金的成矿作用奏始于碰撞造山作用的后期,主成矿期发生在造山作用期后以伸展体制为主导的晚燕山期.碰撞造山带在造山作用期后常常发育伸展构造,伸展体制下的变形变质演化和多源流体活动使大规模成矿作用成为可能. 相似文献
5.
义敦岛弧是喜马拉雅巨型造山带中的一个复合造山带,它经历了印支期洋壳俯冲造山、燕山湖弧-陆碰撞和喜马拉雅期陆内走滑作用诸演化历史。可能由于洋壳板片俯冲角度不同,义敦晚三叠世古岛弧带(206～237 Ma)南北两段具有不同的发育历史,北段昌台弧以发育孤间裂谷为特色,具张性弧特征,发育扩张环境流体聚敛成矿系统,形成VMS型Zn-Pb-Cu矿床和浅成低温热液型Ag-Au-Hg矿床;南段中甸弧不发育弧后盆地,但广泛发育钙碱性弧火山岩-玢岩-斑岩杂岩系和挤压环境岩浆-流体成矿系统,形成斑岩型-夕卡岩型铜多金属矿床。在三叠纪-侏罗纪之交的弧-陆碰撞作用中,早期大陆板片俯冲形成同碰撞花岗岩带(约200 Ma),晚期造山后伸展作用,形成A型花岗岩带(75～138 Ma),伴随扬子大陆板片俯冲而发生的强烈剪切和推覆,在甘孜-理塘蛇绿混杂带发育挤压剪切环境流体聚敛成矿系统,形成剪切带型金矿。伴随造山后伸展和A型花岗岩侵位,发育伸张环境岩浆-流体聚敛成矿系统,主要形成夕卡岩型锡矿和构造破碎带热浪脉型银多金属矿床。印度-亚洲大陆碰撞在义敦造山带主要表现为陆内走滑作用,并控制碱性花岗岩和花岗斑岩的发育(50～30 Ma),伴随斑岩型金矿的形成。 相似文献
6.
三叠纪构造演化在中国地质历史过程中具有强度大、影响广泛的特点,然而与三叠纪重大构造事件有关的成矿作用研究明显滞后。本文基于最新研究成果,初步系统论述了中国三叠纪大规模成矿时空分布及基本特点。中国三叠纪金属矿产主要分布在昆仑—秦岭和红河—哀牢山两个三叠纪主造山带及其邻区,另外在华南、东北和新疆三个板内也发育有一系列多金属矿产。三叠纪矿床类型主要包括:①与基性-超基性岩有关的Cu-Ni硫化物矿;②与中酸性-酸性岩有关的斑岩Cu-Au、Cu-Mo、Mo矿,矽卡岩型Cu-Pb-Zn、Cu-Fe、Sn、W矿和脉状Au矿;③与高温气液-流体有关的伟晶岩型稀有金属矿;④与造山过程构造-热-流体有关的造山型Au矿;⑤与造山过程盆地流体有关的MVT型Pb-Zn矿;⑥与地幔流体有关的碳酸岩脉型Mo矿。昆仑—秦岭造山带内大多数三叠纪矿产都形成于碰撞造山或后碰撞环境,以前者为主。在东秦岭地区,三叠纪矿床以Mo、Au矿为主,形成时代集中在233～221 Ma;西秦岭地区三叠纪Au矿和Pb-Zn矿广泛分布,其中金矿受北西向脆韧性剪切构造带控制,而Pb-Zn矿集中出现在西成和凤太两大盆地内,成矿时代集中在晚三叠世(232～214 Ma);东昆仑地区新探明的一系列Cu-Mo-Fe多金属矿床,其成矿时代为240～210 Ma。红河—哀牢山造山带受新特提斯构造演化影响,三叠纪矿产呈零星出露,主要出现在中甸古岛弧区、造山带东侧的滇黔川接壤区和滇东南都龙地区。在中甸岛弧区整体表现为中部以斑岩-矽卡岩型Cu矿床为主,向南北两侧变为斑岩-浅成低温热液型Cu-Pb-Zn矿床和Au矿床,成岩成矿年龄集中于228～201 Ma;川滇黔地区近几年的测年结果显示出其主要的Pb-Zn矿都形成于三叠纪;滇东南都龙地区新近发现一组三叠纪W-Sn矿床,成矿时代集中在214～209 Ma。除两条主碰撞带外,三叠纪矿床还有华南稀有、W-Sn矿床,新疆稀有金属、Mo矿和东北及其邻区斑岩Mo矿、Cu-Ni硫化物矿和脉状Au矿等,其与板块碰撞的远程效应关系密切。其中,华南大多数三叠纪矿产与东西向构造-岩浆活动有关,来源于加厚地壳重熔形成的过铝质花岗岩上侵定位,而东北及其邻区、新疆及其毗邻的蒙古和俄罗斯阿尔泰及紧邻西伯利亚的三叠纪成矿作用则可能与地幔柱活动有关。 相似文献
7.
造山带热结构对大陆碰撞带的形态大小、构造式样、岩浆活动和变质作用具有重要控制作用。然而,热结构对碰撞成矿作用的控制还不清楚。本文概述比利牛斯、阿尔卑斯、加里东、扎格罗斯、青藏高原和华力西等全球主要碰撞带的热结构与成矿系统发育特征,对比各个造山带内不同矿床类型成矿温度变化,探讨热结构对碰撞成矿的控制作用。研究表明,碰撞带主要发育盆地流体有关的密西西比河谷型铅锌矿床、变质流体有关的造山型金矿床和岩浆热液有关矿床(斑岩铜矿床、云英岩型钨锡矿床和岩浆热液有关的铌钽锂铍矿床等)。其中,前两者在大多数碰撞带内均有发育,代表了大陆碰撞成矿作用的基本类型。这些矿床的成矿温度在热碰撞带比较高而在冷碰撞带则偏低。岩浆热液有关矿床一般只出现在比较热的碰撞带内,这些热碰撞带的温度压力条件有很大区域在湿固相线以内,热扰动能够造就地壳发生部分熔融形成含矿岩浆。 相似文献
8.
初论陆-陆碰撞与成矿作用——以青藏高原造山带为例 总被引：54，自引：9，他引：45
青藏高原碰撞造山带以其成矿规模大、形成时代新、矿床类型多、保存条件好诸特征而被誉为研究大陆成矿作用的天然实验室。文章基于青藏高原已有的矿产勘查与研究成果,概述了大陆碰撞过程中的主要成矿作用及其成矿带的时空分布,初步分析了陆一陆碰撞所造就的成矿背景和成矿环境以及控制成矿作用的关键地质过程．并草拟了可供今后研究的工作模型。初步研究认为,始于60Ma的印度大陆与亚洲大陆碰撞至少形成了3个重要的控矿构造单元,即雅鲁藏布江以北的主碰撞变形带,雅鲁藏布江以南的藏南拆离-逆冲带和高原东缘的藏东构造转换带。主碰撞变形带以巨大规模的地壳缩短、双倍地壳加厚、大规模逆冲系和SN向正断层系统发育为特征,控制了冈底斯斑岩铜矿带(含浅成低温热液金矿)、安多锑矿化带和风火山铜矿化带及腾冲锡矿带的形成及分布;藏南拆离一逆冲带由藏南拆离系(STDS6)和一系列北倾的叠瓦状逆冲断裂带构成,控制了藏南变质核杂岩型金矿化、热液脉型金锑矿化和蚀变破碎带型金锑矿化的形成;藏东构造转换带以发育大规模走滑断裂系统、大型剪切带、富碱斑岩带和走滑拉分盆地为特征,控制了玉龙斑岩铜矿带、哀牢山和锦屏山金矿带及兰坪盆地银多金属矿带的分布。按成矿系统的基本思想,初步将青藏高原碰撞造山带的成矿作用划分为3个成矿巨系统：大陆俯冲碰撞成矿巨系统、陆内走滑一剪切成矿巨系统和碰撞后伸展成矿巨系统。在大陆俯冲碰撞阶段,主要发育与流体迁移汇聚和排泄有关的锑金铜热液成矿系统和碰撞期花岗岩岩浆．流体锡稀有金属成矿系统;伴随陆．陆碰撞而发生的陆内走滑．剪切作用,主要导致了走滑拉分盆地银多金属热液成矿系统、斑岩型铜钼金成矿系统和剪切带型金成矿系统的形成;在碰撞后伸展阶段,主要发育受SN向正断层系统控制的斑岩铜矿成矿系统、浅成低温热液金矿成矿系统和热水沉积铯锂硼金属成矿系统。在此基础上,初步提出了碰撞造山带成矿作用的构造控制模型。 相似文献
9.
新疆北部金矿化与碰撞造山作用的耦合及金等矿床的分布规律 总被引：12，自引：0，他引：12
北疆是世界第二大碰撞造山带－乌拉尔－蒙古造山带的重要组成部分，是全球最典型的碰撞造山地区之一。该区的碰撞造山作用发生在石炭纪和二叠纪，呈先挤压后伸展的特征。北疆地区金等矿床的成矿作用主要发生在二叠纪，少数发生在晚石炭世，与碰撞造山作用的时间一致；金等矿床主要分布在碰撞造山作用较强烈的地带，金矿化与碰撞作用的空间吻合；金等矿床的成矿地球动力学背景是碰撞造山作用的挤压－伸展转变期。成矿时间、空间、地球 相似文献
10.
大陆碰撞成矿论 总被引：54，自引：2，他引：52
基于经典的板块构造而建立的成矿理论已日臻完善,完好地解释了增生造山成矿作用及汇聚边缘成矿系统发育机制,但却无法解释碰撞造山成矿作用及大陆碰撞带成矿系统。通过对青藏高原碰撞造山与成矿作用的详细研究,并与中国秦岭和其它碰撞造山带综合对比,本文系统提出了一套全新的大陆碰撞成矿理论,简称"大陆碰撞成矿论",初步阐明了大陆碰撞带成矿系统和大型矿床的成矿动力背景、深部作用过程和形成机制。该理论认为,伴随大陆三段式碰撞过程而发育的主碰撞陆陆汇聚环境、晚碰撞构造转换环境和后碰撞地壳伸展环境,是大陆碰撞带成矿系统和大型矿床的主要成矿构造背景。对应于三段式碰撞而在深部出现的俯冲板片断离、软流圈上涌和岩石圈拆沉过程,是导致大规模成矿作用的异常热能驱动力。伴随三段式碰撞而分别出现的压-张交替或压扭/张扭转换的应力场演变,是驱动成矿系统形成发育的构造应力机制。大陆碰撞产生的不同尺度的高热流、不同起源的富金属流体流、不同级次的走滑-剪切-拆离-推覆构造系统和张性裂隙系统,是形成成矿系统和大型矿床的主导因素。成矿金属在碰撞形成的壳/幔混源高fO2岩浆-热液系统、地壳深熔低fO2岩浆-热液系统、剪切变质-富CO2流体系统以及逆冲推覆构造驱动的区域卤水系统和浅位岩浆房诱发的对流循环流体系统中,伴随成矿金属的积聚与淀积是形成大型矿床的关键机制。"大陆碰撞成矿论"还强调,完整的大陆碰撞过程可以引发三次大规模成矿作用,形成一系列标示性的大型矿床:在主碰撞陆陆汇聚成矿期,大陆碰撞引发地壳加厚与深熔,产生富W-Sn壳源花岗岩,形成花岗岩型Sn-W矿床;大陆俯冲板片断离诱发软流圈上涌,产生富金属的壳/幔混源花岗闪长岩,形成岩浆-热液型或叠合型Pb-Zn-Mo-Fe矿床;大陆碰撞从变质地体排挤出富CO2流体,在剪切带形成造山型Au矿,从造山带排泄出建造流体,在前陆盆地形成MVT型Zn-Pb矿。在晚碰撞构造转换成矿期,大规模走滑断裂系统诱发壳幔过渡带和富集地幔减压熔融,其岩浆在浅部地壳岩浆房出溶成矿流体,分别形成斑岩型Cu(-Mo-Au)矿床和碳酸岩型REE矿床;深切岩石圈的剪切作用与下地壳变质产生含Au富CO2流体,形成造山型Au矿;逆冲推覆构造驱动地壳流体长距离迁移汇聚、走滑拉分导致流体大量排泄和充填,形成Pb-Zn-Cu-Ag矿。在后碰撞地壳伸展成矿期,新生下地壳部分熔融产生富金属、富水、高fO2埃达克质岩浆浅成侵位和流体出溶,产生斑岩型Cu矿;中上地壳部分熔融层(岩浆房)驱动地热流体系统,在地热区发育热泉型Cs-Au矿,在构造拆离带形成热液脉型Pb-Zn-Sb和Sb-Au矿。 相似文献
11.
利用GC-MS（气相色谱—质谱仪）,对采自湖北清江流域和尚洞洞顶的土壤样品与洞内石笋样品进行分析,发现土壤中存在的七个系列单甲基支链烷烃在所有的石笋样品中均可以找到,呈现相似的分布模式,石笋中七个系列支链烷烃有可能来自洞穴滴水携带的土壤中的支链烷烃,但是也不能排除石笋原地生长的微生物的贡献。烷基环己烷的分布在土壤与石笋中呈现了相似的分布模式,但是主峰碳数有所变化,高碳数部分与低碳数部分的相对含量也发生了变化。主要原因可能是微生物选择性降解的结果,也有可能是土壤与石笋中微生物种类分布差异所造成的。本次研究初步显示了相对封闭稳定的洞穴沉积物与上覆土壤层中生物标志化合物的异同。 相似文献
12.
At 31 sites in Finland the Zn content was determined of the epiphytic lichen Hypogymnia physodes (L.) Nyl. growing on pine and birch, the terricolous lichen Cladina spp. in pine bark, and the inner part of birch bark. The anomalous contents of Zn in H. physodes on pine and Cladina spp. in soil appeared to be strongly related to sulphide ore deposits. Anthropogenic Zn correlated closely with S and Fe in H. physodes on pine and with Fe in Cladina spp. The binding of geogenic Zn was related to iron hydroxides, and was attributed to the different uptake mechanism of S in these lichens. Elevated values of Zn in H. physodes on birch were due to both geogenic and anthropogenic sources. Zinc in pine bark increased with the Zn content in H. physodes and reached a limiting value. 相似文献
13.
Friedemann Freund 《Physics and Chemistry of Minerals》1987,15(1):1-18
The dissolution of H2O and CO2 in structurally dense, nominally anhydrous and non-carbonate oxide matrices such as MgO and CaO is reviewed. H2O and CO2 are treated as gaseous oxide components which enter into solid solution with the refractory oxide hosts. They form anion complexes associated with cation vacancy sites. Evidence is presented that OH? pairs which derive from the dissolution of H2O are subject to a charge transfer (CT) conversion into peroxy moieties and molecular hydrogen, O 2 2? ... H2. Because the O 2 2? moiety is small (O?-O? distance ≈ 1.5 Å) high pressure probably favors the CT conversion. Mass spectroscopic studies show that molecular H2 may be lost from the solid which retains excess oxygen in the form of O 2 2? , leading to the release of atomic O. The dissociation of O 2 2? moieties into a vacancy-bound O? state and an unbound O? state can be followed by measuring the internal redox reactions involving transition metal impurities, the transient paramagnetism of the O? and their effect on the d.c. conductivity. Evidence is presented that CO2 molecules dissolve dissociatively in the structurally dense oxide matrix, as if they were first to dissociate into CO+O and then to form separate solute moieties CO 2 2? and O 2 2? , both associated with cation vacancy sites. In the CO 2 2? moiety (C-O? distance 1.2–1.3 Å, OCO angle ≈ 130°) the C atom probably sits off center. The transition of the C atom into interstitial sites is accompanied by dissociation of the CO 2 2? moiety into CO? and O?. This transition can be followed by infrared spectroscopy, using OH? as local probes. Further support derives from magnetic susceptibility, thermal expansion, low frequency dielectric loss and low temperature deformation measurements. The recently observed emission of O and Mg atoms besides a variety of molecules such as CO, CO2, CH4, HCN and other hydrocarbons during impact fracture of MgO single crystals is presented and discussed in the light of the other experimental data. 相似文献
14.
There are few inter-African country urban analyses because of the continent’s enormous size and socioeconomic diversity, language barriers, and wide variations in national and regional urban research capacity. Nevertheless, comparative urban studies are critical in understanding contemporary African urbanization. In this comparative spatial and temporal analysis of Ghana and Kenya’s urbanization, we find that both countries are urbanizing rapidly and are faced with many common urban problems. Moreover, Ghana is more urbanized than Kenya and has a larger indigenous urban imprint and a more widely dispersed urban pattern. Besides their physiographic and population conditions, we trace these countries’ convergent and divergent urban trends to their shared but unique experiences of colonialism, nationalism and globalization. 相似文献
15.
Temporal and spatial variations in water discharge and sediment load in the Alaknanda and Bhagirathi Rivers in Himalaya, India 总被引：2，自引：0，他引：2
The Alaknanda and Bhagirathi Rivers originate in the mountainous regions of the Himalayas (Garhwal) and result in high sediment yields causing flood hazards downstream of the Ganga River and high sediment flux to the Bay of Bengal. The rivers are perennial, since runoff in these rivers is controlled by both precipitation and glacial melt. In the present study, three locations in the upper reaches of the Ganga River were monitored for 1 yr (daily observations of, more than >1000 samples) for suspended sediment concentrations. In addition, more than one hundred samples were collected from various locations of the Alaknanda and Bhagirathi Rivers at different periods to observe spatial and temporal variations in river suspensions. Further, multi-annual data (up to 40 yrs) of water flow and sediment concentrations were used for inferring the variations in water flow and sediment loads on longer time scales. In most previous studies of Himalayan Rivers, there has been a general lack of long term water flow and sediment load data. In the present study, we carried out high frequency sampling, considered long term discharge data and based on these information, discussed the temporal and spatial variations in water discharge and sediment loads in the rivers in the Himalayan region. The results show that, >75% of annual sediment loads are transported during the monsoon season (June through September). The annual physical weathering rates in the Alaknanda and Bhagirathi River basins at Devprayag are estimated to be 863 tons km−2 yr−1 (3.25 mm yr−1) and 907 tons km−2 yr−1 (3.42 mm yr−1) respectively, which are far in excess of the global average of 156 tons km−2 yr−1 (0.58 mm yr−1). 相似文献
16.
Discovery of Cinnabar in Soils in Hg Anomalous Zones in City and Town Areas and Their Surroundings and Its Significance 总被引：1，自引：1，他引：0
ZHU Lixin MA Shengming WANG Zhifeng China University of Geosciences Beijing Institute of Geophysical Geochemical Exploration Chinese Academy of Geological Sciences Langfang Hebei 《《地质学报》英文版》2005,79(2):286-290
As a result of systematic study on heavy minerals in soils at city and town areas and their surroundings,cinnabar was discovered for the first time in areas of Hg anomalies in China, and it was found that the distribution of cinnabar was basically coincident in scope with that of Hg anomalies, showing that Hg anomalies were‘closely related to cinnabar. This finding provides a theoretical basis for a verification of Hg anomalies in soils in city and town areas and their surroundings, as well as evaluation of its ecological effects, and is significant to revealing the occurrence modes and origin of Hg in soils. 相似文献
17.
《China Geology》2019,2(3):382-390
Ground gravity survey for regional structure unit delineation and oil and gas exploration in China is addressed in this paper with examples. Gravity survey scales, coverage, technical regulations and achievements at the national level are introduced, including data processing and anomaly interpretation techniques. Bouguer anomalies of terrestrial territories of China and classification of anomalous feature zones are also described; they are well correlated with lithotectonical boundaries, fault zones, and unexposed igneous plutons. Recent study results of petroliferous sedimentary basins are presented as well, including concealed boundaries and major structures of large basins. It is concluded that gravity survey is the most effective and economic method in unveiling unexposed and deep-seated structures, targeting and delineating oil and gas-bearing sedimentary basins, and locating main trap structures within prolific basins in early stage of exploration in China. Suggestions for improving exploration of both conventional and unconventional oil and gas reservoirs in China are also given in the paper. 相似文献
18.
煤中气孔和镶嵌结构及其在煤变质研究中的意义 总被引：1，自引：0，他引：1
河南省禹县、新密和荥巩煤田山西组Ⅱ1煤的贫煤和无烟煤中,气孔发育。气孔形态有椭圆状（图版1）、圆状及不规则状（图版2）,有的几个气孔连在一起呈大的朵状气孔(图版3)。此外,在荥巩煤田西部无烟煤中还发育有镀嵌结构(图版4)。 相似文献
19.
Using improved analytical techniques, which reduce the Re blanks by factors of 8 to 10, we report new Re-Os data on low Re and low PGE pallasites (PAL-anom) and IIIAB irons. The new pallasite samples nearly double the observed range in Re/Os for pallasites and allow the determination of an isochron of slope 0.0775 ± 0.0008 (T = 4.50 ± 0.04 Ga, using the adjusted λ187Re = 1.66 × 10−11 a−1) and initial (187Os/188Os)0 = 0.09599 ± 0.00046. If the data on different groups of pallasites (including the “anomalous” pallasites) are considered to define a whole-rock isochron, their formation would appear to be distinctly younger than for the iron meteorites by ∼60 Ma. Five IIIAB irons (Acuna, Bella Roca, Chupaderos, Grant, and Bear Creek), with Re contents ranging from 0.9 to 2.8 ppb, show limited Re/Os fractionation and plot within errors on the IIAB iron meteorite isochron of slope 0.07848 ± 0.00018 (T = 4.56 ± 0.01 Ga) and initial (187Os/188Os)0 = 0.09563 ± 0.00011. Many of the meteorites were analyzed also for Pd-Ag and show 107Ag enrichments correlated with Pd/Ag, requiring early formation and fractionation of the FeNi metal, in a narrow time interval, after injection of live 107Pd (t1/2 = 6.5 Ma) into the solar nebula. Based on Pd-Ag, the typical range in relative ages of these meteorites is ≤10 Ma. The Pd-Ag results suggest early formation and preservation of the 107Pd-107Ag systematics, both for IIIAB irons and for pallasites, while the younger Re-Os apparent age for pallasites suggests that the Re-Os system in pallasites was subject to re-equilibration. The low Re and low PGE pallasites show significant Re/Os fractionation (higher Re/Os) as the Re and PGE contents decrease. By contrast, the IIIAB irons show a restricted range in Re/Os, even for samples with extremely low Re and PGE contents. There is a good correlation of Re and Ir contents. The correlation of Re and Os contents for IIIAB irons shows a similar complex pattern as observed for IIAB irons (Morgan et al., 1995), and neither can be ascribed to a continuous fractional crystallization process with uniform solid-metal/liquid-metal distribution coefficients. 相似文献
20.
Trends in Analytical Developments and Earth Science Applications in LA-ICP-MS and LA-MC-ICP-MS for 2004 and 2005 总被引：1，自引：0，他引：1
Paul J. Sylvester 《Geostandards and Geoanalytical Research》2006,30(3):197-207
This review of laser ablation-inductively coupled plasma-mass spectrometry includes research that employed quadrupole instruments, and single-collector and multicollector magnetic sector field instruments. The most important trend in 2004–2005 was the growing appreciation that small matrix effects in LA-(MC)-ICP-MS need to be addressed in order to produce highly precise and accurate data by the method. The issue is most acute for isotope ratio measurements that require standard-sample-standard bracketing but can also be important for certain elemental analysis. Matrix-dependent elemental and isotopic fractionations were studied from the standpoint of laser-sample interactions and the behaviour of laser-generated particles in the ablation cell, transfer tubing and ICP torch. Innovations in LA-(MC)-ICP-MS involved signal smoothing, in torch laser ablation, on-line isotope dilution and molecular oxide monitoring. Other important research was carried out on the calibration and homogeneity of various reference materials; and the exploration of mature ( in situ U-Pb geochronology) and emerging (apatite fission-track chronometry, U-Th/He thermochronology, boron/strontium/uranium-series isotopic microanalysis) applications in the Earth sciences. 相似文献