共查询到20条相似文献，搜索用时 78 毫秒
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在硫酸溶液中，以Ag2SO4为摧化剂，加入过量K2Cr2O7标准溶液氧化土壤中的有机碳，然后用FeSO4标准溶液滴定剩余的K2Cr2O7标准溶液，返滴定法测定有机碳含量。实验测得S为0．0186(n＝15)，RSD％为3．60(X^-＝0．518％)；到定土境和水系沉积物等国家标准物质中有机碳的含量，相对误差小于11．5％。 相似文献
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对藏南发育完整的、厚度巨大的海相白垩纪地层中的暗色泥、页岩开展了有机质丰度研究。综合分析结果表明：该区泥、页岩中残余有机碳含量在0.05％~1.1％之间,平均值约为0.42％,其中下白垩统约为0.531％,上白垩统约为0.265％,有机碳平均含量变化特征与该区的古地理格局及海平面升降有关。氯仿沥青‘A’含量在0.0009％~0.0072％之间,平均含量约为0.0040％。有机碳与氯仿沥青‘A’最大值与最小值之比分别为22和8。有机碳与氯仿沥青‘A’这种弱负相关性与两者遭受剧烈的地表风化作用、强烈的紫外线照射和高程度有机质热演化后的损失量有关,后者远大于前者。白垩系残余有机碳含量大于0.6％的中等—好生油岩样10件,占样品总数的27％,下白垩统样品9件,占样品总数的24.3％,上白垩统样品1件,占样品总数的2.7％,表明来自北喜马拉雅地区东山组和康马—隆子地区甲不拉组的早白垩世泥、页岩为该区主要的有效生油岩。 相似文献
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对黔北地区上奥陶统五峰组烃源岩的有机碳、类异戊间二烯烃、萜烷等有机地球化学特征进行研究,发现具有以下特征：①有机碳含量大于3％,且纵向变化小分布稳定;②有机硫碳比值倾向于高值,平均可达0．1;③Pr／Ph比值小于1,具有明显的植烷优势;④伽马蜡烷指数大于0．15;⑤δ^13Corg-30％。普遍偏轻;⑥Ts／（Tm＋Ts）在0;361-0．518之间,平均为0．455。这些特征均指示研究区五峰期的有机物产率高,同时具有有利于有机质保存的还原环境。对比岩性及有机地球化学剖面,认为晚五峰期有机质保存条件优于早期,中五峰期上升洋流活跃。 相似文献
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用有机岩石学、元素分析和饱和烃气相色谱等方法,分析了凡口铅锌矿矿区有机质的有机地球化学特征,对有机质在该铅锌矿成矿地球化学过程中的作用进行了初步探讨。该矿区的主岩富含有机质,有机碳含量为0．03％-0．4％,平均为0．16％,有机碳和金属矿化有同步变化趋势。有机质具有高的演化程度,经换算,镜质体反射率为1．92％-3．55％,且绝大多数高于3．0％。饱和烃气相色谱的特征表明,含矿地段的有机质在成矿热液的作用下发生热裂解和热变质,其裂解产生的甲烷和新生成的干酪根等有机化合物作为还原剂,使硫酸根还原成硫化氢,还原生成的硫化氢进一步与成矿金属离子反应生成金属硫化物沉淀,并最终富集成矿。另外,草莓状黄铁矿的存在,说明了在沉积作用早期,细菌可能直接参与了成矿作用。 相似文献
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胶州湾李村河口沉积物中硫化物形成的控制因素 总被引：1，自引：0，他引：1
在胶州湾李村河口,对多个短柱状岩芯沉积物中的有机质（有机碳和有机氮）、酸可挥发性硫化物（AVS）、黄铁矿及活性铁等进行了分析。结果表明,样品的有机质含量较高,有机碳含量为0．16％～3．21％,有机氮含量为0．002％-0．2％;6个短柱状样的AVS含量变化较大：198．4—0．4umol／g,平均35．6umol／g;活性铁含量为47．5～169．3umol／g,平均91．4umol／g;黄铁矿含量为14．8～41．0umol／g,平均28．7umol／g。通过计算沉积物中活性铁的黄铁矿化度（DOP）与硫化度（DOS）指标,及分析各参数间相关性,发现以下现象：（1）胶州湾李村河口沉积物中的活性铁被转化为硫化物的程度较高,被转化为黄铁矿的程度较低,沉积物中的黄铁矿得到了较好保存。DOP不适宜用作河口区氧化还原状态的判断指标,DOS对氧化还原状态的响应更加灵敏;（2）距河口较近的区域,受李村河河水的影响较大,易分解有机质供应充足,AVS大量形成,其向黄铁矿的转化并不充分,活性铁成为硫化物形成的控制因素。距河口较远的站位,活性铁含量相对充足,有机质含量相对不足,因此有机质含量成为硫化物形成的控制因素,AVS向黄铁矿的转化比较充分;（3）有机质尤其是易分解有机质含量是李村河口硫化物形成、活性铁富集及其黄铁矿化度的主要控制因素。AVS的形成主要受到有机氮的限制,而黄铁矿的形成主要受到有机碳的限制。因此,河流输入物质对河口区沉积物中C、S和Fe的循环具有显著的影响。 相似文献
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黔北早寒武世缺氧事件：生物标志化合物及有机碳同位素特征 总被引：8，自引：1，他引：8
本文首次报道了黔北早寒武世黑色岩系的生物标志化合物，并结合有机碳同位素组成特征，探讨该时期所发生的重大地质事件。所有样品均检出了丰富的正构烷烃、类异戊二烯烃、萜类化合物以及甾类化舍物。在GC谱图上，正构烷烃显示明显的单峰型分布特征，碳数分布范围为nC14-nC31主峰碳为nC18、nC19或nC20，nC17／nC31为1．15～50．17，显示轻烃组分占绝对优势，OEP值为0．84～1．11，CPI值为0．92～1．16，接近平衡值1．0，无明显的奇偶碳数优势分布。Pr／Ph值为0．24～0．79，具有明显的植烷优势。萜烷化合物以C30藿烷占优势，其相对丰度三环萜烷〉五环三萜烷〉四环萜烷，并且检出少量的γ-蜡烷。规则甾烷C27-C28-C29呈“V”字型分布，∑（C27＋C28）〉∑C29，其比值为1．25～1．99，∑C27／∑C29为0．78～1．22，重排甾烷C27／规则甾烷C27值为0．21～0．47。4-甲基甾烷普遍存在，但丰度相对较低。在地层剖面上，有机碳含量（TOC（％））从0．05～7．91％，平均为2．52％；有机碳同位素组成（δ^13Corg）从-29．49‰～-34．41‰（PDB），发生负偏移，偏移量达到4．3‰，代表该期海平面处于上升阶段，底层水处于严重缺氧状态，底栖生物缺乏。本文根据生物标志化合物特征参数，结合有机碳同位素组成变化，详细分析了黔北早寒武世这套黑色岩系的有机质来源、成熟度、沉积环境以及古海洋意义，将为我国南方早寒武纪古地理重建、地质事件记录提供可靠依据。 相似文献
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以29口钻孔的重矿物百分含量数据来分析样本,通过Q型聚类分析、因子分析方法恢复不同物源体系的发育范围及其母岩类型,并以不同物源体系的边界范围为限定条件,结合ZTR指数及其等值线图,对珠江口盆地惠州凹陷M层物源特征进行了系统的研究。研究结果表明：研究区发育3大物源沉积区,分别为东北-北部物源沉积区、西北物源沉积区和东南物源沉积区,且各区重矿物组合特征明显,主次物源分明,整体表现为母岩类型复杂的特征。东北-北部沉积物主要母岩为酸性岩浆岩,次要母岩为变质岩和沉积岩,西北沉积物主要母岩为中性及基性岩浆岩,次要母岩为酸性岩浆岩和变质岩,东南沉积物主要母岩为中性及基性岩浆岩,次要母岩为变质岩。东北-北部物源区和西北物源区为远源沉积的产物,而东南物源区为近源沉积的产物。东北-北部物源区沉积物来自北方和东北方向,而西北物源区和东南物源区沉积物分别来自西北方向和东南方向。 相似文献
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两种煤质分析指标的关联方程组研究 总被引：5，自引：0，他引：5
在综合分析大量文献资料的基础上，采用多元线性回归方法，利用MATLAB对大量煤质分析结果进行了回归分析，推导出了煤质元素分析与工业分析的关联方程组。新方法实现了由工业分析结果求元素分析成分的目的，具有重大的实用意义。 相似文献
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An algorithm andFortran-iv computer program,cabfac, forQ-mode factor analysis is described. The program will accept up to 1500 items and 50 variables on a moderate-size computer. 相似文献
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A piston core from the southern Blake Basin penetrated nine distinct bioclastic carbonate turbidites separated by pelagic terrigenous clay units. X-ray diffraction analysis of the carbonate mineralogy of the graded, laminated, and homogenous units of the individual turbidite units indicated a general loss of unstable carbonates in the homogenous unit beyond that contained in the lower two units. Univariate and multivariate statistical tests were employed to determine the significance of the changes and to determine if different units of a turbidite sequence could be consistently grouped by statistical methods. Principal components, discriminant function, and cluster analysis were used in the multivariate tests. The graded and laminated units were closely related in mineralogy with little significant differences. The mineralogy of the homogenous units was significantly different than that of the other two units except in one example. Cluster analysis generated five groupings of the samples with the end members consisting of graded and laminated units at one end and homogenous units at the other. 相似文献
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Ibsen Chivatá Cárdenas 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2019,13(1):53-65
In this paper, we report on the use of Bayesian networks, BNs, learnt from data generated by physical and numerical models, to overcome to a certain degree a number of complications in traditional slope stability analyses that jointly consider the mechanical and hydraulic properties of soils. Discrete Bayesian networks resulted to be useful and efficient to acquire knowledge from simulated data and to identify significant factors by the combined use of backward inference and global sensitivity analysis. Further, BNs enable decision thresholds to be estimated quickly. Along with this, backward inference and global sensitivity analysis are performed in BNs at low computation costs. Moreover, under conditions in which knowledge is scarce, we show how a practitioner can be better informed using the proposed approach. All these previously under-reported modelling features in the specialised literature encourage the further application of the proposed approach to enhance slope stability analysis. 相似文献
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以有限元结构矩阵分析为理论基础，结合应力应变测试和现场实际使用情况，利用计算机结构分析程序，对ＺＴ－Ａ系列三个不同高度钻塔的天梁、塔腿和绷绳做了结构应力分析，弄清了Ａ形塔在承受垂直荷载、水平荷载以及偏载条件下，组成钻塔的各构件的荷载及应力分布；对钻塔设计提出了改进意见；并从整体角度分析了绷绳的作用；对在不同荷载条件下有无绷绳时钻塔的结构应力从量上做了对比；最后提出了应当如何布置提升系统才会使钻塔处 相似文献
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Ulf Grenander 《Mathematical Geology》1975,7(3):267-278
A deformation mechanism is described and analyzed. It is intended for height patterns exposed to erosion and tectonic activity.
A simulation experiment is carried out for this model. Closedform expressions are derived for the covariance field, the properties
of spectral estimates, and for the optimal retrospective reconstruction of earlier, unknown height patterns. For obvious reasons
the author is in no position to make claims about the verisimilitude of the model. It is offered as an example of a potential
application to geology of the theory of patterns developed by the author and his coworkers in recent years. It is hoped that
those more qualified than the author in the subject matter area can extend and modify the analysis to make it closer to geological
reality.
supported by NSF grant GJ-3100X. 相似文献
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Finite element limit analysis with plane strain condition is employed to determine the upper and lower bound solutions of the undrained limiting pressure behind soil gaps and the lateral force acting on a pile per unit length in a contiguous pile wall. Computed bound solutions confirm serious limitations of existing studies in predicting these two solutions. Predicted failure mechanisms and the arching effect behind soil gaps are discussed. A closed-form equation of the limiting pressure factor is proposed for a convenient and accurate prediction of the lateral force acting on a pile in contiguous pile walls in practice. 相似文献
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Paul F. Czeglédy 《Mathematical Geology》1972,4(4):291-305
On the basis of samples taken from a known topographic surface, the parameters of two types of linear models are estimated. The first category is defined by polynomials or trigonometric functions, whose parameters are simultaneously computed from available data. In the second category a set of local centers is defined, and in the neighborhood of each center a fixed-degree polynomial is developed. An approximative resemblance index is calculated, and contour maps corresponding to various models are compared with the topographic map. It is found that with an increasing number of grid points, maps of local polynomials are converging both in continuity and in resemblance. For a sufficient number of grid points, this resemblance is always higher than those produced by models of the first category. 相似文献
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正Shrimps of genus Artemia are the inhabitants of continental and marine waters with salinity of 70 to 350 g/l and above.Artemia is able to survive in the conditions in which other animals cannot exist.This is due to adaptations:effective osmoregulation system,the ability to synthesize of respiratory pigment(hemoglobin)and diapauses cysts(Litvinenko at.al.,2009).Cysts of this 相似文献